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RESEARCH PAPER · Dalton Transactions · 2021

Recent advances in the synthesis and derivatization of N-heterocyclic carbene metal complexes

Vladislav A. Voloshkin, Nikolaos V. Tzouras, Steven P. Nolan

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Recent advances in the synthesis and derivatization of N-heterocyclic carbene metal complexesOriginalContinuous Flow Synthesis of Sulfur‐ and Selenium−NHC Compounds (NHC=N‐Heterocyclic Carbene)14Understanding the Binding Properties of N‐heterocyclic Carbenes through BDE Matrix App8A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope14A greener approach towards the synthesis of N-heterocyclic thiones and selones using the mechanochemical technique7Energy transfer (EnT) photocatalysis enabled by gold-N-heterocyclic carbene (NHC) complexes65Improved synthetic routes to N -heterocyclic carbene-metal-diketonato complexes of gold and copper7Continuous Flow Synthesis of NHC‐Coinage Metal Amido and Thiolato Complexes: A Mechanism‐based Process Development8Versatile and Highly Efficient trans ‐[Pd(NHC)Cl 2 (DMS/THT)] Precatalysts for C−N and C−C Coupling Reactions in Green Solvents29Synthesis and characterization of chiral bidentate bis(N-heterocyclic carbene)-carboxylate palladium and nickel complexes9A new class of deep blue emitting four-coordinate NHC-Cu(I) complexes bearing nonconjugated triazolyl-imidazolylidene-type ligand: Synthesis, photophysical properties and theoretical investigations6Addition of aliphatic, secondary amines to coordinated isonitriles. N-acyclic carbene (NAC) platinum(II) complexes from trans-[Pt(μ-Cl)Cl(PPh3)]29Chirality influence on the cytotoxic properties of anionic chiral bis(N-heterocyclic carbene)silver complexes12Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N -Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical Properties239A Review on Generation and Reactivity of the N-Heterocyclic Carbene-Bound Alkynyl Acyl Azolium Intermediates25Synthesis, Modification And Click Of Arylopeptoids Using Carbene-Based Catalysts0Simple synthetic access to [Au(IBiox)Cl] complexes2Therapeutic potential of Ag( i )–, Au( i )–, and Au( iii )–NHC complexes of 3-pyridyl wingtip N-heterocyclic carbenes (NHCs) against lung cancer5A pyridine promoted ‘weak base route’ to (NHC)2NiCl2 complexes with bulky N,N'-diaryl carbene ligands3A Straightforward Access to Cyclic (Alkyl)(amino)carbene Copper (I) Complexes15Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and Reactivity4Gold(III) assisted C-N bond dissociation; Synthesis, structure, photoluminescence, and pharmacokinetic studies of 1,10/- phenanthroline-gold(III)-N-heterocyclic carbene4Synthesestrategien für die Funktionalisierung homogener Katalysatoren zur Verbesserung ihrer Abtrennbarkeit0Synthesis Strategies towards Tagged Homogeneous Catalysts To Improve Their Separation19Pt II −N‐Heterocyclic Carbene Complexes in Solvent‐Free Alkene Hydrosilylation23Remote Steric and Electronic Effects of N-Heterocyclic Carbene Ligands on Alkene Reactivity and Regioselectivity toward Hydrocupration Reactions: The Role of Expanded-Ring N-Heterocyclic Carbenes1Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route46Half-sandwich Ni( ii ) complexes bearing enantiopure bidentate NHC-carboxylate ligands: efficient catalysts for the hydrosilylative reduction of acetophenones7Synthesis and Anticancer Activities of some Ag(I) Complexes Involving N ‐Heterocyclic Carbene Ligands10Using Speciation to Gain Insight into Sustainable Coupling Reactions and Their Catalysts1Pd–NHC (NHC = N-Heterocyclic Carbene)-Catalyzed B-Alkyl Suzuki Cross-Coupling of 2-Pyridyl Ammonium Salts by N–C Activation: Application to the Discovery of Agrochemical Molecular Hybrids7Antimicrobial Activity of Anionic Bis(N-Heterocyclic Carbene) Silver Complexes16When Chirality Makes the Difference: The Case of Novel Enantiopure N-Heterocyclic Carbene–Gold and –Silver Complexes12Recent update on catalytic activity of N-heterocyclic carbene supported on graphene nanosheets: A mini review2IPr* and Its Analog for Arene-Induced Precatalyst Activation and Stabilization in Ni-Catalyzed Kumada–Tamao–Corriu Coupling of Unactivated Aryl Halides2Theoretical Prediction of the Electronic Properties of Bidentate Ligands (HEP2) and Synthesis of Bis( N -heterocyclic carbene) Silver and Palladium Complexes3Unveiling the versatility and reactivity of N-heterocyclic carbene complexes with metal and non-metal fluorides: a comprehensive review0

