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RESEARCH PAPER · Crystal Growth & Design · 2012

pH-Controlled Assembly of Two Unusual Entangled Motifs Based on a Tridentate Ligand and Octamolybdate Clusters: 1D + 1D → 3D Poly-Pseudorotaxane and 2D → 2D → 3D Polycatenation

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pH-Controlled Assembly of Two Unusual Entangled Motifs Based on a Tridentate Ligand and Octamolybdate Clusters: 1D + 1D → 3D Poly-Pseudorotaxane and 2D → 2D → 3D PolycatenationOriginalA series of POM/Ag-based hybrids: distinct forms and assembly of [AgxLy] complexes through combinational effects of POM and isomeric ligands34The first 2D→3D polycatenation array built on (3,4)-connected bilayer nets22Unprecedented three-level hierarchical entanglement in a coordination polymer43Unusual High Thermal Stablility of a 2D → 3D Polycatenated Fe(II) Metal–Organic Framework Showing Guest-Dependent Spin-Crossover Behavior and High Spin-Transition Temperature65Syntheses, Characterizations, and Properties of Five Interpenetrating Complexes Based on 1,4-Benzenedicarboxylic Acid and a Series of Benzimidazole-Based Linkers58A novel 2D organic–inorganic hybrid based on [P2W18O62]6− polyoxoanion and Cu–bbi coordination polymers15Two novel octamolybdate-based frameworks decorated by flexible bis-pyridyl-bis-amide ligands with different spacer lengths41Structural evolution via modifying (6,3) layer: from inclined polycatenation to parallel polyrotaxane-like interpenetration10Structural modulation and properties of four cadmium(ii) coordination architectures based on 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole and aromatic polycarboxylate ligands32Three new inorganic–organic hybrid compounds constructed from two kinds of octamolybdate clusters and flexible multidentate N-donor ligand: syntheses, structures, electrochemistry, luminescence, and photocatalytic properties37Polycatenated Bilayer Structure Containing Honeycomb-like 63 Layers1Construction of Two New Metal–Organic Entangled Frameworks Via Varying Flexible Bis(Imidazole)-based Auxiliary Ligands19Self-assembly of a 3-D self-catenated framework based on [V4O12]4−polyoxoanions and cobalt-organic polymer4Interpenetration control in metal–organic frameworks for functional applications563A novel chain structure constructed from copper complexes and dimers based on bi-capped Keggin clusters6Polyoxometalate-Induced New Self-Assemblies Based on Copper Ions and Bichelate-Bridging Ligands50Construction of Entangled Coordination Polymers Based on M2+ Ions, 4,4′-{[1,2-Phenylenebis(methylene)]bis(oxy)}dibenzoate and Different N-Donor Ligands69Two octamolybdate-based complexes: hydrothermal synthesis, structural characterization and properties21pH-controlled assembly of hybrid architectures based on Anderson-type polyoxometalates and silver coordination units41Synthesis, Crystal Structures and Thermal Analysis of Two Co(II) Coordination Polymers: 3D Interdigitated Framework to fourfold Interpenetrated dia Net2Ligand geometry-directed assembly of seven entangled coordination polymers49Structures and properties of four coordination polymers constructed from 1,3-bis-(4-pyridyl)-propane and aromatic dicarboxylic acids11Two unprecedented entangled coordination polymers based on α-{SiW 12 O 40 } 4−12pH-Controlled Two New Co(II) Coordination Polymers Based on 5-Pyrimidyl Benzoic Acid: Synthesis, Structures, and Properties1New organic–inorganic hybrid assemblies based on copper(I) ion, bichelate-bridging ligand and Lindqvist-type polyoxometalate3Entangled structures in polyoxometalate-based coordination polymers112A novel 2-D structure constructed from copper complexes and bi-capped tungsten-based Keggin clusters6Entangled Two-Dimensional Coordination Networks: A General Survey285Two new helical compounds based on Keggin clusters and N-donor multidentate ligand: Syntheses, structures and properties9New Metal–Organic Frameworks Constructed from the 4-Imidazole-Carboxylate Ligand: Structural Diversities, Luminescence, and Gas Adsorption Properties74Assembly of Six Polyoxometalate-Based Hybrid Compounds from a Simple Supramolecule to a Complicated Pseudorotaxane Framework via Tuning the pH of the Reaction Systems72Synthesis and Crystal Structure of the Coordination Polymer of Ni-Mo8-Pyrazinecarboxylic Acid3Two-level hierarchical entangled framework in a novel