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RESEARCH PAPER · Inorganic Chemistry · 2013

From Order to Disorder and Back Again: In Situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates

Eric M. Villa, Connor J. Marr, Juan Diwu, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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From Order to Disorder and Back Again: In Situ Hydrothermal Redox Reactions of Uranium Phosphites and PhosphatesOriginalStructural changes within the alkaline earth uranyl phosphites9Synthesis, characterization and selective de-esterification of diorganotinbis(O-methylphosphite)s5Syntheses, Structures, and Comparisons of Thallium Uranium Phosphites, Mixed Phosphate-Phosphites, and Phosphate22ChemInform Abstract: From Order to Disorder and Back Again: In situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates.0One-pot synthesis of Mn-containing 2D framework based on 5-nitro-1,2,3-benzenetricarboxylic and 2-hydroxy-5-nitroisophthalic ligands: Synthesis, structure and magnetic properties1Crystal growth, structural characterization, cation–cation interaction classification, and optical properties of uranium( vi ) containing oxychlorides, A 4 U 5 O 16 Cl 2 (A = K, Rb), Cs 5 U 7 O 22 Cl 3 , and AUO 3 Cl (A = Rb, Cs)27Effects of ionic liquid media on the cation selectivity of uranyl structural units in five new compounds produced using the ionothermal technique16Topologically identical, but geometrically isomeric layers in hydrous α-, β-Rb[UO2(AsO3OH)(AsO2(OH)2)]·H2O and anhydrous Rb[UO2(AsO3OH)(AsO2(OH)2)]6Straightforward Reductive Routes to Air-Stable Uranium(III) and Neptunium(III) Materials15Th(AsIII4AsV4O18): a Mixed-Valent Oxoarsenic(III)/arsenic(V) Actinide Compound Obtained under Extreme Conditions17Morphotropy and Temperature-Driven Polymorphism in A2Th(AsO4)2 (A = Li, Na, K, Rb, Cs) Series19Influence of extreme conditions on the formation and structures of caesium uranium( vi ) arsenates10A Cubic Non-Centrosymmetric Mixed-Valence Iron Borophosphate–Phosphite6Hydrolytically Stable Nanoporous Thorium Mixed Phosphite and Pyrophosphate Framework Generated from Redox-Active Ionothermal Reactions20Synthesis and crystal structure of cerium(IV) bis(phosphite)0An Ultrastable Heterobimetallic Uranium(IV)/Vanadium(III) Solid Compound Protected by a Redox-Active Phosphite Ligand: Crystal Structure, Oxidative Dissolution, and First-Principles Simulation11A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions26A Family of Layered Phosphates Crystallizing in a Rare Geometrical Isomer of the Phosphuranylite Topology: Synthesis, Characterization, and Computational Modeling of A4[(UO2)3O2(PO4)2] (A = Alkali Metal) Exhibiting Intralayer Ion Exchange21pH Driven Hydrothermal Syntheses of Neodymium Sulfites and Mixed Sulfate-Sulfites7New Uranyl Open Framework and Sheet Compounds Formed via In-Situ Protonation of Piperazine by Phosphorous Acid1Crystal Growth and Structure Characterization of Three Layered Uranyl Phosphates and Their Relation to the Phosphuranylite Family13Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties19Structural and Spectroscopic Investigation of Novel 2D and 3D Uranium Oxo-Silicates/Germanates and Some Statistical Aspects of Uranyl Coordination in Oxo-Salts14Redox mechanism and stability of uranyl phosphites at mineral surfaces: Cooperative proton/electron transfer and high efficacy for Uranium(VI) reduction12Structural Variations in Complex Sodium Thorium Arsenates9Studies on the Genesis and Proton Conductivity of Imidazole-Based Linear and Open-Framework Zinc Phosphites11Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant0

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27 direct citing papers saved.

  1. Structural changes within the alkaline earth uranyl phosphites

    Dalton Transactions · 2013-01-01

    Eric M. Villa, Juan Diwu, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  2. Synthesis, characterization and selective de-esterification of diorganotinbis(O-methylphosphite)s

    Dalton Transactions · 2013-01-01

    Ravi Shankar, Meenal Asija, Nisha Singla, Suddhasatwa Basu, Gabriele I. Kociok-Köhn, Kieran C. Molloy

    Read original paper ↗ ·

  3. Syntheses, Structures, and Comparisons of Thallium Uranium Phosphites, Mixed Phosphate-Phosphites, and Phosphate

    Crystal Growth & Design · 2013-03-08

    Eric M. Villa, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  4. ChemInform Abstract: From Order to Disorder and Back Again: In situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates.

