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RESEARCH PAPER · ACS Catalysis · 2017

Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?

Alessandro Trovarelli, Jordi Llorca

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Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?OriginalNovel nanowire self-assembled hierarchical CeO2 microspheres for low temperature toluene catalytic combustion177Rendering Photoreactivity to Ceria: The Role of Defects53Reaction Sensitivity of Ceria Morphology Effect on Ni/CeO2 Catalysis in Propane Oxidation Reactions160O2 Activation on Ceria Catalysts—The Importance of Substrate Crystallographic Orientation138A kinetic study of catalytic hydrothermal reactions of acetaldehyde with cubic CeO2 nanoparticles55Shape Effect Undermined by Surface Reconstruction: Ethanol Dehydrogenation over Shape-Controlled SrTiO3 Nanocrystals70Enhanced visible-light photocatalytic degradation by Mn 3 O 4 /CeO 2 heterojunction: a Z-scheme system photocatalyst66Tailored metastable Ce–Zr oxides with highly distorted lattice oxygen for accelerating redox cycles63The enzyme-like catalytic activity of cerium oxide nanoparticles and its dependency on Ce 3+ surface area concentration326Three-dimensional nitrogen-doped porous carbon anchored CeO 2 quantum dots as an efficient catalyst for formaldehyde oxidation66Nanoceria-Supported Ruthenium(0) Nanoparticles: Highly Active and Stable Catalysts for Hydrogen Evolution from Water94Ceria nanoparticles shape effects on the structural defects and surface chemistry: Implications in CO oxidation by Cu/CeO2 catalysts500Acid-Promoter-Free Ethylene Methoxycarbonylation over Ru-Clusters/Ceria: The Catalysis of Interfacial Lewis Acid–Base Pair258On the soot combustion mechanism using 3DOM ceria catalysts108Density gradient ultracentrifugation for colloidal nanostructures separation and investigation66In Situ Characterization of Cu/CeO2 Nanocatalysts for CO2 Hydrogenation: Morphological Effects of Nanostructured Ceria on the Catalytic Activity233A review on oxygen storage capacity of CeO2-based materials: Influence factors, measurement techniques, and applications in reactions related to catalytic automotive emissions control386Low content of CoOx supported on nanocrystalline CeO2 for toluene combustion: The importance of interfaces between active sites and supports166Effect of CeO2 morphologies on toluene catalytic combustion159Study on different CeO2 structure stability during ethanol steam reforming reaction over Ir/CeO2 nanocatalysts55The critical role of CeO2 crystal-plane in controlling Pt chemical states on the hydrogenolysis of furfuryl alcohol to 1,2-pentanediol126Getting Insights into the Influence of Crystal Plane Effect of Shaped Ceria on Its Catalytic Performances57Synthesis in a Glovebox: Utilizing Surface Oxygen Vacancies To Enhance the Atomic Dispersion of Palladium on Ceria for Carbon Monoxide Oxidation and Propane Combustion56Structural origin of high catalytic activity for preferential CO oxidation over CuO/CeO2 nanocatalysts with different shapes191Control of coordinatively unsaturated Zr sites in ZrO2 for efficient C–H bond activation231Design of Effective Catalysts for Selective Alkyne Hydrogenation by Doping of Ceria with a Single-Atom Promotor298Enhanced ceria nanoflakes using graphene oxide as a sacrificial template for CO oxidation and dry reforming of methane64Catalytic CO Oxidation over Au Nanoparticles Supported on CeO 2 Nanocrystals: Effect of the Au–CeO 2 Interface241Experimental and Theoretical Study on the Nature of Adsorbed Oxygen Species on Shaped Ceria Nanoparticles88Rare Earth Doped Ceria: The Complex Connection Between Structure and Properties154Roles of oxygen vacancy and O− in oxidation reactions over CeO2 and Ag/CeO2 nanorod model catalysts145Interface interactions and CO oxidation activity of Ag/CeO2 catalysts: A new approach using model catalytic systems62Breaking H2 with CeO2: Effect of Surface Termination78Simultaneous enzyme mimicking and chemical reduction mechanisms for nanoceria as a bio-antioxidant: a catalytic model bridging computations and experiments for nanozymes188Support morphology-dependent alloying behaviour and interfacial effects of bimetallic Ni–Cu/CeO 2 catalysts53Catalytic ammonia decomposition for hydrogen production on