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RESEARCH PAPER · Small · 2024

A Noncentrosymmetric Metal‐Free Borophosphate: Achieving a Large Birefringence and Excellent Stability by Covalent‐Linkage

Hui‐Li Zhang, Dong‐Xue Jiao, Xiaofei Li, Chao He, Xi‐Ming Dong, Kai Huang, Jinhua Li, Xing‐Tao An, Qi Wei, Guo‐Ming Wang

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A Noncentrosymmetric Metal‐Free Borophosphate: Achieving a Large Birefringence and Excellent Stability by Covalent‐LinkageOriginalStructural characterisation and optical properties of new alkaline earth phosphate CaMg(P 4 O 12 ) and alkaline alumophosphate Cs 3 Al 4 (PO 4 ) 51Ultraviolet Nonlinear Optical Single Crystals of A Three‐Dimensional Chiral Covalent Framework Containing Te−O−B−O Bonds3Ultraviolet Nonlinear Optical Single Crystals of A Three‐Dimensional Chiral Covalent Framework Containing Te−O−B−O Bonds19Modeling of graphene like structure by utilizing phenanthrocarbazole for tailoring the second-order nonlinear optical properties2(C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions2Stimulus-responsive multifunctions in a zinc( ii ) sulfate complex: photochromism, photoswitching nonlinear optical properties, amine detection and visual film application9Deep ultraviolet transparent borophosphates LiAB 2 P 2 O 9 (A = NH 4 , K) and LiNaB 2 P 2 O 8 (OH) 2 ·H 2 O exhibiting a moderate second-harmonic generation response4[C(NH 2 ) 3 ] 2 [C 2 H 5 (C 2 O 4 )]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs5Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties11Chiral-Unit-Oriented Design of Non-π-Conjugated Noncentrosymmetric Phosphates with Short Absorption Edges4(C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption23Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence8Methyl substitution induced noncentrosymmetric alignment: a new thiazolium-based nonlinear optical crystal of HDT-N1S2Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting16[C(NH2)3]Y(HCOO)4: Constructing 3D Framework for Guanidine-Based UV Nonlinear Optical Crystals with Good Performance8Halide Ion-Directed Symmetry Control in π-Conjugated Molecular Crystals6Designing hybrid zinc-based ultraviolet nonlinear optical crystal with strong NLO response and dual-color luminescence via the integration of two different SHG-active genes6Room temperature phosphorescence and photochromism in a series of pyridine-based hybrid compounds2Computational study on optoelectronic properties of perylene diimide derivatives and their supramolecular complexes with guanosine monophosphate2Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity0Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation6Hybrid Cd 2+ -Based Halide Birefringent Crystals Achieving Tunable Dual-Color Emission for Multifunctional LED and Anticounterfeiting Applications2The Metal Coordination Effects on the Optoelectronic Properties of Perylene Diimide and Nucleotide Supramolecular Complex (GMP:PDI: Ag(I)/Co(II)/Zn(II)): Computational and Experimental Studies3C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties2Phosphonic Acid-Boronic Acid Anhydrides Demonstrate Class A–D β-Lactamase Inhibition2Effect of freeze-thaw cycles on thermal stability and fire retardancy of P/N/B wood composites1The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap2

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  1. Structural characterisation and optical properties of new alkaline earth phosphate CaMg(P 4 O 12 ) and alkaline alumophosphate Cs 3 Al 4 (PO 4 ) 5

    Dalton Transactions · 2024-01-01

    Maierhaba Abudoureheman, Jia Lv, Menglin Zhu, Hongheng Chen, Bo Wei, Lijun Jin, Qun Jing, Zhaohui Chen

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  2. Ultraviolet Nonlinear Optical Single Crystals of A Three‐Dimensional Chiral Covalent Framework Containing Te−O−B−O Bonds

