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RESEARCH PAPER · Inorganica Chimica Acta · 2006

Supramolecular networks of transition metal sulfates templated by piperazine

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Supramolecular networks of transition metal sulfates templated by piperazineOriginalCrystal structure, phase transition and thermal behaviour of dabcodiium hexaaquacopper(II) bis(sulfate), (C6H14N2)[Cu(H2O)6](SO4)246Synthesis, crystal structure, phase transition and thermal behaviour of a new dabcodiium hexaaquanickel(II) bis(sulphate), (C6H14N2)[Ni(H2O)6](SO4)235A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition33Piperazine pivoted transition metal dithiocarbamates25Synthesis, crystal structures, phase transition characterization and thermal decomposition of a new dabcodiium hexaaquairon(II) bis(sulfate): (C6H14N2)[Fe(H2O)6](SO4)260[NH3(CH2)2NH3][Co(SO4)2(H2O)4]: Chemical preparation, crystal structure, thermal decomposition and magnetic properties40Mononuclear indolyldithiocarbamates of SnCl4 and R2SnCl2: Spectroscopic, thermal characterizations and cytotoxicity assays in vitro372,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate)2New transition metal sulfates templated by 1,4-butanediamine, (C4H14N2)[MII(H2O)6](SO4)2·4H2O (MII: Co, Ni): Structure, reactivity and thermal decomposition23Synthesis, structural characterisation and thermal decomposition of a new organic–inorganic hybrid material (C5H14N2)[Cu(SO4)2(H2O)4]·H2O16Ethylenediammonium tetraaquadisulfatomagnesium(II)10Crystal structure, phase transition and thermal decomposition of a copper (II) sulfate dihydrate containing a chiral organic ammonium cation23Synthesis, characterization and magnetic properties of four new organically templated metal sulfates [C5H14N2][MII(H2O)6](SO4)2, (MII = Mn, Fe, Co, Ni)35Crystal Structure, Phase Transition and Thermal Behaviour of Dabcodiium hexaaquacopper(II) bis(selenate/sulfate), (C6H14N2)[Cu(H2O)6](S0.66Se0.34O4)28Ethylenediammonium tetraaquadisulfatocadmate7Synthesis, Crystal Structure and Characterization of a New Dabcodiium Hexaaquacobalt(II) Bis(Selenate), (C6H14N2)[Co(H2O)6](SeO4)215Synthesis, crystal structures and thermal behaviour of organic–inorganic hybrids incorporating a chiral diamine19Crystal structures of two enantiomorphous 2-ethylpiperazinediium hexaaquacopper sulfates [(R or S)-C5H14N2][Cu(H2O)6](SO4)26Noncentrosymmetry in new 2-methylpiperazinediium hexaaquazinc(II) bis(sulfate)4Capture and Characterization of a Iron(II) Precursor Complex [FeCl3(Hpipz)(pipz)] for Coordination Polymer Synthesis from a Piperazine Melt10Three organically templated magnesium sulfates: Chemical preparation, hydrogen-bonded structures and thermal behavior16Piperazinediium Diselenatohexaaquacobaltate(II) Dihydrate (C4H12N2)[Co(SeO4)2(H2O)4]·2H2O12A new organically templated magnesium sulfate: structure, spectroscopic analysis, and thermal behaviour7Crystal structures and characterization of two divalent metal selenates templated by dabco, (C6H14N2)[MII(H2O)6](SeO4)2 (MII: NiII, ZnII)11Crystal architecture and thermal decomposition of two new organically templated cadmium sulfates3Double piperazinediium and 1,4-diazabicyclo[2.2.2]octanediium MII selenates (MII= CoII, NiII, CuII, ZnII) as effective catalysts for Henry reaction34A new nickel selenate templated by piperazine: chemical preparation, crystal structure, thermal decomposition, and magnetic properties13Tuning of the dimensional linkage from the complex to the framework by thermal conversion in the system Fe/Cl/piperazine3Divalent Copper Selenate Complex: Two Types of Octahedral Coordination in the Unit Cell and Disordered 1,4‐Diazabicyclo[2.2.2]octane5Crystal structure of new organically templated copper sulfate with 2-aminopyridinium13Synthesis and characterization of diethyl-dithiocarbamic acid 2-[4-(2-diethylthiocarbamoylsulfanyl-2-phenyl-acetyl)-2,5-dioxo-piperazin-1-yl]-2-oxo-1-phenyl-ethyl ester as new reversible addition-fragmentation chain transfer agent for polymerization of ethyl methacrylate6Synthesis, crystal structure and disorder–order phase transition of a new diamine templated metal sulfate, (C 3 H 12 N 2 ) 2 [Cu(H 2 O) 4 (SO 4 ) 2 ](HSO 4 ) 212Synthesis, structural characterization, IR- and Raman spectroscopy, magnetic properties of new organically templated metal sulfates with 4-aminopyridinium20Switchable dielectric behavior induced by a disorder–order structural phase transition in (C3H12N2)2(HSO4)2[Mn(H2O)4(SO4)2]5Non-covalently generated 3D supramolecular crystal structure in a new family of hybrid nitrates templated by piperazine: Thermal behavior and in vitro antimicrobial potential12Phase Transition Originating from Disorder–Order Transformation Coupled with Reorientation in the Organic–Inorganic Hybrid Compound (C4H14N2)[Cd2(H2O)6(SO4)3]7Thermal decomposition and biological activity of two supramolecular hybrid nitrates templated by piperazine5Structure, proton conductivity and molecular dynamics of guanidine zinc sulfate8Effect of the partial substitution of sulfur by selenium on the atomic arrangement in sulfate- and selenate-based compounds3Structural, vibrational, DFT and optical studies of a new non-centrosymmetric hybrid material (C4H12N2)[CoBr4]41Structure features, thermal analysis, model and experiment magnetic behavior of tetranuclear oxo and sulfato bridged copper (II) aggregate13NCI calculations for understanding a physical phase transition in (C 6 H 14 N 2 )[Mn(H 2 O) 6 ](SeO 4 ) 26Synthesis, crystal structure and thermal study of the hybrid nickel sulfate: C6N2H16[Ni(H2O)6(SO4)2].2H2O0Two organically templated metal sulfate/selenate: IR spectroscopy, crystal structure, and thermal behaviour3Phase transition from disordered high-temperature to twinned low-temperature structure of tris(ethylenediamine)zinc(II) selenate3Chemical preparation, crystal structure, Hirshfeld surface analysis, spectroscopy, DFT studies, thermal decomposition and magnetic measurements of (C4H12N2)[FeCl3(H2O)3]Cl26A novel sulfate-bridged binuclear copper( ii ) complex: structure, optical, ADMET and in vivo approach in a murine model of bone metastasis44New Cobalt and Nickel Sulfates Templated with N,N'-Dimethyletethylenediammonium Cation: Synthesis, Crystal Structures, and Topological Features1Double sulfates with 1-methylpiperazinediium and divalent cations: Synthesis, structures, spectroscopic characterization, thermal stability, and topological features of (C5H14N2)[M(H2O)6](SO4)2∙H2O (M = Mg, Mn, Fe, Co, Ni, Zn, and Cd) and (C5H14N2)(SO4)∙H2O2

