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RESEARCH PAPER · Science and Technology of Advanced Materials · 2024

Supra-ceramics: a molecule-driven frontier of inorganic materials

Kazuhiko Maeda, Teruki Motohashi, Ryo Ohtani, Kunihisa Sugimoto, Yuta Tsuji, Akihide Kuwabara, Satoshi Horike

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Supra-ceramics: a molecule-driven frontier of inorganic materialsOriginalFlexible organic–inorganic hybrid crystals of tin( iv ) chloride and naphthalenediimide: exploring elasticity, mechanochromism, and photothermal conversion8Photosalient [2 + 2] photodimerization in metal chloride-templated organic crystals0Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids with cyanoborate anions4Thermal conversion of metal hydroxide acrylate nanoparticles immobilized on TiO 2 toward noble-metal-free photocatalytic H 2 production4Thermally stable proton-conducting oxy-hydroxides synthesized in concentrated water vapor2Tunable optical properties in the (110) p -oriented layered halide perovskite FA 4 Pb 2 I 7.5 (SCN) 0.5 by Br substitution0Wet chemistry nanoarchitectonics for nanocrystal-based films3Zinc-based mixed-anion catalysts for photochemical reduction of carbon dioxide0Layer-by-Layer Nanoarchitectonics: A Method for Everything in Layered Structures29Rectified Water Migration Behavior in the Noncentrosymmetric Channels of a Ferroelectric Proton Conductor4Post‐synthetic Breaking of Inversion Symmetry in Metal Complex‐based Host–guest Systems2Hand Milling Induced Phase Transition for Marcasite-type Carbodiimide5Nanoarchitectonics of Polymers at Interfaces6Anion-Controlled Inorganic Materials as Catalysts for Small-Molecule Conversion Reactions8Dynamic Flow-Assisted Nanoarchitectonics7Nanoarchitectonics for Pentagon Defects in Carbon: Properties and Catalytic Role in Oxygen Reduction Reaction26Single-Atom Nanoarchitectonics for Robotics and Other Functions9A Structure‐Preserving, Dimensionality‐Increasing Strategy for the Stepwise Synthesis of Microporous α‐MoO 3 with a Broad (100) Surface0A Structure‐Preserving, Dimensionality‐Increasing Strategy for the Stepwise Synthesis of Microporous α‐MoO 3 with a Broad (100) Surface3Host-guest chemistry of vanadium-oxygen molecular anions2Thiolate coordination polymers featuring (–M–S–) networks: Synthetic strategies and emerging properties4A Hybrid Photocatalyst Panel Consisting of a Molecular Ru(II) Complex, Polymeric Carbon Nitride, and Titania for Visible‐Light CO 2 Reduction0Recent Advances in Octacalcium Phosphate with Incorporated Carboxylate Ions: A Review5A Sr–Ga Oxy-Hydroxide with High Thermal Stability: Unraveling Its Characteristic Hydrogen-Bond Network0From Inception to Innovation: 20 Years of Nanoarchitectonics21Crystalline water intercalation into the Kitaev honeycomb cobaltate N a 2 C o 2 Te O 60Topotaxy in Layered Cobalt Oxide/Oxyhydroxide Thin Films0Compositionally Optimized Bone Scaffolds Based on Carbonate Apatite and Silver Phosphate for Osteogenesis, Scaffold Resorption, and Photoactivated Antibacterial Activity3Fascinating Frontier, Nanoarchitectonics, as Method for Everything in Materials Science7Pressure-Induced Stabilization of 3D Hyperhoneycomb Li 2 (Sn 1– x Ru x )O 32Counter-Anion-Controlled Energy Transfer Leading to Triplet Formation in Aqueous Triplet–Triplet Annihilation Upconversion: Toward Efficient Aqueous Upconversion Systems0Formation of calcium-phosphate-based supra-ceramics in solutions containing glutaric acid derivatives0Photoinduced reversible assembly of polynuclear complexes from Ru-containing ionic liquids with accompanying ionic conductivity modulations1Refining hydrogen positions in α-FeOOH through combined neutron diffraction and computational techniques2Review of Organic Persistent Phosphors: Classifications by Material Forms, Applications, and Mechanisms3Substituent-Position-Dependent Electrochemical CO 2 Reduction Activity of Pb–S-Based Coordination Polymers1Bifunctional interface engineering for stable perovskite photovoltaics: Synergistic crystallization and defect passivation with a pyridine-3,5-dicarboxylic acid interlayer2Foreword to the focus issue, ’nanoarchitectonics reloaded: method for everything in materials science’0Large structure of layer-by-layer-deposited supra-ceramic nanosheet films: characterized by GISAXS and GIWAXS techniques1A Lead(II)-Based Coordination Polymer Exhibiting Photocatalytic and Electrochemical CO 2 Reduction Activities0Quaternary Ammonium Salts with B(CN) 4 or C(CN) 3 Anions: From Ionic Plastic Crystals and Ionic Liquids to Meltable Coordination Polymers2Counter-anion-controlled energy transfer leading to triplet formation in aqueous triplet–triplet annihilation upconversion: toward efficient aqueous Upconversion systems2Nanoarchitectonics Together with Self-Assembly for Materials Construction in Mesoscopic Range0Photochromic Donor–Acceptor Naphthalenediimides Enabling Near‐Infrared Photothermal Conversion for Seawater Desalination1Broadband solar-responsive supra-ceramic TNS/AgNP composite for efficient photothermal conversion and dual-mode antibacterial function0

