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RESEARCH PAPER · Coordination Chemistry Reviews · 2026

Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals

Ailijiang Abudurusuli, Linan Wang, Junben Huang, Xueling Hou, Miriding Mutailipu, Shilie Pan, Junjie Li

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Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystalsOriginalKGdSiSe 4 and KGdGeSe 4 : two rare earth-based selenides with wide bandgaps and large nonlinear optical responses0Recent advances in organic–inorganic hybrid materials for optical waveguides and regulation0Te–Se replacement induced structural transition and enhanced band gaps in Cd 5 Se 4 O 12 Cl 2 and Cd 5 Se 4 O 12 Br 21Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response0K 3 Mg 2 [K 6 MgCl 3 ][Ga 20 S 36 ]: A Diamond-like Framework Based on Mixed-Type Supertetrahedra for Excellent Nonlinear Optical Property1Defect Diamond‐Like d 10 Metal Indium Selenium With Strong Second‐Harmonic Generation and Enhanced Laser‐Induced Damage Threshold2Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal0Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal0Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0AlGaS3: a wide band gap ternary diamond-like infrared nonlinear optical material with high laser-induced damage threshold1Crystallographic insights into tetrahedral coordination for advanced electrocatalysis0Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance0

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  1. KGdSiSe 4 and KGdGeSe 4 : two rare earth-based selenides with wide bandgaps and large nonlinear optical responses

    Dalton Transactions · 2026-01-01

    Zhenglong Li, Guansong Zheng, Chen Bai, Leyan Nian, Shilie Pan, Junjie Li

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  2. Recent advances in organic–inorganic hybrid materials for optical waveguides and regulation

    Materials Horizons · 2026-01-01

    Zhenhong Qi, Changxin Shi, Anru Guo, Dongpeng Yan

    Read original paper ↗ ·

  3. Te–Se replacement induced structural transition and enhanced band gaps in Cd 5 Se 4 O 12 Cl 2 and Cd 5 Se 4 O 12 Br 2

    Dalton Transactions · 2026-01-01

    Maqsood Iqbal, Jiazheng Zhou, Aqsa Munawar, Juanjuan Lu, Junjie Li

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  4. Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response

    Dalton Transactions · 2026-01-01

    Qixian Ren, Junwei Feng, Longquan Shao, Meihuizi Zhou, Chen Cui, Yabo Wu

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  5. K 3 Mg 2 [K 6 MgCl 3 ][Ga 20 S 36 ]: A Diamond-like Framework Based on Mixed-Type Supertetrahedra for Excellent Nonlinear Optical Property

    Chemistry of Materials · 2026-04-22

    Jun-Long Chen, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo-Cong Guo

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  6. Defect Diamond‐Like d 10 Metal Indium Selenium With Strong Second‐Harmonic Generation and Enhanced Laser‐Induced Damage Threshold

    Small · 2026-05-17

    Muhammad Zeeshan, Zhiyong Bai, Kaijie Xie, Jin Zhou, Ji Qi, Muhammad Arsalan, Liangmeng Zhu, Weiqi Huang, Junhua Luo, Sangen Zhao

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  7. Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects

    Advanced Optical Materials · 2026-07-21

    Xiangran Kong, Jingdong Yan, Zi Wang, Hongwei Leng, Shichao Cheng, Sue Hao, Xiaoran Niu, Zuotao Lei, Chunhui Yang

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  8. Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal

    Angewandte Chemie International Edition · 2026-07-24

    Yan Guo, Ming‐Xin Li, Ying Guo, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  9. Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal

    Angewandte Chemie · 2026-07-24

    Yan Guo, Ming‐Xin Li, Yi Guo, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

    Read original paper ↗ ·

  10. Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization

    Coordination Chemistry Reviews · 2026-08-14

    Dan-Dan Zhou, Tian-Tian He, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  11. AlGaS3: a wide band gap ternary diamond-like infrared nonlinear optical material with high laser-induced damage threshold

    Science China Materials · 2026-09-04

    Yunfei Shi, Hongshan Wang, Yu Chu, Xin Su, Zhenglong Li, Juanjuan Lu, Ailijiang Abudurusuli, Junjie Li, Shilie Pan

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  12. Crystallographic insights into tetrahedral coordination for advanced electrocatalysis

    Coordination Chemistry Reviews · 2026-09-16

    Aoxiang Zhu, Mincan Yang, Linai Zhou, Hui Wang, Weilin Xu, Jun Wan

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  13. Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance

    Coordination Chemistry Reviews · 2026-09-17

    Bo Zhao, Yaozu Li, Danyang Dou, Wenjing Zhang, Huiyi Zhang, Bingbing Zhang, Ying Wang

    Read original paper ↗ ·
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