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  1. Crystal structure, phase transition and thermal behaviour of dabcodiium hexaaquacopper(II) bis(sulfate), (C6H14N2)[Cu(H2O)6](SO4)2

    Polyhedron · 2006-07-26

    Houcine Naı̈li, Walid Rekik, Thierry Bataille B, Tahar Mhiri

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  2. Synthesis, crystal structure, phase transition and thermal behaviour of a new dabcodiium hexaaquanickel(II) bis(sulphate), (C6H14N2)[Ni(H2O)6](SO4)2

    Journal of Organometallic Chemistry · 2006-07-30

    Walid Rekik, Houcine Naı̈li, Thierry Bataille B, Tahar Mhiri

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  3. A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition

    Journal of Chemical Crystallography · 2006-11-30

    Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  4. Piperazine pivoted transition metal dithiocarbamates

    Journal of Molecular Structure · 2007-05-28

    Sadaf Sultan Khan, Shahab A.A. Nami, Khwaja Salahuddin Siddiqi

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  5. Synthesis, crystal structures, phase transition characterization and thermal decomposition of a new dabcodiium hexaaquairon(II) bis(sulfate): (C6H14N2)[Fe(H2O)6](SO4)2

    Journal of Solid State Chemistry · 2007-10-24

    S. Yahyaoui, Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  6. [NH3(CH2)2NH3][Co(SO4)2(H2O)4]: Chemical preparation, crystal structure, thermal decomposition and magnetic properties

    Materials Research Bulletin · 2007-10-31

    Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  7. Mononuclear indolyldithiocarbamates of SnCl4 and R2SnCl2: Spectroscopic, thermal characterizations and cytotoxicity assays in vitro

