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RESEARCH PAPER · Laser & Photonics Review · 2024

Designing a Heteroleptic Tetrahedral Group with an Ultrahigh Polarizability Anisotropy by Optimizing the Bonding Electrons Activity and Their Distribution

Hongyuan Sha, Dongling Yang, Qinghe Li, Lilin Yang, Zujian Wang, Rongbing Su, Chao He, Bin Su, Xiaoming Yang, Xifa Long

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Designing a Heteroleptic Tetrahedral Group with an Ultrahigh Polarizability Anisotropy by Optimizing the Bonding Electrons Activity and Their DistributionOriginalHg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Birefringence Modulation by Phenyl and Acyl Groups in Urea-Based Crystals3La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13KF·[SO 2 (NH 2 ) 2 ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure13KF·[SO 2 (NH 2 ) 2 ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure5The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates4Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5The Enhancement of Phase‐Matching Capability by Recombining π‐Conjugated Group in Nonlinear Optical Sulfates1Accelerated Discovery of Fluorophosphates as Deep‐Ultraviolet Nonlinear Optical Materials in the Y–P–O–F System: Unveiling New Composition‐Structure‐Property Rules1A novel tetrafluoroborate with giant birefringence assembled from biocompatible adenine0An Excellent Deep‐Ultraviolet Nonlinear Optical Crystal Realized via a Functional Group Based on a Two‐in‐One Strategy0Crystallographic insights into tetrahedral coordination for advanced electrocatalysis0

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  1. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  2. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  3. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  4. Birefringence Modulation by Phenyl and Acyl Groups in Urea-Based Crystals

    Crystal Growth & Design · 2025-01-21

    Dongling Yang, Hongyuan Sha, Qinghe Li, Lilin Yang, Zujian Wang, Rongbing Su, Chao He, Bin Su, Xiaoming Yang, Xifa Long

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  5. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  6. KF·[SO 2 (NH 2 ) 2 ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure

    Angewandte Chemie International Edition · 2025-09-14

    Yuchen Yan, Xin Wen, Piao Tang, Jingyao Lu, Jindong Chen, Jiyang Wang, Zhanggui Hu, Ning Ye, Guang Peng

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  7. KF·[SO 2 (NH 2 ) 2 ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure

    Angewandte Chemie · 2025-09-14

    Yuchen Yan, Xin Wen, Piao Tang, Jingyao Lu, Jindong Chen, Jiyang Wang, Zhanggui Hu, Ning Ye, Guang Peng

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  8. The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates

    Advanced Functional Materials · 2026-03-16

    Qinghe Li, Lilin Yang, Hongyuan Sha, Dongling Yang, Zujian Wang, Xiaoming Yang, Rongbing Su, Bin Su, Chao He, Xifa Long

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  9. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  10. The Enhancement of Phase‐Matching Capability by Recombining π‐Conjugated Group in Nonlinear Optical Sulfates

    Advanced Optical Materials · 2026-04-25

    Lilin Yang, Qinghe Li, Dongling Yang, Hongyuan Sha, Zujian Wang, Xiaoming Yang, Rongbing Su, Bin Su, Chao He, Xifa Long

    Read original paper ↗ ·

  11. Accelerated Discovery of Fluorophosphates as Deep‐Ultraviolet Nonlinear Optical Materials in the Y–P–O–F System: Unveiling New Composition‐Structure‐Property Rules

    Laser & Photonics Review · 2026-05-19

    Wenqi Jin, Congwei Xie, Ran An, Shilie Pan, Zhihua Yang

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  12. A novel tetrafluoroborate with giant birefringence assembled from biocompatible adenine

    Journal of Molecular Structure · 2026-09-06

    Guangzhizhen Fan, Yuze Li, Lixiang Qin, Zhou Yanling, Hongming Liu

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  13. An Excellent Deep‐Ultraviolet Nonlinear Optical Crystal Realized via a Functional Group Based on a Two‐in‐One Strategy

    Energy & environment materials · 2026-09-15

    Xiliang Jiang, Hongyuan Sha, Xieming Xu, Chenrui Wang, Luying Zheng, Haotian Tian, Binwen Liu, Shuai‐Hua Wang, Guo‐Cong Guo

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  14. Crystallographic insights into tetrahedral coordination for advanced electrocatalysis

    Coordination Chemistry Reviews · 2026-09-16

    Aoxiang Zhu, Mincan Yang, Linai Zhou, Hui Wang, Weilin Xu, Jun Wan

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