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RESEARCH PAPER · Journal of Materials Chemistry · 2004

Organically templated rare earth sulfates with three-dimensional and layered structures

Meenakshi Dan-Hardi, J. N. Behera, C. N. R. Rao

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Organically templated rare earth sulfates with three-dimensional and layered structuresOriginalSynthesis of single-phase layered oxychalcogenide La2CdO2Se2: crystal structure, optical and electrical properties38The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfates4620 New compounds and structures in the solid state5Coordination Polymers Based on Inorganic Lanthanide(III) Sulfate Skeletons and an Organic Isonicotinate N-oxide Connector: Segregation into Three Structural Types by the Lanthanide Contraction Effect172Toward the Rational Design of Open-Framework Materials21[H2en]2{La2M(SO4)6(H2O)2} (M=Co, Ni): First organically templated 3d–4f mixed metal sulfates381-Dimensional and 2-dimensional coordination network structures in the Ba–Ce–dipicH2 system (dipicH2=dipicolinic acid)30Low‐Dimensional Structural Units in Amine‐Templated Uranyl Oxoselenates(VI): Synthesis and Crystal Structures of [C3H12N2][(UO2)(SeO4)2(H2O)2](H2O), [C5H16N2]2[(UO2)(SeO4)2(H2O)](NO3)2, [C4H12N][(UO2)(SeO4)(NO3)], and [C4H14N2][(UO2)(SeO4)2(H2O)]40Organically‐Templated Zinc and Thorium Sulfates with Chain and Layered Structures17Organically-templated metal sulfates, selenites and selenates194Two novel luminescent lanthanide sulfate–carboxylates with an unusual 2-D bamboo-raft-like structure based on the linkages of left- and right-handed helical tubes involving in situ decarboxylation147Two new 3D organically templated cerium sulfates, hydrothermal synthesis and structural characterization7Supramolecular networks of transition metal sulfates templated by piperazine49Organically Directed Iron Sulfate Chains: Structural Diversity Based on Hydrogen Bonding Interactions31Organic–inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic 4,5-imidazoledicarboxylic acid115Coordination Polymers of the Lanthanide Elements: A Structural Survey20Synthesis, crystal structures, phase transition characterization and thermal decomposition of a new dabcodiium hexaaquairon(II) bis(sulfate): (C6H14N2)[Fe(H2O)6](SO4)260Synthesis and structural characterization of four new organically-directed bismuth sulfates5Solvothermal Synthesis, Crystal Structure and Properties of a New Organic Templated Lanthanum Sulfate [C4N3H16][La(SO4)3(H2O)]25Synthesis, crystal structures and properties of three new lanthanide 2,6-pyridinedicarboxylate complexes with zero-dimensional structure49The first hybrid organic–inorganic frameworks based on lanthanide(III) sulfate chains, in situ generated oxalate and organic pillars of 1,4-piperazinediacetic acid20Synthesis and Structural Characterization of Open-Framework Copper (II) Sulfates22New transition metal sulfates templated by 1,4-butanediamine, (C4H14N2)[MII(H2O)6](SO4)2·4H2O (MII: Co, Ni): Structure, reactivity and thermal decomposition23Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate21Hydrothermal synthesis and crystal structure study of two novel 3-D mellitates {Nd2[C6(COO)6] (H2O)6} and {Ho2[C6(COO)6](H2O)6}13Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]·H2O, a New Organically Templated Neodymium(III) Oxalate‐sulfate9Solvothermal Synthesis, Crystal Structure and Properties of the First Organic‐templated Holmium Sulfate [C2N2H10]3[Ho2(SO4)6·2H2O]24One new lanthanide complex with mixed sulfate and oxalate ligands: hydrothermal synthesis, crystal structure, and magnetic properties7Solvothermal synthesis, crystal structure and properties of a novel 1-D organic amine templated holmium sulfate19Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatolanthanum(III)]]2Glycine-Templated Manganese Sulfate with New Topology and Canted Antiferromagnetism35(C 2 H 8 N) 9 [Eu 5 (SO 4 ) 12 ]·2H 2 O: the first europium sulfate open-framework containing two kinds of intersecting extra-large 20-membered ring