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RESEARCH PAPER · Journal of Catalysis · 2017

Peculiar hydrogenation reactivity of Ni–Niδ+ clusters stabilized by ceria in reducing nitrobenzene to azoxybenzene

Tingting Hou, Yehong Wang, Jian Zhang, Mingrun Li, Jianmin Lü, Marc Heggen, Carsten Sievers, Feng Wang

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Peculiar hydrogenation reactivity of Ni–Niδ+ clusters stabilized by ceria in reducing nitrobenzene to azoxybenzeneOriginalWell-distributed cobalt-based catalysts derived from layered double hydroxides for efficient selective hydrogenation of 5-hydroxymethyfurfural to 2,5-methylfuran47High Catalytic Performance of a CeO2-Supported Ni Catalyst for Hydrogenation of Nitroarenes, Fabricated via Coordination-Assisted Strategy137Efficient Solar-Driven Hydrogen Transfer by Bismuth-Based Photocatalyst with Engineered Basic Sites85Modulating the catalytic behavior of non-noble metal nanoparticles by inter-particle interaction for chemoselective hydrogenation of nitroarenes into corresponding azoxy or azo compounds77Selective Transfer Coupling of Nitrobenzene to Azoxybenzene on Rh Nanoparticle Catalyst Promoted by Photoexcited Hot Electrons25Uniform small metal nanoparticles anchored on CeO 2 nanorods driven by electroless chemical deposition10Enhanced catalytic performance of nitrogen-doped carbon supported FeOx-based catalyst derived from electrospun nanofiber crosslinked N, Fe-containing MOFs for efficient hydrogenation of nitroarenes24Mg-vacancy-induced Ni-vacancy clusters: highly efficient hydrogen production from cellulose26Tandem selective reduction of nitroarenes catalyzed by palladium nanoclusters58Room temperature selective reduction of nitroarenes to azoxy compounds over Ni-TiO2 catalyst23Surrounded catalysts prepared by ion-exchange inverse loading40The relationship of morphology and catalytic performance of CeO2 catalysts for reducing nitrobenzene to azoxybenzene under the base-free condition9Size Effects of Ni Particles on the Cleavage of C–H and C–C Bonds toward Hydrogen Production from Cellulose26Ru single atoms for efficient chemoselective hydrogenation of nitrobenzene to azoxybenzene77Unsaturated Mo in Mo 4 O 4 N 3 for efficient catalytic transfer hydrogenation of nitrobenzene using stoichiometric hydrazine hydrate52Highly efficient N‐doped carbon supported FeS x ‐Fe 2 O 3 catalyst for hydrogenation of nitroarenes via pyrolysis of sulfurized N,Fe‐containing MOFs33Ceria-Based Materials for Thermocatalytic and Photocatalytic Organic Synthesis369Bimetallic CuZn-MOFs derived Cu-ZnO/C catalyst for reductive amination of nitroarenes with aromatic aldehydes tandem reaction40Tandem synthesis of tertiary amines using graphene encapsulated Ni nanocatalyst via nitro compounds hydrogenation and primary amine methylation5Contribution of Different Species in Ni‐Ceria Nanorods Catalysts Applied to Steam Reforming of Ethanol6Catalytic selective oxidation of aromatic amines to azoxy derivatives with an ultralow loading of peroxoniobate salts8Cotton Fiber-Anchored Nb Single-Site Catalyst for Selective Oxidation of Anilines to Azoxybenzenes9Polar hydrogen species mediated nitroarenes selective reduction to anilines over an [FeMo]S x catalyst9UV-Light-Induced Dehydrogenative N-Acylation of Amines with 2-Nitrobenzaldehydes To Give 2-Aminobenzamides7A durable Ni/La-Y catalyst for efficient hydrogenation of γ-valerolactone into pentanoic biofuels39Evolution of multiple spillover hydrogen species on anatase titanium dioxide12Simple and straightforward method to prepare highly dispersed Ni sites for selective nitrobenzene coupling to Azo/Azoxy compounds30Structure engineering of CeO 2 for boosting the Au/CeO 2 nanocatalyst in the green and selective hydrogenation of nitrobenzene17Small interface with ample impact: Synergistic catalysis between Ni0 and Ni2+ during nitrobenzene hydrogenation37Recent Advances on Heterogeneous Non-noble Metal Catalysts toward Selective Hydrogenation Reactions164Tuning the selectivity of nitrobenzene hydrogenation over Pd/CeO2 catalysts for azoxybenzene synthesis under solvent-free conditions5First Principles Study on the Mechanism of Nitrobenzene Hydrogenation by a Ni 1 /CeO 2-x (111) Single-Atom Catalyst20Heterogeneous synergistic catalysts enable efficient catalytic transfer hydrogenation of nitro compounds via in-situ provided hydrogen17Synergy of Oxygen Vacancies and Base Sites for Transfer Hydrogenation of Nitroarenes on Ceria Nanorods7Synergy of Oxygen Vacancies and Base Sites for Transfer Hydrogenation of Nitroarenes on Ceria Nanorods48P-induced electron transfer interaction for enhanced selective hydrogenation rearrangement of furfural to cyclopentanone51Elucidating the atomic stacking structure of nickel phyllosilicate catalysts and their consequences on efficient hydrogenation of 1,4-butynediol to 1,4-butanediol23CO2 reforming of ethane using Ni-La intermetallic sites within a nanocapsule framework16Interface Catalysis of PdO/TiO2 in the Transformation of Formate3Synergy of Rh Nanoparticles With Fe 3 O 4 for Efficient Selective Catalytic Transfer Hydrogenation of Nitrostyrenes Using Stoichiometric Hydrazine Hydrate4Water-assisted preparation of Ni/La(OH)3 catalyst for efficient catalytic C-O bond hydrogenolysis of tetrahydrofuran-dimethanol9Ni2+/Ni0 Ratio-Controlled Hydrazine Dehydrogenation for Semi-Hydrogenation of 1,4-Butynediol0High Activity and Selectivity CeO2 Nanorod Catalysts for Azoxybenzene Synthesis from Transfer Hydrogenation of Nitrobenzene2High-Performance Nickel Phosphide Confined in SBA-15 for Low-Temperature Hydrogenation of Biomass-Derived Compounds25Charge redistribution of Mo-incorporated Fe2Ni2N customizes potential-determining step for highly selective electroreduction of nitrobenzene to azoxybenzene7Deciphering Ni0/Ni(OH)+ interfacial sites for deep hydrogenation of dicyclopentadiene resin3MnO Interface-Induced Ni Electronic Reconfiguration for Hydrogen-Activated Heterolysis and Enhanced Catalytic Hydrogenation of N-Ethylcarbazole7Mg-doped Chlorine-etched self-supported foam iron catalyst for efficient electrocatalytic nitrobenzene hydrogenation coupling to generate azoxybenzene0Recent advances in selectivity control for the catalytic reduction of functionalized nitroarenes over metal-based catalysts5Ni-Doped Amorphous Al2O3 for One-Pot Synthesis of Azoxybenzene via Nitrobenzene Reduction with Sodium Borohydride0Crystal Phase-Dependent Electronic Metal-Support Interactions Enable Chemoselective Hydrogenation of α, β-Unsaturated Aldehydes0

