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RESEARCH PAPER · Chemistry of Materials · 2004

Isolation of Intermediate-Valent Ce(III)/Ce(IV) Hydrolysis Products in the Preparation of Cerium Iodates: Electronic and Structural Aspects of Ce2(IO3)6(OHx) (x ≈ 0 and 0.44)

Richard E. Sykora, Laura Deakin, A. Mar, S. Skanthakumar, L. Soderholm, Thomas E. Albrecht‐Schmitt

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Isolation of Intermediate-Valent Ce(III)/Ce(IV) Hydrolysis Products in the Preparation of Cerium Iodates: Electronic and Structural Aspects of Ce2(IO3)6(OHx) (x ≈ 0 and 0.44)OriginalMolecular design of inorganic scintillators: from alkoxides to scintillating materials66Isolation of Intermediate‐Valent Ce(III)/Ce(IV) Hydrolysis Products in the Preparation of Cerium Iodates: Electronic and Structural Aspects of Ce2(IO3)6(OHx) (x ≈ 0 and 0.44).1Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)348Chapter 229 Applications of tetravalent cerium compounds39Na2.4CeSi6O15·2.6H2O: Hydrothermal synthesis, characterization and properties of a new luminescent microporous cerium silicate20Hydrothermal synthesis and structure characterization of the first organically templated metal iodates2Hydrothermal Synthesis, Structural Characterisations, and Photoluminescence Properties of Four Inorganic‐Organic Hybrid Compounds in the Indium/Gallium Iodate Family11Magnetism and Raman spectroscopy of the dimeric lanthanide iodates Ln(IO3)3 (Ln=Gd, Er) and magnetism of Yb(IO3)322Hydrothermal Synthesis and X‐ray Crystal Structure of Four Inorganic‐Organic Hybrid Compounds in Vanadium /Copper Iodate Family0The use of hydrogenated Schiff base ligands in the synthesis of multi-metallic compounds34The use of hydrogenated Schiff base ligands in the synthesis of multi-metallic compounds II36BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks30Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)29Comparisons of Plutonium, Thorium, and Cerium Tellurite Sulfates41Thermochromism, the Alexandrite Effect, and Dynamic Jahn–Teller Distortions in Ho2Cu(TeO3)2(SO4)221Iodosylbenzene and iodylbenzene adducts of cerium( iv ) complexes bearing chelating oxygen ligands18Effects of Air Annealing on Luminescent Properties of Cerium-Doped Lutetium Oxyorthosilicate Scintillation Ceramics8Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates22Dispersion of ceria nanoparticles on γ-alumina surface functionalized using long chain carboxylic acids29A new cerium iodate infrared nonlinear optical material with a large second-harmonic generation response30Incipient class II mixed valency in a plutonium solid-state compound38Electronic Structure and Properties of Berkelium Iodates38[Ag 2 M(Te 2 O 5 ) 2 ]SO 4 (M = Ce IV or Th IV ): A New Purely Inorganic d/f-Heterometallic Cationic Material12A x Ce 9 (IO 3 ) 36 (A = K, La): the effects of a change in the intermediate valence on the second-harmonic generation response7Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L 3 ‐edge Puzzle46Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L3‐edge Puzzle15Self-healing performance and corrosion resistance of novel CeO2-sealed MAO film on aluminum alloy62Reactivity of a Chloride Decorated, Mixed Valent Ce III/IV 38 –Oxo Cluster16Preparation and properties of MAO self-healing anticorrosion film on 5B70 Al alloy4Photoabsorption of 1–2 nm molecular Ce-oxo nanoclusters versus ceria: intervalence charge transfer but no size effects7Synthesis and Properties of Stable Oxo-Bridged Dinuclear Pr IV Complexes3

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  1. Molecular design of inorganic scintillators: from alkoxides to scintillating materials

    Journal of Materials Chemistry · 2004-01-01

    Christelle Mansuy, Jean‐Marie Nédélec, Rachid Mahiou

    Read original paper ↗ ·

  2. Isolation of Intermediate‐Valent Ce(III)/Ce(IV) Hydrolysis Products in the Preparation of Cerium Iodates: Electronic and Structural Aspects of Ce2(IO3)6(OHx) (x ≈ 0 and 0.44).