channels32[Cu4OCl6(DABCO)2]·0.5DABCO·4CH3OH (“MFU-5”): Modular synthesis of a zeolite-like metal-organic framework constructed from tetrahedral {Cu4OCl6} secondary building units and linear organic linkers22Solvothermal syntheses, crystal structures and luminescence properties of three new lanthanide sulfate fluorides33(H3O)Nd(SO4)23Solvothermal Synthesis, Crystal Structure, and Properties of a New Organic‐Templated Holmium Sulfate with 1D Single Ladder Chains14Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate–oxalates13Two novel organic amine templated lanthanide sulfates: Layer H3DETA · [Nd(H2O)(SO4)3] and chain-like H3DETA · [Ho(H2O)2(SO4)3]1Hydrothermal synthesis and characterization of a Na+ templated new 3-D lanthanum sulfate Na[C6H14N2][La3(SO4)6(H2O)3] constructed from La–O–S tubes and cubic cages12Second structural directing agent induces the formation of 1D organic templated terbium sulfate17Solvothermal synthesis, crystal structure and luminescence property of a new 1D organic amine templated europium sulfate with helical chains17Hydrothermal Synthesis, Crystal Structure and Properties of Two Organic Amine Templated Lanthanide Sulfates4Synthesis, characterization and very strong luminescence of a new 3 D europium sulfate Eu2(H2O)4(SO4)35Structural systematic design of organic templated samarium sulfates and their luminescence property14Solvothermal synthesis, crystal structure and properties of three new 1D and 3D organically templated lanthanide sulfates7A series of new rare earth sulfates based on lanthanide contraction and dual organic-amine templating effects12Solvothermal synthesis, structure and characterization of 1D chain and 2D layered rare earth sulfates in the presence of cyclic diamines4Lanthanide Coordination Polymers Constructed from Imidazole-4,5-Dicarboxylate and Sulfate: Syntheses, Structural Diversity, and Photoluminescent Properties812-Dihydromethylpiperazinediium-M II (M II = Cu II , Fe II , Co II , Zn II ) double sulfates and their catalytic activity in diastereoselective nitroaldol (Henry) reaction49l - and d -[Ln(HCO2)(SO4)(H2O)]n (Ln = La, Ce, Pr, Nd, and Eu): Chiral Enantiomerically 3D Architectures Constructed by Double −[Ln–O]n– Helices29Piperazinediium Diselenatohexaaquacobaltate(II) Dihydrate (C4H12N2)[Co(SeO4)2(H2O)4]·2H2O12Two new piperazine templated lanthanide sulfates with 2D corrugated layered crystal structures5(C4N2H12)3[Ln3(OH)(SO4)7] (Ln = Sm, Eu, and Tb): A Series of Honeycomb-like Open-Framework Lanthanide Sulfates with Extra-Large Channels Containing 24-Membered Rings31Solvothermal Synthesis, Crystal Structure, and Strong Luminescence of the First Organic‐Templated Europium Sulfate Chloride5Synthesis, structure and photoluminescence properties of amine-templated open-framework bismuth sulfates9A new nickel selenate templated by piperazine: chemical preparation, crystal structure, thermal decomposition, and magnetic properties133-D Hydrogen bonded networks of three organically templated cadmium sulfates. Dehydration reactions and crystallization behavior5Gadolinium Sulfate Modified by Formate To Obtain Optimized Magneto-Caloric Effect35Three rare Ln–Na heterometallic 3D polymers based on sulfate anion: Syntheses, structures, and luminescence properties13Two novel 2D lanthanide sulfate frameworks: Syntheses, structures, and luminescence properties5Effect of the partial substitution of sulfur by selenium on the atomic arrangement in sulfate- and selenate-based compounds3NCI calculations for understanding a physical phase transition in (C 6 H 14 N 2 )[Mn(H 2 O) 6 ](SeO 4 ) 26The Synthesis of New-Type Rare Earth Luminescent Material [Eu(SO4)F·H2O]0Thorium Oxo‐Clusters as Building Blocks for Open Frameworks37Carbonate and phosphite encaged in frameworks constructed from square lanthanum aminopolycarboxylates and sodium chloride5Noncovalent Interactions inN‐Heterocyclic Chemistry1Syntheses, Structures, Structural Transformation, and Properties of Neodymium Sulfate Based Inorganic Networks0The crystal structure of samarium sulfate pentahydrate, Sm2(SO4)3(H2O)50

