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RESEARCH PAPER · Inorganic Chemistry · 2022

Modulating Two Pairs of Chiral Dy III Enantiomers by Distinct β-Diketone Ligands to Show Giant Differences in Single-Ion Magnet Performance and Nonlinear Optical Response

Xi-Li Li, Ailing Wang, Minghui Cui, Congli Gao, Xiaojing Yu, Bing Su, Liming Zhou, Cai‐Ming Liu, Hong‐Ping Xiao, Yi‐Quan Zhang

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Modulating Two Pairs of Chiral Dy III Enantiomers by Distinct β-Diketone Ligands to Show Giant Differences in Single-Ion Magnet Performance and Nonlinear Optical ResponseOriginalTwo-dimensional dysprosium(III) coordination polymer: Structure, single-molecule magnetic behavior, proton conduction, and luminescence13ZnII-DyIII single-molecule magnets constructed by salen-type ligand, acetate and β-diketonate2Effects of Counterions, Coordination Anions, and Coordination Solvent Molecules on Single-Molecule Magnetic Behaviors and Nonlinear Optical Properties of Chiral Zn2Dy Schiff Base Complexes41Syntheses of ferrocene-functionalized indium-based metal–organic frameworks for third order nonlinear optical application13A pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses12Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses20Two temperature-induced 1D Cu II chain enantiomeric pairs showing different magnetic properties and nonlinear optical responses14Two Chiral YbIII Enantiomeric Pairs with Distinct Enantiomerically Pure N-Donor Ligands Presenting Significant Differences in Photoluminescence, Circularly Polarized Luminescence, and Second-Harmonic Generation30Two Pairs of Homochiral Parallelogram-like Dy 4 Cluster Complexes with Strong Magneto-Optical Properties15Homochiral Dy 2 single-molecule magnets with strong magneto-optical Faraday effects and strong third-harmonic generation23Slow magnetic relaxation and luminescence properties in β-diketonate lanthanide( iii ) complexes. Preparation of Eu( iii ) and Yb( iii ) OLED devices30Two chiral Co III and Ni II complexes with identical ligands presenting different nonlinear optical responses4Two chiral Eu III and Sm III enantiomeric pairs with enantiopure N-donor ligands: showing strong third-harmonic generation and photoluminescence properties7Two chiral lanthanide Pr III and Ho III complexes: NIR luminescence and nonlinear optical properties14Assembly of Homochiral Magneto-Optical Dy6 Triangular Clusters by Fixing Carbon Dioxide in the Air7Chiral mono- and dinuclear CoII and CuII enantiomeric pairs with distinct enantiopure N-donor ligands: Presenting highly enhanced third-harmonic generation responses6Homochiral Dy 2 zero-field single-molecule magnets derived from axial chiral ligands ( R )/( S )-octahydro-1,1′-bi-2-naphthyl phosphate9Homochiral Dy 2 Zn 2 zero-field single-molecule magnets derived from ( R )/( S )-2-methoxy-2-phenylacetic acids3Impact of nuclear number on SHG and THG performances: a comparative study of chiral mono- and dinuclear Tb III complexes with identical organic ligands22D Chiral Ag(I) Complexes with A-π–A- and D-π–A-Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses5Homochiral Dy 2 Schiff Base Complexes Based on ( R )/( S )‐Chlocyphos: Single‐Molecule Magnet Behaviours, Proton Conductivities and MCD Effects9Photoactive isomerism and magnetic relaxation dynamics in a family of β-diketonate/azopyridine-based lanthanide single-molecule magnets3Multifunctional chiral dinuclear DyIII enantiomeric pairs: showing single-molecule magnet behaviors with very strong third-harmonic generation responses5Two Chiral EuIII Enantiomeric Pairs with Significantly Enhanced Photophysical and Third-Harmonic Generation Performances through the Coordination Roles of Enantiopure Bi- and Tridentate N-Donors9Synergistic structural-electronic strategy enhances magnetic relaxation in DyIII single-molecule magnets3Recent developments in magnetic lanthanoid complexes supported by β-diketonate or pyridyl-pyrazolate ligands5Precise Control of Homochiral Multifunctional Dy 2 Single-Molecule Magnets by Changing the Positions of the Two Heterocyclic Nitrogen Atoms in the Schiff Base Ligands4Chiral Lead-Oxyiodide Nonlinear Optical Crystals Constructed on l -Malate Groups5Effect of solvents on multifunctional Dy 2 complexes with axial chiral ligands ( R )/( S )-1,1′-binaphthyl-2,2′-diyl phosphate0Simultaneously switching both the magnetic behaviors and nonlinear optical processes in mononuclear DyIII complexes0Simultaneously switching both the magnetic behavior and nonlinear optical process in mononuclear DyIII complexes via the coordination role of enantiopure N3-pincers2Multifunctional Lanthanide Molecular Ferroelectrics [ R / S -H 2 MPPA][Ln(btfa) 4 ] 2 Constructed by Hydrogen Bond Linking Functional Blocks3Tuning linear and nonlinear optical performances of two eight- and nine-coordinated chiral SmIII enantiomeric pairs by enantiopure N-donor ligands1Tuning Homochiral Dy2 SMMs Based on ( R )/( S )-2-Chloropropionate through Atom Modification on the Aromatic Rings of Schiff Base Ligands0Chiral dinuclear EuIII enantiomeric pairs: simultaneously showing photoluminescences, circularly polarized luminescences, second- and third-harmonic generations with enhanced performances0

