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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2010

Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) – Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling

Sergey V. Krivovichev

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Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) – Structural Diversity, Nanoscale Chemistry, and Cellular Automata ModelingOriginalChemInform Abstract: Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) — Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling1Syntheses and single-crystal structures of CsTh(MoO4)2Cl and Na4Th(WO4)410Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands45Nanoscale Chemistry of Uranyl Selenates1Design and parameterization of a stochastic cellular automaton describing a chemical reaction14Cation–Cation Interactions: Crystal Structures of Neptunyl(V) Selenate Hydrates, (NpO2)2(SeO4)(H2O)n (n = 1, 2, and 4)36Layered and Three-Dimensional Framework Cesium and Barium Uranyl Carboxyphenylphosphonates69Two New Neptunyl(V) Selenites: A Novel Cation–Cation Interaction Framework in (NpO2)3(OH)(SeO3)(H2O)2·H2O and a Uranophane-Type Sheet in Na(NpO2)(SeO3)(H2O)29Synthesis and structural study of new potassium uranyl selenates K2(H5O2)(H3O)[(UO2)2(SeO4)4(H2O)2](H2O)4 and K3(H3O)[(UO2)2(SeO4)4(H2O)2](H2O)57Synthesis and characterization of uranyl chromate sheet compounds containing edge-sharing dimers of uranyl pentagonal bipyramids19Unprecedented Bidentate Coordination of the Uranyl Cation by the Chromate Anion in the Structure of [(CH3)2CHNH3]2[UO2(CrO4)2]21Mixed-ligand coordination of the (UO2)2+ cation and apophyllite topology of uranyl chlorochromate layer in the structure of ((CH3)2CHNH3)[(UO2)(CrO4)Cl(H2O)]18Algorithmic crystal chemistry: A cellular automata approach13Polytypism and oxo-tungstate polyhedra polymerization in novel complex uranyl tungstates13Syntheses and crystal structures of two novel alkaline uranyl chromates A2(UO2)(CrO4)2 (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions20Synthesis and structural studies of a new potassium uranyl selenate K(H5O2)[(UO2)2(SeO4)3(H2O)] with strongly deformed layers8Synthesis, characterization, and crystal structures of uranyl compounds containing mixed chromium oxidation states7Isopropylammonium Layered Uranyl Chromates: Syntheses and Crystal Structures of [(CH3)2CHNH3]3[(UO2)3(CrO4)2O(OH)3] and[(CH3)2CHNH3]2[(UO2)2(CrO4)3(H2O)]30Structural topology and dimensional reduction in uranyl oxysalts: eight novel phases in the methylamine–(UO2)(NO3)2–H2SeO4–H2O system24THE CRYSTAL STRUCTURE OF SVYATOSLAVITE AND EVOLUTION OF COMPLEXITY DURING CRYSTALLIZATION OF A CaAl2Si2O8 MELT: A STRUCTURAL AUTOMATA DESCRIPTION34Influence of the Organic Species and Oxoanion in the Synthesis of two Uranyl Sulfate Hydrates, (H3O)2[(UO2)2(SO4)3(H2O)]·7H2O and (H3O)2[(UO2)2(SO4)3(H2O)]·4H2O, and a Uranyl Selenate‐Selenite [C5H6N][(UO2)(SeO4)(HSeO3)]15Nanoscale Hemispheres in Novel Mixed-Valent Uranyl Chromate(V,VI), (C3NH10)10[(UO2)13(Cr125+O42)(Cr6+O4)6(H2O)6](H2O)618A calorimetric and thermodynamic investigation of potassium uranyl tungstate K2[(UO2)(W2O8)]7New Reactivity of the Uranyl(VI) Ion116Crystal structure and formula revision of deliensite, Fe[(UO2)2(SO4)2(OH)2](H2O)717Cellular automata as models of inorganic structures self-assembly (Illustrated by uranyl selenate)4Crystal Chemistry of Uranium Oxides and Minerals27Actinide Colloids and Particles of Environmental Concern179Structural complexity of minerals: information storage and processing in the mineral world281CrVI→CrV Transition in Uranyl Chromium Compounds: Synthesis and High‐temperature X‐ray Diffraction Study of Cs2[(UO2)2(CrO4)3]24Cation–cation interactions and cation exchange in a series of isostructural framework uranyl tungstates17A Highly Adjustable Coordination System: Nanotubular and Molecular Cage Species in Uranyl Ion Complexes with Kemp’s Triacid46Mathesiusite, K5(UO2)4(SO4)4(VO5)(H2O)4, a new uranyl vanadate-sulfate from Jachymov, Czech Republic27On the algorithmic complexity of crystals15Increasing Complexity in the Uranyl Ion–Kemp’s Triacid System: From One- and Two-Dimensional Polymers to Uranyl–Copper(II) Dodeca- and Hexadecanuclear Species47Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Geschieberite, K2(UO2)(SO4)2(H2O)2, a new uranyl sulfate mineral from Jáchymov19Topologically and geometrically flexible structural units in seven new organically templated uranyl selenates and selenite–selenates22Hydrothermal syntheses and characterization of uranyl tungstates with electro-neutral structural units0Bobcookite, NaAl(UO2)2(SO4)4·18H2O and wetherillite, Na2Mg(UO2)2(SO4)4·18H2O, two new uranyl sulfate minerals from the Blue Lizard mine, San Juan County, Utah, USA26Fermiite, Na4(UO2)(SO4)3·3H2O and oppenheimerite, Na2(UO2)(SO4)2·3H2O, two new uranyl sulfate minerals from the Blue Lizard mine, San Juan County, Utah, USA24Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method19Structure description, interpretation and classification in mineralogical crystallography50Structure description, interpretation and classification in structural mineralogy5Variations on the Honeycomb Topology: From Triangular- and Square-Grooved Networks to Tubular Assemblies in Uranyl Tricarballylate Complexes34Klaprothite, péligotite and ottohahnite, three new minerals with bidentate UO7–SO4linkages from the Blue Lizard mine, San Juan County, Utah, USA21The (3+3) commensurately modulated structure of the uranyl silicate mineral swamboite-(Nd), Nd0.333[(UO2)(SiO3OH)](H2O)2.417A novel sheet topology in the structure of kamitugaite, PbAl[(UO2)5(PO4)2.38(AsO4)0.62O2(OH)2](H2O)11.53Uranyl Sulfate Nanotubules Templated by N-phenylglycine16Kurchatovite and Clinokurchatovite, Ideally CaMgB2O5: An Example of Modular Polymorphism7Horákite, a new hydrated bismuth uranyl-arsenate-phosphate mineral from Jáchymov (Czech Republic) with a unique uranyl-anion topology8Synchrotron Diffraction Study of the Crystal Structure of Ca(UO2)6(SO4)2O2(OH)6·12H2O, a Natural Phase Related to Uranopilite1Structural complexity of natural uranyl sulfates51Chemically induced symmetry breaking in the crystal structure of guanidinium uranyl sulfate10An experimental calorimetric and a DFT + U study of the thermodynamic properties of Cs 4 UO 2 4 WO 5 W 2 O 8 O 2 and Cs 4 [ UO 2 7 WO 5 3 O 3 ]4Topological analysis of the layered uranyl compounds bearing slabs with UO2:TO4ratio of 2:35A combined experimental and theoretical study on an ionic cobalt(III/II) complex with a Schiff base ligand11Theoretical Insight into Coordination Chemistry of Am(VI) and Am(V) with Phenanthroline Ligand: Implications for High Oxidation State Based Minor Actinide Separation27Cellular Automata in Chemistry and Chemical Engineering25Secondary Role of Aliphatic and Heterocyclic Amines in the Formation of Low-Temperature Amine-Bearing U, Np, and Pu(VI) Chromates2DISTRIBUTION OF MINERALS IN NATURE IN THE CONTEXT OF EVOLUTIONARY VIEWS IN MODERN MINERALOGY0Periodic Trends in the Stabilization of Actinyls in Their Higher Oxidation States Using Pyrrophen Ligands16Which nets are the most common? Reticular chemistry and information entropy12Results of 25-Year Studies of Uranium Compounds at the Department of Crystallography of St. Petersburg State University3Extending the mineralogy of U 6+ (IV): Uranyl phosphate sheet of novel topology in the crystal structure of ranunculite0The Crystal Chemistry and Topology of Modular Structures. III. 2D and 3D Zeolites Containing Tetrahedral Layers with the Apophyllite-Type Topology2The crystal chemistry and topology of modular structures. II. Heteropolyhedral substitutions and “blocky isomorphism” in inorganic compounds0

