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RESEARCH PAPER · Nano Letters · 2015

Adhesion and Atomic Structures of Gold on Ceria Nanostructures: The Role of Surface Structure and Oxidation State of Ceria Supports

Yuyuan Lin, Zili Wu, Jianguo Wen, Kunlun Ding, Xiaoyun Yang, Kenneth Reinhard Poeppelmeier, Laurence D. Marks

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Adhesion and Atomic Structures of Gold on Ceria Nanostructures: The Role of Surface Structure and Oxidation State of Ceria SupportsOriginalCan Si-embedded boron nitride nanotubes act as a favorable metal-free catalyst for CO oxidation by N 2 O?35Methanol Adsorption and Reaction on Samaria Thin Films on Pt(111)9Ceria-Based Materials in Catalysis58Nanoparticle shape, thermodynamics and kinetics306Ceria and Its Defect Structure: New Insights from a Combined Spectroscopic Approach263Shape Engineering of Oxide Nanoparticles for Heterogeneous Catalysis61Highly active and sintering-resistant heteroepitaxy of Au nanoparticles on ZnO nanowires for CO oxidation30Adsorption and Adhesion of Au on Reduced CeO 2 (111) Surfaces at 300 and 100 K40CO2 Activation on Ni/γ–Al2O3 Catalysts by First-Principles Calculations: From Ideal Surfaces to Supported Nanoparticles118Al- or Si-decorated graphene oxide: A favorable metal-free catalyst for the N2O reduction35Substrate-dependent Au cluster: A new insight into Au /CeO216Atomic Surface Structures of Oxide Nanoparticles with Well-defined Shapes0Effects of surface charges of gold nanoclusters on long-term in vivo biodistribution, toxicity, and cancer radiation therapy92Real-Time Dynamical Observation of Lattice Induced Nucleation and Growth in Interfacial Solid–Solid Phase Transitions22Controlled Growth of Ceria Nanoarrays on Anatase Titania Powder: A Bottom-up Physical Picture36Characterization and thermal stability of Yb-doped ceria prepared by methods enabling control of the crystal morphology9Pd–ZnO nanowire arrays as recyclable catalysts for 4-nitrophenol reduction and Suzuki coupling reactions37Shape, Thermodynamics, Kinetics and Growth Mechanisms of Metal and Bimetallic Nanoparticles0Synthesis of a hollow structured core–shell Au@CeO 2 –ZrO 2 nanocatalyst and its excellent catalytic performance33Water‐Gas‐Shift over Metal‐Free Nanocrystalline Ceria: An Experimental and Theoretical Study14Performance of Mn-based H2S sorbents in dry, reducing atmosphere – Manganese oxide support effects24Orientation Selection during Heterogeneous Nucleation: Implications for Heterogeneous Catalysis17Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?789A Theoretical Insight into Enhanced Catalytic Activity of Au by Multiple Twin Nanoparticles5Peculiar hydrogenation reactivity of Ni–Niδ+ clusters stabilized by ceria in reducing nitrobenzene to azoxybenzene51Atomic layer reversal on CeO2 (100) surface20Activation and Deactivation of Gold/Ceria–Zirconia in the Low‐Temperature Water–Gas Shift Reaction69Activation and Deactivation of Gold/Ceria–Zirconia in the Low‐Temperature Water–Gas Shift Reaction5Synthesis and CO Oxidation Activity of 1D Mixed Binary Oxide CeO2-LaO x Supported Gold Catalysts7Advanced Electron Microscopy Techniques Toward the Understanding of Metal Nanoparticles and Clusters5Black TiO 2−x with stable surface oxygen vacancies as the support of efficient gold catalysts for water-gas shift reaction70Hydrogen-Etched TiO2−x as Efficient Support of Gold Catalysts for Water–Gas Shift Reaction27Surface/Interfacial Catalysis of (Metal)/Oxide System: Structure and Performance Control39CO oxidation over ceria supported Au22 nanoclusters: Shape effect of the support50Morphology and Size Effect of Ceria Nanostructures on the Catalytic Performances of Pd/CeO2 Catalysts for Methanol Decomposition to Syngas42Reconstruction of Supported Metal Nanoparticles in Reaction Conditions102Reconstruction of Supported Metal Nanoparticles in Reaction Conditions34The effect of AuNP modification on the antioxidant activity of CeO2 