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RESEARCH PAPER · Applied Catalysis B: Environmental · 2024

Pt enhanced C–H bond activation for efficient and low-methane-selectivity hydrogenolysis of polyethylene over alloyed RuPt/ZrO2

Chengyang Sun, Jia Wang, Jianjian Wang, Mohsen Shakouri, Bianfang Shi, Xiaohui Liu, Guo Yong, Yongfeng Hu, Xin‐Ping Wu, Yanqin Wang

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Pt enhanced C–H bond activation for efficient and low-methane-selectivity hydrogenolysis of polyethylene over alloyed RuPt/ZrO2OriginalRecent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design25Theoretical determination of a model molecule for the catalytic upcycling of polyolefins1Synergistic effect and role of light for efficient photothermocatalytic CO2 reduction by CH4 on Pd/Co-Al1Mg3Ox16Polyethylene hydrogenolysis by dilute RuPt alloy to achieve H2-pressure-independent low methane selectivity70Efficient upgrading of polystyrene plastics to nitriles through a catalytic oxidative amination process9Highly energy-efficient hydrogenolysis of high-density polyethylene via hydrogen nonthermal plasma reaction engineering4Ru nanoparticles encapsulated in defective UiO-66 def for the hydrogenation of benzene rings in polyethylene terephthalate degraded chemicals4Synergistic effect of acidic sites and mesoporous confinement in Ce-doped Ru/SBA-15 catalysts for efficient hydrogenolysis of low-density polyethylene to liquid fuels7Theoretical determination of a model molecule for the catalytic upcycling of polyethylene and polypropylene0Strategies and technologies for sustainable plastic waste treatment and recycling17Tandem Catalysis for Plastic Depolymerization: In Situ Hydrogen Generation via Methanol Aqueous Phase Reforming for Sustainable Polyethylene Hydrogenolysis2Tandem Catalysis for Plastic Depolymerization: In Situ Hydrogen Generation via Methanol Aqueous Phase Reforming for Sustainable Polyethylene Hydrogenolysis27Protons Selectively Regulate the Asymmetric Activation of the C─H Bonds of Methanol Molecules3Enhanced hydrodeoxygenation of biomass-derived polyols to light alkanes over boron oxide modified nickel silicate catalysts3Recent Advances in Pt-Based Ordered Intermetallic Catalysts for Glycerol Oxidation8Nickel-based bimetallic coated monolith catalysts for hydrogen production by steam reforming of JP-106Catalytic Upgrading of Plastic Wastes into High-Value Carbon Nanomaterials: Synthesis and Applications59Hydrocracking of Polyethylene to Gasoline-Range Hydrocarbons over a Ruthenium-Zeolite Bifunctional Catalyst System with Optimal Synergy of Metal and Acid Sites9Enhancing Waste Plastic Hydrogenolysis on Ru/CeO 2 Through Concurrent Incorporation of Fe Single Atoms and FeO x Nanoclusters27Enhancing Waste Plastic Hydrogenolysis on Ru/CeO 2 Through Concurrent Incorporation of Fe Single Atoms and FeO x Nanoclusters4Synergistic Catalysis for Recycling and Upcycling of Plastics35Predicting a generalized mechanism of branched alkane hydrogenolysis on Ru, Ir, and Pt surfaces relevant to polymer upcycling applications3Coordinating cracking and hydrogenation of polyethylene waste via acid-metal site isolation for selective hydrocarbon production10Hydrogenolysis of LDPE over Ni-catalyst promoted by n-hexane solvent7Rational design of zeolite-based composite catalysts in catalytic cracking of polyethylene6Sustainable Treatment of Plastic Wastes with Photocatalytic Technologies: A Review7Restructured Three‐Coordinated Ni─Se Catalytic Sites for Enhanced Cross‐Condensation of Methanol and Ethanol15Restructured Three‐Coordinated Ni─Se Catalytic Sites for Enhanced Cross‐Condensation of Methanol and Ethanol1CO-promoted polyethylene hydrogenolysis with renewable formic acid as hydrogen donor20Stable single-site organonickel catalyst preferentially hydrogenolyses branched polyolefin C–C bonds12Plasma catalytic hydrogenolysis of polyethylene to gasoline-range fuels over Sm/USY catalysts10Chemical recycling of polyethylenes with low gas products by catalytic hydrogenolysis with heterogeneous CeO2-supported Cu-doped Ru catalyst5Study on the enhancement of stability in ambient pressure CO2-FTS for the production of α-olefins by Pt-modified FeZn catalysts4Synergy Effects in a Bimetallic Ru ─ Pt Alloy Catalyst for Low‐H 2 ‐Pressure Hydrogenolysis of Low‐Density Polyethylene3Plasma Catalysis for Plastic Waste Conversion into Value‐Added Products: Advancements and Perspectives11Polyethylene hydrogenolysis to liquid products over