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RESEARCH PAPER · Journal of the American Chemical Society · 2013

From Yellow to Black: Dramatic Changes between Cerium(IV) and Plutonium(IV) Molybdates

Justin N. Cross, Patrick M. Duncan, Eric M. Villa, Matthew J. Polinski, Jean‐Marie Babo, Evgeny V. Alekseev, Corwin H. Booth, Thomas E. Albrecht‐Schmitt

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From Yellow to Black: Dramatic Changes between Cerium(IV) and Plutonium(IV) MolybdatesOriginalCrystal Growth and First Crystallographic Characterization of Mixed Uranium(IV)–Plutonium(III) Oxalates51Actinide oxalates, solid state structures and applications160The crystal chemistry of uranium carboxylates394Challenges in the Search for Magnetic Coupling in 3d/4f Materials: Syntheses, Structures, and Magnetic Properties of the Lanthanide Copper Heterobimetallic Compounds, RE2Cu(TeO3)2(SO4)229High-Temperature Phase Transitions, Spectroscopic Properties, and Dimensionality Reduction in Rubidium Thorium Molybdate Family23Synthesis and Spectroscopy of New Plutonium(III) and -(IV) Molybdates: Comparisons of Electronic Characteristics12Exploring Actinide Materials Through Synchrotron Radiation Techniques104Coordination chemistry of 2,2′-biphenylenedithiophosphinate and diphenyldithiophosphinate with U, Np, and Pu40Multifunctional luminescent nanomaterials from NaLa(MoO4)2:Eu3+/Tb3+ with tunable decay lifetimes, emission colors and enhanced cell viability47The structural effects of alkaline- and rare-earth element incorporation into thorium molybdates8Giant Volume Change and Topological Gaps in Temperature‐ and Pressure‐Induced Phase Transitions: Experimental and Computational Study of ThMo2O811Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates22Controllable synthesis and photocatalytic properties of spherical and flower-like Ce2(MoO4)3 hierarchical architectures14A Macrocyclic Chelator That Selectively Binds Ln4+ over Ln3+ by a Factor of 102935Synthesis and structure of dodecamolybdates of tetravalent cerium, thorium, uranium, neptunium, and plutonium11Synthetic Access to Cubic Rare Earth Molybdenum Oxides RE6MoO12−δ(RE = Tm–Lu) Representing a New Class of Ion Conductors20Characterization of Lanthanide Complexes with Bis-1,2,3-triazole-bipyridine Ligands Involved in Actinide/Lanthanide Separation36Electronic Structure and Properties of Berkelium Iodates38Précipitation des molybdates mixtes zirconium-cérium/plutonium en milieu aqueux HNO30Uncovering the Origin of Divergence in the CsM(CrO4)2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis20Exploring Actinide Materials through Synchrotron Radiation Techniques4Immobilization of Alkali Metal Fluorides via Recrystallization in a Cationic Lamellar Material, [Th(MoO4)(H2O)4Cl]Cl·H2O3Synthesis, characterization and solubility of mixed zirconium-cerium molybdate precipitates7Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties19Origins of the odd optical observables in plutonium and americium tungstates7Experimental evidence and quantum chemical insights into extraction and third phase aggregation trends in Ce(IV) organophosphates20From Thorium to Plutonium: Trends in Actinide(IV) Chloride Structural Chemistry27Extreme condition high temperature and high pressure studies of the K–U–Mo–O system7Targeting complex plutonium oxides by combining crystal chemical reasoning with density-functional theory calculations: the quaternary plutonium oxide Cs 2 PuSi 6 O 159Thorium(IV) and Uranium(IV) Complexes with Cucurbit[8]Uril: Supramolecular Structures Via Direct Coordination and Second-Shell Interactions4Molybdenum Disorder in Hydrated Sedovite, Ideally U(MoO4)2·nH2O, a Microporous Nanocrystalline Mineral Characterized by Three-Dimensional Electron Diffraction, Density Functional Theory Computations, and Complexity Analysis3Highly efficient group separation of hexavalent actinides from lanthanides through a biphasic cooperative extraction system8Development of highly efficient Ce(MoO4)2/g-C3N4 composite for the photocatalytic degradation of methylene blue and ciprofloxacin under visible light32PuCl 3 {CoCp[OP(OEt) 2 ] 3 }: transuranic elements entering the field of heterometallic molecular chemistry0Flux Synthesis of Alkaline-Earth Lanthanide Borates as Potential Nuclear Waste Forms2Review of the solid chemistry of highly active liquid waste at Sellafield in support of future nuclear fuel recycling0Zirconium molybdate precipitates in used nuclear fuel reprocessing and their interactions with tetravalent actinides: a review0

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37 direct citing papers saved.