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  1. Flexible organic–inorganic hybrid crystals of tin( iv ) chloride and naphthalenediimide: exploring elasticity, mechanochromism, and photothermal conversion

    Journal of Materials Chemistry C · 2025-01-01

    Sotaro Kusumoto, Shunya Masuda, Ryo Suzuki, Masaru Tachibana, Masaya Shimabukuro, Mamiko Kobayashi, Naoki Ogiwara, Sayaka Uchida, Tomoya Fukui, Yuta Tsuji, Masaya Okamura, Shiro Hikichi, Yang Kim, Yoshihiro Koide

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  2. Photosalient [2 + 2] photodimerization in metal chloride-templated organic crystals

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    Sotaro Kusumoto, Kippei Usuda, Kenta Rakumitsu, Yang Kim, Yoshihiro Koide

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  3. Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids with cyanoborate anions

    Chemical Communications · 2025-01-01

    Haruka Koshino, Zi Lang Goo, Kunihisa Sugimoto, Tomoyuki Mochida

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  4. Thermal conversion of metal hydroxide acrylate nanoparticles immobilized on TiO 2 toward noble-metal-free photocatalytic H 2 production

    Nanoscale · 2025-01-01

    Naoki Tarutani, Rei Nitomakida, Kiyofumi Katagiri, Kei Inumaru, S. Inoue, Hiroki Yamada, Toshiaki Ina, Yousuke Ooyama

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  5. Thermally stable proton-conducting oxy-hydroxides synthesized in concentrated water vapor

    Journal of Materials Chemistry A · 2025-01-01

    Kenji I. Arai, Yoko Kokubo, Yusuke Asai, Satoshi Ogawa, Miwa Saito, Maria A. Kirsanova, Iaroslava Shakhova, Artem M. Abakumov, Fumitaka Takeiri, Hiroshi Kageyama, Teruki Motohashi

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  6. Tunable optical properties in the (110) p -oriented layered halide perovskite FA 4 Pb 2 I 7.5 (SCN) 0.5 by Br substitution

    Dalton Transactions · 2025-01-01

    Koki Matsushima, Takuya Ohmi, Wataru Taniguchi, Shoya Nagano, Tomoya Fukui, Takanori Fukushima, Muhammad Awais, Makhsud I. Saidaminov, Masaki Azuma, Takafumi Yamamoto

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  7. Wet chemistry nanoarchitectonics for nanocrystal-based films

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  8. Zinc-based mixed-anion catalysts for photochemical reduction of carbon dioxide

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  9. Layer-by-Layer Nanoarchitectonics: A Method for Everything in Layered Structures

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  10. Rectified Water Migration Behavior in the Noncentrosymmetric Channels of a Ferroelectric Proton Conductor

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  11. Post‐synthetic Breaking of Inversion Symmetry in Metal Complex‐based Host–guest Systems

    European Journal of Inorganic Chemistry · 2025-03-12

    Yuxin Shi, Yuudai Iwai, Benjamin Le Ouay, Masaaki Ohba, Ryo Ohtani

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  12. Hand Milling Induced Phase Transition for Marcasite-type Carbodiimide

    Journal of the American Chemical Society · 2025-03-24

    Yuzuki Yamamoto, Kazuki Kume, Suzuka Miyazaki, Ayako Shinozaki, Peng Song, Sayed Sahriar Hasan, Kenta Hongo, Ryo Maezono, Hiroki Ubukata, Hiroshi Kageyama, Mikio Higuchi, Yuji Masubuchi

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  13. Nanoarchitectonics of Polymers at Interfaces

    Macromolecular Chemistry and Physics · 2025-04-02

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  14. Anion-Controlled Inorganic Materials as Catalysts for Small-Molecule Conversion Reactions

    ACS Applied Materials & Interfaces · 2025-04-17

    Megumi Okazaki, Yuta Tsuji, Daisuke Tanaka, Hiroshi Kageyama, Kazuhiko Maeda

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  15. Dynamic Flow-Assisted Nanoarchitectonics

    ACS Applied Materials & Interfaces · 2025-04-21

    Katsuhiko Ariga, Shuta Fujioka, Yu Yamashita

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  16. Nanoarchitectonics for Pentagon Defects in Carbon: Properties and Catalytic Role in Oxygen Reduction Reaction

