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RESEARCH PAPER · Nature Communications · 2026

[Hg3Se2]2- cluster drives giant optical anisotropy and broad infrared transparency

Qixian Ren, Chen Cui, Xinchen Chen, Yabo Wu, Ran An, Zhihua Yang, Shilie Pan

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[Hg3Se2]2- cluster drives giant optical anisotropy and broad infrared transparencyOriginalStereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5[Al(H 2 O) 6 ](NO 3 )Cl 2 : achieving parallel arrangement of functional units and birefringence enhancement through free halogen-mediated structural regulation0[Cd 4 P 2 ][I 3 ] and [Cd 2 P][CdCl 3 ]: two Millon's phase phosphides exhibiting wide band gaps and large birefringence0[Rb 4 Cl][Cd 11 In 9 Se 26 ]: a salt inclusion chalcogenide with a diamond-like framework for infrared nonlinear optics0A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )1A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Na 2 SnSO 4 F 2 : an ultraviolet-transparent sulfate crystal with large birefringence driven by stereochemically active tin( ii )1Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering0Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response0Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals11Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Bio-inspired proton-conformation-coupled hydrogen-bond network reconfiguration for adaptive optical anisotropy0Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units0Unlocking Structural Anisotropy by Guest-Symmetry Modulation Strategy to Achieve Giant Birefringence in Molecular Crystals0Heavy‐Halide Coordination and Lattice‐Confined Molecular Alignment Enable Giant Birefringence in Hybrid Metal Halides0Mechanism-metric correspondence in two-dimensional infrared photodetectors0

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16 direct citing papers saved.

  1. Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )

    Inorganic Chemistry Frontiers · 2025-01-01

    Jingdong Yan, Xiangran Kong, Shichao Cheng, Tao Liu, Hongwei Leng, Yunfei Shang, Zuotao Lei, Chunhui Yang

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  2. [Al(H 2 O) 6 ](NO 3 )Cl 2 : achieving parallel arrangement of functional units and birefringence enhancement through free halogen-mediated structural regulation

    Inorganic Chemistry Frontiers · 2026-01-01

    Z B Zhang, Luyong Zhang, Ruyi Niu, Hussin Elkik, Xue Bai, Jin Li, Shujuan Han

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  3. [Cd 4 P 2 ][I 3 ] and [Cd 2 P][CdCl 3 ]: two Millon's phase phosphides exhibiting wide band gaps and large birefringence

    Dalton Transactions · 2026-01-01

    Fupeng Wang, Guang Peng, Ning Ye, Jindong Chen

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  4. [Rb 4 Cl][Cd 11 In 9 Se 26 ]: a salt inclusion chalcogenide with a diamond-like framework for infrared nonlinear optics

    Dalton Transactions · 2026-01-01

    Pengzhi Xie, Qixian Ren, Junwei Feng, Hong Lei Du, Shuyi Mi

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  5. A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )

    New Journal of Chemistry · 2026-01-01

    Jia Wang, Wenbin Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  6. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  7. Na 2 SnSO 4 F 2 : an ultraviolet-transparent sulfate crystal with large birefringence driven by stereochemically active tin( ii )

    Dalton Transactions · 2026-01-01

    Jia Wang, Wenbin Zhang, X. Ma, Fangfang Zhang, Hong Du, Shujuan Han

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  8. Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering

    Chemical Communications · 2026-01-01

    Xinyao Qi, Haonan Liu, Yu-Jie Zhang, Shihui Ma, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  9. Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response

    Dalton Transactions · 2026-01-01

    Qixian Ren, Junwei Feng, Longquan Shao, Meihuizi Zhou, Chen Cui, Yabo Wu

    Read original paper ↗ ·

  10. Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals

    Journal of the American Chemical Society · 2026-03-05

    Chong‐An Chen, Yang Li, Congcong Jin, S. D. Lee, Zhihua Yang, Kang Min Ok

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  11. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  12. Bio-inspired proton-conformation-coupled hydrogen-bond network reconfiguration for adaptive optical anisotropy

    Research Square · 2026-06-02

    Kang Min Ok, Yayong Sun, Jiachen Lu, Yanqiang Li, Wei Zeng, Chong‐An Chen, Congcong Jin, Hyungjin Lim, S. D. Lee, Hanjung Kim, Junhua Zhang, Tianhua Zhou

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  13. Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units

    Inorganic Chemistry · 2026-06-15

    Xinchen Chen, Yabo Wu, Wangfei Che, Shuyi Mi, Juanjuan Lu, Chen Cui

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  14. Unlocking Structural Anisotropy by Guest-Symmetry Modulation Strategy to Achieve Giant Birefringence in Molecular Crystals

    Journal of the American Chemical Society · 2026-06-16

    Chao‐Hong Xie, Yuan-Feng Li, Bin‐Wen Liu, Guo‐Cong Guo

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  15. Heavy‐Halide Coordination and Lattice‐Confined Molecular Alignment Enable Giant Birefringence in Hybrid Metal Halides

    Advanced Functional Materials · 2026-08-07

    Mingshu Zhang, Shuya Zhao, Zhen‐Cheng Wu, Zheyu Zhang, Sheng‐Ping Guo, Yan Zhou

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  16. Mechanism-metric correspondence in two-dimensional infrared photodetectors

    Cell Reports Physical Science · 2026-09-10

    Lijing Su, Yi Xiong, Haoyang Shan, Xuan Pan

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