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RESEARCH PAPER · Journal of Materials Chemistry C · 2021

β-BaGa 4 Se 7 : a promising IR nonlinear optical crystal designed by predictable structural rearrangement

Zhen Qian, Qiang Bian, Hongping Wu, Hongwei Yu, Zheshuai Lin, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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β-BaGa 4 Se 7 : a promising IR nonlinear optical crystal designed by predictable structural rearrangementOriginalAn excellent lead oxyiodide with a strong second-harmonic generation response and a large birefringence induced by the oriented arrangement of highly distorted [PbO 4 I 2 ] polyhedra13APb 2 (C 7 H 3 NO 4 ) 2 I (A = K, Rb, Cs): rare stable nonlinear optical crystals with second-harmonic generation response and highly distorted lead core coordination polyhedra2Na 4 Ga 8 S 14 : a Ga-enriched wide band gap ternary alkali-metal sulfide with unique [Ga 12 S 42 ] 12-membered rings2Rational design via dual-site aliovalent substitution leads to an outstanding IR nonlinear optical material with well-balanced comprehensive properties68The exploration of new infrared nonlinear optical crystals based on the polymorphism of BaGa 4 S 731Design of a diamond-like infrared nonlinear optical material LiBS2 with ultra-wide band gap11The Combination of Structure Prediction and Experiment for the Exploration of Alkali‐Earth Metal‐Contained Chalcopyrite‐Like IR Nonlinear Optical Material104BaSi7P10 and SrSi7P10: Two Infrared Nonlinear Optical Phosphides with T2 Supertetrahedra Exhibiting Strong Second‐Harmonic Generation Effects22A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications114Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain2LiAlS2: A promising infrared frequency-conversion material with ultrawide band gap and high laser-induced damage threshold19AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units152Syntheses, structures, and characterization of new heteroanionic chalcohalides: Na2Ba17In8Q21F18 (Q = S, Se), KBa2InQ3F2 (Q = S, Se)5AeMg6Ga6S16 (Ae = Ca, Sr, Ba): The First Double Alkaline‐Earth Metal Chalcogenides with Excellent Performances29The Antiperovskite‐Type Oxychalcogenides Ae3Q[GeOQ3] (Ae = Ba, Sr; Q = S, Se) with Large Second Harmonic Generation Responses and Wide Band Gaps68γ-P 4 S 3 I 2 : a new metal-free infrared second-order nonlinear optical crystal designed by polymorphism strategy17Structural features of Li0.55Ag0.45InSe2 and Li0.37Ag0.63InSe2 crystals7Nitrides: a promising class of nonlinear optical material candidates9Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties12[Ba4(S2)][ZnGa4S10]: Design of an Unprecedented Infrared Nonlinear Salt‐Inclusion Chalcogenide with Disulfide‐Bonds36NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances13A potassium lead 2-methylmalonate-iodide nonlinear optical crystal with strong second-harmonic generation response and large birefringence2Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Effectively designing infrared nonlinear optical materials with magnetism, MMn 6 Ga 6 S 16 (M = Ca, Sr, Ba, and Pb), aided by stable open frameworks13External electric field driven electronic structures: tunable nonlinear optical properties of helical bilayer nanographenes2Cs 3 In(In 4 Se 7 )(P 2 Se 6 ): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting55Cs3In(In4Se7)(P2Se6): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting2[Na2PbI][Ga7S12]: Combining Diamond-Like Anionic Framework with Polycationic Chain toward Achieving Remarkable Nonlinear Optical Response21Phase Transitions and Nonlinear Optical Property Modifications in BaGa 4 Se 77ACuGa 6 S 10 (A = Rb, Cs): Design and Synthesis of Two New Cavity‐Chalcopyrite Chalcogenides Based on “Iterative Substitution” Strategy4Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy4Hetero‐Anionic Oxychalcogenides with Structures and Properties Tuned by the O:S Ratio14AI2Mg3Ga12S22 (AI = K, Rb): T2-type supertetrahedra coupled with [MgS6] octahedra for designing wide-band gap infrared nonlinear optical materials with well-balanced properties16Two-in-one: assembling hybrid supertetrahedra chromophores and achieving high-performance “hexagonal warriors” in nonlinear optical crystals6Synergically Assembling Advantageous Groups toward High‐Performance Infrared Nonlinear Optical Materials A II CdSiSe 4 (A II = Sr, Ba)40SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold4NaAg3Ga8S14: A new diamond-like framework infrared nonlinear optical material derived from AgGaS26Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties6[Rb 4 Cl][Cd 11 In 9 Se 26 ]: a salt inclusion chalcogenide with a diamond-like framework for infrared nonlinear optics0ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）0Selenium-Based Molecular Cage Crystal β-P 4 Se 3 Br 2 : A Promising Candidate for Infrared Nonlinear Optical Applications1Topology-Guided Discovery of BaIn 2 Si 7 P 12 : A Quaternary Diamond-like Framework Phosphide with Giant Second-Harmonic Generation and High Laser-Induced Damage Threshold22K 3 Mg 2 [K 6 MgCl 3 ][Ga 20 S 36 ]: A Diamond-like Framework Based on Mixed-Type Supertetrahedra for Excellent Nonlinear Optical Property1Design of a High-Performance Infrared Nonlinear Optical Crystal via a Multiple Flexible-Group Synergistic Polarization Strategy10A new phase and transformation mechanism in BaGa4Se7 infrared nonlinear optical crystal0