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  1. Synthesis of single-phase layered oxychalcogenide La2CdO2Se2: crystal structure, optical and electrical properties

    Journal of Materials Chemistry · 2004-01-01

    Hidenori Hiramatsu, Kazushige Ueda, Toshio Kamiya, Hiromichi Ohta, Masahiro Hirano, Hideo Hosono

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  2. The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfates

    Dalton Transactions · 2004-01-01

    M.B. Doran, Ben E. Cockbain, Alexander J. Norquist, Dermot M. O'Hare

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  3. 20 New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2005-01-01

    Gary B. Hix

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  4. Coordination Polymers Based on Inorganic Lanthanide(III) Sulfate Skeletons and an Organic Isonicotinate N-oxide Connector: Segregation into Three Structural Types by the Lanthanide Contraction Effect

    Inorganic Chemistry · 2005-01-28

    Zheng He, En‐Qing Gao, Zhe‐Ming Wang, Chun‐Hua Yan, Mohamedally Kurmoo

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  5. Toward the Rational Design of Open-Framework Materials

    MRS Bulletin · 2005-02-01

    Anthony Kevin Cheetham, C. N. R. Rao

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  6. [H2en]2{La2M(SO4)6(H2O)2} (M=Co, Ni): First organically templated 3d–4f mixed metal sulfates

    Journal of Solid State Chemistry · 2005-05-29

    Yan-Ping Yuan, Rui‐Yao Wang, Deyuan Kong, Jiang‐Gao Mao, Abraham Clearfield

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  7. 1-Dimensional and 2-dimensional coordination network structures in the Ba–Ce–dipicH2 system (dipicH2=dipicolinic acid)

    Polyhedron · 2005-06-20

    T.K. Prasad, S. Sailaja, M.V. Rajasekharan

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  8. Low‐Dimensional Structural Units in Amine‐Templated Uranyl Oxoselenates(VI): Synthesis and Crystal Structures of [C3H12N2][(UO2)(SeO4)2(H2O)2](H2O), [C5H16N2]2[(UO2)(SeO4)2(H2O)](NO3)2, [C4H12N][(UO2)(SeO4)(NO3)], and [C4H14N2][(UO2)(SeO4)2(H2O)]

    Zeitschrift für anorganische und allgemeine Chemie · 2005-08-29

    Sergey V. Krivovichev, Volker Kahlenberg

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  9. Organically‐Templated Zinc and Thorium Sulfates with Chain and Layered Structures

    Zeitschrift für anorganische und allgemeine Chemie · 2005-11-01

    J. N. Behera, C. N. R. Rao

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  10. Organically-templated metal sulfates, selenites and selenates

    Chemical Society Reviews · 2006-01-01

    C. N. R. Rao, J. N. Behera, Meenakshi Dan-Hardi

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  11. Two novel luminescent lanthanide sulfate–carboxylates with an unusual 2-D bamboo-raft-like structure based on the linkages of left- and right-handed helical tubes involving in situ decarboxylation

    Chemical Communications · 2006-01-01

    Yan‐Qiong Sun, Jie Zhang, Guo‐Yu Yang

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  12. Two new 3D organically templated cerium sulfates, hydrothermal synthesis and structural characterization

    Journal of Molecular Structure · 2006-01-19

    Yunlong Fu, Zhiwei Xu, Jia-Lin Ren

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  13. Supramolecular networks of transition metal sulfates templated by piperazine

    Inorganica Chimica Acta · 2006-06-08

    Walid Rekik, Houcine Naı̈li, Thierry Bataille B, Thierry Roisnel, Tahar Mhiri

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  14. Organically Directed Iron Sulfate Chains: Structural Diversity Based on Hydrogen Bonding Interactions

    Inorganic Chemistry · 2006-09-01

    Yunlong Fu, Zhiwei Xu, Jia-Lin Ren, Hai‐Shun Wu, Rong Yuan

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  15. Organic–inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic 4,5-imidazoledicarboxylic acid

    Dalton Transactions · 2007-01-01

    Yan‐Qiong Sun, Guo‐Yu Yang

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  16. Coordination Polymers of the Lanthanide Elements: A Structural Survey

    Progress in inorganic chemistry · 2007-06-26

    Daniel T. de Lill, Christopher L. Cahill

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  17. Synthesis, crystal structures, phase transition characterization and thermal decomposition of a new dabcodiium hexaaquairon(II) bis(sulfate): (C6H14N2)[Fe(H2O)6](SO4)2

    Journal of Solid State Chemistry · 2007-10-24

    S. Yahyaoui, Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  18. Synthesis and structural characterization of four new organically-directed bismuth sulfates

    Dalton Transactions · 2008-01-01

    Yunlong Fu, Yu Zhang, Zhiwei Xu

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  19. Solvothermal Synthesis, Crystal Structure and Properties of a New Organic Templated Lanthanum Sulfate [C4N3H16][La(SO4)3(H2O)]

    Zeitschrift für anorganische und allgemeine Chemie · 2008-01-21

    Yalin Zhu, Guangpeng Zhou, Yan Xu, Dunru Zhu, Xuefang Zheng

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  20. Synthesis, crystal structures and properties of three new lanthanide 2,6-pyridinedicarboxylate complexes with zero-dimensional structure

