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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2019

Lewis Acidic Behavior of MoOF4 towards the Alkali Metal Fluorides in Anhydrous Hydrogen Fluoride Solutions

Riane E. Stene, Benjamin Scheibe, Antti J. Karttunen, W. Petry, Florian Kraus

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Lewis Acidic Behavior of MoOF4 towards the Alkali Metal Fluorides in Anhydrous Hydrogen Fluoride SolutionsOriginalChromium Oxide Tetrafluoride and Its Reactions with Xenon Hexafluoride; the [XeF 5 ] + and [Xe 2 F 11 ] + Salts of the [Cr VI OF 5 ] − , [Cr V OF 5 ] 2− , [Cr V 2 O 2 F 8 ] 2− , and [Cr IV F 6 ] 2− Anions12Synthesis and Characterization of the Tetrafluoridochlorates(III) A[ClF4] (A = K, Rb, Cs)16Synthesis and Characterization of the Hexafluoridomolybdates(V) A[MoF6] (A = Li – Cs)4Group 6 Oxyfluoro‐Anion Salts of [XeF5]+ and [Xe2F11]+: Syntheses and Structures of [XeF5][M2O2F9] (M=Mo, W), [Xe2F11][M′OF5] (M′=Cr, Mo, W), [XeF5][HF2]⋅CrOF4, and [XeF5][WOF5]⋅XeOF417Synthesis and Characterization of A [W 2 O 2 F 9 ] ( A = Li – Cs)6Reactions of Molybdenum and Tungsten Oxide Tetrafluoride with Sulfur(IV) Lewis Bases: Structure and Bonding in [WOF4]4, MOF4(OSO), and [SF3][M2O2F9] (M = Mo, W)10Reactions of ClF3 with Main Group and Transition Metal Oxides: Access to Dioxychloronium(V) Fluoridometallates and Oxidofluoridometallates11Lewis Acid Behavior of MoF5 and MoOF4: Syntheses and Characterization of MoF5(NCCH3), MoF5(NC5H5)n, and MoOF4(NC5H5)n (n = 1, 2)8Thermal and mechanical properties of the clathrate-II Na24Si1365Bromine Pentafluoride BrF 5 , the Formation of [BrF 6 ] − Salts, and the Stereochemical (In)activity of the Bromine Lone Pairs12Investigating the hydrolysis of cryogenically layered molybdenum hexafluoride through a disordered hydrogen-bonded network8A new high-pressure polymorph of K 2 MoO 2 F 40Investigation on the predictive power of tolerance factor τ for A-site double perovskite oxides60Overcoming the Sticking Point: Electrical Conductivity of Carbon Nanotube Networks Containing 3d Metals5Discrete Mono-, Di-, and Trinuclear Anions [MoOF5]−, [MoVOF5]2–, [MoO2F4]2–, [Mo2O2F9]−, [Mo3O3F13]−, and the Infinite Chain Anion [MoO2F3]− Obtained from Reactions of MoOF4: Synthesis and Analysis of the Structure-Chemical Relations of the Compounds4Pyroelectric Effect in Tetragonal Ferroelectrics BaTiO3 and KNbO3 Studied with Density Functional Theory11Direct Band Gap Semiconductors with Two‐ and Three‐Dimensional Triel‐Phosphide Frameworks (Triel=Al, Ga, In)3Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Electronic Structure Analysis of the A10Tt2P6 System (A=Li−Cs; Tt=Si, Ge, Sn) and Synthesis of the Direct Band Gap Semiconductor K10Sn2P65Further Insights into the Chemical Synthesis of F2 and on Drying moist HF6Na3Ge2P3: A Zintl Phase Featuring [P3Ge–GeP3] Dimers as Building Blocks1The Peculiar Molecular [(IF5)6(HF2)4]4− Anion of the Compound K4[(IF5)6(HF2)4]2Large Number of Direct or Pseudo-Direct Band Gap Semiconductors among A3TrPn2 Compounds with A = Li, Na, K, Rb, Cs; Tr = Al, Ga, In; Pn = P, As2Open Sn Framework Structure Hosting Bi Guest atoms–Synthesis, Crystal and Electronic Structure of Na 13 Sn 26 Bi0Mono‐, Di‐, and Trinuclear Complex Anions of RuF 5 in Rb[RuF 6 ], Cs[Ru 2 F 11 ], and [O 2 ][Ru 3 F 16 ]3Reactions of Binary Nitrides in Liquid Hydrogen Fluoride and the First Calcium Oxidofluoridometallate of a Group Six Element Ca[Mo2O2F9]2 ⋅ HF1Syntheses, crystal structures, and electronic structures of new barium fluoromolybdates1Syntheses and Crystal Structures of the Novel Salts Sr[MoVI2O2F9]2·HF, Ba[MoVI2O2F9]2·2HF, and of Ba[MoVOF5]0Pyroelectric Properties of A-Site Ordered [K0.5Na0.5]NbO3 Perovskite Studied with Hybrid Density Functional Method1Icosahedral Clusters [In@Tr12]10–: Synthesis, Characterization, and Electronic Structure Investigations of Na4A6Tr13 (A = Rb, Cs; Tr = In, Tl)1Incorporation of uranium to the langbeinite family in Cs2UⅣLn(PO4)3 actinide waste forms3Synthesis and Structure Solution of Ba[SeCN] 20Synthesis, structural characterization, and electronic structure of monoclinic α-[SeCl 3 ][MoOCl 4 ]0