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  1. Continuous Flow Synthesis of Sulfur‐ and Selenium−NHC Compounds (NHC=N‐Heterocyclic Carbene)

    European Journal of Organic Chemistry · 2021-10-27

    Thibault Cauwenbergh, Thomas Scattolin, Andreas Simoens, Nikolaos V. Tzouras, Christian Victor Stevens, Steven P. Nolan

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  2. Understanding the Binding Properties of N‐heterocyclic Carbenes through BDE Matrix App

    European Journal of Inorganic Chemistry · 2021-11-29

    Lucía Morán‐González, Jaime Rodrı́guez-Guerra, María Besora, Feliu Maseras

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  3. A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope

    Dalton Transactions · 2022-01-01

    Benon P. Maliszewski, Ida Ritacco, Marek Beliš, Ishfaq Ibni Hashim, Nikolaos V. Tzouras, Lucia Caporaso, Luigi Cavallo, Kristof Van Hecke, Fady Nahra, Catherine S. J. Cazin, Steven P. Nolan

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  4. A greener approach towards the synthesis of N-heterocyclic thiones and selones using the mechanochemical technique

    Dalton Transactions · 2022-01-01

    Siddhartha, Shalini Rangarajan, Harish S. Kunchur, Maravanji Shivaramaiah Balakrishna

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  5. Energy transfer (EnT) photocatalysis enabled by gold-N-heterocyclic carbene (NHC) complexes

    Chemical Science · 2022-01-01

    Ekaterina A. Martynova, Vladislav A. Voloshkin, Sébastien G. Guillet, Francis Bru, Marek Beliš, Kristof Van Hecke, Catherine S. J. Cazin, Steven P. Nolan

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  6. Improved synthetic routes to N -heterocyclic carbene-metal-diketonato complexes of gold and copper

    Dalton Transactions · 2022-01-01

    Ishfaq Ibni Hashim, Nikolaos V. Tzouras, Xinyuan Ma, Laurens Bourda, Kristof Van Hecke, Steven P. Nolan, Catherine S. J. Cazin

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  7. Continuous Flow Synthesis of NHC‐Coinage Metal Amido and Thiolato Complexes: A Mechanism‐based Process Development

    Chemistry - Methods · 2022-01-20

    Thibault Cauwenbergh, Nikolaos V. Tzouras, Thomas Scattolin, Andreas Simoens, Christian Victor Stevens, Catherine S. J. Cazin, Steven P. Nolan

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  8. Versatile and Highly Efficient trans ‐[Pd(NHC)Cl 2 (DMS/THT)] Precatalysts for C−N and C−C Coupling Reactions in Green Solvents

    European Journal of Organic Chemistry · 2022-03-22

    Yaxu Liu, Vladislav A. Voloshkin, Thomas Scattolin, Min Peng, Kristof Van Hecke, Steven P. Nolan, Catherine S. J. Cazin

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  9. Synthesis and characterization of chiral bidentate bis(N-heterocyclic carbene)-carboxylate palladium and nickel complexes

    Inorganica Chimica Acta · 2022-04-05

    Adrián Sánchez, Jorge Sanz-Garrido, Carlos J. Carrasco, Francisco Montilla, Eleuterio Álvarez, Camino González‐Arellano, Juan Carlos Flores, Agustı́n Galindo

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  10. A new class of deep blue emitting four-coordinate NHC-Cu(I) complexes bearing nonconjugated triazolyl-imidazolylidene-type ligand: Synthesis, photophysical properties and theoretical investigations

    Journal of Photochemistry and Photobiology A Chemistry · 2022-05-10

    Rou Wang, Xiaoyun Wu, Yaqian Wu, Jinglan Wang, Huade Huang, Yibo Wang, Haifeng He, Feng Qi Zhao

