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RESEARCH PAPER · Advanced Optical Materials · 2020

Enhanced Cyan Emission and Optical Tuning of Ca 3 Ga 4 O 9 :Bi 3+ for High‐Quality Full‐Spectrum White Light‐Emitting Diodes

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Enhanced Cyan Emission and Optical Tuning of Ca 3 Ga 4 O 9 :Bi 3+ for High‐Quality Full‐Spectrum White Light‐Emitting DiodesOriginalRechargeable and sunlight-activated Sr3Y2Ge3O12:Bi3+ UV–Visible-NIR persistent luminescence material for night-vision signage and optical information storage108Design of a Bismuth-Activated Narrow-Band Cyan Phosphor for Use in White Light Emitting Diodes and Field Emission Displays100Ba 3 YB 3 O 9 based phosphor ceramic plates with excellent thermal stability for wLED applications18Preparation of zero-thermal-quenching tunable emission bismuth-containing phosphors through the topochemical design of ligand configuration31Structure and photoluminescence of Eu 3+ doped Sr 2 InTaO 6 red phosphor with high color purity90Designing multi-mode optical thermometers via the thermochromic LaNbO4:Bi3+/Ln3+ (Ln = Eu, Tb, Dy, Sm) phosphors321Rare-Earth-Free Barium Borostannate with Deep-Blue Light Emission16Effect of the anion on the luminescence properties of Bi3+-doped X-mayenite (X=O, F, Cl) phosphors8Improving the Light Quality of White Light‐Emitting Diodes Using Cellulose Nanocrystal‐Filled Phosphors11Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor21Bi3+ occupancy rearrangement in K2-xAxMgGeO4 phosphor to achieve ultra-broad-band white emission based on alkali metal substitution engineering38Site occupancy and photoluminescence properties of cyan-emitting K2Ca2Si2O7:Bi3+ phosphor for white light emitting diodes44Orange-emitting bimetallic nanoclusters combined with cyan-emitting Fe@TAOH as white light-emitting materials5Bismuth‐activated, narrow‐band, cyan garnet phosphor Ca 3 Y 2 Ge 3 O 12 :Bi 3+ for near‐ultraviolet‐pumped white LED application39The synthesis and photoluminescence characteristics Bi3+/Dy3+ doped Ca2LaTaO6 phosphors upon the NUV light excitation11Tailored Luminescence Output of Bi3+-Doped BaGa2O4 Phosphors with the Assistance of the Introduction of Sr2+ Ions as Secondary Cations23Constructing a Model for Tuning the Thermal Quenching Properties of Bismuth-Doped Phosphors by Energy-Gap Modulation34Novel Cyan-Green-Emitting Bi3+-Doped BaScO2F, R+ (R = Na, K, Rb) Perovskite Used for Achieving Full-Visible-Spectrum LED Lighting51Improved photoluminescence and multi-mode optical thermometry of Er3+/Yb3+ co-doped (Ba,Sr)3Lu4O9 phosphors66Variable temperature persistent luminescence properties of phosphors with continuous traps20Multifunctional Ca9NaZn1-Mg (PO4)7:Eu2+ phosphor for full-spectrum lighting, optical thermometry and pressure sensor applications112Anti-thermal-quenching, color-tunable and ultra-narrow-band cyan green-emitting phosphor for w-LEDs with enhanced color rendering85Construction of Novel Luminescent Thermometers Based on Dual-Emission Centers of Rare-Earth and Bismuth Ions33Enabling narrowband cyan photoluminescence and long-lasting ultraviolet-A persistent luminescence in Bi 3+ single-doped Sr 3 Sc 2 Ge 3 O 12 phosphors by selective site occupation48Improving the luminescence property of the novel yellow-emitting phosphor SrLa 2 Sc 2 O 7 :Bi 3+ with charge compensators (Li + , Na + , K + ) and its application in NUV-based white LEDs12Novel spectral