    Journal of Organometallic Chemistry · 2008-02-11

    Sadaf Sultan Khan, Shahab A.A. Nami, Khwaja Salahuddin Siddiqi

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  8. 2,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate)

    Acta Crystallographica Section E Structure Reports Online · 2008-07-08

    Mukhtar A. Kurawa, Christopher J. Adams, A. Guy. Orpen

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  9. New transition metal sulfates templated by 1,4-butanediamine, (C4H14N2)[MII(H2O)6](SO4)2·4H2O (MII: Co, Ni): Structure, reactivity and thermal decomposition

    Solid State Sciences · 2008-11-15

    Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  10. Synthesis, structural characterisation and thermal decomposition of a new organic–inorganic hybrid material (C5H14N2)[Cu(SO4)2(H2O)4]·H2O

    Polyhedron · 2009-04-01

    Fadhel Hajlaoui, S. Yahyaoui, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  11. Ethylenediammonium tetraaquadisulfatomagnesium(II)

    Acta Crystallographica Section E Structure Reports Online · 2009-10-22

    Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  12. Crystal structure, phase transition and thermal decomposition of a copper (II) sulfate dihydrate containing a chiral organic ammonium cation

    Inorganica Chimica Acta · 2009-11-24

    Fadhel Hajlaoui, S. Yahyaoui, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  13. Synthesis, characterization and magnetic properties of four new organically templated metal sulfates [C5H14N2][MII(H2O)6](SO4)2, (MII = Mn, Fe, Co, Ni)

    Dalton Transactions · 2011-01-01

    Fadhel Hajlaoui, Houcine Naı̈li, S. Yahyaoui, Mark M. Turnbull, Tahar Mhiri, Thierry Bataille B

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  14. Crystal Structure, Phase Transition and Thermal Behaviour of Dabcodiium hexaaquacopper(II) bis(selenate/sulfate), (C6H14N2)[Cu(H2O)6](S0.66Se0.34O4)2

    Journal of Chemical Crystallography · 2011-06-22

    Nouha Loulou Nkhili, Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  15. Ethylenediammonium tetraaquadisulfatocadmate

    Acta Crystallographica Section E Structure Reports Online · 2011-08-02

    Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  16. Synthesis, Crystal Structure and Characterization of a New Dabcodiium Hexaaquacobalt(II) Bis(Selenate), (C6H14N2)[Co(H2O)6](SeO4)2

    Journal of Chemical Crystallography · 2011-11-30

    Omar Kammoun, Nouha Loulou, Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  17. Synthesis, crystal structures and thermal behaviour of organic–inorganic hybrids incorporating a chiral diamine

    Journal of Organometallic Chemistry · 2011-12-01

    Fadhel Hajlaoui, Houcine Naı̈li, S. Yahyaoui, Alexander J. Norquist, Tahar Mhiri, Thierry Bataille B

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  18. Crystal structures of two enantiomorphous 2-ethylpiperazinediium hexaaquacopper sulfates [(R or S)-C5H14N2][Cu(H2O)6](SO4)2

    Journal of Structural Chemistry · 2012-03-01

    Fadhel Hajlaoui, Houcine Naı̈li, S. Yahyaoui, Tahar Mhiri, Thierry Bataille B

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  19. Noncentrosymmetry in new 2-methylpiperazinediium hexaaquazinc(II) bis(sulfate)

    Journal of Coordination Chemistry · 2012-03-13

    Houcine Naı̈li

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  20. Capture and Characterization of a Iron(II) Precursor Complex [FeCl3(Hpipz)(pipz)] for Coordination Polymer Synthesis from a Piperazine Melt

    Zeitschrift für anorganische und allgemeine Chemie · 2012-08-03

    Fabian Schönfeld, Larissa Valerie Meyer, Florian Winter, Oliver Niehaus, Ute Ch. Rodewald, Rainer Pöttgen, Klaus Müller‐Buschbaum

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  21. Three organically templated magnesium sulfates: Chemical preparation, hydrogen-bonded structures and thermal behavior

    Solid State Sciences · 2012-09-11

    Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  22. Piperazinediium Diselenatohexaaquacobaltate(II) Dihydrate (C4H12N2)[Co(SeO4)2(H2O)4]·2H2O

    Diffusion and defect data, solid state data. Part B, Solid state phenomena/Solid state phenomena · 2012-11-29

    Nouha Loulou Nkhili, Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  23. A new organically templated magnesium sulfate: structure, spectroscopic analysis, and thermal behaviour