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  1. Well-distributed cobalt-based catalysts derived from layered double hydroxides for efficient selective hydrogenation of 5-hydroxymethyfurfural to 2,5-methylfuran

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  2. High Catalytic Performance of a CeO2-Supported Ni Catalyst for Hydrogenation of Nitroarenes, Fabricated via Coordination-Assisted Strategy

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  3. Efficient Solar-Driven Hydrogen Transfer by Bismuth-Based Photocatalyst with Engineered Basic Sites

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  4. Modulating the catalytic behavior of non-noble metal nanoparticles by inter-particle interaction for chemoselective hydrogenation of nitroarenes into corresponding azoxy or azo compounds

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  5. Selective Transfer Coupling of Nitrobenzene to Azoxybenzene on Rh Nanoparticle Catalyst Promoted by Photoexcited Hot Electrons

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  6. Uniform small metal nanoparticles anchored on CeO 2 nanorods driven by electroless chemical deposition

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  7. Enhanced catalytic performance of nitrogen-doped carbon supported FeOx-based catalyst derived from electrospun nanofiber crosslinked N, Fe-containing MOFs for efficient hydrogenation of nitroarenes

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  8. Mg-vacancy-induced Ni-vacancy clusters: highly efficient hydrogen production from cellulose

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  9. Tandem selective reduction of nitroarenes catalyzed by palladium nanoclusters

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  10. Room temperature selective reduction of nitroarenes to azoxy compounds over Ni-TiO2 catalyst

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  12. The relationship of morphology and catalytic performance of CeO2 catalysts for reducing nitrobenzene to azoxybenzene under the base-free condition

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  13. Size Effects of Ni Particles on the Cleavage of C–H and C–C Bonds toward Hydrogen Production from Cellulose

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  14. Ru single atoms for efficient chemoselective hydrogenation of nitrobenzene to azoxybenzene

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  15. Unsaturated Mo in Mo 4 O 4 N 3 for efficient catalytic transfer hydrogenation of nitrobenzene using stoichiometric hydrazine hydrate

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  16. Highly efficient N‐doped carbon supported FeS x ‐Fe 2 O 3 catalyst for hydrogenation of nitroarenes via pyrolysis of sulfurized N,Fe‐containing MOFs

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  17. Ceria-Based Materials for Thermocatalytic and Photocatalytic Organic Synthesis

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  18. Bimetallic CuZn-MOFs derived Cu-ZnO/C catalyst for reductive amination of nitroarenes with aromatic aldehydes tandem reaction

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  19. Tandem synthesis of tertiary amines using graphene encapsulated Ni nanocatalyst via nitro compounds hydrogenation and primary amine methylation

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