band: ultraviolet A mechanoluminescence from Bi 3+ -doped LiYGeO 455Obtain full visible spectrum light-emitting diode illumination via bismuth-activated cyan phosphors23Effects of activated Sr 2+ ion content on strong blue‐emitting Ca 2 Sb 2 O 7 materials for high‐quality WLED devices5Pressure-driven Eu2+-doped K3Sc(PO4)2: A broad cyan-green emitting phosphor for closing the cyan cavity in solid-state lighting and applying in optical pressure sensor18Enhancing the optical information storage performance of Ca3Ga4O9: Bi3+ by co-doping with Zn2+ ions19Luminescence characteristics of SrZnSO:M (M = Bi3+, Mn2+ and Tb3+) phosphors16Single Bi3+ Ultrabroadband White Luminescence in Double Perovskite via Crystal Lattice Engineering toward Light‐Emitting Diode Applications86Optical thermometry based on enhanced up-conversion luminescence in Ba3-Yb4-O9:xEr3+,yM2+ (M=Mg, Sr, Ca) phosphors8Enhanced thermostability of Eu3+ ions photoluminescence by multi-level electron traps with various temperature responses4A novel Bi3+-Activated garnet phosphor with site-selected excitations and high temperature sensitivity42Tunable and high-color-rendering white light emissions in full visible spectral range in Ag-aggregates/Sm3+ co-doped germanate glass fluorophors16Bi 3+ /Mn 4+ co‐doped dual‐emission phosphors for potential plant lighting50Multiple Strategies to Approach High-Efficiency Luminescence Controllable in Blue/Cyan/Green-Emitting Bi 3+ -Activated Phosphors30Long persistent luminescence property of green emitting Sr3Ga4O9: Tb3+ phosphor for anti-counterfeiting application20Site‐selective occupation and luminescence property investigation of Ca 18 Na 3 Y(PO 4 ) 14 :Eu 2+ phosphor for full‐spectrum LED21Thermal Quenching Mechanism of Metal–Metal Charge Transfer State Transition Luminescence Based on Double-Band-Gap Modulation24Controlling defects to improve the emission intensity of NaMgBO3:1%Ce3+ blue-cyan phosphor3Low-concentration Ce3+-activated ScCaO(BO3) blue-cyan phosphor with high efficiency toward full-spectrum white LED applications58High-Efficiency Continuous-Luminescence-Controllable Performance and Antithermal Quenching in Bi 3+ -Activated Phosphors35Light-Induced Charge Transfer to Achieve Deep-Red Emission in SrSc2O4:Bi toward Multiple Optical Applications17Complete B-site cation regulation accomplish UV-excited red phosphors in double perovskite oxides13Design of novel cyan phosphor Ca7NaLu(PO4)6:Eu2+ for full-visible-spectrum white LED: enhanced thermal stability and tuned emission by neighbor cation effect30Luminescence Properties and Energy Transfer in SrLa2Sc2O7 Co-Doped with Bi3+/M (M = Eu3+, Mn4+, or Yb3+)4Comparison of luminescence between Eu2+-activated Na2CaPO4F and NaCaPO4 green-emitting phosphors for pc-wLEDs17Highly stable Ga-doped ZnO/polystyrene nanocomposite film with narrow-band cyan emission16High sensitivity and multicolor tunable optical thermometry in Bi3+/Eu3+ co-doped Ca2Sb2O7 phosphors64Ba5GeO4Br6:Bi3+, a promising cyan phosphor for high-quality full-spectrum white light illumination34A metal-to-metal charge transfer induced green-yellow phosphor CsAlGe 2 O 6 :Bi 3+ for full-spectrum LED devices13Ba 3 LuGa 2 O 7.5 :Bi 3+ phosphors with potential application in full-spectrum WLEDs and temperature sensing73Color-tunable emissions realized by Tb 3+ to Eu 3+ energy transfer in ZnGdB 5 O 10 under near-UV excitation9Exclusive confinement of Bi 3+ -activators in the triangular