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RESEARCH PAPER · Dalton Transactions · 2021

Conversion of Pd( i ) off-cycle species into highly efficient cross-coupling catalysts

Yaxu Liu, Vladislav A. Voloshkin, Thomas Scattolin, Luigi Cavallo, Büşra Dereli, Catherine S. J. Cazin, Steven P. Nolan

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15 direct citing papers in this saved network. Explore the next layer with second-order citations.

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Conversion of Pd( i ) off-cycle species into highly efficient cross-coupling catalystsOriginalRecent advances in the synthesis and derivatization of N-heterocyclic carbene metal complexes36Simple synthesis of [Ru(CO 3 )(NHC)( p -cymene)] complexes and their use in transfer hydrogenation catalysis18A Simple Synthetic Route to Well‐Defined [Pd(NHC)Cl(1‐tBu‐indenyl)] Pre‐catalysts for Cross‐Coupling Reactions18C−I Selective Sonogashira and Heck Coupling Reactions Catalyzed by Aromatic Triangular Tri‐palladium10Versatile and Highly Efficient trans ‐[Pd(NHC)Cl 2 (DMS/THT)] Precatalysts for C−N and C−C Coupling Reactions in Green Solvents29Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route46The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions5Alkyl Cyclopropyl Ketones in Catalytic Formal [3 + 2] Cycloadditions: The Role of SmI 2 Catalyst Stabilization32Metal complexes of backbone-halogenated imidazol-2-ylidenes4Experimental Evidence for Zerovalent Pd(NHC) as a Competent Catalyst in C–N Cross-Coupling (NHC = DiMeIHeptCl)19[Pd(NHC)(μ-Cl)Cl]2: The Highly Reactive Air- and Moisture-Stable, Well-Defined Pd(II)-N-Heterocyclic Carbene (NHC) Complexes for Cross-Coupling Reactions24Impact of the N-Heterocyclic Carbene (NHC) Ligand on the trans-[Pd(NHC)(NH2nBu)Cl2] Precatalyst Architecture in C–N Bond-Forming Reactions4A robust [Pd(BIAN-IPr # )Cl 2 (H 2 O)] catalyst employing water as a disposable ligand for C–S cross coupling of aryl chlorides and thiols0A well-defined Pd( ii )-NHC aqua complex for ambient Buchwald–Hartwig amination in tert -butanol2Solvent-Free Suzuki-Miyaura Coupling Unleashed by Mechanochemical Pd(II)-NHC Catalysis0

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  1. Recent advances in the synthesis and derivatization of N-heterocyclic carbene metal complexes

    Dalton Transactions · 2021-01-01

    Vladislav A. Voloshkin, Nikolaos V. Tzouras, Steven P. Nolan

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  2. Simple synthesis of [Ru(CO 3 )(NHC)( p -cymene)] complexes and their use in transfer hydrogenation catalysis

    Dalton Transactions · 2021-01-01

    Xinyuan Ma, Sébastien G. Guillet, Yaxu Liu, Catherine S. J. Cazin, Steven P. Nolan

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  3. A Simple Synthetic Route to Well‐Defined [Pd(NHC)Cl(1‐tBu‐indenyl)] Pre‐catalysts for Cross‐Coupling Reactions

    European Journal of Inorganic Chemistry · 2021-11-26

    Yaxu Liu, Thomas Scattolin, Alberto Gobbo, Marek Beliš, Kristof Van Hecke, Steven P. Nolan, Catherine S. J. Cazin

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  4. C−I Selective Sonogashira and Heck Coupling Reactions Catalyzed by Aromatic Triangular Tri‐palladium

    European Journal of Organic Chemistry · 2022-02-22

    Xiaoshuang Wang, Lei Sun, Miaomiao Wang, Giovanni Maestri, Max Malacrìa, Xiang Liu, Yanlan Wang, Lingang Wu

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  5. Versatile and Highly Efficient trans ‐[Pd(NHC)Cl 2 (DMS/THT)] Precatalysts for C−N and C−C Coupling Reactions in Green Solvents

    European Journal of Organic Chemistry · 2022-03-22

    Yaxu Liu, Vladislav A. Voloshkin, Thomas Scattolin, Min Peng, Kristof Van Hecke, Steven P. Nolan, Catherine S. J. Cazin

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  6. Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route

    Organometallics · 2023-09-21

    Thomas Scattolin, Aleksei A. Logvinov, Nikolaos V. Tzouras, Catherine S. J. Cazin, Steven P. Nolan

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  7. The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions

    Dalton Transactions · 2024-01-01

    Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine S. J. Cazin, Steven P. Nolan

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  8. Alkyl Cyclopropyl Ketones in Catalytic Formal [3 + 2] Cycloadditions: The Role of SmI 2 Catalyst Stabilization

    Journal of the American Chemical Society · 2024-04-25

    Jack I. Mansell, Song Yu, Mu-Ze Li, Emma Pye, Chaofan Yin, Frédéric Beltran, James A. Rossi‐Ashton, Ciro Romano, Nikolas Kaltsoyannis, David J. Procter

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  9. Metal complexes of backbone-halogenated imidazol-2-ylidenes

    Inorganica Chimica Acta · 2024-07-20

    Alejandro Bugarin, Siddappa A. Patil, Ryan Q Tran, Kostiantyn O. Marichev

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  10. Experimental Evidence for Zerovalent Pd(NHC) as a Competent Catalyst in C–N Cross-Coupling (NHC = DiMeIHeptCl)

    Journal of the American Chemical Society · 2024-10-10

    Volodymyr Semeniuchenko, Sepideh Sharif, Neha Rana, Nalin Chandrasoma, Wilfried M. Braje, R. Tom Baker, Jeffrey M. Manthorpe, William J. Pietro, Michael G. Organ

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  11. [Pd(NHC)(μ-Cl)Cl]2: The Highly Reactive Air- and Moisture-Stable, Well-Defined Pd(II)-N-Heterocyclic Carbene (NHC) Complexes for Cross-Coupling Reactions

    Accounts of Chemical Research · 2024-11-06

    Shiyi Yang, Tongliang Zhou, Xiang Yu, Steven P. Nolan, Michal Szostak

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  12. Impact of the N-Heterocyclic Carbene (NHC) Ligand on the trans-[Pd(NHC)(NH2nBu)Cl2] Precatalyst Architecture in C–N Bond-Forming Reactions

    Organometallics · 2024-11-11

    Nestor Bracho Pozsoni, Fady Nahra, Kristof Van Hecke, Catherine S. J. Cazin, Steven P. Nolan

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  13. A robust [Pd(BIAN-IPr # )Cl 2 (H 2 O)] catalyst employing water as a disposable ligand for C–S cross coupling of aryl chlorides and thiols

    Dalton Transactions · 2026-01-01

    Ziyi Quan, Zheng Wang, Yaxu Liu, Yuanchao Sun, Bo Wang

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  14. A well-defined Pd( ii )-NHC aqua complex for ambient Buchwald–Hartwig amination in tert -butanol

    Green Chemistry · 2026-01-01

    Yaxu Liu, Zheng Wang, Ziyi Quan, Fengze Sun, Lixing Zhao, Lei Guo, Yixuan Gao, Bo Wang

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  15. Solvent-Free Suzuki-Miyaura Coupling Unleashed by Mechanochemical Pd(II)-NHC Catalysis

    ACS Sustainable Chemistry & Engineering · 2026-05-02

    Yaxu Liu, Ziyi Quan, Zheng Wang, Lixing Zhao, Jifu Sun, Lei Guo, Bo Wang

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