bimetallic catalysts with favorable environmental footprint and economics17Transforming Waste Polyvinyl Chloride into Strong Adhesives by NiCl 2 ‐Catalyzed Amination at Near‐Ambient Temperature0Advances of rare earth-based catalysts for recycling CO 2 and plastic waste17Highly Efficient Catalyst Derived from Ultrathin Co-Based Layered Double Hydroxide for Catalytic Transfer Hydrogenation of Guaiacol under Mild Conditions1Surface and Interface Properties of Metal Species for Waste Plastic Hydroconversion6A self-regenerative Sn–W/γ-Al 2 O 3 catalyst for low-carbon and scalable polyolefin upcycling via tandem dehydrogenation–metathesis2Research progress of high value utilization of waste polyethylene plastics6Catalytic valorization of polyolefins: from catalysts and processes to reactors0Electronegativity-driven d-band center shifts in Ru–Ni alloys for low methane hydrogenolysis of polyolefin plastics2Enhancing aromatic yield by zeolites in polypropylene hydrocracking to jet fuel over Ru 1 -ZrO 2 without forming CH 40Highly selective hydrocracking of polypropylene to gasoline-range fuels over the Pt/MCM-22 catalyst0Highly Selective Conversion of Polyethylene Terephthalate into Liquid Fuel via Nb-Assisted Ru Bimetallic Catalyst15Enhancing Hydrogen Spillover via Crystalline-Phase Engineering of Ru/ZrO 2 for Selective Liquid Alkane Production in Polyethylene Hydrogenolysis6Heterogeneous catalytic aldehyde-water shift of benzaldehyde into benzoic acid and hydrogen0Acid sites in hydrogen-involved polyolefin upcycling: mechanistic insights and design principles0Tailoring the polyolefin hydrogenolysis performance of Ru/TiO2 through TiO2 support facet engineering1Local electron transfer in RuNi alloy catalysts for selective hydrogenolysis of lignin-derived C−O bonds5Structure–performance relationships in heterogeneous catalysts for polyolefin plastic hydroconversion1Highly Selective Gasoline Production by Polyethylene Hydrogenolysis Using Ternary RuNiPt Nanoalloy Catalyst1Oxygen vacancy promoted C–H activation enhancing hydrogenolysis of polyethylene plastics over Ru/CeO2 catalyst0Advances in Catalytic Hydrogenolysis of Waste Plastics to Value-Added Products0Co 1 /Ru Single‐Atom Alloy Catalyst for Sustainable Polypropylene Hydrogenolysis to Long‐Chain Liquid Products1Solvent-free chemical recycling of polyolefins and polystyrene under mild conditions via GaCl3-based molten catalysts0Catalytic Hydrogenolysis of Polyethylene-Based Plastics into Fuels Using Ruthenium Catalysts Supported on Micro/Mesoporous Carbons0Mechanistic insights into the Cr-Zr/ZSM-5 catalyzed cracking of waste polyethylene: Steering product distribution toward BTX aromatics and sustainable aviation fuel0Defect-Engineered Pd/ZSM-5 for Hydroconversion of LDPE to Light Alkanes0Frustrated Lewis Pairs Enable Efficient Polyethylene Oxidative Upcycling0Frustrated Lewis Pairs Enable Efficient Polyethylene Oxidative Upcycling0

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  3. Synergistic effect and role of light for efficient photothermocatalytic CO2 reduction by CH4 on Pd/Co-Al1Mg3Ox

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  4. Polyethylene hydrogenolysis by dilute RuPt alloy to achieve H2-pressure-independent low methane selectivity

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  5. Efficient upgrading of polystyrene plastics to nitriles through a catalytic oxidative amination process

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  6. Highly energy-efficient hydrogenolysis of high-density polyethylene via hydrogen nonthermal plasma reaction engineering

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  7. Ru nanoparticles encapsulated in defective UiO-66 def for the hydrogenation of benzene rings in polyethylene terephthalate degraded chemicals

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  8. Synergistic effect of acidic sites and mesoporous confinement in Ce-doped Ru/SBA-15 catalysts for efficient hydrogenolysis of low-density polyethylene to liquid fuels

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  10. Strategies and technologies for sustainable plastic waste treatment and recycling

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  13. Protons Selectively Regulate the Asymmetric Activation of the C─H Bonds of Methanol Molecules

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  24. Hydrogenolysis of LDPE over Ni-catalyst promoted by n-hexane solvent

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