    ChemInform · 2013-03-25

    Eric M. Villa, Connor J. Marr, Juan Diwu, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  5. One-pot synthesis of Mn-containing 2D framework based on 5-nitro-1,2,3-benzenetricarboxylic and 2-hydroxy-5-nitroisophthalic ligands: Synthesis, structure and magnetic properties

    Inorganic Chemistry Communications · 2013-07-04

    Yu-Ting Yang, Chang‐Zheng Tu, Feixiang Cheng, Fan Wang

    Read original paper ↗ ·

  6. Crystal growth, structural characterization, cation–cation interaction classification, and optical properties of uranium( vi ) containing oxychlorides, A 4 U 5 O 16 Cl 2 (A = K, Rb), Cs 5 U 7 O 22 Cl 3 , and AUO 3 Cl (A = Rb, Cs)

    CrystEngComm · 2014-01-01

    Cory Michael Read, Jeongho Yeon, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  7. Effects of ionic liquid media on the cation selectivity of uranyl structural units in five new compounds produced using the ionothermal technique

    CrystEngComm · 2014-01-01

    Ernest M. Wylie, P. A. Smith, Kathryn Peruski, J. S. Smith, Megan K. Dustin, Peter Carman Burns

    Read original paper ↗ ·

  8. Topologically identical, but geometrically isomeric layers in hydrous α-, β-Rb[UO2(AsO3OH)(AsO2(OH)2)]·H2O and anhydrous Rb[UO2(AsO3OH)(AsO2(OH)2)]

    Journal of Solid State Chemistry · 2014-03-22

    Na Yu, Vladislav V. Klepov, Eric M. Villa, Dirk Bosbach, Evgeny V. Suleimanov, Wulf Depmeier, Thomas E. Albrecht‐Schmitt, Evgeny V. Alekseev

    Read original paper ↗ ·

  9. Straightforward Reductive Routes to Air-Stable Uranium(III) and Neptunium(III) Materials

    Inorganic Chemistry · 2014-06-25

    Justin N. Cross, Eric M. Villa, Victoria R. Darling, Matthew J. Polinski, Jian Hung Lin, Xiaoyan Tan, Naoki Kikugawa, Michael Shatruk, Ryan Baumbach, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  10. Th(AsIII4AsV4O18): a Mixed-Valent Oxoarsenic(III)/arsenic(V) Actinide Compound Obtained under Extreme Conditions

    Inorganic Chemistry · 2014-07-30

    Na Yu, Vladislav V. Klepov, Philip Kegler, Dirk Bosbach, Thomas E. Albrecht‐Schmitt, Evgeny V. Alekseev

    Read original paper ↗ ·

  11. Morphotropy and Temperature-Driven Polymorphism in A2Th(AsO4)2 (A = Li, Na, K, Rb, Cs) Series

    Inorganic Chemistry · 2014-10-02

    Na Yu, Vladislav V. Klepov, Giuseppe Modolo, Dirk Bosbach, Evgeny V. Suleimanov, Thorsten M. Gesing, Lars Robben, Evgeny V. Alekseev

    Read original paper ↗ ·

  12. Influence of extreme conditions on the formation and structures of caesium uranium( vi ) arsenates

    Dalton Transactions · 2015-01-01

    Na Yu, Philip Kegler, Vladislav V. Klepov, Jakob Dellen, Hartmut Schlenz, Eike M. Langer, Dirk Bosbach, Evgeny V. Alekseev

    Read original paper ↗ ·

  13. A Cubic Non-Centrosymmetric Mixed-Valence Iron Borophosphate–Phosphite

    Crystal Growth & Design · 2016-01-25

    Hooman Yaghoobnejad Asl, Ronetta Morris, T. Thao Tran, P. Shiv Halasyamani, K. Ghosh, Amitava Choudhury

    Read original paper ↗ ·

  14. Hydrolytically Stable Nanoporous Thorium Mixed Phosphite and Pyrophosphate Framework Generated from Redox-Active Ionothermal Reactions