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  1. Chromium Oxide Tetrafluoride and Its Reactions with Xenon Hexafluoride; the [XeF 5 ] + and [Xe 2 F 11 ] + Salts of the [Cr VI OF 5 ] − , [Cr V OF 5 ] 2− , [Cr V 2 O 2 F 8 ] 2− , and [Cr IV F 6 ] 2− Anions

    Chemistry - A European Journal · 2019-08-22

    James T. Goettel, Mark R. Bortolus, Daniel Stuart, Hélène P. A. Mercier, Gary J. Schrobilgen

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  2. Synthesis and Characterization of the Tetrafluoridochlorates(III) A[ClF4] (A = K, Rb, Cs)

    European Journal of Inorganic Chemistry · 2020-02-24

    Benjamin Scheibe, Sergei I. Ivlev, Antti J. Karttunen, Florian Kraus

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  3. Synthesis and Characterization of the Hexafluoridomolybdates(V) A[MoF6] (A = Li – Cs)

    European Journal of Inorganic Chemistry · 2020-03-26

    Riane E. Stene, Benjamin Scheibe, W. Petry, Florian Kraus

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  4. Group 6 Oxyfluoro‐Anion Salts of [XeF5]+ and [Xe2F11]+: Syntheses and Structures of [XeF5][M2O2F9] (M=Mo, W), [Xe2F11][M′OF5] (M′=Cr, Mo, W), [XeF5][HF2]⋅CrOF4, and [XeF5][WOF5]⋅XeOF4

    Chemistry - A European Journal · 2020-03-30

    Mark R. Bortolus, Hélène P. A. Mercier, Gary J. Schrobilgen

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  5. Synthesis and Characterization of A [W 2 O 2 F 9 ] ( A = Li – Cs)

    European Journal of Inorganic Chemistry · 2020-05-01

    Riane E. Stene, Benjamin Scheibe, Antti J. Karttunen, W. Petry, Florian Kraus

    Read original paper ↗ ·

  6. Reactions of Molybdenum and Tungsten Oxide Tetrafluoride with Sulfur(IV) Lewis Bases: Structure and Bonding in [WOF4]4, MOF4(OSO), and [SF3][M2O2F9] (M = Mo, W)

    Inorganic Chemistry · 2020-11-17

    Douglas Turnbull, Praveen Chaudhary, Dakota Leenstra, Paul Hazendonk, Stacey D. Wetmore, Michael Gerken

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  7. Reactions of ClF3 with Main Group and Transition Metal Oxides: Access to Dioxychloronium(V) Fluoridometallates and Oxidofluoridometallates

