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RESEARCH PAPER · Chinese Chemical Letters · 2024

π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performance

Miao‐Bin Xu, Qianqian Chen, Qian-Qian Chen, Bingxuan Li, Ke-Zhao Du, Jin Chen

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π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performanceOriginalExploring short-wavelength birefringent crystals via triggering cooperative arrangement between different π-conjugated groups8CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”11Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Synergistic engineering of ultraviolet metal-free crystals with exceptional birefringence via pyridine-derived dimers14A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy22A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy5From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal4From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal28Zero-Dimensional Plastic Phase Transition Iron-Based Compounds with High T c and Switchable SHG Responses5Tuning Birefringence in Supramolecular Mg-PDA Frameworks: Modulating Bonding and Layer Connectivity0Na[B3IO7(OH)] and Na2[B4IO9](IO3): Explorations of Boroiodates with Strong Second Harmonic Generation Response and Large Birefringence54La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13Breaking the Birefringence Barrier in B–O Crystals via B–C π-scaffolding36Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate14Organic cation functionalization of zinc-based hybrid perovskite materials on synergistic modulation of phase transition and nonlinear optical properties3Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals27Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response7Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap3Exceptional Enhancement of Optical Anisotropy Achieved via the Strategy of Combining Rigid Groups with High Symmetry and π‐Conjugated Organic Groups in Hybrid Fluorides33K2HGa(IO3)6: A new member of iodate families with [M(IO3)6] building blocks0[ICl 4 ] − : A large anisotropic planar anion group produces giant birefringence2Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution1Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Noncovalent Assembly Engineering Achieves Excellent Birefringence in Crystals0Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals1Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design0IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F20A Pyrazinamide–Iodic Acid Cocrystal Exhibiting Strong Second Harmonic Generation for Nonlinear Optics0Halogen‐Bond Dimensionality Controls π–π Packing to Unlock Ultrahigh Second‐Harmonic Generation and Giant Birefringence0

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29 direct citing papers saved.

  1. Exploring short-wavelength birefringent crystals via triggering cooperative arrangement between different π-conjugated groups

    Chemical Communications · 2024-01-01

    Xiao Wang, Tingwen Han, Kenneth Reinhard Poeppelmeier, Xueling Hou, Shilie Pan, Fangfang Zhang

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  2. CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”

    Inorganic Chemistry Frontiers · 2025-01-01

    Jie Gou, Yaolong Zhu, Xin Su, Can Hui Yang, YunJie Wang, Qingwen Zhu, Yi Xiong, Qi Wu

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  3. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  4. Synergistic engineering of ultraviolet metal-free crystals with exceptional birefringence via pyridine-derived dimers

    Chemical Science · 2025-01-01

    Jiachen Lu, Kang Min Ok

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  5. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie International Edition · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Fang Kong, Jiang‐Gao Mao

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  6. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  7. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie · 2025-02-22

    Xinyang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  8. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie International Edition · 2025-02-22

    Xin‐Yang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  9. Zero-Dimensional Plastic Phase Transition Iron-Based Compounds with High T c and Switchable SHG Responses

    Inorganic Chemistry · 2025-03-14

    Jing Wei, Qiulan Tan, Xi-Xi Wang, Rong-Jie Hao, Yi-Xin Luo, Yun‐Zhi Tang, Nan Ma, Xiao‐Wei Fan, Yu‐Hui Tan

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  10. Tuning Birefringence in Supramolecular Mg-PDA Frameworks: Modulating Bonding and Layer Connectivity

    Inorganic Chemistry · 2025-03-21

    Miao‐Bin Xu, Ning Yu, Jiajia Li, Mingchang Wang, Mo-Fan Zhuo, Ke‐Zhao Du, Jin Chen, Yan Chen

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  11. Na[B3IO7(OH)] and Na2[B4IO9](IO3): Explorations of Boroiodates with Strong Second Harmonic Generation Response and Large Birefringence