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  1. ChemInform Abstract: Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) — Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling

    ChemInform · 2010-07-29

    Sergey V. Krivovichev

    Read original paper ↗ ·

  2. Syntheses and single-crystal structures of CsTh(MoO4)2Cl and Na4Th(WO4)4

    Journal of Solid State Chemistry · 2010-12-06

    Geng Bang Jin, L. Soderholm

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  3. Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands

    Crystal Growth & Design · 2010-12-09

    P. Thuéry

    Read original paper ↗ ·

  4. Nanoscale Chemistry of Uranyl Selenates

    Springer eBooks · 2011-01-01

    Sergey V. Krivovichev, Vladislav V. Gurzhiy, Ivan Gundarovich Tananaev, Boris F. Myasoedov

    Read original paper ↗ ·

  5. Design and parameterization of a stochastic cellular automaton describing a chemical reaction

    Journal of Computational Chemistry · 2011-03-31

    Pieter Van der Weeën, Jan Marcel Baetens, Bernard De Baets C

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  6. Cation–Cation Interactions: Crystal Structures of Neptunyl(V) Selenate Hydrates, (NpO2)2(SeO4)(H2O)n (n = 1, 2, and 4)

    Inorganic Chemistry · 2011-04-26

    Geng Bang Jin, S. Skanthakumar, L. Soderholm

    Read original paper ↗ ·

  7. Layered and Three-Dimensional Framework Cesium and Barium Uranyl Carboxyphenylphosphonates

    Crystal Growth & Design · 2011-05-18

    Pius O. Adelani, Allen G. Oliver, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  8. Two New Neptunyl(V) Selenites: A Novel Cation–Cation Interaction Framework in (NpO2)3(OH)(SeO3)(H2O)2·H2O and a Uranophane-Type Sheet in Na(NpO2)(SeO3)(H2O)

    Inorganic Chemistry · 2011-06-07

    Geng Bang Jin, S. Skanthakumar, L. Soderholm

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  9. Synthesis and structural study of new potassium uranyl selenates K2(H5O2)(H3O)[(UO2)2(SeO4)4(H2O)2](H2O)4 and K3(H3O)[(UO2)2(SeO4)4(H2O)2](H2O)5

    Radiochemistry · 2011-12-01

    Vladislav V. Gurzhiy, Olga S. Tyumentseva, Sergey V. Krivovichev, Ivan Gundarovich Tananaev, Boris F. Myasoedov

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  10. Synthesis and characterization of uranyl chromate sheet compounds containing edge-sharing dimers of uranyl pentagonal bipyramids

    Journal of Solid State Chemistry · 2011-12-06

    Daniel K. Unruh, Michelle Baranay, Laura Pressprich, Megan Stoffer, Peter Carman Burns

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  11. Unprecedented Bidentate Coordination of the Uranyl Cation by the Chromate Anion in the Structure of [(CH3)2CHNH3]2[UO2(CrO4)2]

    European Journal of Inorganic Chemistry · 2011-12-08

    Oleg I. Siidra, Еvgeny V. Nazarchuk, Sergey V. Krivovichev

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  12. Mixed-ligand coordination of the (UO2)2+ cation and apophyllite topology of uranyl chlorochromate layer in the structure of ((CH3)2CHNH3)[(UO2)(CrO4)Cl(H2O)]

