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RESEARCH PAPER · Chinese Chemical Letters · 2025

Bromine for iodine: Unlocking short-wavelength UV phase matching in nonlinear optical metal halides

Mingchang Wang, Zhi Rong Lin, Jiajia Li, Jia-Min Lian, Yunxia Hu, Yan Chen, Ke‐Zhao Du, Jin Chen

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Bromine for iodine: Unlocking short-wavelength UV phase matching in nonlinear optical metal halidesOriginalOrganic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response7Solving the long-standing hygroscopicity and thermal stability issues of the nonlinear optical crystal α-LiIO 3 via homogeneous cation exchange0[CdCl 2 (4-Aminopyridine) 2 ] n : Synergistic Enhancement of Second-Harmonic Generation and Birefringence Enabled by a π-Conjugated Ligand for UV Nonlinear Optics5C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties2Dual‐Role BF 3 Anchoring Enables Giant Birefringence in Short‐Wave UV‐Transparent Fluoroborates0Halogen‐Bond Dimensionality Controls π–π Packing to Unlock Ultrahigh Second‐Harmonic Generation and Giant Birefringence0

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  1. Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response

    Inorganic Chemistry · 2025-09-17

    Mingchang Wang, Jiajia Li, Yan Chen, Ke‐Zhao Du, Jin Chen

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  2. Solving the long-standing hygroscopicity and thermal stability issues of the nonlinear optical crystal α-LiIO 3 via homogeneous cation exchange

    Inorganic Chemistry Frontiers · 2026-01-01

    Jiahao Wan, Zhengli Liang, Xiuying Zhang, Hongming Liu, Le Yang, Ping Wang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Qi Wu

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  3. [CdCl 2 (4-Aminopyridine) 2 ] n : Synergistic Enhancement of Second-Harmonic Generation and Birefringence Enabled by a π-Conjugated Ligand for UV Nonlinear Optics

    Inorganic Chemistry · 2026-01-06

    Qingwen Zhu, Jie Gou, Yunjie Wang, Yaolong Zhu, Qi Wu

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  4. C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties

    Advanced Optical Materials · 2026-02-28

    Chuanying Shen, Jiaxi Ding, Zhengao Xie, Kang Yang, Xunwang Yan, Bingbing Zhang, Kui Wu, Jiyang Wang, Duanliang Wang

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  5. Dual‐Role BF 3 Anchoring Enables Giant Birefringence in Short‐Wave UV‐Transparent Fluoroborates

    Advanced Functional Materials · 2026-09-30

    Jin Chen, Jia‐Min Lian, Huai‐Yu Wu, Yun‐Xia Hu, Jinyu Luo, Yiru Fu, Cai‐Yi Liu, Ke‐Zhao Du

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  6. Halogen‐Bond Dimensionality Controls π–π Packing to Unlock Ultrahigh Second‐Harmonic Generation and Giant Birefringence

    Small · 2026-10-04

    Jin Chen, Yun‐Xia Hu, Huai‐Yu Wu, Jia‐Min Lian, Jinyu Luo, Yiru Fu, Ke‐Zhao Du

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