    Angewandte Chemie · 2024-07-22

    Miaomiao Xue, Lei Zhang, Xin Meng, Jinglun Yang, Yan‐Ping He, Chun‐Sing Lee, Jian Zhang, Qichun Zhang

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  3. Ultraviolet Nonlinear Optical Single Crystals of A Three‐Dimensional Chiral Covalent Framework Containing Te−O−B−O Bonds

    Angewandte Chemie International Edition · 2024-07-22

    Miaomiao Xue, Lei Zhang, Xin Meng, Jinglun Yang, Yan‐Ping He, Chun‐Sing Lee, Jian Zhang, Qichun Zhang

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  4. Modeling of graphene like structure by utilizing phenanthrocarbazole for tailoring the second-order nonlinear optical properties

    Materials Science in Semiconductor Processing · 2024-09-25

    Santosh Kumar Yadav, Rajneesh Kumar, Ajeet Singh

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  5. (C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions

    Inorganic Chemistry · 2024-10-19

    Yuhang Wang, De-Xuan Jiang, De‐Xuan Liu, Fu-Ying Li, He Zhao, Jie Pan, Qi Wei, Li Wei, Guo‐Yu Yang

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  6. Stimulus-responsive multifunctions in a zinc( ii ) sulfate complex: photochromism, photoswitching nonlinear optical properties, amine detection and visual film application

    Journal of Materials Chemistry C · 2024-10-31

    Shuai Liang, Shi-Kun Yan, Yu-Xuan Wen, Yanrui Zhao, Jin Zhang, Ji‐Xiang Hu, Guo-Ming Wang

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  7. Deep ultraviolet transparent borophosphates LiAB 2 P 2 O 9 (A = NH 4 , K) and LiNaB 2 P 2 O 8 (OH) 2 ·H 2 O exhibiting a moderate second-harmonic generation response

    Journal of Materials Chemistry C · 2024-12-23

    Huanhuan Zhao, Chenxu Li, Juanjuan Lu, Zhihua Yang, Jian Wei Han, Shilie Pan

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  8. [C(NH 2 ) 3 ] 2 [C 2 H 5 (C 2 O 4 )]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs

    Chemical Communications · 2025-01-01

    Yu-Ming Pan, Xinyou An, Zhi Gang Fang

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  9. Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties

    Chemistry of Materials · 2025-01-20

    Yunseung Kuk, Zhiyong Bai, Yang Li, Kang Min Ok

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  10. Chiral-Unit-Oriented Design of Non-π-Conjugated Noncentrosymmetric Phosphates with Short Absorption Edges

    The Journal of Physical Chemistry Letters · 2025-02-17

    Kai Huang, Xi-Ming Dong, Chao He, Zi-Xuan Zhao, Wei Chen, Hui‐Yan Zhao, Ji‐Xiang Hu, Qi Wei, Guo‐Ming Wang

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  11. (C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption

    Chemical Engineering Journal · 2025-03-09

    Chuanying Shen, Chenyi Zhang, Chenyi Zhang, Qiwei Xing, Defu Sun, Kui Wu, Bingbing Zhang, Jiyang Wang, Jiyang Wang, Duanliang Wang

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  12. Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence

    Chemistry - A European Journal · 2025-04-07

    Yang Li, Jihyun Lee, Kang Min Ok

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  13. Methyl substitution induced noncentrosymmetric alignment: a new thiazolium-based nonlinear optical crystal of HDT-N1S

    Journal of Molecular Structure · 2025-05-17

    Bin Li, Xinyuan Zhang, Zhanggui Hu, Ning Ye

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  14. Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting

    Advanced Optical Materials · 2025-05-21

    Duanliang Wang, Qiwei Xing, Defu Sun, Chuanrui Zhu, Kui Wu, Bingbing Zhang, Guangxia Liu, Jiyang Wang, Chuanying Shen

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  15. [C(NH2)3]Y(HCOO)4: Constructing 3D Framework for Guanidine-Based UV Nonlinear Optical Crystals with Good Performance