  1. Crystal Growth and First Crystallographic Characterization of Mixed Uranium(IV)–Plutonium(III) Oxalates

    Inorganic Chemistry · 2013-04-11

    Christelle Tamain, Bénédicte Arab-Chapelet, Murielle Rivenet, F. Abraham, R. Caraballo, S. Grandjean

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  2. Actinide oxalates, solid state structures and applications

    Coordination Chemistry Reviews · 2013-09-06

    F. Abraham, Bénédicte Arab-Chapelet, Murielle Rivenet, Christelle Tamain, S. Grandjean

    Read original paper ↗ ·

  3. The crystal chemistry of uranium carboxylates

    Coordination Chemistry Reviews · 2013-09-08

    Thierry Loiseau, Ionut Mihalcea, Natacha Henry, Christophe Volkringer

    Read original paper ↗ ·

  4. Challenges in the Search for Magnetic Coupling in 3d/4f Materials: Syntheses, Structures, and Magnetic Properties of the Lanthanide Copper Heterobimetallic Compounds, RE2Cu(TeO3)2(SO4)2

    Chemistry of Materials · 2014-03-01

    Jian Hung Lin, Ping Chai, Kariem Diefenbach, Michael Shatruk, Thomas E. Albrecht‐Schmitt

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  5. High-Temperature Phase Transitions, Spectroscopic Properties, and Dimensionality Reduction in Rubidium Thorium Molybdate Family

    Inorganic Chemistry · 2014-03-06

    Bin Xiao, Thorsten M. Gesing, Philip Kegler, Giuseppe Modolo, Dirk Bosbach, Hartmut Schlenz, Evgeny V. Suleimanov, Evgeny V. Alekseev

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  6. Synthesis and Spectroscopy of New Plutonium(III) and -(IV) Molybdates: Comparisons of Electronic Characteristics

    Inorganic Chemistry · 2014-03-06

    Justin N. Cross, Samantha K. Cary, Jared T. Stritzinger, Matthew J. Polinski, Thomas E. Albrecht Schmitt

    Read original paper ↗ ·

  7. Exploring Actinide Materials Through Synchrotron Radiation Techniques

    Advanced Materials · 2014-08-28

    Wei‐Qun Shi, Li‐Yong Yuan, Cong‐Zhi Wang, Lin Wang, Lei Mei, Chengliang Xiao, Li Zhang, Zi‐Jie Li, Yuliang Zhao, Zhifang Chai

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  8. Coordination chemistry of 2,2′-biphenylenedithiophosphinate and diphenyldithiophosphinate with U, Np, and Pu

    Dalton Transactions · 2015-01-01

    Joseph A. Macor, Jessie L. Brown, Justin N. Cross, Scott R. Daly, Andrew J. Gaunt, Gregory S. Girolami, Michael T. Janicke, Stosh A. Kozimor, Mary P. Neu, Angela C. Olson, Sean D. Reilly, Brian L. Scott

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  9. Multifunctional luminescent nanomaterials from NaLa(MoO4)2:Eu3+/Tb3+ with tunable decay lifetimes, emission colors and enhanced cell viability

    Scientific Reports · 2015-08-11

    Mei Yang, Youlong Liang, Qingyuan Gui, Bingxin Zhao, Dayong Jin, Mimi Lin, Lu Yan, Hongpeng You, Liming Dai, Yong Liu

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  10. The structural effects of alkaline- and rare-earth element incorporation into thorium molybdates

    CrystEngComm · 2015-11-12

    Bin Xiao, Hartmut Schlenz, Dirk Bosbach, Evgeny V. Suleimanov, Evgeny V. Alekseev

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  11. Giant Volume Change and Topological Gaps in Temperature‐ and Pressure‐Induced Phase Transitions: Experimental and Computational Study of ThMo2O8

    Chemistry - A European Journal · 2015-12-02

    Bin Xiao, Philip Kegler, Thorsten M. Gesing, Lars Robben, Ariadna Blanca‐Romero, Piotr M. Kowalski, Yan Li, Vladislav V. Klepov, Dirk Bosbach, Evgeny V. Alekseev

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  12. Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates

    Inorganic Chemistry · 2016-04-12

    Samantha K. Cary, Maryline G. Ferrier, Ryan Baumbach, Mark A. Silver, Juan S. Lezama-Pacheco, Stosh A. Kozimor, Henry S. La Pierre, Benjamin William Stein, Alexandra A. Arico, Danielle L. Gray, Thomas E. Albrecht‐Schmitt

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  13. Controllable synthesis and photocatalytic properties of spherical and flower-like Ce2(MoO4)3 hierarchical architectures

    Materials Research Innovations · 2016-04-22

    Guangjian Xing, Hongli Guo, Zhixin Yang, Chunna Yu, Yongliang Li, Zhenglong Wu, Chang Ming Zhao