    Zeitschrift für Kristallographie - Crystalline Materials · 2011-12-21

    Oleg I. Siidra, Еvgeny V. Nazarchuk, Sergey V. Krivovichev

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  13. Algorithmic crystal chemistry: A cellular automata approach

    Crystallography Reports · 2012-01-01

    Sergey V. Krivovichev

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  14. Polytypism and oxo-tungstate polyhedra polymerization in novel complex uranyl tungstates

    Dalton Transactions · 2012-01-01

    Andrey Seliverstov, Evgeny V. Suleimanov, Evgeny V. Chuprunov, Н. В. Сомов, Elena M. Zhuchkova, Maxim I. Lelet, Konstantin Rozov, Wulf Depmeier, Sergey V. Krivovichev, Evgeny V. Alekseev

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  15. Syntheses and crystal structures of two novel alkaline uranyl chromates A2(UO2)(CrO4)2 (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions

    Journal of Solid State Chemistry · 2012-01-30

    Oleg I. Siidra, Еvgeny V. Nazarchuk, Sergey V. Krivovichev

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  16. Synthesis and structural studies of a new potassium uranyl selenate K(H5O2)[(UO2)2(SeO4)3(H2O)] with strongly deformed layers

    Radiochemistry · 2012-02-01

    Vladislav V. Gurzhiy, Olga S. Tyumentseva, Sergey V. Krivovichev, Ivan Gundarovich Tananaev, Boris F. Myasoedov

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  17. Synthesis, characterization, and crystal structures of uranyl compounds containing mixed chromium oxidation states

    Journal of Solid State Chemistry · 2012-03-16

    Daniel K. Unruh, Andrew N. Quicksall, Laura Pressprich, Megan Stoffer, Jie Qiu, Kirill B. Nuzhdin, Weiqiang Wu, Mariya Vyushkova, Peter Carman Burns

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  18. Isopropylammonium Layered Uranyl Chromates: Syntheses and Crystal Structures of [(CH3)2CHNH3]3[(UO2)3(CrO4)2O(OH)3] and[(CH3)2CHNH3]2[(UO2)2(CrO4)3(H2O)]

    Zeitschrift für anorganische und allgemeine Chemie · 2012-03-29

    Oleg I. Siidra, Еvgeny V. Nazarchuk, Sergey V. Krivovichev

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  19. Structural topology and dimensional reduction in uranyl oxysalts: eight novel phases in the methylamine–(UO2)(NO3)2–H2SeO4–H2O system

    Structural Chemistry · 2012-05-05

    Vadim M. Kovrugin, Vladislav V. Gurzhiy, Sergey V. Krivovichev

    Read original paper ↗ ·

  20. THE CRYSTAL STRUCTURE OF SVYATOSLAVITE AND EVOLUTION OF COMPLEXITY DURING CRYSTALLIZATION OF A CaAl2Si2O8 MELT: A STRUCTURAL AUTOMATA DESCRIPTION

    The Canadian Mineralogist · 2012-06-01

    Sergey V. Krivovichev, Е. П. Щербакова, T. P. Nishanbaev

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  21. Influence of the Organic Species and Oxoanion in the Synthesis of two Uranyl Sulfate Hydrates, (H3O)2[(UO2)2(SO4)3(H2O)]·7H2O and (H3O)2[(UO2)2(SO4)3(H2O)]·4H2O, and a Uranyl Selenate‐Selenite [C5H6N][(UO2)(SeO4)(HSeO3)]

    Zeitschrift für anorganische und allgemeine Chemie · 2012-08-08

    Laurent J. Jouffret, Ernest M. Wylie, Peter Carman Burns

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  22. Nanoscale Hemispheres in Novel Mixed-Valent Uranyl Chromate(V,VI), (C3NH10)10[(UO2)13(Cr125+O42)(Cr6+O4)6(H2O)6](H2O)6