prism enabling efficient and thermally stable green emission in the tridymite-type phosphor CaBaGa 4 O 8 :Bi 3+13Novel highly efficient Bi 3+ -activated phosphors for warm WLEDs39Achievement of full-visible-spectrum lighting in Bi3+-activated strontium gallates via lattice site occupancy engineering toward WLEDs applications32Deep blue, cyan, orange-red, and white multicolor emissions generated by Bi3+/Eu3+ activated KBaYSi2O7 luminescent materials for white light-emitting diodes19A nitriding garnet structure cyan emitting phosphor Ca2(Y, Ce)Hf2(Al, Si)3(O, N)12 with high efficiency and excellent thermal stability10Synthesis and luminescence properties of Ca3Ga4O9:Eu3+: An efficient red-emitter for WLEDs39Tunable-Color UV-Excitation Sb3+/(Bi3+, Ag+)-Doped Cs2NaInCl6 Perovskite for High-Color-Rendering Full-Spectrum w-LEDs15Low temperature photo-luminescence properties of Bi3+ doped Ca3Ga4O9 phosphor6Design efficient energy transfer Ca2Al2SiO7: Bi3+, Eu3+ phosphors by cationic substitution for full-spectrum W-LED lighting23Dual-mode optical thermometers based on YNbO4:Bi3+,Sm3+ phosphors21A self-referenced fluorescence intensity ratio optical temperature sensing materials K3YSi2O7:Bi3+/Sm3+based on multi-strategy combination32Tailored luminescence of Bi doped Ca3Ga4O9 phosphors with the substitution of strontium ions4Luminescence characteristics of Ce3+/Eu2+ activated (Ba, Sr)3YB3O9 phosphors3Structural, optical, elemental and photometric properties of Sm3+ activated Ca3Ga4O9 oxide phosphors for WLEDs15Regulation of Bi3+ emission in Ca3Ga4O9 phosphors through doping concentration and solid-solution component design15Energy transfer and photoluminescence properties of CaYGaO4:Bi3+,Tb3+ phosphors14A Novel Cyan Phosphor (K,Rb) 3 GdSi 2 O 7 :Ce 3+ for Full‐Spectrum Lighting through Local Structure Tailoring48Highly efficient blue‐emitting phosphor via charge compensation strategy and its application for white LED lighting10Superior temperature sensitive luminescent properties of BaY2Al2Ga2GeO12:Bi3+8Regulation of Anti‐Thermal Quenching and Emission Color in Eu 2+ ‐Activated Na‐Beta‐Alumina Phosphors for Full‐Spectrum Illumination11A potential cyan phosphor for full spectrum light-emitting diodes: Bi3+ activated SrBaGdGaO5 phosphor20Charge compensating effect of cation doping on the enhanced luminescent and stability of La2LiTaO6:Mn4+ red phosphor21A novel blue emitting phosphor Ca 1− y Sr y ScBO 4 :Bi 3+ with zero-thermal quenching for multi-scenario application13Bright white light emission from lanthanide oxide LaGdO 3 for LED lighting by Bi 3+ to Eu 3+ energy transfer14Crystal structure, Bi 3+ yellow luminescence, and high quantum efficiency of Ba 3 SbAl 3 Ge 2 O 14 :Bi 3+ phosphor for white light-emitting diodes31Structure and photoluminescence of Mn 2+/4+ -activated doubly ordered spinel Mg 4 (Ga/Al)SbO 8 : site-selective Al 3+ -to-Ga 3+ substitution enabling Mn 4+ accumulation, excellent anti-thermal quenching of Mn 2+ green emission, and optical thermometry17Structure modification and luminescence regulation in new violet light excitable Sr (2− y ) Ba y Y 4 La 4 (SiO 4 ) 6 O 2 : x Eu 2+ phosphors via cation substitution6Photoluminescence property, energy transfer mechanism, and optical thermometric behavior of bismuth-europium codoped disordered melilite-type phosphor11Tunable emission of Ce 3+ in (K, Rb) 3 GdSi 2 O 7 phosphors toward broadband cyan luminescence5Synergistic effects of