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  14. A Macrocyclic Chelator That Selectively Binds Ln4+ over Ln3+ by a Factor of 1029

    Inorganic Chemistry · 2016-06-24

    Tiffany A. Pham, Alison B. Altman, S. Chantal E. Stieber, Corwin H. Booth, Stosh A. Kozimor, Wayne W. Lukens, Daniel T. Olive, Tolek Tyliszczak, Jian Wang, Stefan G. Minasian, Kenneth N. Raymond

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  15. Synthesis and structure of dodecamolybdates of tetravalent cerium, thorium, uranium, neptunium, and plutonium

    Radiochemistry · 2016-09-01

    I. A. Charushnikova, Andrei V. Gogolev, Mikhail S. Grigoriev, А. М. Федосеев

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  16. Synthetic Access to Cubic Rare Earth Molybdenum Oxides RE6MoO12−δ(RE = Tm–Lu) Representing a New Class of Ion Conductors

    Chemistry of Materials · 2016-09-22

    Daniel Schildhammer, Gerda Fuhrmann, Lucas L. Petschnig, Simon Penner, Michaela Kogler, Thomas Götsch, Andreas Schaur, Nikolaus Weinberger, Andreas Saxer, Herwig Schottenberger, Hubert Huppertz

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  17. Characterization of Lanthanide Complexes with Bis-1,2,3-triazole-bipyridine Ligands Involved in Actinide/Lanthanide Separation

    Inorganic Chemistry · 2016-10-14

    Julie M. Muller, Shane S. Galley, Thomas E. Albrecht‐Schmitt, Kenneth L. Nash

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  18. Electronic Structure and Properties of Berkelium Iodates

    Journal of the American Chemical Society · 2017-08-17

    Mark A. Silver, Samantha K. Cary, Alejandro J. Garza, Ryan Baumbach, Alexandra A. Arico, Gregory A. Galmin, Kuan-Wen Chen, Jason A. Johnson, Jamie C. Wang, Ronald Jene Clark, Alexander T. Chemey, Teresa M. Eaton, Matthew L. Marsh, Kevin Seidler, Shane S. Galley, Lambertus J. van de Burgt, Ashley L. Gray, David E. Hobart, Kenneth Hanson, Shelley M. Van Cleve, Frédéric Gendron, Jochen Autschbach, Gustavo E. Scuseria, Laurent Maron, Manfred Speldrich, Paul Kögerler, Cristian Celis‐Barros, Dayán Páez‐Hernández, Ramiro Arratia‐Pérez, Michael Ruf, Thomas E. Albrecht‐Schmitt

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  19. Précipitation des molybdates mixtes zirconium-cérium/plutonium en milieu aqueux HNO3

    Unknown journal · 2017-11-24

    Margot Nadolny

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  20. Uncovering the Origin of Divergence in the CsM(CrO4)2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis

    Journal of the American Chemical Society · 2018-01-10

    Shane S. Galley, Alexandra A. Arico, Tsung-Han Lee, Xiaoyu Deng, Yongxin Yao, Joseph M. Sperling, Vanessa Proust, Julia S. Storbeck, V. Dobrosavljević, Jennifer Neu, Theo Siegrist, Ryan Baumbach, Thomas E. Albrecht‐Schmitt, Nikolas Kaltsoyannis, Nicola Lanatà

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  21. Exploring Actinide Materials through Synchrotron Radiation Techniques

    Unknown journal · 2018-02-16

    Wei‐Qun Shi, Li‐Yong Yuan, Cong‐Zhi Wang, Lin Wang, Lei Mei, Chengliang Xiao, Li Zhang, Zi‐Jie Li, Yuliang Zhao, Zhifang Chai

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  22. Immobilization of Alkali Metal Fluorides via Recrystallization in a Cationic Lamellar Material, [Th(MoO4)(H2O)4Cl]Cl·H2O

    Inorganic Chemistry · 2018-06-05

    Jian Hung Lin, Hongliang Bao, Meiying Qie, Mark A. Silver, Zenghui Yue, Xiaoyun Li, Lin Hong Zhu, Xiaomei Wang, Linjuan Zhang, Jian‐Qiang Wang

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  23. Synthesis, characterization and solubility of mixed zirconium-cerium molybdate precipitates

    Journal of Nuclear Science and Technology · 2018-07-23

    Sandrine Jakab-Costenoble, Ingrid Rumaux, Elodie Odore, Sébastien Picart

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  24. Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties

    Dalton Transactions · 2019-01-01

    Jian Hung Lin, Qi Liu, Zenghui Yue, Kariem Diefenbach, Liwei Cheng, Yue‐Jian Lin, Jian‐Qiang Wang

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  25. Origins of the odd optical observables in plutonium and americium tungstates