Ni, Ru and Ni Ru supported on CeO2265Ceria-Based Materials in Hydrogenation and Reforming Reactions for CO2 Valorization146Structure of the catalytically active copper–ceria interfacial perimeter655In situ Raman analyses of the soot oxidation reaction over nanostructured ceria-based catalysts157Insight into the effect of morphology on catalytic performance of porous CeO2 nanocrystals for H2S selective oxidation320The effect of Ti4+ dopant in the 5 wt% Ni/Ce1-xTixO2- catalyst on the carbon pathways of dry reforming of methane studied by various transient and isotopic techniques68Ceria Nanocrystals Supporting Pd for Formic Acid Electrocatalytic Oxidation: Prominent Polar Surface Metal Support Interactions53Ceria and its related materials for VOC catalytic combustion: A review190Surface Reconstructions of Metal Oxides and the Consequences on Catalytic Chemistry221Dry reforming of methane over Pt-Ni/CeO2 catalysts: Effect of the metal composition on the stability151UV-irradiated photocatalytic performance of yttrium doped ceria for hazardous Rose Bengal dye97Towards dense single-atom catalysts for future automotive applications444Surface chemistry and catalysis of oxide model catalysts from single crystals to nanocrystals145Dynamic charge and oxidation state of Pt/CeO2 single-atom catalysts435Engineered nanomaterials: From their properties and applications, to their toxicity towards marine bivalves in a changing environment77Recent advances in ruthenium-based electrocatalysts for the hydrogen evolution reaction333Morphology-dependent CeO2 catalysis in acetylene semihydrogenation reaction52Distribution and Valence State of Ru Species on CeO 2 Supports: Support Shape Effect and Its Influence on CO Oxidation306Cu-Ce-La-Ox as efficient CO oxidation catalysts: Effect of Cu content70Structure and Chemical Properties of Oxide Nanoparticles Determined by Surface-Ligand IR Spectroscopy56Interstitial Boron Atoms in the Palladium Lattice of an Industrial Type of Nanocatalyst: Properties and Structural Modifications62Ammonia decomposition over 3D-printed CeO2 structures loaded with Ni78Direct copolymerization of carbon dioxide and 1,4-butanediol enhanced by ceria nanorod catalyst80Emerging investigator series: molecular mechanisms of plant salinity stress tolerance improvement by seed priming with cerium oxide nanoparticles225Engineered defects in cerium oxides: tuning chemical reactivity for biomedical, environmental, & energy applications121One-pot production of ceria nanosheet-supported PtNi alloy nanodendrites with high catalytic performance toward methanol oxidation and oxygen reduction54Synergistic effects between polyvinylpyrrolidone and oxygen vacancies on improving the oxidase-mimetic activity of flower-like CeO 2 nanozymes60A review of the interactions between ceria and H2 and the applications to selective hydrogenation of alkynes57Electronic and geometric structure of the copper-ceria interface on Cu/CeO2 catalysts95Insights into facet-dependent reactivity of CuO–CeO2 nanocubes and nanorods as catalysts for CO oxidation reaction73Structure-activity relationship in Pd/CeO2 methane oxidation catalysts99Recent Advances on the Rational Design of Non-Precious Metal Oxide Catalysts Exemplified by CuOx/CeO2 Binary System: Implications of Size, Shape and Electronic Effects on Intrinsic Reactivity and Metal-Support Interactions87Cu-Mn-Ce mixed oxides catalysts for soot oxidation and their mechanistic chemistry52Ceria-Based Catalysts Studied by Near Ambient Pressure X-ray Photoelectron Spectroscopy: A Review70Differentiating Surface Ce Species among CeO 2 Facets by Solid-State NMR for Catalytic Correlation114Raman spectroscopy as a powerful tool to characterize ceria-based catalysts332Support morphology effect on the selective oxidation of glycerol over AuPt/CeO2 catalysts66Insight into the effect of facet-dependent surface and oxygen vacancies of CeO2 for Hg removal: From theoretical and experimental studies58Cu, Sm co-doping effect on the CO oxidation activity of CeO2. A combined experimental and density functional study92Performance of an aliovalent-substituted CoCeOx catalyst from bimetallic MOF for VOC oxidation in air183Sustainable synthesis of supported metal nanocatalysts for electrochemical hydrogen evolution88Enhanced Hydrolysis of p -Nitrophenyl