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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2021

Novel noncentrosymmetric polar coordination compounds derived from chiral histidine ligands

Wooyoung Seo, Kang Min Ok

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Novel noncentrosymmetric polar coordination compounds derived from chiral histidine ligandsOriginal( R )- and ( S )-[C 8 H 10 NO 3 ] 2 [NbOF 5 ]: noncentrosymmetric niobium oxyfluorides with large optical anisotropy3Chiral 2D organic–inorganic hybrid perovskites based on l -histidine9Chiral coordination compounds with exceptional enantioselectivity10Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures12Novel layered heterobimetallic fluorides with large optical band gaps3Driving Nonlinear Optical Activity with Dipolar 2-Aminopyrimidinium Cations in (C4H6N3)+(H2PO3)−115Corrugated 1D Hybrid Metal Halide [C6H7ClN]CdCl3 Exhibiting Broadband White-Light Emission46Modulating Two Pairs of Chiral Dy III Enantiomers by Distinct β-Diketone Ligands to Show Giant Differences in Single-Ion Magnet Performance and Nonlinear Optical Response35Achieving Large Second Harmonic Generation Effects via Optimal Planar Alignment of Triangular Units64A pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses12From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence50High stability and moderate second-order nonlinear optical properties of hybrid lead-free perovskite [(CH 3 ) 3 NCH 2 Cl]CdCl 3 bulk crystals12Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses20Second-Harmonic Generation in Homochiral Antimony Halides Directed by l -Histidine24Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)34Two chiral Co III and Ni II complexes with identical ligands presenting different nonlinear optical responses4Design of Deep-Ultraviolet Zero-Order Waveplate Materials by Rational Assembly of [AlO2F4] and [SO4] Groups9Multiple Functions of l -Thioproline in the Synthesis of Chiral Metal Bromides Showing Second-Harmonic-Generation Responses18l -Homoproline-Directed Synthesis of Organic–Inorganic Metal Iodides for Second Harmonic Generation14Enhanced second-harmonic generation response in a chiral lead iodide induced by amino acid coordination8Ligand substitution in organic–inorganic hybrid zinc iodides for second-harmonic generation7Designing Polar Covalent Hybrid Cadmium‐Based Chalcohalides Ultraviolet Nonlinear Optical Crystal with Strong Optical Anisotropy via Double‐Site Dual FBUs Tailoring25Toward the Strongest Nonlinear Optical Response and Largest Birefringence in Solvent‐Free Organic–Inorganic Metal Halides by Hydrogen Bond Engineering39Phase-Matching Second-Harmonic Generation in Zero-Dimensional Zinc Thiocyanates Ligated with Chiral Amino Acids6Synthesis and crystal structure of catena -poly[[bis(nitrato-κ 2 O , O ′)strontium(II)]-di-μ- L -histidine-κ 3 O , O ′: O ;κ 2 O : O ′]0Recent Advances in Low‐Dimensional Organic–Inorganic Hybrid Metal Halides (0D–2D) for Solid‐State Lighting21Chiral calcium thiocyanate hybrids: amino acid-enabled structural diversity and second-harmonic generation0Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering0Second-harmonic generation in two hybrid organic–inorganic metal chlorides based on l -thioproline ligand1Second-harmonic generation responses in low-dimensional metal bromides functionalized with l -arginine1Supramolecular template modulation in chiral lead bromide hybrids toward enhanced second-harmonic generation0Nonlinear Optical Responses in One-Dimensional Zinc Thiocyanates Functionalized with Natural Amino Acids8Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly1Amino Acid-Directed Synthesis of Chiral Manganese Chlorides with One-Dimensional Helical Structures0Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0

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  1. ( R )- and ( S )-[C 8 H 10 NO 3 ] 2 [NbOF 5 ]: noncentrosymmetric niobium oxyfluorides with large optical anisotropy

    Inorganic Chemistry Frontiers · 2022-01-01

    Jihyeon Moon, Kang Min Ok

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  2. Chiral 2D organic–inorganic hybrid perovskites based on l -histidine

    Dalton Transactions · 2022-01-01

    Valerii Y. Sirenko, Olesia I. Kucheriv, Elżbieta Gumienna‐Kontecka, Sergiu G. Shova, Il’ya A. Gural’skiy

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  3. Chiral coordination compounds with exceptional enantioselectivity

    Journal of Materials Chemistry C · 2022-01-01

    Minju Lee, Kang Min Ok

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  4. Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures

    Chemistry - A European Journal · 2022-01-27

    Yunseung Kuk, Joonhyuk Kee, Kang Min Ok

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  5. Novel layered heterobimetallic fluorides with large optical band gaps