    European Journal of Inorganic Chemistry · 2020-12-16

    Benjamin Scheibe, Antti J. Karttunen, Florian Kraus

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  8. Lewis Acid Behavior of MoF5 and MoOF4: Syntheses and Characterization of MoF5(NCCH3), MoF5(NC5H5)n, and MoOF4(NC5H5)n (n = 1, 2)

    Inorganic Chemistry · 2021-10-05

    Janelle Bykowski, Douglas Turnbull, Nolan Hahn, Renè T. Boeré, Stacey D. Wetmore, Michael Gerken

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  9. Thermal and mechanical properties of the clathrate-II Na24Si136

    Physical review. B./Physical review. B · 2022-06-30

    Matt Beekman, Antti J. Karttunen, Winnie Wong-Ng, Mingjian Zhang, Yu‐Sheng Chen, Christian Posadas, Andrew Jarymowycz, E Cruse, Wanyue Peng, Alexandra Zevalkink, James A. Kaduk, George S. Nolas

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  10. Bromine Pentafluoride BrF 5 , the Formation of [BrF 6 ] − Salts, and the Stereochemical (In)activity of the Bromine Lone Pairs

    Chemistry - A European Journal · 2022-09-15

    Martin Möbs, Tim Graubner, Kim Eklund, Antti J. Karttunen, Florian Kraus

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  11. Investigating the hydrolysis of cryogenically layered molybdenum hexafluoride through a disordered hydrogen-bonded network

    Physical Chemistry Chemical Physics · 2022-12-22

    Louis E. McNamara, Abigail Waldron, Michael Brandon Thomas, Willis Jones, Patrick O’Rourke, D.W. Simmons, K. Alicia Strange Fessler

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  12. A new high-pressure polymorph of K 2 MoO 2 F 4

    Dalton Transactions · 2023-01-01

    Fabian Zimmerhofer, Hubert Huppertz

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  13. Investigation on the predictive power of tolerance factor τ for A-site double perovskite oxides

    Dalton Transactions · 2023-01-01

    Elisabeth K. Albrecht, Antti J. Karttunen

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  14. Overcoming the Sticking Point: Electrical Conductivity of Carbon Nanotube Networks Containing 3d Metals

    The Journal of Physical Chemistry C · 2023-04-20

    Kevin M. Conley, Antti J. Karttunen

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  15. Discrete Mono-, Di-, and Trinuclear Anions [MoOF5]−, [MoVOF5]2–, [MoO2F4]2–, [Mo2O2F9]−, [Mo3O3F13]−, and the Infinite Chain Anion [MoO2F3]− Obtained from Reactions of MoOF4: Synthesis and Analysis of the Structure-Chemical Relations of the Compounds

    Inorganic Chemistry · 2023-08-09

    Tobias Burghardt Wassermann, Riane E. Stene, Benjamin Scheibe, Antti J. Karttunen, Florian Kraus

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  16. Pyroelectric Effect in Tetragonal Ferroelectrics BaTiO3 and KNbO3 Studied with Density Functional Theory

    The Journal of Physical Chemistry C · 2023-11-01

    Kim Eklund, Antti J. Karttunen

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  17. Direct Band Gap Semiconductors with Two‐ and Three‐Dimensional Triel‐Phosphide Frameworks (Triel=Al, Ga, In)

    Chemistry - A European Journal · 2023-12-31

    Tassilo M. F. Restle, Sabine Zeitz, Philip M. Stanley, Antti J. Karttunen, Jan Meyer, Gabriele Raudaschl‐Sieber, Wilhelm Klein, Thomas F. Fässler

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  18. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

    Materials Chemistry Frontiers · 2024-01-01

    Karishma Prasad, Vivian Nguyen, Bingheng Ji, Jasmine Quah, Danielle Goodwin, Jian Wang

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  19. Electronic Structure Analysis of the A10Tt2P6 System (A=Li−Cs; Tt=Si, Ge, Sn) and Synthesis of the Direct Band Gap Semiconductor K10Sn2P6