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  11. Addition of aliphatic, secondary amines to coordinated isonitriles. N-acyclic carbene (NAC) platinum(II) complexes from trans-[Pt(μ-Cl)Cl(PPh3)]2

    Inorganica Chimica Acta · 2022-06-16

    Anna Farasat, Luca Labella, Fabio Marchetti, Simona Samaritani

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  12. Chirality influence on the cytotoxic properties of anionic chiral bis(N-heterocyclic carbene)silver complexes

    Journal of Inorganic Biochemistry · 2022-07-08

    Carlos J. Carrasco, Francisco Montilla, Eleuterio Álvarez, José Manuel Calderón‐Montaño, Miguel López‐Lázaro, Agustı́n Galindo

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  13. Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N -Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical Properties

    Chemical Reviews · 2022-10-31

    Hani Amouri

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  14. A Review on Generation and Reactivity of the N-Heterocyclic Carbene-Bound Alkynyl Acyl Azolium Intermediates

    Molecules · 2022-11-17

    Ziyang Dong, Chengming Jiang, Changgui Zhao

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  15. Synthesis, Modification And Click Of Arylopeptoids Using Carbene-Based Catalysts

    Unknown journal · 2022-12-09

    Ayman Akhdar

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  16. Simple synthetic access to [Au(IBiox)Cl] complexes

    Dalton Transactions · 2023-01-01

    Ekaterina A. Martynova, Marco Zuccarello, Domenic Kronenberg, Marek Beliš, Agnieszka Czapik, Ziyun Zhang, Kristof Van Hecke, Marcin Kwit, Olivier Baudoin, Luigi Cavallo, Steven P. Nolan

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  17. Therapeutic potential of Ag( i )–, Au( i )–, and Au( iii )–NHC complexes of 3-pyridyl wingtip N-heterocyclic carbenes (NHCs) against lung cancer

    New Journal of Chemistry · 2023-01-01

    Prafulla K Behera, Lakshmikanta Maity, Sraddhya Roy, Ananya Das, Priyanka Sahu, Hemanta K. Kisan, Avtar Changotra, Anvarhusein Abdulkadir Isab, Mohammed Fettouhi, Aparajita Bairagi, Nabanita Chatterjee, Joydev Dinda

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  18. A pyridine promoted ‘weak base route’ to (NHC)2NiCl2 complexes with bulky N,N'-diaryl carbene ligands

    Mendeleev Communications · 2023-03-01

    Oleg Vladimirovich Khazipov, Anastasia S. Pyatachenko, Пасюков Дмитрий Викторович, Mikhail Evgenievich Minyaev, Victor M. Chernyshev

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  19. A Straightforward Access to Cyclic (Alkyl)(amino)carbene Copper (I) Complexes

    European Journal of Inorganic Chemistry · 2023-03-10

    Jan Lorkowski, Melinda R. Serrato, Milan Gembicky B, Marc Mauduit, Guy Bertrand, Rodolphe F. R. Jazzar

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  20. Dibromo–Isonitrile and N-acyclic Carbene Complexes of Platinum(II): Synthesis and Reactivity

    Inorganics · 2023-03-23

    Anna Farasat, Francesca Nerli, Luca Labella, Marco Taddei, Simona Samaritani

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  21. Gold(III) assisted C-N bond dissociation; Synthesis, structure, photoluminescence, and pharmacokinetic studies of 1,10/- phenanthroline-gold(III)-N-heterocyclic carbene

    Journal of Molecular Structure · 2023-03-27

    Priyanka Sahu, Atala Bihari Jena, Sahadev Barik, Hemanta K. Kisan, Anvarhusein Abdulkadir Isab, Jagneshwar Dandapat, Joydev Dinda

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  22. Synthesestrategien für die Funktionalisierung homogener Katalysatoren zur Verbesserung ihrer Abtrennbarkeit

    Angewandte Chemie · 2023-05-11

    Justus Diekamp, Thomas Seidensticker

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  23. Synthesis Strategies towards Tagged Homogeneous Catalysts To Improve Their Separation

    Angewandte Chemie International Edition · 2023-05-11

    Justus Diekamp, Thomas Seidensticker

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  24. Pt II −N‐Heterocyclic Carbene Complexes in Solvent‐Free Alkene Hydrosilylation