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  1. An excellent lead oxyiodide with a strong second-harmonic generation response and a large birefringence induced by the oriented arrangement of highly distorted [PbO 4 I 2 ] polyhedra

    Inorganic Chemistry Frontiers · 2022-01-01

    Ziqi Zhou, Ruibiao Fu, Hong‐Xin Tang, Zuju Ma, Xin‐Tao Wu

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  2. APb 2 (C 7 H 3 NO 4 ) 2 I (A = K, Rb, Cs): rare stable nonlinear optical crystals with second-harmonic generation response and highly distorted lead core coordination polyhedra

    Inorganic Chemistry Frontiers · 2022-01-01

    Zilong Geng, Ziqi Zhou, Hong‐Xin Tang, Wen-Xiu Bao, Ruibiao Fu, Xin‐Tao Wu

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  3. Na 4 Ga 8 S 14 : a Ga-enriched wide band gap ternary alkali-metal sulfide with unique [Ga 12 S 42 ] 12-membered rings

    Dalton Transactions · 2022-01-01

    Ling Luo, Linan Wang, Chen Bai, Jiazheng Zhou, Lai Wei, Xin Su

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  4. Rational design via dual-site aliovalent substitution leads to an outstanding IR nonlinear optical material with well-balanced comprehensive properties

    Chemical Science · 2022-01-01

    Hedi Yang, Mao‐Yin Ran, Shenghua Zhou, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  5. The exploration of new infrared nonlinear optical crystals based on the polymorphism of BaGa 4 S 7

    Inorganic Chemistry Frontiers · 2022-01-01

    Zhen Qian, Haonan Liu, Yu-Jie Zhang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  6. Design of a diamond-like infrared nonlinear optical material LiBS2 with ultra-wide band gap

    Journal of Alloys and Compounds · 2022-01-19

    Kewang Zhang, Dongdong Chu, Congwei Xie, Zhihua Yang, Shilie Pan

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  7. The Combination of Structure Prediction and Experiment for the Exploration of Alkali‐Earth Metal‐Contained Chalcopyrite‐Like IR Nonlinear Optical Material

    Advanced Science · 2022-04-11

    Peng Wang, Yu Chu, Abudukadi Tudi, Congwei Xie, Zhihua Yang, Shilie Pan, Junjie Li

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  8. BaSi7P10 and SrSi7P10: Two Infrared Nonlinear Optical Phosphides with T2 Supertetrahedra Exhibiting Strong Second‐Harmonic Generation Effects

    Advanced Optical Materials · 2022-06-05

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  9. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  10. Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain

    Inorganic Chemistry · 2022-09-20

    Peng Wang, Maierhaba Abudoureheman, Kewang Zhang, Juanjuan Zheng, Zhaohui Chen, Qi Wu

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  11. LiAlS2: A promising infrared frequency-conversion material with ultrawide band gap and high laser-induced damage threshold