    Inorganic Chemistry · 2025-06-02

    Jiayin Tang, Xin Wen, Huili Zhang, Yuchen Yan, Jindong Chen, Shihui Ma, Min Luo, Chensheng Lin, Ning Ye, Guang Peng

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  16. Halide Ion-Directed Symmetry Control in π-Conjugated Molecular Crystals

    Inorganic Chemistry · 2025-06-17

    Yu Zhang, Han Luo, Shunke Zhang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  17. Designing hybrid zinc-based ultraviolet nonlinear optical crystal with strong NLO response and dual-color luminescence via the integration of two different SHG-active genes

    Materials Today Chemistry · 2025-07-24

    Kang Yang, Duanliang Wang, Chuanrui Zhu, Kui Wu, Guangxia Liu, Jiyang Wang, Chuanying Shen

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  18. Room temperature phosphorescence and photochromism in a series of pyridine-based hybrid compounds

    CrystEngComm · 2025-12-09

    Tong Liu, Xu Jing, Jia-Li Chen, Xue-Yao Ding, Song‐De Han, Zhen‐Zhen Xue, Honghua Huang, Jie Pan

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  19. Computational study on optoelectronic properties of perylene diimide derivatives and their supramolecular complexes with guanosine monophosphate

    Inorganic Chemistry Communications · 2025-12-27

    Ali Raza Ayub, Salba, Muhammad Zeshan, Karim Youssef Nabat, Javed Iqbal M, Hui Li

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  20. Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity

    Materials Chemistry Frontiers · 2026-01-01

    Peng Zhuang, Chun‐Li Hu, Bing‐Ping Yang, Jiang‐Gao Mao

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  21. Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation

    Advanced Optical Materials · 2026-01-09

    Limin Duan, Xiaomin Zhang, Yan Chun Xiao, Daqing Yang, Y. Y. Wang, Bingbing Zhang

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  22. Hybrid Cd 2+ -Based Halide Birefringent Crystals Achieving Tunable Dual-Color Emission for Multifunctional LED and Anticounterfeiting Applications

    ACS Applied Materials & Interfaces · 2026-01-14

    Duanliang Wang, Qiwei Xing, Zhengao Xie, Xunwang Yan, Chuanrui Zhu, Bingbing Zhang, Xiao‐Wu Lei, Chuanying Shen

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  23. The Metal Coordination Effects on the Optoelectronic Properties of Perylene Diimide and Nucleotide Supramolecular Complex (GMP:PDI: Ag(I)/Co(II)/Zn(II)): Computational and Experimental Studies

    Inorganic Chemistry · 2026-01-29

    Ali Raza Ayub, Salba, Muhammad Zeshan, Karim Youssef Nabat, Javed Iqbal M, Hui Li

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  24. C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties

    Advanced Optical Materials · 2026-02-28

    Chuanying Shen, Jiaxi Ding, Zhengao Xie, Kang Yang, Xunwang Yan, Bingbing Zhang, Kui Wu, Jiyang Wang, Duanliang Wang

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  25. Phosphonic Acid-Boronic Acid Anhydrides Demonstrate Class A–D β-Lactamase Inhibition

    The Journal of Organic Chemistry · 2026-02-28

    Elisa Ospanow, Mirele Barsoum, Carol A. Tanner, Martin Lanteigne, Bradley Haltli, Gary I. Dmitrienko, David L. Jakeman

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  26. Effect of freeze-thaw cycles on thermal stability and fire retardancy of P/N/B wood composites

    Journal of Building Engineering · 2026-03-11

    Xi Deng, Kaiyuan Li, Yongqiang Ye, Xinke Huo, Wei He, Fei Xiao

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  27. The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap

    Applied Physics Letters · 2026-06-15

    Xinyue Shi, Xueqing Liu, Yipeng Pang, Yuan Fang, Degao Zhong, Bing Teng, Y Huang, Zhoubin Lin, Shijia Sun

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