nanomaterials with different morphologies27Geometrical Structure of the Gold–Iron(III) Oxide Interfacial Perimeter for CO Oxidation68Geometrical Structure of the Gold–Iron(III) Oxide Interfacial Perimeter for CO Oxidation12Shape-controlled synthesis of Pd nanocrystals with exposed {110} facets and their catalytic applications51Synthesis in a Glovebox: Utilizing Surface Oxygen Vacancies To Enhance the Atomic Dispersion of Palladium on Ceria for Carbon Monoxide Oxidation and Propane Combustion58Understanding CeO2‐Based Nanostructures through Advanced Electron Microscopy in 2D and 3D36Nucleation of Cun (n = 1–5) Clusters and Equilibrium Morphology of Cu Particles Supported on CeO2 Surface: A Density Functional Theory Study24A translational approach to assess the metabolomic impact of stabilized gold nanoparticles by NMR spectroscopy13Selective reduction of CO2 to CO under visible light by controlling coordination structures of CeOx-S/ZnIn2S4 hybrid catalysts65Atomic-Level Analysis of Oxygen Exchange Reactions on Ceria-based Catalysts0Support morphology-dependent alloying behaviour and interfacial effects of bimetallic Ni–Cu/CeO 2 catalysts54Transformations of supported gold nanoparticles observed by in situ electron microscopy24Influence of {111} nanofaceting on the dynamics of CO adsorption and oxidation over Au supported on CeO2 nanocubes: An operando DRIFT insight25Half-Encapsulated Au Nanorods@CeO2 Core@Shell Nanostructures for Near-Infrared Plasmon-Enhanced Catalysis36Structure of the catalytically active copper–ceria interfacial perimeter660Surface Reconstructions of Metal Oxides and the Consequences on Catalytic Chemistry225Gold Stabilized with Iridium on Ceria–Niobia Catalyst: Activity and Stability for CO Oxidation12Catalysis by shapely nanocrystals of the Ce1−xYbxO2−x/2 mixed oxides — Synthesis and phase stability7Surface chemistry and catalysis of oxide model catalysts from single crystals to nanocrystals146Thermally induced sintering and redispersion of Au nanoparticles supported on Ce1-xEuxO2 nanocubes and their influence on catalytic CO oxidation12Atomic-Scale Observation of Bimetallic Au-CuOx Nanoparticles and Their Interfaces for Activation of CO Molecules29CeO2 nanorods supported M–Co bimetallic oxides (M = Fe, Ni, Cu) for catalytic CO and C3H8 oxidation70Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity2375Divergent influence of {1 1 1} vs. {1 0 0} crystal planes and Yb 3+ dopant on CO oxidation paths in mixed nano-sized oxide Au/Ce 1−x Yb x O 2−x/2 ( x = 0 or 0.1) systems6Shapes of epitaxial gold nanocrystals on SrTiO 3 substrates15Insights into facet-dependent reactivity of CuO–CeO2 nanocubes and nanorods as catalysts for CO oxidation reaction74NAP-XPS and In Situ DRIFTS of the Interaction of CO with Au Nanoparticles Supported by Ce1–xEuxO2 Nanocubes18Decoration of Cube‐Like Ceria Crystals by Well‐Dispersed Au Nanoparticles: Surface Influence4In Situ TEM Studies of Catalysts Using Windowed Gas Cells39Crystal Facet Induced Single‐Atom Pd/CoxOy on a Tunable Metal–Support Interface for Low Temperature Catalytic Oxidation27The Sintering of Au Nanoparticles on Flat {100}, {111} and Zigzagged {111}-Nanofacetted Structures of Ceria and Its Influence on Catalytic Activity in CO Oxidation and CO PROX15Design strategies for ceria nanomaterials: untangling key mechanistic concepts73Impact of morphology and collagen-functionalization on the redox equilibria of nanoceria for cancer therapies7Enhanced and stabilized hydrogen production from methanol by ultrasmall Ni nanoclusters immobilized on defect-rich h-BN nanosheets69Recent Progresses on Structural Reconstruction of Nanosized Metal Catalysts via Controlled-Atmosphere Transmission Electron Microscopy: A Review118Experimental investigation of cold adhesion failure physical mechanism of gold plated contact within the Micro-Electromechanical-Relay10Niobia-Supported Metal Catalysts for Synthesis Gas Conversion1Self-assembly of nickel icosahedrons and truncated