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RESEARCH PAPER · Inorganic Chemistry · 2019

K 6 ACaSc 2 (B 5 O 10 ) 3 (A = Li, Na, Li 0.7 Na 0.3 ): Nonlinear-Optical Materials with Short UV Cutoff Edges

Jianghe Feng, Xiang Xu, Chun‐Li Hu, Jiang‐Gao Mao

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K 6 ACaSc 2 (B 5 O 10 ) 3 (A = Li, Na, Li 0.7 Na 0.3 ): Nonlinear-Optical Materials with Short UV Cutoff EdgesOriginalSynthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)28Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)33Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra10From BaAl 2 (BO 3 ) 2 O to SnAl 2 (BO 3 ) 2 F 2 : structure transformation based on ion regulation3Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways5Nonlinear-Optical Crystal Rb3YB6O12 with Condensed B5O10 Blocks That Exhibits an Intriguing Structural Arrangement and a Short Ultraviolet Absorption Edge26Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa2Sm2(BO3)(PO4)24Borates: A Rich Source for Optical Materials1089Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks15Large Magnetocaloric Effect in Li3K9Gd3(BO3)7 Crystal Featuring Sandwich-Like Three-Dimensional Framework22K5Mg2La3(BO3)6: An Efficient, Deep-Ultraviolet Nonlinear Optical Material70Two deep-ultraviolet nonlinear optical barium borates framework: Alkali metal enhances the second-harmonic generation response13CsBaB9O15: a high performance ultraviolet nonlinear optical material activated by the peculiar double layered configuration80Cr 3+ -doped borate phosphors for broadband near-infrared LED applications68Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges4Sc 2 F 2 (B 2 O 5 ): a deep ultraviolet scandium borate fluoride exhibiting large birefringence induced by the synergistic effect of B 2 O 5 and ScO n F 2 groups38Deep Ultraviolet-Transparent Materials with Strong Second-Harmonic Response50Two non-centrosymmetric mixed alkali metal and alkaline earth metal scandium borate nonlinear optical materials with short ultraviolet cutoff edges14Three Borates Belonging to the A(I)7Ae(II)Re(III)2B15O30 Family as Promising Nonlinear Optical Crystals12Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12A bifunctional primitive strategy induces enhancements of large second harmonic generation and wide UV transmittance in rare-earth borates containing [B 5 O 10 ] groups22Enhanced UV Nonlinear Optical Properties in Layered Germanous Phosphites through Functional Group Sequential Construction11Enhanced UV Nonlinear Optical Properties in Layered Germanous Phosphites through Functional Group Sequential Construction116Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Ba2ScBSi2O9: A Mixed-Coordination Borosilicate with a Low B/Si Ratio Exhibiting Enhanced Second Harmonic Generation Response7K3Y3(BO3)4: A Potential UV Nonlinear-Optical Crystal Designed by a Chemical Substitution Strategy14Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement1K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family4Designing rare earth borates as UV nonlinear optical crystals exhibiting strong second-harmonic generation responses15Search for New Members of the Abre(B15o30)N Family with Significant Shg Effects Based on Chemical Substitution Strategy0Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups3A New Short-Wavelength UV NLO Material based on Dual Alkaline-Earth Metal Borophosphate with 1D Helical Anionic Chains0Rb7.5Ln2.5B15O30 (Ln = Gd and Eu): All-in-One Noncentrosymmetric Pentaborates with Strong Second-Harmonic Generation and Efficient Luminescence0Two scandium borate UV NLO crystals designed through chemical element substitution1[Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units1A Rare-Earth Borophosphate Ultraviolet Nonlinear Optical Crystal Featuring P–O–P Linkages0

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  1. Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)

    Science China Materials · 2019-03-22

    Zhiqing Xie, Ying Wang, Shichao Cheng, Guopeng Han, Zhihua Yang, Shilie Pan

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  2. Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)

    Inorganic Chemistry · 2019-06-04

    Fengjiao Guo, Jian Wei Han, Shichao Cheng, Sujuan Yu, Zhihua Yang, Shilie Pan

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  3. Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