    Chemical Papers · 2013-06-21

    Dhouha Ben Hassan, Walid Rekik, Houcine Naı̈li, Tahar Mhiri

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  24. Crystal structures and characterization of two divalent metal selenates templated by dabco, (C6H14N2)[MII(H2O)6](SeO4)2 (MII: NiII, ZnII)

    Arabian Journal of Chemistry · 2013-09-18

    Nouha Loulou Nkhili, Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  25. Crystal architecture and thermal decomposition of two new organically templated cadmium sulfates

    Journal of Structural Chemistry · 2013-11-01

    Raja Jlassi, Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille B

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  26. Double piperazinediium and 1,4-diazabicyclo[2.2.2]octanediium MII selenates (MII= CoII, NiII, CuII, ZnII) as effective catalysts for Henry reaction

    Inorganica Chimica Acta · 2013-12-21

    Nouha Loulou Nkhili, Walid Rekik, Tahar Mhiri, Kamran T. Mahmudov⧫, Maximilian N. Kopylovich, Houcine Naı̈li

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  27. A new nickel selenate templated by piperazine: chemical preparation, crystal structure, thermal decomposition, and magnetic properties

    Monatshefte für Chemie - Chemical Monthly · 2014-01-23

    Nouha Loulou Nkhili, Walid Rekik, Houcine Naı̈li

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  28. Tuning of the dimensional linkage from the complex to the framework by thermal conversion in the system Fe/Cl/piperazine

    Dalton Transactions · 2014-08-20

    Fabian Schönfeld, Raphael Wirthensohn, Hans‐Christian Schmitt, Philipp Constantinidis, Ingo Fischer, Klaus Müller‐Buschbaum

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  29. Divalent Copper Selenate Complex: Two Types of Octahedral Coordination in the Unit Cell and Disordered 1,4‐Diazabicyclo[2.2.2]octane

    Zeitschrift für anorganische und allgemeine Chemie · 2014-09-30

    Walid Rekik, Nouha Loulou Nkhili, Houcine Naı̈li, Slimane Dahaoui B

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  30. Crystal structure of new organically templated copper sulfate with 2-aminopyridinium

    Acta Crystallographica Section E Crystallographic Communications · 2015-10-09

    Tamara J. Lukianova, Vasyl Kinzhybalo, A. Pietraszko

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  31. Synthesis and characterization of diethyl-dithiocarbamic acid 2-[4-(2-diethylthiocarbamoylsulfanyl-2-phenyl-acetyl)-2,5-dioxo-piperazin-1-yl]-2-oxo-1-phenyl-ethyl ester as new reversible addition-fragmentation chain transfer agent for polymerization of ethyl methacrylate

    Designed Monomers & Polymers · 2015-11-02

    Elaheh Abdollahi, Majid Abdouss, Mehdi Salami‐Kalajahi, Ali Mohammadi, Ali Khalafi‐Nezhad

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  32. Synthesis, crystal structure and disorder–order phase transition of a new diamine templated metal sulfate, (C 3 H 12 N 2 ) 2 [Cu(H 2 O) 4 (SO 4 ) 2 ](HSO 4 ) 2

    CrystEngComm · 2016-01-01

    Chun‐Hong Chen, Rong Mu, Li Zhang, Guan‐Cheng Xu

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  33. Synthesis, structural characterization, IR- and Raman spectroscopy, magnetic properties of new organically templated metal sulfates with 4-aminopyridinium

    Journal of Molecular Structure · 2016-05-11

    Tamara J. Bednarchuk, Vasyl Kinzhybalo, Oleksandr Bednarchuk, A. Pietraszko

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  34. Switchable dielectric behavior induced by a disorder–order structural phase transition in (C3H12N2)2(HSO4)2[Mn(H2O)4(SO4)2]

    Polyhedron · 2016-05-24

    Guan‐Cheng Xu, Chun‐Hong Chen, Li Zhang

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  35. Non-covalently generated 3D supramolecular crystal structure in a new family of hybrid nitrates templated by piperazine: Thermal behavior and in vitro antimicrobial potential

    Polyhedron · 2016-09-09

    Dhouha Ben Hassan, Walid Rekik, Alberto Otero‐de‐la‐Roza, Fedia Ben Mefteh, Thierry Roisnel, Thierry Bataille B, Houcine Naı̈li