copper(I) coordination polymer with multiform helical features and unprecedented self-penetrated subnet7Syntheses, structures, characterization and photoluminescent properties of six coordination polymers based on multidentate N-donor ligands and polycarboxylate anions9Structural diversity of five new bitriazole-based complexes: luminescence, sorption, and magnetic properties71Three coordination polymers based on different carboxylates, metals and a tri(4-imidazolylphenyl)amine ligand5Metal(II)-Directed Various Polyoxometalates-Based Hybrid Compounds: Assembly, Structures and Properties5A series of entangled coordination polymers assembled by a V-shaped bisimidazole ligand and various dicarboxylic acids: synthesis, characterization and luminescence properties21Hydrothermal syntheses and characterization of two 1D chain complexes and tetra-capped Keggin clusters3Syntheses and structures of three transition metal coordination polymers based on 5-Aminonicotinic acid5Construction of a Series of Zn(II) Compounds with Different Entangle Motifs by Varying Flexible Aliphatic Dicarboxylic Acids49Acid‐ or Base‐Induced Rearrangements of Ferrocenyl‐Decorated Organotin Sulfide Cages14Construction of two novel borotungstates modified by different ligands connected with single/double bridges14pH-Dependent assembly of three novel inorganic–organic hybrids based on different isopolymolybdates and Cu I/II (bbx) n units8Hydrothermal synthesis and electrochemical properties of a coordination polymer based on dinuclear (Pyrazinyl tetrazolate) Copper(II) cations and β-Octamolybdate Anions9An unprecedented self-penetrating Cu(I)-MOF based on a new 1D-ladder+ 2D-layer→ 3D polycatenation subnet showing luminescent sensing for nitrobenzene7Construction of Noninterpenetrating and Interpenetrating (4-Fold and 8-Fold) 3-D Cd(II) Networks with Tris(1,2,4-triazol-4-yl)phenyl)amine Modulated by Aromatic Dicarboxylate Coligands43Fluorescence detection of Mn 2+ , Cr 2 O 7 2− and nitroexplosives and photocatalytic degradation of methyl violet and rhodamine B based on two stable metal–organic frameworks70Interpenetrated Network Crystals0Polycatenation tuned microporosity of two metal–tris(4′-carboxybiphenyl)amine frameworks with multilayer structures11Highly efficient removal of Pb 2+ by a polyoxomolybdate-based organic-inorganic hybrid material {(4-Hap) 4 [Mo 8 O 26 ]}32New Route toward POM[6]Catenane Members for Lithium-Ion Batteries35Luminescent sensing of Cu 2+ , CrO 4 2− and photocatalytic degradation of methyl violet by Zn(II) metal-organic framework (MOF) having 5,5′-(1H-2,3,5-triazole-1,4-diyl)diisophthalic acid ligand28Syntheses, Structures and Properties of Two Transition Metal-Flexible Ligand Coordination Polymers3Three inorganic-organic hybrid complexes based on isopolymolybdate and derivatives of 1H-4-nitroimidazole4A novel two-fold interpenetrating 3D metal-organic framework based on Lindqvist-type hexamolybdate: Synthesis, structure, electrochemical and photocatalytic properties10Molecular structures of some bivalent metal complexes of 1-(4-acetylphenyl)imidazole and co-ligands5Construction of Cd(II) coordination polymers from a fluorene-based bisimidazole ligand and polycarboxylic acids: syntheses, structures and properties9Five new 3D transition MOFs based on 1-(3,5-dicarboxylatobenzyl)-3,5-pyrazole dicarboxylic acid displaying unique luminescence sensing towards Fe 3+ and magnetic properties20Three novel polyoxometalate-based inorganic–organic hybrid materials based on 2,6-bis(1,2,4-triazol-1-yl)pyridine18Layered CuI-MOFs containing [Mo8O26]4− clusters as supercapacitor electrode materials70Synthesis and characterization of a new (1D+1D) polyoxometalate-based polypseudo-rotaxane coordination polymer5Three new entangled Zn(II)/Cd(II)-MOFs based on a triangular tri(4- imidazolylphenyl)amine and different carboxylic acid : Crystal structures, and luminescent properties5One new hexatungstate-based binuclear nickel(II) complex with high selectivity adsorption for organic dyes8Structure, Luminescent Sensing and Proton Conduction of a Boiling-Water-Stable Zn(II) Metal-Organic Framework7The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks9Assembly of unique interpenetrated metal–organic frameworks based on flexible tetra-carboxylate ligands3Bifunctional MOFs possessing both proton conductivity and fluorescence detection capabilities2