    Journal of the American Chemical Society · 2025-04-07

    Ya-Lan Deng, Chun‐Li Hu, Xiang Xu, Mingzhi Zhang, Jiang‐Gao Mao

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  12. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  13. Breaking the Birefringence Barrier in B–O Crystals via B–C π-scaffolding

    Journal of the American Chemical Society · 2025-07-04

    Jiajia Li, Miao‐Bin Xu, Mingchang Wang, Zhi Wei Lin, Yuan Hua Lin, Yun-Xia Hu, Jia-Min Lian, Jin Chen, Ke‐Zhao Du

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  14. Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate

    Chinese Journal of Structural Chemistry · 2025-07-29

    Ziqi Chen, Miriding Mutailipu

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  15. Organic cation functionalization of zinc-based hybrid perovskite materials on synergistic modulation of phase transition and nonlinear optical properties

    Journal of Molecular Structure · 2025-08-18

    Xiuli You, Siqi Yang, Feiyan Liu, Guoyong Chen, Mingjun Zou, Guobing Yan, Xing‐Cong Wang, Zhenhong Wei

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  16. Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals

    Journal of the American Chemical Society · 2025-09-16

    Jiachen Lu, Yang Li, Kang Min Ok

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  17. Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response

    Inorganic Chemistry · 2025-09-17

    Mingchang Wang, Jiajia Li, Yan Chen, Ke‐Zhao Du, Jin Chen

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  18. Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap

    Inorganic Chemistry · 2025-09-30

    Dandan Zhou, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  19. Exceptional Enhancement of Optical Anisotropy Achieved via the Strategy of Combining Rigid Groups with High Symmetry and π‐Conjugated Organic Groups in Hybrid Fluorides

    Advanced Science · 2025-10-06

    Ru‐Ling Tang, Bing-Wei Miao, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo

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  20. K2HGa(IO3)6: A new member of iodate families with [M(IO3)6] building blocks

    Journal of Molecular Structure · 2025-11-30

    Runqing Liu, Yuntian Zhao, Huaifeng Wang, Jiming Huang, Shibo Guan, Senlin Leng

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  21. [ICl 4 ] − : A large anisotropic planar anion group produces giant birefringence

    Chemical Communications · 2026-01-01

    Yi-Chen Liu, Ming‐Zhi Zhang, Chun‐Li Hu, Jiang‐Gao Mao

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  22. Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution

    Inorganic Chemistry Frontiers · 2026-01-01

    Mei Hu, Zhencheng Wu, Xin Su, Hongheng Chen, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

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  23. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  24. Noncovalent Assembly Engineering Achieves Excellent Birefringence in Crystals

    Inorganic Chemistry · 2026-04-24

    Mengqing Wu, Yiman Yang, Xinyi Wang, Yaoguo Shen

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  25. Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals

    Advanced Functional Materials · 2026-06-01

    Hangwei Jia, Yaqi Jin, Muhammad Arif, Bailin Chen, Zhihua Yang, Xueling Hou, Shilie Pan

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  26. Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design

    Inorganic Chemistry · 2026-07-07

    Yi-Xiang Wang, Shu‐Fang Li, Xin-Ran Hao, Zhixiang Wang, Chu Chu, Bingbing Zhang, Dong Yan

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  27. IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F2

    Inorganic Chemistry · 2026-08-04

    Yanhong Wang, Shuaikun Li, Haibo Li, Yun Lv, О. С. Волкова, Alexander N. Vasiliev, Zhengcai Xia, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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  28. A Pyrazinamide–Iodic Acid Cocrystal Exhibiting Strong Second Harmonic Generation for Nonlinear Optics

    Advanced Optical Materials · 2026-08-31

    M. Duan, Chun‐Li Hu, Jiang‐Gao Mao, Bing‐Ping Yang

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  29. Halogen‐Bond Dimensionality Controls π–π Packing to Unlock Ultrahigh Second‐Harmonic Generation and Giant Birefringence

    Small · 2026-10-04

    Jin Chen, Yun‐Xia Hu, Huai‐Yu Wu, Jia‐Min Lian, Jinyu Luo, Yiru Fu, Ke‐Zhao Du

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