    Inorganica Chimica Acta · 2008-03-06

    C. Brouca-Cabarrecq, Jeannette Dexpert‐Ghys, Auguste Fernandes, Joël Jaud, Jean‐Christian Trombe

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  21. The first hybrid organic–inorganic frameworks based on lanthanide(III) sulfate chains, in situ generated oxalate and organic pillars of 1,4-piperazinediacetic acid

    Polyhedron · 2008-05-17

    Juan Yang, Ning Lü, Zhang Gong, Lin Cheng, Shaohua Gou

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  22. Synthesis and Structural Characterization of Open-Framework Copper (II) Sulfates

    Crystal Growth & Design · 2008-11-14

    Jian Lin, Dongwei Guo, Yun‐Qi Tian

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  23. New transition metal sulfates templated by 1,4-butanediamine, (C4H14N2)[MII(H2O)6](SO4)2·4H2O (MII: Co, Ni): Structure, reactivity and thermal decomposition

    Solid State Sciences · 2008-11-15

    Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  24. Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate

    Inorganica Chimica Acta · 2008-11-28

    Yalin Zhu, Xiaochang Sun, Dunru Zhu, Yan Xu

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  25. Hydrothermal synthesis and crystal structure study of two novel 3-D mellitates {Nd2[C6(COO)6] (H2O)6} and {Ho2[C6(COO)6](H2O)6}

    Journal of Rare Earths · 2008-12-01

    Xiao‐Yong Tang, Shan‐Tang Yue, Ping Li, Ning Wang, Yingliang Liu

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  26. Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]·H2O, a New Organically Templated Neodymium(III) Oxalate‐sulfate

    Zeitschrift für anorganische und allgemeine Chemie · 2009-01-23

    Ning Xu, Yan Xing, Xianchun Liu, Danhui Song, Ling Ma, Xiujuan Sun

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  27. Solvothermal Synthesis, Crystal Structure and Properties of the First Organic‐templated Holmium Sulfate [C2N2H10]3[Ho2(SO4)6·2H2O]

    Zeitschrift für anorganische und allgemeine Chemie · 2009-02-09

    Wanli Zhou, Qi Henry Chen, Dunru Zhu, Yan Xu

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  28. One new lanthanide complex with mixed sulfate and oxalate ligands: hydrothermal synthesis, crystal structure, and magnetic properties

    Journal of Coordination Chemistry · 2009-02-17

    Ning Wang, Shan‐Tang Yue, Yingliang Liu

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  29. Solvothermal synthesis, crystal structure and properties of a novel 1-D organic amine templated holmium sulfate

    Inorganica Chimica Acta · 2009-03-11

    Wanli Zhou, Qi Henry Chen, Ning Jiang, Meng Xiang, Dunru Zhu, Yan Xu

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  30. Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatolanthanum(III)]]

    Acta Crystallographica Section E Structure Reports Online · 2009-06-16

    Yuanrui Wang, Yong‐Sheng Hu, Cui-Li Shi, Danping Li, Yafeng Li

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  31. Glycine-Templated Manganese Sulfate with New Topology and Canted Antiferromagnetism

    Inorganic Chemistry · 2009-08-21

    Zhehui Weng, Zilu Chen, Fupei Liang

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  32. (C 2 H 8 N) 9 [Eu 5 (SO 4 ) 12 ]·2H 2 O: the first europium sulfate open-framework containing two kinds of intersecting extra-large 20-membered ring channels

    CrystEngComm · 2009-10-15

    Lei Zheng, Yan Xu, Xiaoliang Zhang, Zhibin Zhang, Dunru Zhu, Su Chen, Shanmugam Palani Elangovan

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  33. [Cu4OCl6(DABCO)2]·0.5DABCO·4CH3OH (“MFU-5”): Modular synthesis of a zeolite-like metal-organic framework constructed from tetrahedral {Cu4OCl6} secondary building units and linear organic linkers

    Journal of Solid State Chemistry · 2009-11-01

    Ying‐Ya Liu, Maciej Grzywa, Matthias Weil, Dirk Volkmer

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  34. Solvothermal syntheses, crystal structures and luminescence properties of three new lanthanide sulfate fluorides

    Dalton Transactions · 2010-01-01

    Wanli Zhou, Yan Xu, Lijie Han, Dunru Zhu

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  35. (H3O)Nd(SO4)2

    Acta Crystallographica Section C Crystal Structure Communications · 2010-01-05

    Zaichao Zhang, Zhibin Zhang

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  36. Solvothermal Synthesis, Crystal Structure, and Properties of a New Organic‐Templated Holmium Sulfate with 1D Single Ladder Chains