    Journal of Solid State Chemistry · 2022-02-02

    Belal Ahmed, Kang Min Ok

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  6. Driving Nonlinear Optical Activity with Dipolar 2-Aminopyrimidinium Cations in (C4H6N3)+(H2PO3)−

    Chemistry of Materials · 2022-02-08

    Zi‐Peng Zhang, Xin Liu, Xiaomeng Liu, Zhong-Wei Lu, Xin Sui, Bo-Yu Zhen, Zheshuai Lin, Ling Chen, Li‐Ming Wu

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  7. Corrugated 1D Hybrid Metal Halide [C6H7ClN]CdCl3 Exhibiting Broadband White-Light Emission

    Inorganic Chemistry · 2022-03-09

    Haiping Xu, Zhizhuan Zhang, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  8. Modulating Two Pairs of Chiral Dy III Enantiomers by Distinct β-Diketone Ligands to Show Giant Differences in Single-Ion Magnet Performance and Nonlinear Optical Response

    Inorganic Chemistry · 2022-06-03

    Xi-Li Li, Ailing Wang, Minghui Cui, Congli Gao, Xiaojing Yu, Bing Su, Liming Zhou, Cai‐Ming Liu, Hong‐Ping Xiao, Yi‐Quan Zhang

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  9. Achieving Large Second Harmonic Generation Effects via Optimal Planar Alignment of Triangular Units

    Advanced Functional Materials · 2022-11-04

    Xinyu Li, Qi Wei, Chun‐Li Hu, Jie Pan, Bingxuan Li, Zhen‐Zhen Xue, Xiao‐Yu Li, Jinhua Li, Jiang‐Gao Mao, Guo‐Ming Wang

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  10. A pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Congli Gao, Zhiqiang Zhang, Bing Su, Xi-Li Li

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  11. From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence

    Chemical Science · 2023-01-01

    Huai‐Yu Wu, Chun‐Li Hu, Miao‐Bin Xu, Qianqian Chen, Nan Ma, Xiao‐Ying Huang, Ke‐Zhao Du, Jin Chen

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  12. High stability and moderate second-order nonlinear optical properties of hybrid lead-free perovskite [(CH 3 ) 3 NCH 2 Cl]CdCl 3 bulk crystals

    CrystEngComm · 2023-01-01

    Chuanying Shen, Jie Liu, Kui Wu, Longyun Xu, Defu Sun, Yangyang Dang, Jiyang Wang, Duanliang Wang

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  13. Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Zhiqiang Zhang, Congli Gao, Fengcai Li, Xi-Li Li

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  14. Second-Harmonic Generation in Homochiral Antimony Halides Directed by l -Histidine

    Inorganic Chemistry · 2023-10-02

    Juan Cheng, Peiqi Qian, Meng Yang, Ling Huang, Hongmei Zeng, Guohong Zou, Zhien Lin

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  15. Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)

    Inorganic Chemistry Frontiers · 2024-01-01

    Jin Chen, Huai-Yu Wu, Miao‐Bin Xu, Mingchang Wang, Qianqian Chen, Bingxuan Li, Chun‐Li Hu, Ke‐Zhao Du

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  16. Two chiral Co III and Ni II complexes with identical ligands presenting different nonlinear optical responses

    New Journal of Chemistry · 2024-01-01

    Taoyu Wang, Yanhong Peng, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  17. Design of Deep-Ultraviolet Zero-Order Waveplate Materials by Rational Assembly of [AlO2F4] and [SO4] Groups

    Inorganic Chemistry · 2024-01-04

    Zhencheng Wu, Huimin Li, Zhiyuan Zhang, Xin Su, Hongsheng Shi, Yineng Huang

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  18. Multiple Functions of l -Thioproline in the Synthesis of Chiral Metal Bromides Showing Second-Harmonic-Generation Responses

    Inorganic Chemistry · 2024-04-23

    Peiqi Qian, Ying Li, Juan Cheng, Jing Li, Hongmei Zeng, Ling Huang, Guohong Zou, Zhien Lin

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  19. l -Homoproline-Directed Synthesis of Organic–Inorganic Metal Iodides for Second Harmonic Generation

    Inorganic Chemistry · 2024-08-15

    Juan Cheng, Gangji Yi, Peiqi Qian, Jing Li, Ling Huang, Hongmei Zeng, Guohong Zou, Zhien Lin

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  20. Enhanced second-harmonic generation response in a chiral lead iodide induced by amino acid coordination