octahedral nanocrystals on a SrTiO3 (111) support0Unraveling the physical chemistry and materials science of CeO2-based nanostructures200Inducing the Metal–Support Interaction and Enhancing the Ammonia Synthesis Activity of Ceria-Supported Ruthenium Catalyst via N2H4 Reduction32Vibrational Spectroscopies4Shape impact of nanostructured ceria on the dispersion of Pd species32Stabilization and Au sintering prevention promoted by ZnO in CeOx–ZnO porous nanorods decorated with Au nanoparticles in the catalysis of the water-gas shift (WGS) reaction123D Atomic Structure of Supported Metallic Nanoparticles Estimated from 2D ADF STEM Images: A Combination of Atom‐Counting and a Local Minima Search Algorithm25Hierarchical Au/CeO 2 systems – influence of Ln 3+ dopants on the catalytic activity in the propane oxidation process1Tuning Interaction Strength between Ceo2 and IR to Promote Co Oxidation Over Ir/Tio20Titanium modified Ru/CeO2 catalysts for ammonia synthesis26Enhancing catalytic performance of Ag-CeO2 catalysts for catalytic CO combustion: Ag-CeO2 interface interaction and Na-promoting action13Structure sensitivity of ceria-supported Au catalysts for CO oxidation20Enhanced CO2 Methanation Activity of Sm0.25Ce0.75O2-δ–Ni by Modulating the Chelating Agents-to-Metal Cation Ratio and Tuning Metal–Support Interactions31Shape, thermodynamics and kinetics of nanoparticles5In situ studies of catalytic processes by Near Ambient X-ray Photoelectron Spectroscopy0In Situ Kinetic Observations on Crystal Nucleation and Growth386Insights into CO Oxidation in Cu/CeO 2 Catalysts: O 2 Activation at the Dual‐Interfacial Sites8Tuning the C 1 /C 2 Selectivity of Electrochemical CO 2 Reduction on Cu–CeO 2 Nanorods by Oxidation State Control85In Situ Spectroscopy and Microscopy Insights into the CO Oxidation Mechanism on Au/CeO2(111)12Ceria-Based Nano-composites: A Comparative Study on Their Contributions to Important Catalytic Processes0In situ diffraction monitoring of nanocrystals structure evolving during catalytic reaction at their surface5Tuning interaction strength between CeO2 and iridium to promote CO oxidation over Ir/TiO29Diving into the interface-mediated Mars-van Krevelen (M−vK) characteristic of CuOx-supported CeO2 catalysts63CeO2 nanorods supported CuOx-RuOx bimetallic catalysts for low temperature CO oxidation25Ce1−xSnxO2 Catalysts Prepared with Combustion Method for Catalytic Combustion of Ethyl Acetate2Surface energy prediction and Winterbottom morphology evolution analysis in Winterbottom construction on various crystal orientations using machine learning4Acetone-Treated Au Nanoparticles Supported on CeO2 for the Wet Air Oxidation of Dimethylformamide6Geometric edge effect on the interface of Au/CeO2 nanocatalysts for CO oxidation13Interfacial Metal–Support Interaction and Catalytic Performance of Perovskite LaCrO3-Supported Ru Catalyst22Insights into the dynamics of supported Au nanoparticles in the wet environments from first-principles and ReaxFF MD simulations6Strong Metal‐Support Interactions in Heterogeneous Oxygen Electrocatalysis27Machine Learning-Assisted Prediction of Surface and Interface Energies Based on Winterbottom Morphology of Au/Tio2 Nanoparticles0Optimizing low-temperature CO oxidation under realistic combustion conditions: The impact of CeO2 morphology on Au/CeO2 catalysts54Visualizing Size-Dependent Dynamics of CeO 2−δ {100}-Supported CoO x Nanoparticles Under CO 2 Hydrogenation Conditions24Advancing atomic electron tomography with neural networks3Using In Situ TEM to Understand the Surfaces of Electrocatalysts at Reaction Conditions: Single‐Atoms to Nanoparticles4Electron-Enriched Ir Centers at Ir-O-W Interfaces Enable O2-Tolerant CO-Assisted NO Reduction0Spontaneous Oxidation Behavior of Ceria Nanoparticles0Atomic-scale observation of electron-beam-induced reduction and reversible phase transformation in ceria nanoparticles0TiO2-facet-dependent reconstruction of Pt nanoparticles during CO oxidation0

