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RESEARCH PAPER · Inorganic Chemistry · 2007

[Mo16O53F2]12-: a New Polyoxofluoromolybdate Anion

Adam K. Stover, Jesse Gutnick, Amy Narducci Sarjeant, Alexander J. Norquist

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[Mo16O53F2]12-: a New Polyoxofluoromolybdate AnionOriginal[Mo16O53F2]12‐: A New Polyoxofluoromolybdate Anion.0Chromium, molybdenum and tungsten1Synthetic Approaches for Noncentrosymmetric Molybdates59Hydrothermal Strategies Towards Polyoxofluoromolybdates(VI)18Charge density matching in templated molybdates26Inorganic–organic hybrid compounds based on the co-existence of different isomers or forms of polymolybdate41Hydrothermal synthesis and structure of a two-dimensional bimetallic copper–molybdophosphonate, [{Cu4(H2O)2(phenbisterpy)2(HO3P(CH2)4PO3H)}(Mo4FO12)2{O3P(CH2)4PO3}]·4H2O, constructed from {Mo4FO12}1− clusters and copper-ligand chains (phenbisterpy = 1,4-bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene)15Hydrothermal Chemistry of Oxomolybdenum-1,4-Carboxyphenylphosphonates in the Presence of M(II)-Organonitrogen Building Blocks (M(II) = Co, Ni, and Cu).43Fluorine Tagging of Polyoxometalates: The Cyclic [{MoV2O4(H2O)}4{O3PC(CF3)(O)PO3}4]12–21Polyoxometalate Supported Transition Metal Complexes: Synthesis, Crystal Structures, and Supramolecular Chemistry41Step-wise synthesis of inorganic–organic hybrid based on γ-octamolybdate-based tectons34“Fluoride molecular scissors”: A rational construction of new Mo(VI) oxofluorido/1,2,4-triazole MOFs16Chromium, molybdenum and tungsten4pH-Controlled Assembly of Two Unusual Entangled Motifs Based on a Tridentate Ligand and Octamolybdate Clusters: 1D + 1D → 3D Poly-Pseudorotaxane and 2D → 2D → 3D Polycatenation68New structural units in molybdenum oxyfluoride chemistry14Cadmium–Organic Coordination Polymers Based on N-Donor Ligands and Small Anions: Syntheses, Crystal Structures, and Photoluminescent Properties44A hybrid compound based on octamolybdates and a rigid multidentate ligand: synthesis, structure and characterization4Unprecedented Trapping of Difluorooctamolybdate Anions within an α-Polonium Type Coordination Network13Solid state coordination chemistry of oxomolybdenum–organodiphosphonate materials: consequences of introducing xylyldiphosphonate components34Synthesis and crystal structures of (pyH)2[Mo2O4F6] and (pipH2)[Mo2O4F6]; vibrational band assignment for [Mo2O4F6]2− anion4Two Hybrid Compounds Based on Octamolybdate and an N‐Donor Multidentate Ligand: Syntheses, Structures, and Properties6[V12O30F4(H2O)2]4−: One-pot synthesis and characterization of a novel fluorinated dodecavanadate9Formation Principles for Vanadium Selenites: The Role of pH on Product Composition12Role of Noncovalent Interactions in Vanadium Tellurite Chain Connectivities14A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of “Rather Labile” Fluoride Anions11A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of “Rather Labile” Fluoride Anions5The role of inorganic acidity on templated vanadate composition and dimensionality4Understanding structural adaptability: a reactant informatics approach to experiment design12Reversible Temperature Dependent Dimerization of Transition Metal Substituted Quasi Wells–Dawson Polyfluoroxometalates5Templated vanadium tellurites: Identifying the effects of low density attractions on inorganic layer topology4Lewis Acidic Behavior of MoOF4 towards the Alkali Metal Fluorides in Anhydrous Hydrogen Fluoride Solutions33Predicting inorganic dimensionality in templated metal oxides8Predicting compositional changes of organic–inorganic hybrid materials with Augmented CycleGAN4Structural Variation In β‐Octamolybdate Polyoxoanion Based Crystals Across Lanthanide Series Isolated from a Water/DMSO Solution0

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  1. [Mo16O53F2]12‐: A New Polyoxofluoromolybdate Anion.