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  1. Two-dimensional dysprosium(III) coordination polymer: Structure, single-molecule magnetic behavior, proton conduction, and luminescence

    Frontiers in Chemistry · 2022-08-08

    Jinfen Chen, Yi-Liang Ge, Donghui Wu, Haotian Cui, Zhilin Mu, Hong‐Ping Xiao, Xin‐Hua Li, Jing‐Yuan Ge

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  2. ZnII-DyIII single-molecule magnets constructed by salen-type ligand, acetate and β-diketonate

    Journal of Molecular Structure · 2022-09-19

    Tiantian Wang, Han Yan, Zi-Wei Che, Wen‐Bin Sun

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  3. Effects of Counterions, Coordination Anions, and Coordination Solvent Molecules on Single-Molecule Magnetic Behaviors and Nonlinear Optical Properties of Chiral Zn2Dy Schiff Base Complexes

    Inorganic Chemistry · 2022-11-08

    Cai‐Ming Liu, Rong Sun, Bing‐Wu Wang, Xiang Hao, Xi-Li Li

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  4. Syntheses of ferrocene-functionalized indium-based metal–organic frameworks for third order nonlinear optical application

    Inorganic Chemistry Frontiers · 2022-11-15

    Rong Zhang, Bing Wang, Fei Wang, Shumei Chen, Jian Zhang

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  5. A pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Congli Gao, Zhiqiang Zhang, Bing Su, Xi-Li Li

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  6. Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Zhiqiang Zhang, Congli Gao, Fengcai Li, Xi-Li Li

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  7. Two temperature-induced 1D Cu II chain enantiomeric pairs showing different magnetic properties and nonlinear optical responses

    Dalton Transactions · 2023-01-01

    Xi-Li Li, Yanan Li, Ailing Wang, Congli Gao, Minghui Cui, Cai‐Ming Liu, Liming Zhou

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  8. Two Chiral YbIII Enantiomeric Pairs with Distinct Enantiomerically Pure N-Donor Ligands Presenting Significant Differences in Photoluminescence, Circularly Polarized Luminescence, and Second-Harmonic Generation

    Inorganic Chemistry · 2023-02-27

    Xi-Li Li, Ailing Wang, Yanan Li, Congli Gao, Minghui Cui, Hong‐Ping Xiao, Liming Zhou

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  9. Two Pairs of Homochiral Parallelogram-like Dy 4 Cluster Complexes with Strong Magneto-Optical Properties

    Inorganic Chemistry · 2023-11-23

    Cai‐Ming Liu, Rong Sun, Xiang Hao, Bing‐Wu Wang

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  10. Homochiral Dy 2 single-molecule magnets with strong magneto-optical Faraday effects and strong third-harmonic generation