    Chemical Science · 2019-01-01

    Justin N. Cross, Tsung-Han Lee, Chang‐Jong Kang, Yongxin Yao, Samantha K. Cary, Jared T. Stritzinger, Matthew J. Polinski, Carla D. McKinley, Thomas E. Albrecht‐Schmitt, Nicola Lanatà

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  26. Experimental evidence and quantum chemical insights into extraction and third phase aggregation trends in Ce(IV) organophosphates

    Separation and Purification Technology · 2019-02-04

    Aditi Chandrasekar, N. Sivaraman, Tapan Kumar Ghanty, A. Suresh

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  27. From Thorium to Plutonium: Trends in Actinide(IV) Chloride Structural Chemistry

    Inorganic Chemistry · 2019-07-12

    Jennifer N. Wacker, Sae Young Han, Aphra V. Murray, Nicole A. Vanagas, Jeffery A. Bertke, Joseph M. Sperling, Robert G. Surbella, Karah E. Knope

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  28. Extreme condition high temperature and high pressure studies of the K–U–Mo–O system

    Dalton Transactions · 2020-01-01

    Gabriel L. Murphy, Philip Kegler, Martina Klinkenberg, Shuao Wang, Evgeny V. Alekseev

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  29. Targeting complex plutonium oxides by combining crystal chemical reasoning with density-functional theory calculations: the quaternary plutonium oxide Cs 2 PuSi 6 O 15

    Chemical Communications · 2020-01-01

    Kristen A. Pace, Vladislav V. Klepov, Matthew S. Christian, Gregory W. Morrison, Travis K. Deason, Ceren Kütahyalı Aslani, Theodore M. Besmann, David P. DiPrete, Jake Amoroso, Hans‐Conrad zur Loye

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  30. Thorium(IV) and Uranium(IV) Complexes with Cucurbit[8]Uril: Supramolecular Structures Via Direct Coordination and Second-Shell Interactions

    Polyhedron · 2020-01-01

    Yingjie Zhang, Inna Karatchevtseva, Ming Liu, Zhu Tao, Gang Wei

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  31. Molybdenum Disorder in Hydrated Sedovite, Ideally U(MoO4)2·nH2O, a Microporous Nanocrystalline Mineral Characterized by Three-Dimensional Electron Diffraction, Density Functional Theory Computations, and Complexity Analysis

    Inorganic Chemistry · 2021-09-24

    Gwladys Steciuk, Boris Kiefer, Wolfgang Hornfeck, Anatoly V. Kasatkin, Jakub Plášil

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  32. Highly efficient group separation of hexavalent actinides from lanthanides through a biphasic cooperative extraction system

    Journal of Molecular Liquids · 2023-08-23

    Huaixin Hao, Qiang Zheng, Yanli Zhang, Qian-ge He, Xiaogui Feng, Zhipeng Wang, Jing Chen

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  33. Development of highly efficient Ce(MoO4)2/g-C3N4 composite for the photocatalytic degradation of methylene blue and ciprofloxacin under visible light

    Journal of Molecular Structure · 2023-10-18

    Ambedkar Gandamalla, Saikumar Manchala, Atul Verma, Yen‐Pei Fu, Vishnu Shanker

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  34. PuCl 3 {CoCp[OP(OEt) 2 ] 3 }: transuranic elements entering the field of heterometallic molecular chemistry

    Chemical Science · 2024-01-01

    Thomas E. Shaw, Zachary R. Jones, Sara L. Adelman, Nickolas H. Anderson, Eric G. Bowes, Eric D. Bauer, David Dan, Jan Klouda, Karah E. Knope, Stosh A. Kozimor, Molly M. MacInnes, Veronika Mocko, Francisca R. Rocha, Harrison D. Root, Benjamin William Stein, Joe D. Thompson, Jennifer N. Wacker

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  35. Flux Synthesis of Alkaline-Earth Lanthanide Borates as Potential Nuclear Waste Forms

    Inorganic Chemistry · 2024-08-08

    Gregory W. Morrison, Adrian T. Hines, Virginia G. Jones, K. Pilar Zamorano, Ethan N. Adams, Mark D. Smith, Hans‐Conrad zur Loye

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  36. Review of the solid chemistry of highly active liquid waste at Sellafield in support of future nuclear fuel recycling

    Progress in Nuclear Energy · 2026-05-19

    Joshua R. Turner, Barbara F. Dunnett, Connor Smith

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  37. Zirconium molybdate precipitates in used nuclear fuel reprocessing and their interactions with tetravalent actinides: a review

    Journal of Radioanalytical and Nuclear Chemistry · 2026-09-30

    Andrew Duckworth, Jarrod M. Gogolski, Tracy Rudisill, Nathalie A. Wall

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