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RESEARCH PAPER · Journal of the American Chemical Society · 2025

Cathode Design Based on Nitrogen Redox and Linear Coordination of Cu Center for All-Solid-State Fluoride-Ion Batteries

Datong Zhang, Kentaro Yamamoto, Zulai Cao, Yanchang Wang, Zhuoyan Zhong, Hisao Kiuchi, Toshiki Watanabe, Toshiyuki Matsunaga, Koji Nakanishi, Hidenori Miki, Hideki Iba, Yoshihisa Harada, Koji Amezawa, Kazuhiko Maeda, Hiroshi Kageyama, Yoshiharu Uchimoto

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Cathode Design Based on Nitrogen Redox and Linear Coordination of Cu Center for All-Solid-State Fluoride-Ion BatteriesOriginalFluorination of single-crystal copper electrodes in fluoride-ion batteries0Highly efficient atomic-scale design of CaF 2 for ultrafast fluoride-ion conduction5Lewis Acid–Base Synergistically Enhancing Practical Composite Electrolyte for Fluoride‐ion Batteries at Room Temperature9Interplay Between Stereochemically Active Lone Pair Repulsions, Sigma Hole Interactions, and Delocalized Redox Processes in Topochemical Fluoride‐Ion Insertion3Interplay Between Stereochemically Active Lone Pair Repulsions, Sigma Hole Interactions, and Delocalized Redox Processes in Topochemical Fluoride‐Ion Insertion0Ion‐Pump‐Regulated Highly Conductive Polymer Electrolyte to Enable the First All‐Solid‐State Rechargeable Fluoride‐Ion Pouch Cells8High-Capacity Intercalation-Based Anodes for Solid-State Fluoride-Ion Batteries Enabled by the Substitution of Conductive Carbon by Metallic Copper2Catalytic activation of electrochemical fluoride-ion introduction into graphene-like graphite in all-solid-state fluoride shuttle batteries2Gas evolution in Ruddlesden–Popper-type intercalation cathodes in all-solid-state fluoride-ion-batteries: implications on battery performance and synthesis of highly oxidized oxyfluorides5Clarifying fluoride-ion conduction of La0.9Ba0.1F2.9 solid electrolyte0Fluoride-Ion Batteries: A Review of Recent Advances and Future Opportunities5Batteries for wearable and implantable biomedical devices: a comprehensive review3Engineering sintering-induced secondary phases in La 0.9 Ba 0.1 F 2.9 -based composite electrolytes for fluoride-ion conduction0Intercalation of I − and Cl − anions into a fluorinated graphite positive electrode for a halogen-based dual-ion battery0Room-Temperature Operation of Thin-Film All-Solid-State Fluoride Shuttle Batteries Using CeF 3 Anodes and Ag Cathodes0A dual-site phosphorus-based acceptor with hydrogen bond donor enables theoretically high-capacity F-ion batteries based on unusual Cu3+ fluorides0Fluoride ions as charge carriers in electrochemical energy storage0Fluoride‐Ion Batteries: Unraveling the Fundamental Science for Next‐Generation Energy Storage0

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18 direct citing papers saved.

  1. Fluorination of single-crystal copper electrodes in fluoride-ion batteries

    Journal of Materials Chemistry A · 2025-01-01

    Shunsuke Kobayashi, Kazuyuki Sato, Hsin‐Hui Huang, Daisaku Yokoe, T. Ogawa, Yuichi Ikuhara, Takeshi Abe, Akihide Kuwabara

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  2. Highly efficient atomic-scale design of CaF 2 for ultrafast fluoride-ion conduction

    Journal of Materials Chemistry A · 2025-01-01

    Yurong Liu, Zeyu Zhang, Xinyi Yan, Jinquan Hou, Zhi‐Wei Liu, Wenjie Liu, Xianyou Wang, Yong Pei, Zhenhua Yang

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  3. Lewis Acid–Base Synergistically Enhancing Practical Composite Electrolyte for Fluoride‐ion Batteries at Room Temperature

    Advanced Science · 2025-04-27

    Hong Cui, Xiao Pei Gao, Keyu Guo, Wu Liu, Bo Ouyang, Wenbin Yi

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  4. Interplay Between Stereochemically Active Lone Pair Repulsions, Sigma Hole Interactions, and Delocalized Redox Processes in Topochemical Fluoride‐Ion Insertion

    Angewandte Chemie International Edition · 2025-06-17

    Anindya Pakhira, Shruti Hariyani, George Agbeworvi, Jaime R. Ayala, Conan R. Weiland, Cherno Jaye, Daniel A. Fischer, Lu Ma, Sarbajit Banerjee

