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RESEARCH PAPER · Angewandte Chemie International Edition · 2025

pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals

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pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical CrystalsOriginalA mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Cation-dominated second-harmonic generation in chiral tetrahydro-1-naphthylammonium halides0Regulating KBBF-like structures via a charge-assisted hydrogen-bonded framework to enable easily grown ultraviolet nonlinear optical crystals0Solving the long-standing hygroscopicity and thermal stability issues of the nonlinear optical crystal α-LiIO 3 via homogeneous cation exchange0The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4Selenium-Based Molecular Cage Crystal β-P 4 Se 3 Br 2 : A Promising Candidate for Infrared Nonlinear Optical Applications1From Coplanarity to Coaxiality: A Linearity-Oriented Design Paradigm for Ultrahigh Ultraviolet Birefringent Inorganic Crystals4Breaking Layered Limitations via Electrostatic-to-Covalent Conversion toward Three-Dimensional T2-Cluster-Based Chalcogenides7The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap2Achieving Excellent Nonlinear Optics in α ‑Ba 2 Ge 4 S 10 via Flux‑Induced Symmetry Breaking1Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal0Steric‐Guided Coordination Engineering Enables Significantly Optimized Optical Anisotropy via Sulfur‐Driven [C 5 H 5 NS] Birefringence‐Active Groups0Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals0

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  1. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  2. Cation-dominated second-harmonic generation in chiral tetrahydro-1-naphthylammonium halides

    Dalton Transactions · 2026-01-01

    Youpei Zhang, Junjie Guan, Junhua Zhang, X Q Li, J Z Zhao, Yimin Yang, Yongshen Zheng, Jialiang Xu

    Read original paper ↗ ·
  3. Regulating KBBF-like structures via a charge-assisted hydrogen-bonded framework to enable easily grown ultraviolet nonlinear optical crystals

    Chemical Science · 2026-01-01

    Mingshu Zhang, Shuya Zhao, Zhen‐Cheng Wu, Yue Yin, Zheyu Zhang, Jiafeng Chen, Sheng‐Ping Guo, Yan Zhou

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  4. Solving the long-standing hygroscopicity and thermal stability issues of the nonlinear optical crystal α-LiIO 3 via homogeneous cation exchange

    Inorganic Chemistry Frontiers · 2026-01-01

    Jiahao Wan, Zhengli Liang, Xiuying Zhang, Hongming Liu, Le Yang, Ping Wang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Qi Wu

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  5. The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals

    Chemical Society Reviews · 2026-01-01

    Hangwei Jia, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  6. Selenium-Based Molecular Cage Crystal β-P 4 Se 3 Br 2 : A Promising Candidate for Infrared Nonlinear Optical Applications

    Inorganic Chemistry · 2026-01-14

    Xingwang Zhu, Chao Wang, Chensheng Lin, Cheng Hu, Shunda Yang, Tao Yan, Min Luo

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  7. From Coplanarity to Coaxiality: A Linearity-Oriented Design Paradigm for Ultrahigh Ultraviolet Birefringent Inorganic Crystals

    Journal of the American Chemical Society · 2026-05-04

    Congcong Jin, Yang Li, Chong‐An Chen, Wei Zeng, S. D. Lee, Kang Min Ok

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  8. Breaking Layered Limitations via Electrostatic-to-Covalent Conversion toward Three-Dimensional T2-Cluster-Based Chalcogenides

    Journal of the American Chemical Society · 2026-06-08

    Shao‐Min Pei, Jun-Long Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  9. The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap

    Applied Physics Letters · 2026-06-15

    Xinyue Shi, Xueqing Liu, Yipeng Pang, Yuan Fang, Degao Zhong, Bing Teng, Y Huang, Zhoubin Lin, Shijia Sun

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  10. Achieving Excellent Nonlinear Optics in α ‑Ba 2 Ge 4 S 10 via Flux‑Induced Symmetry Breaking

    Small · 2026-06-24

    Ying Guo, Guo‐Qiang Wang, Yan Guo, Xiao‐Ming Jiang, B C Liu, Guo‐Cong Guo

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  11. Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal

    Angewandte Chemie International Edition · 2026-07-24

    Yan Guo, Ming‐Xin Li, Ying Guo, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  12. Steric‐Guided Coordination Engineering Enables Significantly Optimized Optical Anisotropy via Sulfur‐Driven [C 5 H 5 NS] Birefringence‐Active Groups

    Small · 2026-08-14

    Jiachen Lu, Chong‐An Chen, Wei Zeng, Kang Min Ok

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  13. Coordination-Mode-Modulated Symmetry Breaking for Nonlinear Optical Crystals

    Inorganic Chemistry · 2026-08-24

    Lan Wang, Zhen Qin, Shu‐Fang Li, Xin-Ran Hao, Chu Chu, Bingbing Zhang, Dong Yan

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