    Inorganic Chemistry · 2012-08-20

    Oleg I. Siidra, Еvgeny V. Nazarchuk, Anatoly A. Petrunin, Roman A. Kayukov, Sergey V. Krivovichev

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  23. A calorimetric and thermodynamic investigation of potassium uranyl tungstate K2[(UO2)(W2O8)]

    The Journal of Chemical Thermodynamics · 2012-10-08

    Maxim I. Lelet, Olga V. Ogurtsova, Evgeny V. Suleimanov, Charles A. Geiger, Wulf Depmeier, Evgeny V. Alekseev

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  24. New Reactivity of the Uranyl(VI) Ion

    Chemistry - A European Journal · 2012-11-14

    Robert J. Baker

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  25. Crystal structure and formula revision of deliensite, Fe[(UO2)2(SO4)2(OH)2](H2O)7

    Mineralogical Magazine · 2012-12-01

    Jakub Plášil, Juerg Hauser, Václav Petříček, Nicolas Meisser, Stuart J. Mills, Radek Škoda, K. Fejfarová, Jiří Čejka, Jiří Sejkora, Jan Hloušek, J.-M. Johannet, Vladimı́r Machovič, Ladislav Lapčák

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  26. Cellular automata as models of inorganic structures self-assembly (Illustrated by uranyl selenate)

    Glass Physics and Chemistry · 2013-01-01

    V. Ya. Shevchenko, Sergey V. Krivovichev, Ivan Gundarovich Tananaev, Boris F. Myasoedov

    Read original paper ↗ ·

  27. Crystal Chemistry of Uranium Oxides and Minerals

    Elsevier eBooks · 2013-01-01

    Sergey V. Krivovichev

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  28. Actinide Colloids and Particles of Environmental Concern

    Chemical Reviews · 2013-01-15

    Clemens Walther, Melissa A. Denecke

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  29. Structural complexity of minerals: information storage and processing in the mineral world

    Mineralogical Magazine · 2013-04-01

    Sergey V. Krivovichev

    Read original paper ↗ ·

  30. CrVI→CrV Transition in Uranyl Chromium Compounds: Synthesis and High‐temperature X‐ray Diffraction Study of Cs2[(UO2)2(CrO4)3]

    Zeitschrift für anorganische und allgemeine Chemie · 2013-07-04

    Oleg I. Siidra, Еvgeny V. Nazarchuk, Roman A. Kayukov, Р. С. Бубнова, Sergey V. Krivovichev

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  31. Cation–cation interactions and cation exchange in a series of isostructural framework uranyl tungstates

    Journal of Solid State Chemistry · 2014-02-10

    Enrica Balboni, Peter Carman Burns

    Read original paper ↗ ·

  32. A Highly Adjustable Coordination System: Nanotubular and Molecular Cage Species in Uranyl Ion Complexes with Kemp’s Triacid

    Crystal Growth & Design · 2014-02-11

    P. Thuéry

    Read original paper ↗ ·

  33. Mathesiusite, K5(UO2)4(SO4)4(VO5)(H2O)4, a new uranyl vanadate-sulfate from Jachymov, Czech Republic

    American Mineralogist · 2014-04-01

    J. Pla il, František Veselovský, J. Hlou ek, Radek Škoda, Mihaly Novak, J. Sejkora, J. ejka, P. kacha, Anatoly V. Kasatkin

    Read original paper ↗ ·

  34. On the algorithmic complexity of crystals

    Mineralogical Magazine · 2014-04-01

    Sergey V. Krivovichev

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  35. Increasing Complexity in the Uranyl Ion–Kemp’s Triacid System: From One- and Two-Dimensional Polymers to Uranyl–Copper(II) Dodeca- and Hexadecanuclear Species

    Crystal Growth & Design · 2014-04-14

    P. Thuéry

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  36. Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies

    Crystal Growth & Design · 2014-07-01

    P. Thuéry, Jack McB. Harrowfield

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  37. Hybrid Materials of the f-Elements Part I