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  1. Can Si-embedded boron nitride nanotubes act as a favorable metal-free catalyst for CO oxidation by N 2 O?

    RSC Advances · 2015-01-01

    Mehdi D. Esrafili, Nasibeh Saeidi, Parisa Nematollahi

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  2. Methanol Adsorption and Reaction on Samaria Thin Films on Pt(111)

    Materials · 2015-09-17

    Jin-Hao Jhang, Andreas Schaefer, Volkmar Zielasek, Jason F. Weaver, Marcus Bäumer

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  3. Ceria-Based Materials in Catalysis

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  4. Nanoparticle shape, thermodynamics and kinetics

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  5. Ceria and Its Defect Structure: New Insights from a Combined Spectroscopic Approach

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  6. Shape Engineering of Oxide Nanoparticles for Heterogeneous Catalysis

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  7. Highly active and sintering-resistant heteroepitaxy of Au nanoparticles on ZnO nanowires for CO oxidation

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    Jiaxin Liu, Jiaxin Liu, Botao Qiao, Yian Song, Hailian Tang, Yudong Huang, Jingyue Liu, Jingyue Liu

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  8. Adsorption and Adhesion of Au on Reduced CeO 2 (111) Surfaces at 300 and 100 K

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  9. CO2 Activation on Ni/γ–Al2O3 Catalysts by First-Principles Calculations: From Ideal Surfaces to Supported Nanoparticles

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  10. Al- or Si-decorated graphene oxide: A favorable metal-free catalyst for the N2O reduction

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  11. Substrate-dependent Au cluster: A new insight into Au /CeO2

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  12. Atomic Surface Structures of Oxide Nanoparticles with Well-defined Shapes

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  13. Effects of surface charges of gold nanoclusters on long-term in vivo biodistribution, toxicity, and cancer radiation therapy

    International Journal of Nanomedicine · 2016-07-01

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  14. Real-Time Dynamical Observation of Lattice Induced Nucleation and Growth in Interfacial Solid–Solid Phase Transitions

    Crystal Growth & Design · 2016-10-24

    Junjie Li, Qiang Li, Zhongchang Wang, Francis Leonard Deepak

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  15. Controlled Growth of Ceria Nanoarrays on Anatase Titania Powder: A Bottom-up Physical Picture

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  16. Characterization and thermal stability of Yb-doped ceria prepared by methods enabling control of the crystal morphology