    Molecules · 2019-07-30

    Yanna Chen, Min Zhang, Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  4. Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra

    Chemical Communications · 2020-01-01

    Wei Li, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  5. From BaAl 2 (BO 3 ) 2 O to SnAl 2 (BO 3 ) 2 F 2 : structure transformation based on ion regulation

    New Journal of Chemistry · 2020-01-01

    Ya Wang, Jian Wei Han, Junben Huang, Zhihua Yang, Shuzhao Huang, Shilie Pan

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  6. Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways

    Dalton Transactions · 2020-01-01

    Mengmeng Ding, Jingjing Xu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  7. Nonlinear-Optical Crystal Rb3YB6O12 with Condensed B5O10 Blocks That Exhibits an Intriguing Structural Arrangement and a Short Ultraviolet Absorption Edge

    Inorganic Chemistry · 2020-09-04

    Zhen Jia, Qindan Zeng, Pifu Gong, Dong Yan, Xiuling Zhang, Bingwei Xin, Zheshuai Lin, Mingjun Xia

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  8. Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa2Sm2(BO3)(PO4)2

    Acta Crystallographica Section C Structural Chemistry · 2020-11-13

    Dan Zhao, Lin-Ying Shi, Rui-Juan Zhang, Ya-Li Xue

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  9. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  10. Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Kening Sun, Guo‐Yu Yang

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  11. Large Magnetocaloric Effect in Li3K9Gd3(BO3)7 Crystal Featuring Sandwich-Like Three-Dimensional Framework

    Inorganic Chemistry · 2021-04-12

    Wang Liu, Fei Liang, Yuwei Chen, Huimin Song, Jingcheng Feng, Jun Shen, Zheshuai Lin, Heng Tu, Guochun Zhang

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  12. K5Mg2La3(BO3)6: An Efficient, Deep-Ultraviolet Nonlinear Optical Material

    Chemistry of Materials · 2021-05-21

    Runqing Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  13. Two deep-ultraviolet nonlinear optical barium borates framework: Alkali metal enhances the second-harmonic generation response

    Journal of Solid State Chemistry · 2021-06-06

    Qi–Ming Qiu, Guo‐Yu Yang

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  14. CsBaB9O15: a high performance ultraviolet nonlinear optical material activated by the peculiar double layered configuration

    中国科学通报：英文版 · 2021-06-25

    Yun Mo Yang, Xiaoyu Dong, Zhihua Yang, Shilie Pan

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  15. Cr 3+ -doped borate phosphors for broadband near-infrared LED applications

    Inorganic Chemistry Frontiers · 2022-01-01

    Jiutian Wang, Lihong Jiang, Ran Pang, Su Zhang, Da Li, Kai Li, Chengyu Li, Hongjie Zhang

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  16. Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges

    New Journal of Chemistry · 2022-01-01

    Jianbang Chen, Jie Zhang, Aixin Zhu, Xuchu Huang

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  17. Sc 2 F 2 (B 2 O 5 ): a deep ultraviolet scandium borate fluoride exhibiting large birefringence induced by the synergistic effect of B 2 O 5 and ScO n F 2 groups

    Inorganic Chemistry Frontiers · 2022-01-01

    Ru‐Ling Tang, Wei Xu, Weijie Xie, Chun‐Li Hu

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  18. Deep Ultraviolet-Transparent Materials with Strong Second-Harmonic Response

    Chemistry of Materials · 2022-08-22

    Binqian Yuan, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  19. Two non-centrosymmetric mixed alkali metal and alkaline earth metal scandium borate nonlinear optical materials with short ultraviolet cutoff edges

    Dalton Transactions · 2023-01-01

    Wenhao Liu, Ming‐Hsien Lee, Ruixin Guo, Jiyong Yao

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  20. Three Borates Belonging to the A(I)7Ae(II)Re(III)2B15O30 Family as Promising Nonlinear Optical Crystals