    ChemInform · 2004-06-15

    Richard E. Sykora, Laura Deakin, Arthur Mar, S. Skanthakumar, L. Soderholm, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  3. Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)3

    Inorganic Chemistry · 2005-07-06

    Richard E. Sykora, Zerihun Assefa, Richard Geoffrey Haire, Thomas E. Albrecht‐Schmitt

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  4. Chapter 229 Applications of tetravalent cerium compounds

    Elsevier eBooks · 2006-01-01

    Koen Binnemans

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  5. Na2.4CeSi6O15·2.6H2O: Hydrothermal synthesis, characterization and properties of a new luminescent microporous cerium silicate

    Microporous and Mesoporous Materials · 2007-06-14

    Guangmei Wang, Wenfu Yan, Peng Chen, Xi Wang, Kun Qian, Tan Su, Jihong Yu

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  6. Hydrothermal synthesis and structure characterization of the first organically templated metal iodates

    Inorganica Chimica Acta · 2008-03-11

    Xiaomin Liu, Guanghua Li, Yawei Hu, Yang Yu, Minghui Bi, Zhan Shi, Shouhua Feng

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  7. Hydrothermal Synthesis, Structural Characterisations, and Photoluminescence Properties of Four Inorganic‐Organic Hybrid Compounds in the Indium/Gallium Iodate Family

    European Journal of Inorganic Chemistry · 2008-04-21

    Xiaomin Liu, Guanghua Li, Bin Hu, Yang Yu, Yawei Hu, Minghui Bi, Zhan Shi, Shouhua Feng

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  8. Magnetism and Raman spectroscopy of the dimeric lanthanide iodates Ln(IO3)3 (Ln=Gd, Er) and magnetism of Yb(IO3)3

    Journal of Solid State Chemistry · 2008-05-04

    Richard E. Sykora, Peter G. Khalifah, Zerihun Assefa, Thomas E. Albrecht‐Schmitt, Richard Geoffrey Haire

    Read original paper ↗ ·

  9. Hydrothermal Synthesis and X‐ray Crystal Structure of Four Inorganic‐Organic Hybrid Compounds in Vanadium /Copper Iodate Family

    Zeitschrift für anorganische und allgemeine Chemie · 2008-06-10

    Xiaomin Liu, Guanghua Li, Minghui Bi, Yawei Hu, Yang Yu, Zhan Shi, Shouhua Feng

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  10. The use of hydrogenated Schiff base ligands in the synthesis of multi-metallic compounds

    Inorganica Chimica Acta · 2008-06-28

    Abdullahi Mustapha, J. Reglinski, Alan Robert Kennedy

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  11. The use of hydrogenated Schiff base ligands in the synthesis of multi-metallic compounds II

    Polyhedron · 2011-04-13

    Abdullahi Mustapha, Christoph Busche, J. Reglinski, Alan Robert Kennedy

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  12. BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response

    Journal of the American Chemical Society · 2011-07-21

    Sau Doan Nguyen, Jeongho Yeon, Sang-Hwan Kim, P. Shiv Halasyamani

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  13. Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks

    Inorganic Chemistry · 2012-09-19

    Jian Hung Lin, Juan Diwu, Justin N. Cross, Eric M. Villa, Thomas E. Albrecht‐Schmitt

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  14. Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)

    Inorganic Chemistry · 2012-10-17

    Jian Hung Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric M. Villa, Thomas E. Albrecht‐Schmitt

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  15. Comparisons of Plutonium, Thorium, and Cerium Tellurite Sulfates

    Inorganic Chemistry · 2013-03-25

    Jian Hung Lin, Justin N. Cross, Juan Diwu, Nathan A. Meredith, Thomas E. Albrecht‐Schmitt

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  16. Thermochromism, the Alexandrite Effect, and Dynamic Jahn–Teller Distortions in Ho2Cu(TeO3)2(SO4)2

    Inorganic Chemistry · 2013-11-01

    Jian Hung Lin, Kariem Diefenbach, Justin N. Cross, Jean‐Marie Babo, Thomas E. Albrecht‐Schmitt

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  17. Iodosylbenzene and iodylbenzene adducts of cerium( iv ) complexes bearing chelating oxygen ligands

    Dalton Transactions · 2016-01-01

    Ka‐Chun Au‐Yeung, Yat‐Ming So, Guocang Wang, Herman H. Y. Sung, Ian Duncan Williams, Wa‐Hung Leung

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  18. Effects of Air Annealing on Luminescent Properties of Cerium-Doped Lutetium Oxyorthosilicate Scintillation Ceramics

    IEEE Transactions on Nuclear Science · 2016-04-01

    Lingcong Fan, Debao Lin, Ying Shi, Jieyu Zhang, Jianjun Xie, Fang Lei, Lei Zhang

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  19. Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates

    Inorganic Chemistry · 2016-04-12

    Samantha K. Cary, Maryline G. Ferrier, Ryan Baumbach, Mark A. Silver, Juan S. Lezama-Pacheco, Stosh A. Kozimor, Henry S. La Pierre, Benjamin William Stein, Alexandra A. Arico, Danielle L. Gray, Thomas E. Albrecht‐Schmitt