    Chemistry - A European Journal · 2023-05-17

    Benon P. Maliszewski, Tahani A. C. A. Bayrakdar, Perrine Lambert, Lama Hamdouna, Xavier Trivelli, Luigi Cavallo, Albert Poater, Marek Beliš, Olivier Lafon, Kristof Van Hecke, Dominic Ormerod, Catherine S. J. Cazin, Fady Nahra, Steven P. Nolan

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  25. Remote Steric and Electronic Effects of N-Heterocyclic Carbene Ligands on Alkene Reactivity and Regioselectivity toward Hydrocupration Reactions: The Role of Expanded-Ring N-Heterocyclic Carbenes

    The Journal of Organic Chemistry · 2023-08-31

    Aqeel A. Hussein, Azhar Ariffin

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  26. Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route

    Organometallics · 2023-09-21

    Thomas Scattolin, Aleksei A. Logvinov, Nikolaos V. Tzouras, Catherine S. J. Cazin, Steven P. Nolan

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  27. Half-sandwich Ni( ii ) complexes bearing enantiopure bidentate NHC-carboxylate ligands: efficient catalysts for the hydrosilylative reduction of acetophenones

    Dalton Transactions · 2023-12-15

    Jorge Sanz-Garrido, Avelino Martı́n, Camino González‐Arellano, Juan Carlos Flores

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  28. Synthesis and Anticancer Activities of some Ag(I) Complexes Involving N ‐Heterocyclic Carbene Ligands

    ChemistrySelect · 2024-02-02

    Ahmed Hassoon Mageed, Israa Sami Hadi

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  29. Using Speciation to Gain Insight into Sustainable Coupling Reactions and Their Catalysts

    Unknown journal · 2024-02-15

    Skyler A. Markham, Debbie C. Crans, Bruce A. Atwater

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  30. Pd–NHC (NHC = N-Heterocyclic Carbene)-Catalyzed B-Alkyl Suzuki Cross-Coupling of 2-Pyridyl Ammonium Salts by N–C Activation: Application to the Discovery of Agrochemical Molecular Hybrids

    Organic Letters · 2024-03-11

    Yanqing Gao, Yuge Hu, Jiuhui Ye, Zhiqing Ma, Juntao Feng, Xili Liu, Peng Lei, Michal Szostak

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  31. Antimicrobial Activity of Anionic Bis(N-Heterocyclic Carbene) Silver Complexes

    Molecules · 2024-09-27

    Carlos J. Carrasco, Francisco Montilla, Eduardo Villalobo, Manuel Angulo, Eleuterio Álvarez, Agustı́n Galindo

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  32. When Chirality Makes the Difference: The Case of Novel Enantiopure N-Heterocyclic Carbene–Gold and –Silver Complexes

    Molecules · 2024-11-07

    Maria Marra, Annaluisa Mariconda, Domenico Iacopetta, Jessica Ceramella, Assunta D’Amato, Camillo Rosano, Kateryna Tkachenko, MICHELE A. PELLEGRINO, Stefano Aquaro, Maria Stefania Sinicropi, Pasquale Longo

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  33. Recent update on catalytic activity of N-heterocyclic carbene supported on graphene nanosheets: A mini review

    Journal of Organometallic Chemistry · 2025-04-10

    Raed Muslim Mhaibes, Abdul Amir H. Kadhum, H. N. K. AL-Salman, Zaid Hamid Mahmoud, Mustafa Mudhafar, Qais R. Lahhob, Guang Shu

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  34. IPr* and Its Analog for Arene-Induced Precatalyst Activation and Stabilization in Ni-Catalyzed Kumada–Tamao–Corriu Coupling of Unactivated Aryl Halides

    Organometallics · 2025-06-17

    Kouki Matsubara, Y. YAMADA, Ayane Tokushige, Aoi Sakamoto, Rion Hosokawa, Yuji Koga

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  35. Theoretical Prediction of the Electronic Properties of Bidentate Ligands (HEP2) and Synthesis of Bis( N -heterocyclic carbene) Silver and Palladium Complexes

    Inorganic Chemistry · 2025-07-16

    Carlos J. Carrasco, Francisco Montilla, Eleuterio Álvarez, Agustı́n Galindo

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  36. Unveiling the versatility and reactivity of N-heterocyclic carbene complexes with metal and non-metal fluorides: a comprehensive review

    Coordination Chemistry Reviews · 2026-01-31

    Evelin Gruden, Gašper Tavčar

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