    Elsevier eBooks · 2015-01-01

    Korey Prescott Carter, Christopher L. Cahill

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  38. Hybrid Materials of the f-Elements Part II

    Elsevier eBooks · 2015-01-01

    Robert G. Surbella, Christopher L. Cahill

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  39. Geschieberite, K2(UO2)(SO4)2(H2O)2, a new uranyl sulfate mineral from Jáchymov

    Mineralogical Magazine · 2015-02-01

    Jakub Plášil, Jan Hloušek, Anatoly V. Kasatkin, Radek Škoda, Mihaly Novak, J. Čejka

    Read original paper ↗ ·

  40. Topologically and geometrically flexible structural units in seven new organically templated uranyl selenates and selenite–selenates

    Journal of Solid State Chemistry · 2015-05-08

    Vladislav V. Gurzhiy, Vadim M. Kovrugin, Olga S. Tyumentseva, Pavel A. Mikhaylenko, Sergey V. Krivovichev, Ivan Gundarovich Tananaev

    Read original paper ↗ ·

  41. Hydrothermal syntheses and characterization of uranyl tungstates with electro-neutral structural units

    Zeitschrift für Kristallographie - Crystalline Materials · 2015-05-23

    Enrica Balboni, Peter Carman Burns

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  42. Bobcookite, NaAl(UO2)2(SO4)4·18H2O and wetherillite, Na2Mg(UO2)2(SO4)4·18H2O, two new uranyl sulfate minerals from the Blue Lizard mine, San Juan County, Utah, USA

    Mineralogical Magazine · 2015-06-01

    Anthony R. Kampf, Jakub Plášil, Anatoly V. Kasatkin, Joe Marty

    Read original paper ↗ ·

  43. Fermiite, Na4(UO2)(SO4)3·3H2O and oppenheimerite, Na2(UO2)(SO4)2·3H2O, two new uranyl sulfate minerals from the Blue Lizard mine, San Juan County, Utah, USA

    Mineralogical Magazine · 2015-10-01

    Anthony R. Kampf, Jakub Plášil, Anatoly V. Kasatkin, Joe Marty, Jiří Čejka

    Read original paper ↗ ·

  44. Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method

    Journal of Crystal Growth · 2016-01-15

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Vladislav V. Gurzhiy, Sergey V. Krivovichev, Olivier Mentré

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  45. Structure description, interpretation and classification in mineralogical crystallography

    Crystallography Reviews · 2016-08-25

    Sergey V. Krivovichev

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  46. Structure description, interpretation and classification in structural mineralogy

    Mineralogical Society of Great Britain and Ireland eBooks · 2017-01-01

    Sergey V. Krivovichev

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  47. Variations on the Honeycomb Topology: From Triangular- and Square-Grooved Networks to Tubular Assemblies in Uranyl Tricarballylate Complexes

    Crystal Growth & Design · 2017-02-16

    P. Thuéry, Jack McB. Harrowfield

    Read original paper ↗ ·

  48. Klaprothite, péligotite and ottohahnite, three new minerals with bidentate UO7–SO4linkages from the Blue Lizard mine, San Juan County, Utah, USA

    Mineralogical Magazine · 2017-06-23

    Anthony R. Kampf, Jakub Plášil, Anatoly V. Kasatkin, Joe Marty, Jiří Čejka

    Read original paper ↗ ·

  49. The (3+3) commensurately modulated structure of the uranyl silicate mineral swamboite-(Nd), Nd0.333[(UO2)(SiO3OH)](H2O)2.41

    Zeitschrift für Kristallographie - Crystalline Materials · 2017-12-21

    Jakub Plášil, Václav Petříček, Andrew J. Locock, Radek Škoda, Peter Carman Burns

    Read original paper ↗ ·

  50. A novel sheet topology in the structure of kamitugaite, PbAl[(UO2)5(PO4)2.38(AsO4)0.62O2(OH)2](H2O)11.5

    Journal of Geosciences · 2018-01-23

    Jakub Plášil

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