    Chemistry - A European Journal · 2024-02-07

    Sabine Zeitz, Hanna Antoniuk, Viktor H. Hlukhyy, Thomas F. Fässler

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  20. Further Insights into the Chemical Synthesis of F2 and on Drying moist HF

    Inorganic Chemistry · 2024-04-09

    Martin Möbs, Antti J. Karttunen, Karl O. Christe, Florian Kraus

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  21. Na3Ge2P3: A Zintl Phase Featuring [P3Ge–GeP3] Dimers as Building Blocks

    Inorganic Chemistry · 2024-04-19

    Manuel Botta, Sabine Zeitz, Wilhelm Klein, Gabriele Raudaschl‐Sieber, Thomas F. Fässler

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  22. The Peculiar Molecular [(IF5)6(HF2)4]4− Anion of the Compound K4[(IF5)6(HF2)4]

    Zeitschrift für anorganische und allgemeine Chemie · 2024-06-25

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  23. Large Number of Direct or Pseudo-Direct Band Gap Semiconductors among A3TrPn2 Compounds with A = Li, Na, K, Rb, Cs; Tr = Al, Ga, In; Pn = P, As

    Molecules · 2024-08-28

    Sabine Zeitz, Yulia Kuznetsova, Thomas F. Fässler

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  24. Open Sn Framework Structure Hosting Bi Guest atoms–Synthesis, Crystal and Electronic Structure of Na 13 Sn 26 Bi

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    Sabine Zeitz, M. Boyko, Siméon Ponou, Viktor H. Hlukhyy, Thomas F. Fässler

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  25. Mono‐, Di‐, and Trinuclear Complex Anions of RuF 5 in Rb[RuF 6 ], Cs[Ru 2 F 11 ], and [O 2 ][Ru 3 F 16 ]

    European Journal of Inorganic Chemistry · 2024-12-06

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  26. Reactions of Binary Nitrides in Liquid Hydrogen Fluoride and the First Calcium Oxidofluoridometallate of a Group Six Element Ca[Mo2O2F9]2 ⋅ HF

    European Journal of Inorganic Chemistry · 2025-01-07

    Tobias Burghardt Wassermann, Lukas Link, Rainer Niewa, Antti J. Karttunen, Florian Kraus

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  27. Syntheses, crystal structures, and electronic structures of new barium fluoromolybdates

    Journal of Solid State Chemistry · 2025-06-26

    Jie Ling, Chloe Jones, Oluwasegun Yusuf Raji, Mohammed Al‐Fahdi, Jackson Jones, Ming Hu

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  28. Syntheses and Crystal Structures of the Novel Salts Sr[MoVI2O2F9]2·HF, Ba[MoVI2O2F9]2·2HF, and of Ba[MoVOF5]

    European Journal of Inorganic Chemistry · 2025-08-07

    Tobias Burghardt Wassermann, Giuliana Hoß, Antti J. Karttunen, Florian Kraus

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  29. Pyroelectric Properties of A-Site Ordered [K0.5Na0.5]NbO3 Perovskite Studied with Hybrid Density Functional Method

    The Journal of Physical Chemistry C · 2025-08-28

    Kim Eklund, Antti J. Karttunen

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  30. Icosahedral Clusters [In@Tr12]10–: Synthesis, Characterization, and Electronic Structure Investigations of Na4A6Tr13 (A = Rb, Cs; Tr = In, Tl)

    European Journal of Inorganic Chemistry · 2025-09-09

    Melissa Janesch, Antti J. Karttunen, Stefanie Gärtner

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  31. Incorporation of uranium to the langbeinite family in Cs2UⅣLn(PO4)3 actinide waste forms

    Communications Chemistry · 2025-11-27

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  32. Synthesis and Structure Solution of Ba[SeCN] 2

    Zeitschrift für anorganische und allgemeine Chemie · 2026-06-16

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  33. Synthesis, structural characterization, and electronic structure of monoclinic α-[SeCl 3 ][MoOCl 4 ]

    Acta Crystallographica Section C Structural Chemistry · 2026-08-10

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