    Chemical Communications · 2025-01-01

    Juan Cheng, Gangji Yi, Qinglan Zhong, Ling Huang, Hongmei Zeng, Guohong Zou, Zhien Lin

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  21. Ligand substitution in organic–inorganic hybrid zinc iodides for second-harmonic generation

    Dalton Transactions · 2025-01-01

    Juan Cheng, Gangji Yi, Ying Long, Qinglan Zhong, Guohong Zou, Lindong Luan, Zhien Lin

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  22. Designing Polar Covalent Hybrid Cadmium‐Based Chalcohalides Ultraviolet Nonlinear Optical Crystal with Strong Optical Anisotropy via Double‐Site Dual FBUs Tailoring

    Small · 2025-01-26

    Yi‐Fan Fu, Wen‐Dong Yao, Jiajing Wu, Qiao‐Feng Huang, Yumei Zhang, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  23. Toward the Strongest Nonlinear Optical Response and Largest Birefringence in Solvent‐Free Organic–Inorganic Metal Halides by Hydrogen Bond Engineering

    Advanced Functional Materials · 2025-03-05

    Yong Wu, Yuchao Li, Yangkai Zhang, Bing Teng, Xingxing Jiang, Hu Chen, Shijia Sun, Lifeng Cao, Jinkang Ma, Kai Xu, Degang Xu, Zheshuai Lin, Degao Zhong

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  24. Phase-Matching Second-Harmonic Generation in Zero-Dimensional Zinc Thiocyanates Ligated with Chiral Amino Acids

    Inorganic Chemistry · 2025-04-17

    Qinglan Zhong, Gangji Yi, Juan Cheng, Xin Wang, Guohong Zou, Ling Huang, Zhien Lin

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  25. Synthesis and crystal structure of catena -poly[[bis(nitrato-κ 2 O , O ′)strontium(II)]-di-μ- L -histidine-κ 3 O , O ′: O ;κ 2 O : O ′]

    Acta Crystallographica Section E Crystallographic Communications · 2025-05-28

    Sathish Marimuthu, T. Balakrishnan, María Judith Percino, Perumal Venkatesan

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  26. Recent Advances in Low‐Dimensional Organic–Inorganic Hybrid Metal Halides (0D–2D) for Solid‐State Lighting

    Advanced Optical Materials · 2025-11-14

    Cong Li, Yuxin Jia, Xiaohua Cheng, Ying Liu, Juan Li, Bin‐Bin Cui

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  27. Chiral calcium thiocyanate hybrids: amino acid-enabled structural diversity and second-harmonic generation

    Chemical Communications · 2026-01-01

    Xuemei Wen, Yingjie Wang, Guohong Zou, Zhien Lin, Kang Min Ok

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  28. Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering

    Chemical Communications · 2026-01-01

    Xinyao Qi, Haonan Liu, Yu-Jie Zhang, Shihui Ma, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  29. Second-harmonic generation in two hybrid organic–inorganic metal chlorides based on l -thioproline ligand

    CrystEngComm · 2026-01-01

    Yingjie Wang, Peiqi Qian, Xuemei Wen, Hongmei Zeng, Guohong Zou, Zhien Lin

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  30. Second-harmonic generation responses in low-dimensional metal bromides functionalized with l -arginine

    CrystEngComm · 2026-01-01

    Juan Cheng, Yingjie Wang, Qinglan Zhong, Ziyu Zhou, Hongmei Zeng, Guohong Zou, Zhien Lin

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  31. Supramolecular template modulation in chiral lead bromide hybrids toward enhanced second-harmonic generation

    Chemical Communications · 2026-01-01

    Juan Cheng, Ziyu Zhou, Yingjie Wang, Lindong Luan, Guohong Zou, Zhien Lin

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  32. Nonlinear Optical Responses in One-Dimensional Zinc Thiocyanates Functionalized with Natural Amino Acids

    Inorganic Chemistry · 2026-02-05

    Xuemei Wen, Qinglan Zhong, Guohong Zou, Jing Li, Zhien Lin

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  33. Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly

    Chemistry of Materials · 2026-04-21

    Yiran Zhang, Qiao Xia, Xiaotian Zhang, Zhipeng Huang, Mark Graeme Humphrey, Liming Cheng, Kasper Moth‐Poulsen, C L Zhang, Chao Wu

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  34. Amino Acid-Directed Synthesis of Chiral Manganese Chlorides with One-Dimensional Helical Structures

    Inorganic Chemistry · 2026-07-02

    Yiwen Xu, Juan Cheng, Gangji Yi, Yingjie Wang, Guohong Zou, Jintong Song, Zhien Lin

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  35. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie International Edition · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

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  36. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

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