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RESEARCH PAPER · Science China Chemistry · 2022

Designing a deep-UV nonlinear optical monofluorophosphate

Qingran Ding, Xingyu Zhang, Zheshuai Lin, Zheyao Xiong, Yusong Wang, Xifa Long, Sangen Zhao, Maochun Hong, Junhua Luo

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Designing a deep-UV nonlinear optical monofluorophosphateOriginalRecent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7Clamping effect driven design and fabrication of new infrared birefringent materials with large optical anisotropy45Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains5Deep-ultraviolet (DUV) nonlinear optical (NLO) crystals: An application in photonic technologies29Form-controlled synthesis of a polymorphic nonlinear optical crystal CsMgPO 4 ·6H 2 O3Hydrated and fluorinated potassium scandium phosphates: topology symmetry analysis and structure prediction1KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties37From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity11Theoretical insight on structure, electronic, and optical properties of two d 0–d 10 electron transition-metal oxyhalides SHG materials2(C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy9MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction1CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”11A HTO‐Type Nonlinear Optical Fluorophosphate with Ultrawide Bandgap16K4CuO2Cl2: A new alkali metal copper oxyhalide via aqueous solution processes0Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge1Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations2Tuning the Anionic Configuration in ASc2(P2O7)2 (A = Ba, Pb) through A-Site Cationic Coordination Engineering0Hydrothermal Synthesis of New Phosphate K2Sc(OH)[PO3(OH)]2, Structure, and Prediction of Variants0Alternating cations intercalation-type chiral-polar hybrid perovskites for efficient self-powered polarization detection0Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence18Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV nonlinear optical material due to π-conjugated cation and hydrogen bonding intervention1A Strategy for Enhancing the Optical Anisotropy of Phosphates via Tetrahedral Unit Modification0

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  1. Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response

    Chinese Journal of Structural Chemistry · 2023-02-13

    Boxuan Zhang, Zhaohui Chen

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  2. Clamping effect driven design and fabrication of new infrared birefringent materials with large optical anisotropy

    Science China Chemistry · 2023-03-13

    Linan Wang, Chenchen Tu, Hongbo Gao, Jiazheng Zhou, Hongshan Wang, Zhihua Yang, Shilie Pan, Junjie Li

    Read original paper ↗ ·

  3. Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains

    Inorganic Chemistry · 2023-06-12

    Ru‐Ling Tang, Lei Huai, Wenlong Liu

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  4. Deep-ultraviolet (DUV) nonlinear optical (NLO) crystals: An application in photonic technologies

    Optical Materials · 2023-08-23

    Biswajit Dalai, Sarat Kumar Dash

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  5. Form-controlled synthesis of a polymorphic nonlinear optical crystal CsMgPO 4 ·6H 2 O

    CrystEngComm · 2024-01-01

    Sheng Lv, Liangcheng Song, Yanling Xu, Hongyan Cui, Haoyu Cheng, Zhihao Wang, Cun Zhu, Chunhui Yang

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  6. Hydrated and fluorinated potassium scandium phosphates: topology symmetry analysis and structure prediction

    New Journal of Chemistry · 2024-01-01

    A. P. Topnikova, Elena L. Belokoneva, Olga V. Dimitrova, Anatoly S. Volkov, Sergey Yu. Stefanovich, Viktor V. Maltsev, Leokadiya V. Zorina

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  7. KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties

    Chemical Science · 2024-01-01

    Mei Yan, Chun‐Li Hu, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  8. From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity

    Inorganic Chemistry · 2024-06-04

    Mei Yan, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  9. Theoretical insight on structure, electronic, and optical properties of two d 0–d 10 electron transition-metal oxyhalides SHG materials

    Journal of Physics D Applied Physics · 2024-06-12

    Jinyu Hu, Jiamei Zhang, Huiyan Zhao, Chao He, Xihu Wang

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  10. (C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy

    Inorganic Chemistry · 2024-07-31

    Yi‐Lei Lv, Liang Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  11. MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction

    The Journal of Physical Chemistry C · 2024-11-26

    Xue Bai, Xin Su, Wenqi Jin

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  12. CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”

    Inorganic Chemistry Frontiers · 2025-01-01

    Jie Gou, Yaolong Zhu, Xin Su, Can Hui Yang, YunJie Wang, Qingwen Zhu, Yi Xiong, Qi Wu

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  13. A HTO‐Type Nonlinear Optical Fluorophosphate with Ultrawide Bandgap

    Small · 2025-01-09

    Shanshan Chen, Zhiyong Bai, Xianyu Song, Tao Ouyang, Yanqiang Li, Qingran Ding, Han Wang, Wen‐Tong Chen, Junhua Luo, Sangen Zhao

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  14. K4CuO2Cl2: A new alkali metal copper oxyhalide via aqueous solution processes

    Solid State Sciences · 2025-02-22

    Li Zhang, Junliang Sun, Xianji Qiao

    Read original paper ↗ ·

  15. Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge

    Journal of Molecular Structure · 2025-04-08

    Xiaotian Ma, Shaohua Liu, Xifa Long, Yun Mo Yang

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  16. Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations

    Inorganic Chemistry · 2025-08-14

    Yuquan Feng, Zhiguo Zhong, Shuyang Chen, Sujuan Jin, Zhaohui Meng, Hongwei Wang

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  17. Tuning the Anionic Configuration in ASc2(P2O7)2 (A = Ba, Pb) through A-Site Cationic Coordination Engineering

    Inorganic Chemistry · 2025-09-05

    Bao Jiang, Hongheng Chen, Xianmeng He, Lei Wu, Xueyin Fu, Yi Huang, Qun Jing, Zhaohui Chen

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  18. Hydrothermal Synthesis of New Phosphate K2Sc(OH)[PO3(OH)]2, Structure, and Prediction of Variants

    Crystallography Reports · 2025-12-01

    A. P. Topnikova, E. L. Belokoneva, A. S. Volkov, О.В. Димитрова, Natalia V. Zubkova

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  19. Alternating cations intercalation-type chiral-polar hybrid perovskites for efficient self-powered polarization detection

    Science China Chemistry · 2026-01-04

    Zeng‐Kui Zhu, Ziyi Qian, Tingting Zhu, Jianbo Wu, Panpan Yu, Ying Zeng, Hui‐Ping Xiao, Huawei Yang, Yueying Wang, Wenhui Wu, Chengmin Ji, Lina Li, Junhua Luo

    Read original paper ↗ ·

  20. Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence

    Science China Chemistry · 2026-01-04

    Chunmei Huang, Xuan Pang, Fuming M. Li, Shumei Cao, Shilie Pan, Miriding Mutailipu

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  21. Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV nonlinear optical material due to π-conjugated cation and hydrogen bonding intervention

    Chinese Journal of Structural Chemistry · 2026-03-07

    Lei Wu, Enshen Wang, Bao Jiang, Xueyin Fu, Kechen Sun, Maierhaba Abudoureheman, Zhaohui Chen, Qun Jing, Yuhong Su

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  22. A Strategy for Enhancing the Optical Anisotropy of Phosphates via Tetrahedral Unit Modification

    Crystal Growth & Design · 2026-06-26

    Bao Jiang, Hongheng Chen, Lei Wu, Xueyin Fu, Maierhaba Abudoureheman, Yi Huang, Ailijiang Abudurusuli, Qun Jing, Xue Yu, Zhaohui Chen

    Read original paper ↗ ·
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