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  17. Pd–ZnO nanowire arrays as recyclable catalysts for 4-nitrophenol reduction and Suzuki coupling reactions

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  18. Shape, Thermodynamics, Kinetics and Growth Mechanisms of Metal and Bimetallic Nanoparticles

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  19. Synthesis of a hollow structured core–shell Au@CeO 2 –ZrO 2 nanocatalyst and its excellent catalytic performance

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  20. Water‐Gas‐Shift over Metal‐Free Nanocrystalline Ceria: An Experimental and Theoretical Study

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  21. Performance of Mn-based H2S sorbents in dry, reducing atmosphere – Manganese oxide support effects

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  22. Orientation Selection during Heterogeneous Nucleation: Implications for Heterogeneous Catalysis

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  23. Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?

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  24. A Theoretical Insight into Enhanced Catalytic Activity of Au by Multiple Twin Nanoparticles

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  25. Peculiar hydrogenation reactivity of Ni–Niδ+ clusters stabilized by ceria in reducing nitrobenzene to azoxybenzene

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  26. Atomic layer reversal on CeO2 (100) surface

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  27. Activation and Deactivation of Gold/Ceria–Zirconia in the Low‐Temperature Water–Gas Shift Reaction

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  28. Activation and Deactivation of Gold/Ceria–Zirconia in the Low‐Temperature Water–Gas Shift Reaction

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  29. Synthesis and CO Oxidation Activity of 1D Mixed Binary Oxide CeO2-LaO x Supported Gold Catalysts

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  31. Black TiO 2−x with stable surface oxygen vacancies as the support of efficient gold catalysts for water-gas shift reaction

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  32. Hydrogen-Etched TiO2−x as Efficient Support of Gold Catalysts for Water–Gas Shift Reaction

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  34. CO oxidation over ceria supported Au22 nanoclusters: Shape effect of the support

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  35. Morphology and Size Effect of Ceria Nanostructures on the Catalytic Performances of Pd/CeO2 Catalysts for Methanol Decomposition to Syngas

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  36. Reconstruction of Supported Metal Nanoparticles in Reaction Conditions

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  37. Reconstruction of Supported Metal Nanoparticles in Reaction Conditions

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  38. The effect of AuNP modification on the antioxidant activity of CeO2 nanomaterials with different morphologies

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  39. Geometrical Structure of the Gold–Iron(III) Oxide Interfacial Perimeter for CO Oxidation

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  40. Geometrical Structure of the Gold–Iron(III) Oxide Interfacial Perimeter for CO Oxidation

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  41. Shape-controlled synthesis of Pd nanocrystals with exposed {110} facets and their catalytic applications

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  42. Synthesis in a Glovebox: Utilizing Surface Oxygen Vacancies To Enhance the Atomic Dispersion of Palladium on Ceria for Carbon Monoxide Oxidation and Propane Combustion

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  43. Understanding CeO2‐Based Nanostructures through Advanced Electron Microscopy in 2D and 3D

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  44. Nucleation of Cun (n = 1–5) Clusters and Equilibrium Morphology of Cu Particles Supported on CeO2 Surface: A Density Functional Theory Study

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  45. A translational approach to assess the metabolomic impact of stabilized gold nanoparticles by NMR spectroscopy

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  46. Selective reduction of CO2 to CO under visible light by controlling coordination structures of CeOx-S/ZnIn2S4 hybrid catalysts

    Applied Catalysis B: Environmental · 2018-12-27

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  47. Atomic-Level Analysis of Oxygen Exchange Reactions on Ceria-based Catalysts

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  48. Support morphology-dependent alloying behaviour and interfacial effects of bimetallic Ni–Cu/CeO 2 catalysts

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  49. Transformations of supported gold nanoparticles observed by in situ electron microscopy

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  50. Influence of {111} nanofaceting on the dynamics of CO adsorption and oxidation over Au supported on CeO2 nanocubes: An operando DRIFT insight

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