    Crystal Growth & Design · 2023-08-21

    Chengfa Wu, Yu Dang, Jianbang Chen, Xueling Hou, Hongsheng Shi

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  21. Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-09-04

    Qianzhen Zhang, Ran An, Abudukadi Tudi, Zhihua Yang, Xifa Long, Yun Mo Yang

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  22. A bifunctional primitive strategy induces enhancements of large second harmonic generation and wide UV transmittance in rare-earth borates containing [B 5 O 10 ] groups

    Chemical Science · 2024-01-01

    Shuaifeng Li, Weiming Li, Xiang Li, Guangsai Yang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  23. Enhanced UV Nonlinear Optical Properties in Layered Germanous Phosphites through Functional Group Sequential Construction

    Angewandte Chemie · 2024-06-08

    Yao Tian, Wei Zeng, Xuehua Dong, Ling Huang, Yuqiao Zhou, Hongmei Zeng, Zhien Lin, Guohong Zou

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  24. Enhanced UV Nonlinear Optical Properties in Layered Germanous Phosphites through Functional Group Sequential Construction

    Angewandte Chemie International Edition · 2024-06-08

    Yao Tian, Wei Zeng, Xuehua Dong, Ling Huang, Yuqiao Zhou, Hongmei Zeng, Zhien Lin, Guohong Zou

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  25. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  26. Ba2ScBSi2O9: A Mixed-Coordination Borosilicate with a Low B/Si Ratio Exhibiting Enhanced Second Harmonic Generation Response

    Inorganic Chemistry · 2024-08-21

    Ming Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  27. K3Y3(BO3)4: A Potential UV Nonlinear-Optical Crystal Designed by a Chemical Substitution Strategy

    Inorganic Chemistry · 2024-09-12

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  28. Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement

    Dalton Transactions · 2024-12-13

    Xiaoqin Ma, Xin-Jun Zhao, QinglianT. Zhang, Xifa Long, Yun Mo Yang

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  29. K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family

    Inorganic Chemistry · 2024-12-19

    Wencong Li, Zhaowei Hu, Yanyan Ding, Yueting Zhu, Qun Jing, Lili Liu

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  30. Designing rare earth borates as UV nonlinear optical crystals exhibiting strong second-harmonic generation responses

    Chemical Communications · 2025-01-01

    Mengru Liu, Xianghao Kong, Shuaifeng Li, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  31. Search for New Members of the Abre(B15o30)N Family with Significant Shg Effects Based on Chemical Substitution Strategy

    SSRN Electronic Journal · 2025-01-01

    Xiaoqin Ma, Shaohua Liu, Wei Wei, Qianzhen Zhang, Xifa Long, Yun Yang

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  32. Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups

    Dalton Transactions · 2025-01-01

    Yixin Song, Hongwei Yu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  33. A New Short-Wavelength UV NLO Material based on Dual Alkaline-Earth Metal Borophosphate with 1D Helical Anionic Chains

    SSRN Electronic Journal · 2026-01-01

    Zhiguo Zhong, Yu-Quan Feng, Jing Li

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  34. Rb7.5Ln2.5B15O30 (Ln = Gd and Eu): All-in-One Noncentrosymmetric Pentaborates with Strong Second-Harmonic Generation and Efficient Luminescence

    SSRN Electronic Journal · 2026-01-01

    S. D. Lee, Yunseung Kuk, Congcong Jin, Wei Zeng, Kang Min Ok

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  35. Two scandium borate UV NLO crystals designed through chemical element substitution

    Chemical Communications · 2026-01-01

    Zelong Liu, Huijian Zhao, Longyun Xu, Ning Jia, Ning Ye, Zhanggui Hu, Conggang Li

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  36. [Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units

    Inorganic Chemistry · 2026-01-07

    Yuquan Feng, Dongqin Bi, K. C. Liu, Shuyang Chen, Limin Gao, Zhaohui Meng

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  37. A Rare-Earth Borophosphate Ultraviolet Nonlinear Optical Crystal Featuring P–O–P Linkages

    Inorganic Chemistry · 2026-08-08

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