    Inorganic Chemistry Frontiers · 2024-01-01

    Cai‐Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bing‐Wu Wang

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  11. Slow magnetic relaxation and luminescence properties in β-diketonate lanthanide( iii ) complexes. Preparation of Eu( iii ) and Yb( iii ) OLED devices

    Journal of Materials Chemistry C · 2024-01-01

    Ànnia Tubau, Laura Rodrı́guez, Piotr Pander, Lucy Weatherill, Fernando B. Dias, Mercè Font‐Bardía, Ramón Vicente

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  12. Two chiral Co III and Ni II complexes with identical ligands presenting different nonlinear optical responses

    New Journal of Chemistry · 2024-01-01

    Taoyu Wang, Yanhong Peng, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  13. Two chiral Eu III and Sm III enantiomeric pairs with enantiopure N-donor ligands: showing strong third-harmonic generation and photoluminescence properties

    CrystEngComm · 2024-01-01

    Jinliang Zhang, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  14. Two chiral lanthanide Pr III and Ho III complexes: NIR luminescence and nonlinear optical properties

    CrystEngComm · 2024-01-01

    Yanhong Peng, Taoyu Wang, Congli Gao, Fengcai Li, Xi-Li Li

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  15. Assembly of Homochiral Magneto-Optical Dy6 Triangular Clusters by Fixing Carbon Dioxide in the Air

    Molecules · 2024-07-19

    Cai‐Ming Liu, Xiang Hao, Xi-Li Li

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  16. Chiral mono- and dinuclear CoII and CuII enantiomeric pairs with distinct enantiopure N-donor ligands: Presenting highly enhanced third-harmonic generation responses

    Journal of Molecular Structure · 2024-09-14

    Xiaodi Du, Chunyang Li, Chunyang Li, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  17. Homochiral Dy 2 zero-field single-molecule magnets derived from axial chiral ligands ( R )/( S )-octahydro-1,1′-bi-2-naphthyl phosphate

    Dalton Transactions · 2025-01-01

    Cai‐Ming Liu, Xiang Hao, Yi‐Quan Zhang

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  18. Homochiral Dy 2 Zn 2 zero-field single-molecule magnets derived from ( R )/( S )-2-methoxy-2-phenylacetic acids

    Dalton Transactions · 2025-01-01

    Cai‐Ming Liu, Xiang Hao, Yi‐Quan Zhang

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  19. Impact of nuclear number on SHG and THG performances: a comparative study of chiral mono- and dinuclear Tb III complexes with identical organic ligands

    CrystEngComm · 2025-01-01

    Taoyu Wang, Yanhong Peng, Yang Wang, Congli Gao, Xi-Li Li

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  20. 2D Chiral Ag(I) Complexes with A-π–A- and D-π–A-Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses

    Inorganic Chemistry · 2025-01-10

    Congli Gao, Xiaoyu Cai, Jinying Huang, Qianrong Li, Huajie Kong, Jimei Yao, Yang Wang, Xi-Li Li

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  21. Homochiral Dy 2 Schiff Base Complexes Based on ( R )/( S )‐Chlocyphos: Single‐Molecule Magnet Behaviours, Proton Conductivities and MCD Effects

    Chinese Journal of Chemistry · 2025-02-13

    Cai‐Ming Liu, Hua‐Hong Zou, Yi‐Quan Zhang, Xiang Hao, Xiao‐Ming Ren

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  22. Photoactive isomerism and magnetic relaxation dynamics in a family of β-diketonate/azopyridine-based lanthanide single-molecule magnets

    Inorganic Chemistry Communications · 2025-02-26

    You-Liang Shi, Dan Liu, Han‐Han Lu, Xinfeng Li, Xin-Feng Li, Meng‐Jia Shang, Liang Rong Zhao, Tao Liu, Yin‐Shan Meng

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  23. Multifunctional chiral dinuclear DyIII enantiomeric pairs: showing single-molecule magnet behaviors with very strong third-harmonic generation responses

    Journal of Molecular Structure · 2025-04-19

    Rong‐Min Wei, Hui Hu, Min Yang, Da‐Shuai Zhang, Dunqing Wang, Chunxiao Jia, Fengcai Li, Xi-Li Li, Xi-Li Li, Cai‐Ming Liu