Tb doping in long-persistent luminescence in Ca3Ga4O9: xBi3+, yZn2+ phosphors: Implications for novel phosphorescent materials11Deep‐Red (Sr,Ba)Lu2O4: Eu2+ Phosphor for Full‐Spectrum Lighting7Superior Quantum Efficiency Blue‐Emitting Phosphors with High Thermal Stability toward Multipurpose LED Applications57Double-perovskite LaBaZnTa1-Mn O6 phosphors for wide-range optical thermometer and high-quality WLED devices5A narrow-band blue emitting phosphor by co-doping Bi3+ and alkali metal ions (Li+, Na+ and K+) with dual luminescence center29Suppressing Self‐Oxidation of Eu 2+ in Li 2 CaSiO 4 for Full‐Spectrum Lighting and Accurate Temperature Sensing65A novel SrLaScO4:Bi layered perovskite phosphor with broad-band green emission: Multi-cationic sites engineering, and application in high color rendering pc-WLED9Crystallographic Engineering to Develop Ultra‐Narrow‐Band Cyan‐Emitting UCr 4 C 4 ‐Type Phosphor for Healthy LED Lighting and Display24Tb3+‐Doped Ca3Ga4O9 Phosphors with Color‐Tunable Photoluminescence and Non‐Pre‐Irradiation Mechanoluminescence for Multimodal Applications23Enhancing the cyan light emission of Ba9Lu2Si6O24:Ce phosphors by crystal-site engineering for full spectrum lighting2A Novel Broadband Green Phosphor La2W2O9: Bi3+, and Its Application in High Color-Rendering Index pc-WLED1Low-temperature synthesis and luminescence properties of blue-emitting β-SiAlON:Eu2+ phosphor using melamine as a self-propagating raw material2Preparation and optical properties of Bi3+-doped K4SrGe3O9 as a UVA phosphor6Improvement in mechanoluminescence performance and implementation of dual-mode photoluminescence based on Bi3+ ion non-intrinsic defect control strategy10Thermally stimulated color-tunable performance of Ca3Ga4O9: Bi3+ by co-doping with alkali metal ions6Structural, optical, and color-tunable luminescence of Dy3+-doped Ca3Ga4O9 phosphors for white-light emitting diode applications9Full-Visible-Spectrum White LEDs Enabled by a Blue-Light-Excitable Cyan Phosphor136Structure–Photoluminescence Relationship in Ce3+-Doped K5Y(P2O7)2 and Its Sensitization to Dy3+ with Enhanced White Light Emission7Customized Cyan Phosphors for Efficient Full‐Spectrum Illumination and Fingerprint Detection22Unveiling the mechanism for excellent thermal stability in Bi3+-doped Y2O3 phosphors for NUV-pumped WLED applications8Structure, luminescence property, and optical thermometry behavior of novel Bi3 +-Eu3+ codoped tricalcium aluminate phosphor9One Pot Synthesis of Cyan Emitting CdZnSSe Quantum Dots for Human Centric Lighting1A Ca 7 Mg 1.8 Zn 0.2 Ga 6 O 18 :Bi 3+ /Mn 4+ phosphor: energy transfer enables tuneable colour emission and high sensitivity in optical thermometry3Insight into temperature dependence of the photoluminescence properties of bright orange-red BaAl 4 Sb 2 O 12 :Bi 3+ phosphors for fluorescence thermometry2A self-recoverable mechano-photonic phosphor for high-level anti-counterfeiting8Multi-color Ca3Ga4O9: Pr3+ phosphors for high-security-level optical information storage6Eco-friendly synthesis and multifunctional applications of Ba2ZnGe2O7:Bi3+ phosphors for advanced radiation dosimetry and high-performance w-LEDs21Trace Bi3+ doped single-phase Ca3WO6 phosphor with tunable cool-to-warm white light emission5Next‐Generation Multilevel Anti‐Counterfeiting Technologies: Deciphering the UV/Violet Luminescence of Bi‐Doped Yttrium Germanates4Mechanoluminescence of Bi‐Activated NaYGeO4 Polycrystals