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  2. The first 2D→3D polycatenation array built on (3,4)-connected bilayer nets

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  3. Unprecedented three-level hierarchical entanglement in a coordination polymer

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  4. Unusual High Thermal Stablility of a 2D → 3D Polycatenated Fe(II) Metal–Organic Framework Showing Guest-Dependent Spin-Crossover Behavior and High Spin-Transition Temperature

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  5. Syntheses, Characterizations, and Properties of Five Interpenetrating Complexes Based on 1,4-Benzenedicarboxylic Acid and a Series of Benzimidazole-Based Linkers

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  6. A novel 2D organic–inorganic hybrid based on [P2W18O62]6− polyoxoanion and Cu–bbi coordination polymers

    Inorganic Chemistry Communications · 2012-10-26

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  7. Two novel octamolybdate-based frameworks decorated by flexible bis-pyridyl-bis-amide ligands with different spacer lengths

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  8. Structural evolution via modifying (6,3) layer: from inclined polycatenation to parallel polyrotaxane-like interpenetration

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  9. Structural modulation and properties of four cadmium(ii) coordination architectures based on 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole and aromatic polycarboxylate ligands

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  10. Three new inorganic–organic hybrid compounds constructed from two kinds of octamolybdate clusters and flexible multidentate N-donor ligand: syntheses, structures, electrochemistry, luminescence, and photocatalytic properties

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  11. Polycatenated Bilayer Structure Containing Honeycomb-like 63 Layers

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  12. Construction of Two New Metal–Organic Entangled Frameworks Via Varying Flexible Bis(Imidazole)-based Auxiliary Ligands

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  13. Self-assembly of a 3-D self-catenated framework based on [V4O12]4−polyoxoanions and cobalt-organic polymer

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  14. Interpenetration control in metal–organic frameworks for functional applications

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  15. A novel chain structure constructed from copper complexes and dimers based on bi-capped Keggin clusters

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  16. Polyoxometalate-Induced New Self-Assemblies Based on Copper Ions and Bichelate-Bridging Ligands

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  17. Construction of Entangled Coordination Polymers Based on M2+ Ions, 4,4′-{[1,2-Phenylenebis(methylene)]bis(oxy)}dibenzoate and Different N-Donor Ligands

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  18. Two octamolybdate-based complexes: hydrothermal synthesis, structural characterization and properties

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  19. pH-controlled assembly of hybrid architectures based on Anderson-type polyoxometalates and silver coordination units

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  20. Synthesis, Crystal Structures and Thermal Analysis of Two Co(II) Coordination Polymers: 3D Interdigitated Framework to fourfold Interpenetrated dia Net

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  21. Ligand geometry-directed assembly of seven entangled coordination polymers

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  22. Structures and properties of four coordination polymers constructed from 1,3-bis-(4-pyridyl)-propane and aromatic dicarboxylic acids

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  23. Two unprecedented entangled coordination polymers based on α-{SiW 12 O 40 } 4−

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  24. pH-Controlled Two New Co(II) Coordination Polymers Based on 5-Pyrimidyl Benzoic Acid: Synthesis, Structures, and Properties

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  31. Assembly of Six Polyoxometalate-Based Hybrid Compounds from a Simple Supramolecule to a Complicated Pseudorotaxane Framework via Tuning the pH of the Reaction Systems

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  32. Synthesis and Crystal Structure of the Coordination Polymer of Ni-Mo8-Pyrazinecarboxylic Acid

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  33. Two-level hierarchical entangled framework in a novel copper(I) coordination polymer with multiform helical features and unprecedented self-penetrated subnet

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  34. Syntheses, structures, characterization and photoluminescent properties of six coordination polymers based on multidentate N-donor ligands and polycarboxylate anions

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  35. Structural diversity of five new bitriazole-based complexes: luminescence, sorption, and magnetic properties

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  36. Three coordination polymers based on different carboxylates, metals and a tri(4-imidazolylphenyl)amine ligand

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  37. Metal(II)-Directed Various Polyoxometalates-Based Hybrid Compounds: Assembly, Structures and Properties

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  38. A series of entangled coordination polymers assembled by a V-shaped bisimidazole ligand and various dicarboxylic acids: synthesis, characterization and luminescence properties

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  39. Hydrothermal syntheses and characterization of two 1D chain complexes and tetra-capped Keggin clusters

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  40. Syntheses and structures of three transition metal coordination polymers based on 5-Aminonicotinic acid

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  41. Construction of a Series of Zn(II) Compounds with Different Entangle Motifs by Varying Flexible Aliphatic Dicarboxylic Acids

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  42. Acid‐ or Base‐Induced Rearrangements of Ferrocenyl‐Decorated Organotin Sulfide Cages

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  43. Construction of two novel borotungstates modified by different ligands connected with single/double bridges

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  44. pH-Dependent assembly of three novel inorganic–organic hybrids based on different isopolymolybdates and Cu I/II (bbx) n units

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  45. Hydrothermal synthesis and electrochemical properties of a coordination polymer based on dinuclear (Pyrazinyl tetrazolate) Copper(II) cations and β-Octamolybdate Anions

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  46. An unprecedented self-penetrating Cu(I)-MOF based on a new 1D-ladder+ 2D-layer→ 3D polycatenation subnet showing luminescent sensing for nitrobenzene

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  47. Construction of Noninterpenetrating and Interpenetrating (4-Fold and 8-Fold) 3-D Cd(II) Networks with Tris(1,2,4-triazol-4-yl)phenyl)amine Modulated by Aromatic Dicarboxylate Coligands

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  49. Interpenetrated Network Crystals

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  50. Polycatenation tuned microporosity of two metal–tris(4′-carboxybiphenyl)amine frameworks with multilayer structures

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