    ChemInform · 2007-07-25

    Adam K. Stover, Jesse Gutnick, Amy Narducci Sarjeant, Alexander J. Norquist

    Read original paper ↗ ·

  2. Chromium, molybdenum and tungsten

    Annual Reports Section A (Inorganic Chemistry) · 2008-01-01

    Alvin A. Holder

    Read original paper ↗ ·

  3. Synthetic Approaches for Noncentrosymmetric Molybdates

    Inorganic Chemistry · 2008-09-29

    Desmond J. Hubbard, Alexander R. Johnston, Hernan Sanchez Casalongue, Amy Narducci Sarjeant, Alexander J. Norquist

    Read original paper ↗ ·

  4. Hydrothermal Strategies Towards Polyoxofluoromolybdates(VI)

    Crystal Growth & Design · 2008-12-15

    Alexej Michailovski, Firasat Hussain, Bernhard Spingler, Jörg Wagler, Greta Ricarda Patzke

    Read original paper ↗ ·

  5. Charge density matching in templated molybdates

    Journal of Solid State Chemistry · 2009-03-07

    Hernan Sanchez Casalongue, Sarah J. Choyke, Amy Narducci Sarjeant, Joshua Schrier, Alexander J. Norquist

    Read original paper ↗ ·

  6. Inorganic–organic hybrid compounds based on the co-existence of different isomers or forms of polymolybdate

    CrystEngComm · 2010-01-01

    Hong‐Ying Zang, Ke Tan, Wei Guan, Shun‐Li Li, Guang‐Sheng Yang, Kui‐Zhan Shao, Li‐Kai Yan, Zhong‐Min Su

    Read original paper ↗ ·

  7. Hydrothermal synthesis and structure of a two-dimensional bimetallic copper–molybdophosphonate, [{Cu4(H2O)2(phenbisterpy)2(HO3P(CH2)4PO3H)}(Mo4FO12)2{O3P(CH2)4PO3}]·4H2O, constructed from {Mo4FO12}1− clusters and copper-ligand chains (phenbisterpy = 1,4-bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene)

    Inorganic Chemistry Communications · 2010-02-05

    Stephanie Jones, Hongxue Liu, W. Ouellette, Katherine Schmidtke, Charles J. O’Connor, Jon A. Zubieta

    Read original paper ↗ ·

  8. Hydrothermal Chemistry of Oxomolybdenum-1,4-Carboxyphenylphosphonates in the Presence of M(II)-Organonitrogen Building Blocks (M(II) = Co, Ni, and Cu).

    Crystal Growth & Design · 2010-04-01

    P. DeBurgomaster, Amanda R. Aldous, Hongxue Liu, Charles J. O’Connor, Jon A. Zubieta

    Read original paper ↗ ·

  9. Fluorine Tagging of Polyoxometalates: The Cyclic [{MoV2O4(H2O)}4{O3PC(CF3)(O)PO3}4]12–

    European Journal of Inorganic Chemistry · 2010-07-21

    Abhishek Banerjee, Bassem S. Bassil, Gerd‐Volker Röschenthaler, Ulrich Kortz

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  10. Polyoxometalate Supported Transition Metal Complexes: Synthesis, Crystal Structures, and Supramolecular Chemistry

    Crystal Growth & Design · 2010-09-21

    T. Arumuganathan, A. Srinivasa Rao, Samar K. Das

    Read original paper ↗ ·

  11. Step-wise synthesis of inorganic–organic hybrid based on γ-octamolybdate-based tectons

    Dalton Transactions · 2011-01-01

    Hong‐Ying Zang, Ya‐Qian Lan, Shun‐Li Li, Guang‐Sheng Yang, Kui‐Zhan Shao, Xinlong Wang, Li‐Kai Yan, Zhong‐Min Su