    Zeitschrift für anorganische und allgemeine Chemie · 2010-01-28

    Wanli Zhou, Xiaorun Ding, Zhibin Zhang, Lei Zheng, Yan Xu, Dunru Zhu

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  37. Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate–oxalates

    Inorganic Chemistry Communications · 2010-04-13

    Li Li, Ranbo Yu, Dan Wang, Xiaoyong Lai, Dan Mao, Mei Yang

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  38. Two novel organic amine templated lanthanide sulfates: Layer H3DETA · [Nd(H2O)(SO4)3] and chain-like H3DETA · [Ho(H2O)2(SO4)3]

    Russian Journal of Coordination Chemistry · 2010-11-01

    Y. Li, Yong‐Sheng Hu, Cui-Li Shi, Dan-Jun Li, L. Jin, Xe‐Qin Ran, Lixiong Zhang

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  39. Hydrothermal synthesis and characterization of a Na+ templated new 3-D lanthanum sulfate Na[C6H14N2][La3(SO4)6(H2O)3] constructed from La–O–S tubes and cubic cages

    Inorganic Chemistry Communications · 2010-11-12

    Lei Zheng, Zhibin Zhang, Dunru Zhu, Yan Xu

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  40. Second structural directing agent induces the formation of 1D organic templated terbium sulfate

    CrystEngComm · 2011-01-01

    Lei Zheng, Xinmin Qiu, Yan Xu, Jie Fu, Yan Yuan, Dunru Zhu, Su Chen

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  41. Solvothermal synthesis, crystal structure and luminescence property of a new 1D organic amine templated europium sulfate with helical chains

    Inorganic Chemistry Communications · 2011-03-17

    Lei Zheng, Xinmin Qiu, Zhibin Zhang, Dunru Zhu, Yan Xu

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  42. Hydrothermal Synthesis, Crystal Structure and Properties of Two Organic Amine Templated Lanthanide Sulfates

    Journal of Chemical Crystallography · 2011-07-14

    Jie Fu, Lei Zheng, Yan Yuan, You Song, Yan Xu

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  43. Synthesis, characterization and very strong luminescence of a new 3 D europium sulfate Eu2(H2O)4(SO4)3

    Journal of Structural Chemistry · 2011-10-01

    X. Zhang, Yu. Ma, Hai Zhao, Chunjie Jiang, Yu Jie Sun, Ya Xu

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  44. Structural systematic design of organic templated samarium sulfates and their luminescence property

    RSC Advances · 2011-11-03

    Deng Zhang, Lei Zheng, Xinmin Qiu, Yan Xu, Jie Fu, Dunru Zhu

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  45. Solvothermal synthesis, crystal structure and properties of three new 1D and 3D organically templated lanthanide sulfates

    Inorganica Chimica Acta · 2011-11-05

    Jie Fu, Lei Zheng, Zhibin Zhang, Yan Xu

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  46. A series of new rare earth sulfates based on lanthanide contraction and dual organic-amine templating effects

    CrystEngComm · 2012-01-01

    Deng Zhang, Yun Lu, Lei Chen, Hu Cai, Dunru Zhu, Yan Xu

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  47. Solvothermal synthesis, structure and characterization of 1D chain and 2D layered rare earth sulfates in the presence of cyclic diamines

    Inorganic Chemistry Communications · 2012-03-17

    Gen-Wu Ge, Zhi-Yuan Qi, Zhigang Ni, Yizhi Li, Hong‐Bin Du, Xiao‐Zeng You

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  48. Lanthanide Coordination Polymers Constructed from Imidazole-4,5-Dicarboxylate and Sulfate: Syntheses, Structural Diversity, and Photoluminescent Properties

    Crystal Growth & Design · 2012-06-12

    Wen‐Guan Lu, Di‐Chang Zhong, Long Jiang, Tong‐Bu Lu

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  49. 2-Dihydromethylpiperazinediium-M II (M II = Cu II , Fe II , Co II , Zn II ) double sulfates and their catalytic activity in diastereoselective nitroaldol (Henry) reaction

    Dalton Transactions · 2012-09-19

    Houcine Naı̈li, Fadhel Hajlaoui, Tahar Mhiri, Tatiana C. O. Mac Leod, Maximilian N. Kopylovich, Kamran T. Mahmudov⧫, Armando J. L. Pombeiro

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  50. l - and d -[Ln(HCO2)(SO4)(H2O)]n (Ln = La, Ce, Pr, Nd, and Eu): Chiral Enantiomerically 3D Architectures Constructed by Double −[Ln–O]n– Helices

    Inorganic Chemistry · 2012-11-26

    Weiwei Ju, Deng Zhang, Dunru Zhu, Yan Xu

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