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  20. Dispersion of ceria nanoparticles on γ-alumina surface functionalized using long chain carboxylic acids

    Applied Surface Science · 2016-12-16

    Karolina Anna Ledwa, Leszek Kępiński

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  21. A new cerium iodate infrared nonlinear optical material with a large second-harmonic generation response

    Journal of Materials Chemistry C · 2017-01-01

    Lei Xiao, Zhenbo Cao, Jiyong Yao, Zheshuai Lin, Zhanggui Hu

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  22. Incipient class II mixed valency in a plutonium solid-state compound

    Nature Chemistry · 2017-05-08

    Samantha K. Cary, Shane S. Galley, Matthew L. Marsh, David L. Hobart, Ryan Baumbach, Justin N. Cross, Jared T. Stritzinger, Matthew J. Polinski, Laurent Maron, Thomas E. Albrecht‐Schmitt

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  23. Electronic Structure and Properties of Berkelium Iodates

    Journal of the American Chemical Society · 2017-08-17

    Mark A. Silver, Samantha K. Cary, Alejandro J. Garza, Ryan Baumbach, Alexandra A. Arico, Gregory A. Galmin, Kuan-Wen Chen, Jason A. Johnson, Jamie C. Wang, Ronald Jene Clark, Alexander T. Chemey, Teresa M. Eaton, Matthew L. Marsh, Kevin Seidler, Shane S. Galley, Lambertus J. van de Burgt, Ashley L. Gray, David E. Hobart, Kenneth Hanson, Shelley M. Van Cleve, Frédéric Gendron, Jochen Autschbach, Gustavo E. Scuseria, Laurent Maron, Manfred Speldrich, Paul Kögerler, Cristian Celis‐Barros, Dayán Páez‐Hernández, Ramiro Arratia‐Pérez, Michael Ruf, Thomas E. Albrecht‐Schmitt

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  24. [Ag 2 M(Te 2 O 5 ) 2 ]SO 4 (M = Ce IV or Th IV ): A New Purely Inorganic d/f-Heterometallic Cationic Material

    Inorganic Chemistry · 2018-04-16

    Todd N. Poe, Frankie D. White, Vanessa Proust, Eric M. Villa, Matthew J. Polinski

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  25. A x Ce 9 (IO 3 ) 36 (A = K, La): the effects of a change in the intermediate valence on the second-harmonic generation response

    Dalton Transactions · 2019-10-14

    Hong‐Xin Tang, Chao Zhuo, Yu‐Xiao Zhang, Qirui Shui, Ruibiao Fu, Zuju Ma, Xin‐Tao Wu

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  26. Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L 3 ‐edge Puzzle

    Chemistry - A European Journal · 2021-02-10

    Dumitru‐Claudiu Sergentu, Corwin H. Booth, Jochen Autschbach

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  27. Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L3‐edge Puzzle

    Chemistry - A European Journal · 2021-04-21

    Dumitru‐Claudiu Sergentu, Corwin H. Booth, Jochen Autschbach

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  28. Self-healing performance and corrosion resistance of novel CeO2-sealed MAO film on aluminum alloy

    Surface and Coatings Technology · 2021-04-21

    Yue Gong, Jiwei Geng, Jie Huang, Zhe Chen, Haowei Wang, Dong Chen, Haowei Wang

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  29. Reactivity of a Chloride Decorated, Mixed Valent Ce III/IV 38 –Oxo Cluster

    Inorganic Chemistry · 2021-12-16

    Jennifer N. Wacker, Alexander S. Ditter, Samantha K. Cary, Aphra V. Murray, Jeffery A. Bertke, Gerald T. Seidler, Stosh A. Kozimor, Karah E. Knope

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  30. Preparation and properties of MAO self-healing anticorrosion film on 5B70 Al alloy

    Physica Scripta · 2023-10-27

    Mingjin Wu, Feng Jiang

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  31. Photoabsorption of 1–2 nm molecular Ce-oxo nanoclusters versus ceria: intervalence charge transfer but no size effects

    Chemical Science · 2025-01-01

    Stephen E. Brown, Sebastian D. Pike

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  32. Synthesis and Properties of Stable Oxo-Bridged Dinuclear Pr IV Complexes

    Journal of the American Chemical Society · 2026-06-15

    Chenyang Hu, Luca Demonti, Pragati Pandey, Thayalan Rajeshkumar, Andrzej Sienkiewicz, Ivica Živković, Rosario Scopelliti, Laurent Maron, Marinella Mazzanti

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