    Read original paper ↗ ·

  12. “Fluoride molecular scissors”: A rational construction of new Mo(VI) oxofluorido/1,2,4-triazole MOFs

    Inorganic Chemistry Communications · 2011-06-03

    Ganna A. Senchyk, A.B. Lysenko, Harald Krautscheid, K.V. Domasevitch

    Read original paper ↗ ·

  13. Chromium, molybdenum and tungsten

    Annual Reports Section A (Inorganic Chemistry) · 2012-01-01

    Alvin A. Holder

    Read original paper ↗ ·

  14. pH-Controlled Assembly of Two Unusual Entangled Motifs Based on a Tridentate Ligand and Octamolybdate Clusters: 1D + 1D → 3D Poly-Pseudorotaxane and 2D → 2D → 3D Polycatenation

    Crystal Growth & Design · 2012-04-04

    Hua Wu, Jin Zhong Yang, Ying‐Ying Liu, Jian‐Fang Ma

    Read original paper ↗ ·

  15. New structural units in molybdenum oxyfluoride chemistry

    Journal of Fluorine Chemistry · 2012-08-09

    David W. Aldous, Philip Lightfoot

    Read original paper ↗ ·

  16. Cadmium–Organic Coordination Polymers Based on N-Donor Ligands and Small Anions: Syntheses, Crystal Structures, and Photoluminescent Properties

    Crystal Growth & Design · 2012-09-19

    Jie Guo, Di Sun, Di Sun, Liangliang Zhang, Qiao Wen Yang, Xiaoliang Zhao, Daofeng Sun, Daofeng Sun

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  17. A hybrid compound based on octamolybdates and a rigid multidentate ligand: synthesis, structure and characterization

    RSC Advances · 2013-01-01

    Shi Lin Zhou, Bo Liu, Ya-Guang Chen, Xiaomin Li, Dongxiao Wang

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  18. Unprecedented Trapping of Difluorooctamolybdate Anions within an α-Polonium Type Coordination Network

    Inorganic Chemistry · 2013-07-12

    Olena V. Sharga, A.B. Lysenko, Marcel Handke, Harald Krautscheid, Eduard B. Rusanov, Alexander N. Chernega, Karl W. Krämer, Shi‐Xia Liu, Silvio Decurtins, Adam J. Bridgeman, K.V. Domasevitch

    Read original paper ↗ ·

  19. Solid state coordination chemistry of oxomolybdenum–organodiphosphonate materials: consequences of introducing xylyldiphosphonate components

    CrystEngComm · 2013-10-09

    Tiffany M. Smith, Kathryn Perkins, Diona Symester, Steve R. Freund, Jose Marcelo Vargas, Leonard Spînu, Jon A. Zubieta

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  20. Synthesis and crystal structures of (pyH)2[Mo2O4F6] and (pipH2)[Mo2O4F6]; vibrational band assignment for [Mo2O4F6]2− anion

    Journal of Fluorine Chemistry · 2013-10-26

    Gleb Veryasov, Dmitry I. Morozov, Evgeny Goreshnik, Adolf Jesih

    Read original paper ↗ ·

  21. Two Hybrid Compounds Based on Octamolybdate and an N‐Donor Multidentate Ligand: Syntheses, Structures, and Properties

    European Journal of Inorganic Chemistry · 2013-11-19

    Shi Lin Zhou, Ya-Guang Chen, Bo Liu, Xiaomin Li, Dong‐Xiao Wang

    Read original paper ↗ ·

  22. [V12O30F4(H2O)2]4−: One-pot synthesis and characterization of a novel fluorinated dodecavanadate