Phosphate by Iron (Hydr)oxide Nanoparticles: Roles of Exposed Facets105NiCo2O4 spinel for efficient toluene oxidation: The effect of crystal plane and solvent64Transformations of Biomass, Its Derivatives, and Downstream Chemicals over Ceria Catalysts128Thermally Stable RuOx–CeO2 Nanofiber Catalysts for Low-Temperature CO Oxidation66Plasmon-driven synthesis of individual metal@semiconductor core@shell nanoparticles81Roles of Oxygen Vacancies in the Bulk and Surface of CeO 2 for Toluene Catalytic Combustion476Catalytic performance of Ni catalysts supported on CeO2 with different morphologies for low-temperature CO2 methanation132Surface Refaceting Mechanism on Cubic Ceria80Design strategies for ceria nanomaterials: untangling key mechanistic concepts73Nature of Active Sites on Cu–CeO 2 Catalysts Activated by High-Temperature Thermal Aging124Recent Advances of Ceria‐Based Materials in the Oxidation of Carbon Monoxide62Soot combustion over Ag catalysts supported on shape-controlled CeO259Toward Informed Design of Nanomaterials: A Mechanistic Analysis of Structure–Property–Function Relationships for Faceted Nanoscale Metal Oxides73Magnetic nanocatalysts as multifunctional platforms in cancer therapy through the synthesis of anticancer drugs and facilitated Fenton reaction58Operando Investigation of Toluene Oxidation over 1D Pt@CeO 2 Derived from Pt Cluster-Containing MOF254Applications of rare earth oxides in catalytic ammonia synthesis and decomposition56The chemistry and applications of hafnium and cerium( iv ) metal–organic frameworks297Critical Roles of Surface Oxygen Vacancy in Heterogeneous Catalysis over Ceria-based Materials: A Selected Review63Atomic Scale Characterization of Fluxional Cation Behavior on Nanoparticle Surfaces: Probing Oxygen Vacancy Creation/Annihilation at Surface Sites52Unraveling the physical chemistry and materials science of CeO2-based nanostructures194Boosting Li-CO2 battery performances by engineering oxygen vacancy on NiO nanosheets array68Facet-Dependent Reactivity of Ceria Nanoparticles Exemplified by CeO2-Based Transition Metal Catalysts: A Critical Review63Design Aspects of Doped CeO2 for Low-Temperature Catalytic CO Oxidation: Transient Kinetics and DFT Approach150Surface Fingerprinting of Faceted Metal Oxides and Porous Zeolite Catalysts by Probe-Assisted Solid-State NMR Approaches53How the Morphology of NiO x ‑Decorated CeO2 Nanostructures Affects Catalytic Properties in CO2 Methanation53Review of the Decomposition of Ammonia to Generate Hydrogen687Citric acid-assisted ultrasmall CeO2 nanoparticles for efficient photocatalytic degradation of glyphosate106Defect engineering for high-selection-performance of NO reduction to NH3 over CeO2 (111) surface: A DFT study82Toward an Atomic-Level Understanding of Ceria-Based Catalysts: When Experiment and Theory Go Hand in Hand111Defect Engineering on CeO 2 ‐Based Catalysts for Heterogeneous Catalytic Applications244Ceria-Based Materials for Thermocatalytic and Photocatalytic Organic Synthesis369On the mechanism of visible-light accelerated methane dry reforming reaction over Ni/CeO2−x catalysts102High-performance water gas shift induced by asymmetric oxygen vacancies: Gold clusters supported by ceria-praseodymia mixed oxides83Roles of Oxygen Vacancies of CeO2 and Mn-Doped CeO2 with the Same Morphology in Benzene Catalytic Oxidation96Low-Temperature Heterogeneous Oxidation Catalysis and Molecular Oxygen Activation91Unveiling the reaction pathway on Cu/CeO2 catalyst for electrocatalytic CO2 reduction to CH4202Current understanding of ceria surfaces for CO2 reduction in SOECs and future prospects – A review69Unraveling the importance between electronic intensity and oxygen vacancy on photothermocatalytic toluene oxidation over CeO268CO2 hydrogenation to methanol on tungsten-doped Cu/CeO2 catalysts162Progress on metal-support interactions in Pd-based catalysts for automobile emission control66Co-promotion of two-type active sites: PtCu single-atom alloy and copper-ceria interface for preferential oxidation of CO64Surface Noble Metal Concentration on Ceria as a Key Descriptor for Efficient Catalytic CO Oxidation58Density Functional Theory Investigation of the Biocatalytic Mechanisms of pH-Driven Biomimetic Behavior in CeO 261Designing Sites in Heterogeneous Catalysis: Are We Reaching Selectivities Competitive With Those of Homogeneous Catalysts?424Interaction Mechanism for Simultaneous Elimination of Nitrogen Oxides and Toluene over the Bifunctional CeO2–TiO2 Mixed Oxide Catalyst143CuO with (001)-plane exposure efficiently induces peroxymonosulfate to form ≡Cu-OOSO3-intermediates directly oxidizing organic contaminants in water61Hydrogen production from ammonia decomposition over Ni/CeO2 catalyst: Effect of CeO2 morphology98Catalytic oxidation of volatile organic compounds by non-noble metal catalyst: Current advancement and future prospectives157CO 2 Activation over Nanoshaped CeO 2 Decorated with Nickel for Low-Temperature Methane Dry Reforming81Insights on catalytic mechanism of CeO2 as multiple nanozymes227Antioxidant technology for durability enhancement in polymer electrolyte membranes for fuel cell applications781D/2D CeO2/ZnIn2S4 Z-scheme heterojunction photocatalysts for efficient H2 evolution under visible light53CeO2 and CeO2-based nanomaterials for photocatalytic, antioxidant and antimicrobial activities201A Review of CeO2 Supported Catalysts for CO2 Reduction to CO through the Reverse Water Gas Shift Reaction122Trace Co doping improves NH3-SCR performance and poisoning resistance of Ce-Mn-based catalysts87Insight into the effect of CeO2 morphology on catalytic performance for steam reforming of glycerol55The Extent of Platinum-Induced Hydrogen Spillover on Cerium Dioxide55Recent advances and perspectives of CeO2-based catalysts: Electronic properties and applications for energy storage and conversion89Recent progress of CeO2-based catalysts with special morphologies applied in air pollutants abatement: A review57Toward a Consistent Prediction of Defect Chemistry in CeO262Revealing the Crystal Facet Effect of Ceria in Pd/CeO 2 Catalysts toward the Selective Oxidation of Benzyl Alcohol133CeO 2 -based oxygen storage capacity materials in environmental and energy catalysis for carbon neutrality: extended application and key catalytic properties133Engineering CeO2 configurations to regulate the CuO dispersion and switch pathways of preferential CO oxidation73Microwave-associated chemistry in environmental catalysis for air pollution remediation: A review100Cerium coordination-dependent surface intermediates regulate activity in dimethyl carbonate synthesis from CO2 and methanol64Mechanism of the Periodic Unsteady-State Water–Gas Shift Reaction on Highly Dispersed Cu-Loaded CeO2 Catalysts61Research Status, Optimization Strategies, and Future Prospects of Ammonia Decomposition Catalysts for COx-Free Hydrogen57Orchestrating dual adsorption sites and unravelling Ce-Mn interaction and reaction mechanisms for efficient NH3-SCR55Deciphering the Role of Nano-Ceo2 Morphology on the Dry Reforming of Methane Over Ni/Ceo2 Using Transient and Isotopic Techniques55Two decades of ceria nanoparticle research: structure, properties and emerging applications125Defect Engineering in Nanocatalysts: From Design and Synthesis to Applications348Optimizing low-temperature CO2 methanation through frustrated Lewis pairs on Ni/CeO2 catalysts92Optimizing low-temperature CO oxidation under realistic combustion conditions: The impact of CeO2 morphology on Au/CeO2 catalysts54Advancing the Understanding of Oxygen Vacancies in Ceria: Insights into Their Formation, Behavior, and Catalytic Roles169

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  47. Oxidation-reduction processes in CeO2-x nanocrystals under UV irradiation

    Journal of Photochemistry and Photobiology A Chemistry · 2018-06-11

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  48. A review on oxygen storage capacity of CeO2-based materials: Influence factors, measurement techniques, and applications in reactions related to catalytic automotive emissions control

    Catalysis Today · 2018-06-15

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  49. Low content of CoOx supported on nanocrystalline CeO2 for toluene combustion: The importance of interfaces between active sites and supports

    Applied Catalysis B: Environmental · 2018-06-15

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  50. Effect of CeO2 morphologies on toluene catalytic combustion

    Catalysis Today · 2018-06-20

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