    Small Methods · 2025-04-22

    Guoping Chen, Taro Koide, Junji Nakamura, Katsuhiko Ariga

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  17. Single-Atom Nanoarchitectonics for Robotics and Other Functions

    ACS Sustainable Chemistry & Engineering · 2025-05-02

    Anna Jančík Procházková, Katsuhiko Ariga

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  18. A Structure‐Preserving, Dimensionality‐Increasing Strategy for the Stepwise Synthesis of Microporous α‐MoO 3 with a Broad (100) Surface

    Angewandte Chemie · 2025-06-18

    Takuo Minato, Misato Miyamoto, Satoshi Ishikawa, Norihito Hiyoshi, Makoto Maeda, Kenji Komaguchi, Masahiro Sadakane

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  19. A Structure‐Preserving, Dimensionality‐Increasing Strategy for the Stepwise Synthesis of Microporous α‐MoO 3 with a Broad (100) Surface

    Angewandte Chemie International Edition · 2025-06-18

    Takuo Minato, Misato Miyamoto, Satoshi Ishikawa, Norihito Hiyoshi, Makoto Maeda, Kenji Komaguchi, Masahiro Sadakane

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  20. Host-guest chemistry of vanadium-oxygen molecular anions

    Journal of Inclusion Phenomena and Macrocyclic Chemistry · 2025-07-18

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  21. Thiolate coordination polymers featuring (–M–S–) networks: Synthetic strategies and emerging properties

    Coordination chemistry research. · 2025-07-25

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  22. A Hybrid Photocatalyst Panel Consisting of a Molecular Ru(II) Complex, Polymeric Carbon Nitride, and Titania for Visible‐Light CO 2 Reduction

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  23. Recent Advances in Octacalcium Phosphate with Incorporated Carboxylate Ions: A Review

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  24. A Sr–Ga Oxy-Hydroxide with High Thermal Stability: Unraveling Its Characteristic Hydrogen-Bond Network

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  25. From Inception to Innovation: 20 Years of Nanoarchitectonics

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  26. Crystalline water intercalation into the Kitaev honeycomb cobaltate N a 2 C o 2 Te O 6

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  27. Topotaxy in Layered Cobalt Oxide/Oxyhydroxide Thin Films

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  28. Compositionally Optimized Bone Scaffolds Based on Carbonate Apatite and Silver Phosphate for Osteogenesis, Scaffold Resorption, and Photoactivated Antibacterial Activity

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  29. Fascinating Frontier, Nanoarchitectonics, as Method for Everything in Materials Science

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  30. Pressure-Induced Stabilization of 3D Hyperhoneycomb Li 2 (Sn 1– x Ru x )O 3

    Journal of the American Chemical Society · 2025-12-15

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  31. Counter-Anion-Controlled Energy Transfer Leading to Triplet Formation in Aqueous Triplet–Triplet Annihilation Upconversion: Toward Efficient Aqueous Upconversion Systems

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  32. Formation of calcium-phosphate-based supra-ceramics in solutions containing glutaric acid derivatives

    Dalton Transactions · 2026-01-01

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  33. Photoinduced reversible assembly of polynuclear complexes from Ru-containing ionic liquids with accompanying ionic conductivity modulations

    Inorganic Chemistry Frontiers · 2026-01-01

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  34. Refining hydrogen positions in α-FeOOH through combined neutron diffraction and computational techniques

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  35. Review of Organic Persistent Phosphors: Classifications by Material Forms, Applications, and Mechanisms

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  36. Substituent-Position-Dependent Electrochemical CO 2 Reduction Activity of Pb–S-Based Coordination Polymers

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  37. Bifunctional interface engineering for stable perovskite photovoltaics: Synergistic crystallization and defect passivation with a pyridine-3,5-dicarboxylic acid interlayer

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  38. Foreword to the focus issue, ’nanoarchitectonics reloaded: method for everything in materials science’

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  39. Large structure of layer-by-layer-deposited supra-ceramic nanosheet films: characterized by GISAXS and GIWAXS techniques

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  41. Quaternary Ammonium Salts with B(CN) 4 or C(CN) 3 Anions: From Ionic Plastic Crystals and Ionic Liquids to Meltable Coordination Polymers

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  42. Counter-anion-controlled energy transfer leading to triplet formation in aqueous triplet–triplet annihilation upconversion: toward efficient aqueous Upconversion systems

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  43. Nanoarchitectonics Together with Self-Assembly for Materials Construction in Mesoscopic Range

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  44. Photochromic Donor–Acceptor Naphthalenediimides Enabling Near‐Infrared Photothermal Conversion for Seawater Desalination

    Chemistry - A European Journal · 2026-07-31

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  45. Broadband solar-responsive supra-ceramic TNS/AgNP composite for efficient photothermal conversion and dual-mode antibacterial function

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