    Inorganic Chemistry Communications · 2014-09-16

    Lukáš Krivosudský, Peter Schwendt, Róbert Gyepes, Juraj Filo

    Read original paper ↗ ·

  23. Formation Principles for Vanadium Selenites: The Role of pH on Product Composition

    Inorganic Chemistry · 2014-11-03

    Jacob H. Olshansky, Karina J. Wiener, Matthew D. Smith, Anahita Nourmahnad, Max J. Charles, Mat­thias Zeller, Joshua Schrier, Alexander J. Norquist

    Read original paper ↗ ·

  24. Role of Noncovalent Interactions in Vanadium Tellurite Chain Connectivities

    Inorganic Chemistry · 2015-01-08

    Anahita Nourmahnad, Matthew D. Smith, Mat­thias Zeller, Gregory M. Ferrence, Joshua Schrier, Alexander J. Norquist

    Read original paper ↗ ·

  25. A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of “Rather Labile” Fluoride Anions

    Angewandte Chemie International Edition · 2015-03-24

    Somenath Garai, Mirta Rubčić, Hartmut Bögge, Erhard T. K. Haupt, Pierre Gouzerh, Achim Müller

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  26. A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of “Rather Labile” Fluoride Anions

    Angewandte Chemie · 2015-03-24

    Somenath Garai, Mirta Rubčić, Hartmut Bögge, Erhard T. K. Haupt, Pierre Gouzerh, Achim Müller

    Read original paper ↗ ·

  27. The role of inorganic acidity on templated vanadate composition and dimensionality

    Journal of Solid State Chemistry · 2015-08-06

    Anahita Nourmahnad, Malia B. Wenny, Mat­thias Zeller, Joshua Schrier, Alexander J. Norquist

    Read original paper ↗ ·

  28. Understanding structural adaptability: a reactant informatics approach to experiment design

    Molecular Systems Design & Engineering · 2018-01-01

    Rosalind J. Xu, Jacob H. Olshansky, Philip Adler, Yongjia Huang, Matthew D. Smith, Mat­thias Zeller, Joshua Schrier, Alexander J. Norquist

    Read original paper ↗ ·

  29. Reversible Temperature Dependent Dimerization of Transition Metal Substituted Quasi Wells–Dawson Polyfluoroxometalates

    European Journal of Inorganic Chemistry · 2018-06-11

    Marco Bugnola, Roy E. Schreiber, Yehonatan Kaufman, Gregory M. Leitus, Linda J. W. Shimon, Ronny Neumann

    Read original paper ↗ ·

  30. Templated vanadium tellurites: Identifying the effects of low density attractions on inorganic layer topology

    Journal of Solid State Chemistry · 2019-02-27

    Xiwen Jia, Jessica L. Dixon, Mat­thias Zeller, Joshua Schrier, Alexander J. Norquist

    Read original paper ↗ ·

  31. Lewis Acidic Behavior of MoOF4 towards the Alkali Metal Fluorides in Anhydrous Hydrogen Fluoride Solutions

    European Journal of Inorganic Chemistry · 2019-07-16

    Riane E. Stene, Benjamin Scheibe, Antti J. Karttunen, W. Petry, Florian Kraus

    Read original paper ↗ ·

  32. Predicting inorganic dimensionality in templated metal oxides

    The Journal of Chemical Physics · 2021-05-12

    Qianxiang Ai, Davion Marquise Williams, Matthew Danielson, Liam G. Spooner, Joshua A. Engler, Zihui Ding, Mat­thias Zeller, Alexander J. Norquist, Joshua Schrier

    Read original paper ↗ ·

  33. Predicting compositional changes of organic–inorganic hybrid materials with Augmented CycleGAN

    Digital Discovery · 2022-01-01

    Qianxiang Ai, Alexander J. Norquist, Joshua Schrier

    Read original paper ↗ ·

  34. Structural Variation In β‐Octamolybdate Polyoxoanion Based Crystals Across Lanthanide Series Isolated from a Water/DMSO Solution

    Chemistry - An Asian Journal · 2024-12-23

    Shailabh Tewari, Shailabh Tewari, Arunachalam Ramanan, Arunachalam Ramanan

    Read original paper ↗ ·
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