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  36. Phase Transition Originating from Disorder–Order Transformation Coupled with Reorientation in the Organic–Inorganic Hybrid Compound (C4H14N2)[Cd2(H2O)6(SO4)3]

    European Journal of Inorganic Chemistry · 2016-12-09

    Rong Mu, Chun‐Hong Chen, Li Zhang, Dianzeng Jia, Guan‐Cheng Xu

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  37. Thermal decomposition and biological activity of two supramolecular hybrid nitrates templated by piperazine

    Journal of Thermal Analysis and Calorimetry · 2016-12-29

    Dhouha Ben Hassan, Walid Rekik, Fedia Ben Mefteh, Houcine Naı̈li

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  38. Structure, proton conductivity and molecular dynamics of guanidine zinc sulfate

    Solid State Ionics · 2017-03-06

    Maria Zdanowska-Frączek, Anna Gągor, K. Hołderna-Natkaniec, Cz. Pawlaczyk, Z. Czapla, Paweł Ławniczak

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  39. Effect of the partial substitution of sulfur by selenium on the atomic arrangement in sulfate- and selenate-based compounds

    Chemical Papers · 2017-05-19

    Ines Kadri, Marwa Abid Derbel, Houcine Naı̈li, Thierry Roisnel, Walid Rekik

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  40. Structural, vibrational, DFT and optical studies of a new non-centrosymmetric hybrid material (C4H12N2)[CoBr4]

    Journal of Molecular Structure · 2017-09-27

    Hafsia Tlili, Sandra Walha, Slim Elleuch, Basem F. Ali, Houcine Naı̈li

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  41. Structure features, thermal analysis, model and experiment magnetic behavior of tetranuclear oxo and sulfato bridged copper (II) aggregate

    Inorganica Chimica Acta · 2017-09-28

    Nabil Hfidhi, Omar Kammoun, Robert Pełka, Magdalena Fitta, Houcine Naı̈li

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  42. NCI calculations for understanding a physical phase transition in (C 6 H 14 N 2 )[Mn(H 2 O) 6 ](SeO 4 ) 2

    Solid State Sciences · 2017-10-23

    Houcine Naı̈li, Michel François, Alexander J. Norquist, Walid Rekik

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  43. Synthesis, crystal structure and thermal study of the hybrid nickel sulfate: C6N2H16[Ni(H2O)6(SO4)2].2H2O

    Journal of Physics Conference Series · 2018-03-01

    F A I Ngopoh, N Hamdi, Souad Chaouch, Mohammed Lachkar, I. da Silva, Brahim El Bali

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  44. Two organically templated metal sulfate/selenate: IR spectroscopy, crystal structure, and thermal behaviour

    Chemical Papers · 2018-05-18

    Marwa Abid Derbel, Ines Kadri, Houcine Naı̈li, Walid Rekik

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  45. Phase transition from disordered high-temperature to twinned low-temperature structure of tris(ethylenediamine)zinc(II) selenate

    Monatshefte für Chemie - Chemical Monthly · 2019-09-17

    Marwa Abid Derbel, Michel François, Houcine Naı̈li, Walid Rekik

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  46. Chemical preparation, crystal structure, Hirshfeld surface analysis, spectroscopy, DFT studies, thermal decomposition and magnetic measurements of (C4H12N2)[FeCl3(H2O)3]Cl2

    Inorganic Chemistry Communications · 2019-12-23

    Ines Kadri, Slim Elleuch, Carlos José Tavares, Manuel Bañobre‐López, Michel François, Walid Rekik

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  47. A novel sulfate-bridged binuclear copper( ii ) complex: structure, optical, ADMET and in vivo approach in a murine model of bone metastasis

    New Journal of Chemistry · 2021-01-01

    Khouloud Hchicha, Marcus Korb, Riadh Badraoui, Houcine Naı̈li

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  48. New Cobalt and Nickel Sulfates Templated with N,N'-Dimethyletethylenediammonium Cation: Synthesis, Crystal Structures, and Topological Features

    Crystallography Reports · 2025-06-01

    Dmitri O. Charkin, V. E. Kireev, Н. В. Сомов, Dmitri N. Dmitriev, A. M. Banaru, Sergey M. Aksenov

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  49. Double sulfates with 1-methylpiperazinediium and divalent cations: Synthesis, structures, spectroscopic characterization, thermal stability, and topological features of (C5H14N2)[M(H2O)6](SO4)2∙H2O (M = Mg, Mn, Fe, Co, Ni, Zn, and Cd) and (C5H14N2)(SO4)∙H2O

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