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  24. Two Chiral EuIII Enantiomeric Pairs with Significantly Enhanced Photophysical and Third-Harmonic Generation Performances through the Coordination Roles of Enantiopure Bi- and Tridentate N-Donors

    Inorganic Chemistry · 2025-06-03

    Xiaodi Du, Chunyang Li, Congli Gao, Xiaoyu Tracy Cai, Jinying Huang, Qianrong Li, Tao Wu, Xi-Li Li

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  25. Synergistic structural-electronic strategy enhances magnetic relaxation in DyIII single-molecule magnets

    Journal of Molecular Structure · 2025-06-11

    Lin-Bo Cao, Han Yan, Qi Tan, Wen‐Bin Sun

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  26. Recent developments in magnetic lanthanoid complexes supported by β-diketonate or pyridyl-pyrazolate ligands

    Inorganica Chimica Acta · 2025-08-29

    Patrick Mangundu, Curtis C. Ho, Rebecca O. Fuller

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  27. Precise Control of Homochiral Multifunctional Dy 2 Single-Molecule Magnets by Changing the Positions of the Two Heterocyclic Nitrogen Atoms in the Schiff Base Ligands

    Precision Chemistry · 2025-11-17

    Cai‐Ming Liu, Yi‐Quan Zhang, Xiang Hao, Xi-Li Li

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  28. Chiral Lead-Oxyiodide Nonlinear Optical Crystals Constructed on l -Malate Groups

    Inorganic Chemistry · 2025-12-08

    Yiting Luo, Shuangcheng Li, Jialin Zeng, Senfu Lei, Zilong Geng, Yulu Wu, Wenjing Yang, Ruibiao Fu, Zuju Ma

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  29. Effect of solvents on multifunctional Dy 2 complexes with axial chiral ligands ( R )/( S )-1,1′-binaphthyl-2,2′-diyl phosphate

    Dalton Transactions · 2026-01-01

    Cai‐Ming Liu, Yi‐Quan Zhang, Xiang Hao, Xi-Li Li

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  30. Simultaneously switching both the magnetic behaviors and nonlinear optical processes in mononuclear DyIII complexes

    SSRN Electronic Journal · 2026-01-01

    Xiaodi Du, Chunyang Li, Congli Gao, Jimei Yao, Cai‐Ming Liu, Yiquan Zhang, Xi-li Li

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  31. Simultaneously switching both the magnetic behavior and nonlinear optical process in mononuclear DyIII complexes via the coordination role of enantiopure N3-pincers

    Journal of Molecular Structure · 2026-02-14

    Xiaodi Du, Chunyang Li, Congli Gao, Jimei Yao, Cai-ming Liu, Yi‐Quan Zhang, Xi-Li Li

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  32. Multifunctional Lanthanide Molecular Ferroelectrics [ R / S -H 2 MPPA][Ln(btfa) 4 ] 2 Constructed by Hydrogen Bond Linking Functional Blocks

    Inorganic Chemistry · 2026-02-24

    Chun-Pu Chen, Xiaolu Guo, Ya Gao, Ping Lu, Dongcheng Liu, Fu-Pei Liang

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  33. Tuning linear and nonlinear optical performances of two eight- and nine-coordinated chiral SmIII enantiomeric pairs by enantiopure N-donor ligands

    Journal of Molecular Structure · 2026-05-19

    Xiaodi Du, Chunyang Li, Yang Wang, Congli Gao, Tao Wu, Xi-Li Li

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  34. Tuning Homochiral Dy2 SMMs Based on ( R )/( S )-2-Chloropropionate through Atom Modification on the Aromatic Rings of Schiff Base Ligands

    Crystal Growth & Design · 2026-08-21

    Cai‐Ming Liu, Xiang Hao, Yi‐Quan Zhang

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  35. Chiral dinuclear EuIII enantiomeric pairs: simultaneously showing photoluminescences, circularly polarized luminescences, second- and third-harmonic generations with enhanced performances

    Journal of Molecular Structure · 2026-08-28

    Xiaodi Du, Chunyang Li, Congli Gao, Tao Wu, Xi-Li Li

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