    Science China Materials · 2022-11-08

    Guangmao Li, Zhihua Yang, Shilie Pan

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  12. AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units

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    Ling Luo, Linan Wang, Jianbang Chen, Jiazheng Zhou, Zhihua Yang, Shilie Pan, Junjie Li

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  13. Syntheses, structures, and characterization of new heteroanionic chalcohalides: Na2Ba17In8Q21F18 (Q = S, Se), KBa2InQ3F2 (Q = S, Se)

    Journal of Alloys and Compounds · 2022-11-22

    Dong Gao, Xiao Ji, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  14. AeMg6Ga6S16 (Ae = Ca, Sr, Ba): The First Double Alkaline‐Earth Metal Chalcogenides with Excellent Performances

    Advanced Optical Materials · 2022-11-24

    Jiale Chen, Yu-Jie Zhang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  15. The Antiperovskite‐Type Oxychalcogenides Ae3Q[GeOQ3] (Ae = Ba, Sr; Q = S, Se) with Large Second Harmonic Generation Responses and Wide Band Gaps

    Advanced Science · 2022-12-05

    Shaoxin Cui, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  16. γ-P 4 S 3 I 2 : a new metal-free infrared second-order nonlinear optical crystal designed by polymorphism strategy

    Inorganic Chemistry Frontiers · 2022-12-19

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  17. Structural features of Li0.55Ag0.45InSe2 and Li0.37Ag0.63InSe2 crystals

    Journal of Crystal Growth · 2022-12-21

    Sergey I. Lobanov, Ksenia E. Korzhneva, S. А. Gromilov, A. S. Sukhikh, L. I. Isaenko

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  18. Nitrides: a promising class of nonlinear optical material candidates

    Materials Chemistry Frontiers · 2023-01-01

    Xin Lei Zhao, Chensheng Lin, Haotian Tian, Chao Wang, Ning Ye, Min Luo

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  19. Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties

    Dalton Transactions · 2023-01-01

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  20. [Ba4(S2)][ZnGa4S10]: Design of an Unprecedented Infrared Nonlinear Salt‐Inclusion Chalcogenide with Disulfide‐Bonds

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  21. NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances

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  22. A potassium lead 2-methylmalonate-iodide nonlinear optical crystal with strong second-harmonic generation response and large birefringence

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  23. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

    Coordination Chemistry Reviews · 2023-12-21

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  24. Effectively designing infrared nonlinear optical materials with magnetism, MMn 6 Ga 6 S 16 (M = Ca, Sr, Ba, and Pb), aided by stable open frameworks

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  25. External electric field driven electronic structures: tunable nonlinear optical properties of helical bilayer nanographenes

    New Journal of Chemistry · 2024-01-01

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  26. Cs 3 In(In 4 Se 7 )(P 2 Se 6 ): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting

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  27. Cs3In(In4Se7)(P2Se6): A Multi‐Chromophore Chalcogenide with Excellent Nonlinear Optical Property Designed by Group Grafting

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  28. [Na2PbI][Ga7S12]: Combining Diamond-Like Anionic Framework with Polycationic Chain toward Achieving Remarkable Nonlinear Optical Response

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  29. Phase Transitions and Nonlinear Optical Property Modifications in BaGa 4 Se 7

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  30. ACuGa 6 S 10 (A = Rb, Cs): Design and Synthesis of Two New Cavity‐Chalcopyrite Chalcogenides Based on “Iterative Substitution” Strategy

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  31. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

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  32. Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy

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  34. AI2Mg3Ga12S22 (AI = K, Rb): T2-type supertetrahedra coupled with [MgS6] octahedra for designing wide-band gap infrared nonlinear optical materials with well-balanced properties

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  37. SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold

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  38. NaAg3Ga8S14: A new diamond-like framework infrared nonlinear optical material derived from AgGaS2

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  40. [Rb 4 Cl][Cd 11 In 9 Se 26 ]: a salt inclusion chalcogenide with a diamond-like framework for infrared nonlinear optics

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  42. Selenium-Based Molecular Cage Crystal β-P 4 Se 3 Br 2 : A Promising Candidate for Infrared Nonlinear Optical Applications

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