    Inorganic Chemistry · 2016-03-25

    Daxiang Gui, Tao Zheng, Lanhua Chen, Yanlong Wang, Yuxiang Li, Daopeng Sheng, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

    Read original paper ↗ ·

  15. Synthesis and crystal structure of cerium(IV) bis(phosphite)

    Acta Crystallographica Section E Crystallographic Communications · 2017-08-04

    Stefano H. Byer, Eric M. Villa

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  16. An Ultrastable Heterobimetallic Uranium(IV)/Vanadium(III) Solid Compound Protected by a Redox-Active Phosphite Ligand: Crystal Structure, Oxidative Dissolution, and First-Principles Simulation

    Inorganic Chemistry · 2018-01-10

    Daxiang Gui, Xing Dai, Tao Zheng, Xiangxiang Wang, Mark A. Silver, Lanhua Chen, Chao Zhang, Juan Diwu, Ruhong Zhou, Zhifang Chai, Shuao Wang

    Read original paper ↗ ·

  17. A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions

    Inorganic Chemistry · 2018-01-18

    Meiying Qie, Jian Hung Lin, Fang Kong, Mark A. Silver, Zenghui Yue, Xiaomei Wang, Linjuan Zhang, Hongliang Bao, Thomas E. Albrecht‐Schmitt, Jian‐Qiang Wang

    Read original paper ↗ ·

  18. A Family of Layered Phosphates Crystallizing in a Rare Geometrical Isomer of the Phosphuranylite Topology: Synthesis, Characterization, and Computational Modeling of A4[(UO2)3O2(PO4)2] (A = Alkali Metal) Exhibiting Intralayer Ion Exchange

    Inorganic Chemistry · 2018-04-02

    Christian A. Juillerat, Emily E. Moore, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  19. pH Driven Hydrothermal Syntheses of Neodymium Sulfites and Mixed Sulfate-Sulfites

    Crystal Growth & Design · 2018-08-03

    Jakob T. Dovgan, Matthew J. Polinski, Brandon Q. Mercado, Eric M. Villa

    Read original paper ↗ ·

  20. New Uranyl Open Framework and Sheet Compounds Formed via In-Situ Protonation of Piperazine by Phosphorous Acid

    Minerals · 2018-11-01

    Eric M. Villa, Justin N. Cross, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  21. Crystal Growth and Structure Characterization of Three Layered Uranyl Phosphates and Their Relation to the Phosphuranylite Family

    Crystal Growth & Design · 2018-12-18

    Christian A. Juillerat, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  22. Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties

    Dalton Transactions · 2019-01-01

    Jian Hung Lin, Qi Liu, Zenghui Yue, Kariem Diefenbach, Liwei Cheng, Yue‐Jian Lin, Jian‐Qiang Wang

    Read original paper ↗ ·

  23. Structural and Spectroscopic Investigation of Novel 2D and 3D Uranium Oxo-Silicates/Germanates and Some Statistical Aspects of Uranyl Coordination in Oxo-Salts

    Inorganic Chemistry · 2019-07-16

    Haijian Li, Eike M. Langer, Philip Kegler, Evgeny V. Alekseev

    Read original paper ↗ ·

  24. Redox mechanism and stability of uranyl phosphites at mineral surfaces: Cooperative proton/electron transfer and high efficacy for Uranium(VI) reduction

    Chemosphere · 2020-04-30

    Qian Wang, Tingting Li, Xiaoxiao Huang, Gang Yang

    Read original paper ↗ ·

  25. Structural Variations in Complex Sodium Thorium Arsenates

    European Journal of Inorganic Chemistry · 2020-07-28

    Yucheng Hao, Evgeny V. Alekseev, Vladislav V. Klepov, Na Yu

    Read original paper ↗ ·

  26. Studies on the Genesis and Proton Conductivity of Imidazole-Based Linear and Open-Framework Zinc Phosphites

    Inorganic Chemistry · 2021-04-16

    Ravi Shankar, Ekta Jakhar, Archishmati Dubey, Priyanka Chauhan, Pankaj Tiwari, Suddhasatwa Basu

    Read original paper ↗ ·

  27. Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant

    Polyhedron · 2021-04-18

    Colin N. Reedy, Eric M. Villa

    Read original paper ↗ ·
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