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  5. Interplay Between Stereochemically Active Lone Pair Repulsions, Sigma Hole Interactions, and Delocalized Redox Processes in Topochemical Fluoride‐Ion Insertion

    Angewandte Chemie · 2025-06-17

    Anindya Pakhira, Shruti Hariyani, George Agbeworvi, Jaime R. Ayala, Conan R. Weiland, Cherno Jaye, Daniel A. Fischer, Lu Ma, Sarbajit Banerjee

    Read original paper ↗ ·

  6. Ion‐Pump‐Regulated Highly Conductive Polymer Electrolyte to Enable the First All‐Solid‐State Rechargeable Fluoride‐Ion Pouch Cells

    Advanced Energy Materials · 2025-11-03

    Qijie Yu, Xiaorong Dong, Lian Xie, G. S. Li, Huiyan Zha, Qiang Yuan, Mengqi Zhang, Chilin Li

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  7. High-Capacity Intercalation-Based Anodes for Solid-State Fluoride-Ion Batteries Enabled by the Substitution of Conductive Carbon by Metallic Copper

    ACS Applied Energy Materials · 2025-11-07

    Tommi Hendrik Aalto, Tobias Widder, Eberhard J. Goering, Peter Nagel, Kerstin Wissel, Oliver Clemens

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  8. Catalytic activation of electrochemical fluoride-ion introduction into graphene-like graphite in all-solid-state fluoride shuttle batteries

    Electrochimica Acta · 2025-11-09

    Akane Inoo, Ryo Tatsukawa, Junichi Inamoto, Y. Matsuo

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  9. Gas evolution in Ruddlesden–Popper-type intercalation cathodes in all-solid-state fluoride-ion-batteries: implications on battery performance and synthesis of highly oxidized oxyfluorides

    Journal of Materials Chemistry A · 2025-11-20

    Tommi Hendrik Aalto, Jonas Jacobs, Felix Frey, Dörthe Schiewe, Oliver Clemens

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  10. Clarifying fluoride-ion conduction of La0.9Ba0.1F2.9 solid electrolyte

    Applied Physics Letters · 2025-12-01

    Chanachai Pattanathummasid, Toshiyuki Matsunaga, Shintaro Kobayashi, Shogo Kawaguchi, Yoshiharu Uchimoto

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  11. Fluoride-Ion Batteries: A Review of Recent Advances and Future Opportunities

    Electrochemical Energy Reviews · 2025-12-01

    Enhao Liu, Youkang Duan, Yu Li, Cong Peng, Wei Feng

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  12. Batteries for wearable and implantable biomedical devices: a comprehensive review

    Biosensors and Bioelectronics X · 2025-12-02

    Pasquale Gargiulo, Maria F. Gaele, Aniello Costantini, Tonia M Di Palma

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  13. Engineering sintering-induced secondary phases in La 0.9 Ba 0.1 F 2.9 -based composite electrolytes for fluoride-ion conduction

    Journal of Materials Chemistry A · 2026-01-01

    Enhao Liu, You‐Kang Duan, Cong Peng, Yu Li, Wei Feng

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  14. Intercalation of I − and Cl − anions into a fluorinated graphite positive electrode for a halogen-based dual-ion battery

    Chemical Communications · 2026-01-01

    Yueyuan Xu, Dongdong Lv, Wei Sun, Hongyu Wang, Yuhao Huang

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  15. Room-Temperature Operation of Thin-Film All-Solid-State Fluoride Shuttle Batteries Using CeF 3 Anodes and Ag Cathodes

    ACS Applied Energy Materials · 2026-05-17

    Katsutoshi Sakurai, Tomotaka Nakatani, Hisao Kiuchi, So Fujinami, Munekazu Motoyama, Koji Nakanishi, Yoshiyuki Morita, Zempachi Ogumi, Takeshi Abe

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  16. A dual-site phosphorus-based acceptor with hydrogen bond donor enables theoretically high-capacity F-ion batteries based on unusual Cu3+ fluorides

    Nano Energy · 2026-06-23

    Zhe Han, Decheng Li, Meng Lei, Chilin Li

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  17. Fluoride ions as charge carriers in electrochemical energy storage

    Nature Materials · 2026-07-10

    George Agbeworvi, Shruti Hariyani, Jing‐Xiang Cheng, Alice R. Giem, Anindya Pakhira, Victor Alexander Gomez, Sarbajit Banerjee

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  18. Fluoride‐Ion Batteries: Unraveling the Fundamental Science for Next‐Generation Energy Storage

    Advanced Energy Materials · 2026-08-04

    Xiao-feng LI, Yue Liu, Tianci Xu, Fenghua Zheng, Qichang Pan, Gemeng Liang, Qingyu Li, Hongqiang Wang, Sijiang Hu

    Read original paper ↗ ·
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