and 3D Printed Scaffolds in the NUV/Blue and NIR Spectral Range3Effect of Ca2+ partial substitution with Mg2+ on luminescence enhancement of Ca3Ga4O9:Bi3+ cyan-emitting phosphors for warm WLEDs4Effects of molten salt assistance on reaction pathways and luminescent properties of Ca14Zn6Ga10O35:Mn4+ phosphors3A multifunctional Sm3+/Mn4+ co-doped stannate phosphor for applications in WLEDs, plant cultivation, and multi-mode temperature sensing8Effect of CaO Content on the Photoluminescence Excitation and Emission Properties of Bi2O3 and ZnO-Co-Doped Ca2+xGa4O8+x Phosphors0Efficient Tuning of Blue-to-Cyan-Green Emission in Bismuth(III)-Doped Alkaline-Earth Aluminates via Crystal Site Engineering2A Novel Substrate‐Free Ultrathin Cyan‐Emitting Phosphor‐Glass Composite Based on Ce‐Activated Ca 2 YAlGa 2 Si 2 O 12 Microcrystal5Effects of alkaline-earth metal oxides and heat treatment on the structure and cyan-luminescence properties of Bi3+-doped SiO2-MO-Y2O3-ZnO-ZrO2-Ga2O3 (M = Ca, Sr, Ba) glass and Y2Zr2O7 transparent glass-ceramic1Multi-site engineering of Bi3+ in Ca3Y2Si3O12 enables excitation-switchable blue-to-green luminescence for full-spectrum white LEDs0Oxygen vacancy‐induced cerium self‐reduction in cyan‐emitting phosphors for high‐quality white lighting and visible light communication applications7A Novel Cyan‐Emitting Phosphor K 3 Ca 0.3 Y 0.7 Si 2 O 7 :Ce 3+ Enables Full‐Spectrum Lighting and Fingerprint Detection via Phase‐Structure Alteration9Near-white emission in Ba2Sc2B4O11: Bi3+, Eu3+ phosphors exhibiting magnetic and electric dipole transition variations4Sn4+ mediated Bi3+ occupation engineering in titanogermanate phosphors: Broad-spectrum emission design for application in healthy lighting0A broadband cyan Na-β"-Al2O3: Eu2+, Ce3+ phosphor based on Eu2+ double-site occupancy for WLED1Enhanced thermal stability of Bi3+-doped CaGa2O4 phosphors for next-gen WLED applications4Enhanced luminescence performance and environment-dependent multicolor emissions of Bi3+-activated KBaYSi2O7 achieved by an efficient doping strategy1Sr2Sb2O7: A multifunctional oxide platform for cyan-compensated healthy lighting and near-infrared applications3Cation substitution strategy drives a 4.8-fold luminescence enhancement in double perovskite phosphors for efficient dual-strategy WLEDs0Eliminating disorderly A sites: Significantly enhanced external quantum efficiency of Bi 3+ luminescence in double perovskite phosphor7Charge compensation to enhance the performance of Mn4+-doped Ba3Al2F12 red phosphor and its applications in warm WLEDs and backlight LEDs1EFFECT OF CAO AND BI 2 O 3 CONTENTS ON THE PHOTOLUMINESCENCE PROPERTIES OF BI 2 O 3 AND ZNO-CO-DOPED CA2+X GA 4 O8+X PHOSPHORS0Double-mode-stimulus multicolor light-emitting phosphor of non-rare-earth activated silicate modulated by cationic substitution engineering used for dynamic fluorescent anti-counterfeiting0K+ and Ce3+ co-doped Ba2.96P4O13:0.04Eu2+ white light emitting phosphor: Crystal phase transformation analysis and luminescence properties0Photoluminescence properties of Bi 3+ doped CaGa 2 O 4 -Ca 3 Ga 4 O 9 phosphors for high color rendering index warm white light emitting diodes applications0Anti-thermal quenching of YNbO4:Eu3+/Er3+ for multi-functional applications0Advancing health-oriented LED illumination using an excellent broadband cyan-emitting Ba2MgGe2O7:Bi3 + phosphor0

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