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RESEARCH PAPER · Chemical Communications · 2025

Designing rare earth borates as UV nonlinear optical crystals exhibiting strong second-harmonic generation responses

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Designing rare earth borates as UV nonlinear optical crystals exhibiting strong second-harmonic generation responsesOriginalKNa 2 Y 2 B 2 O 6 F 3 : a beryllium free deep-UV nonlinear optical crystal with well-balanced properties2Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups3Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20K 2 GdB 3 O 6 F 2 : A Promising Short-Wave UV Birefringent Crystal via Optimized Assembly of π-Conjugated [B 3 O 6 ] Groups8Design and Synthesis of a Rare Earth Borate Ultraviolet Nonlinear Optical Crystal K 3 Lu 2 (BO 3 ) 38Growth and Characterization of Novel SrB2O4 Crystals0Rb7.5Ln2.5B15O30 (Ln = Gd and Eu): All-in-One Noncentrosymmetric Pentaborates with Strong Second-Harmonic Generation and Efficient Luminescence0Two scandium borate UV NLO crystals designed through chemical element substitution1Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials1Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates2Research advances in rare-earth nonlinear optical crystalline materials in 20250Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates0A novel tetrafluoroborate with giant birefringence assembled from biocompatible adenine0Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 100

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  1. KNa 2 Y 2 B 2 O 6 F 3 : a beryllium free deep-UV nonlinear optical crystal with well-balanced properties

    Chemical Communications · 2025-01-01

    Huijian Zhao, Mengru Liu, Weina Nan, Ning Yang, Conggang Li, Ning Ye, Zhanggui Hu

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  2. Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups

    Dalton Transactions · 2025-01-01

    Yixin Song, Hongwei Yu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  3. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

    Coordination Chemistry Reviews · 2025-08-26

    Bailin Chen, Shuai An, Xueling Hou, Shilie Pan

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  4. K 2 GdB 3 O 6 F 2 : A Promising Short-Wave UV Birefringent Crystal via Optimized Assembly of π-Conjugated [B 3 O 6 ] Groups

    Inorganic Chemistry · 2025-10-14

    Mengru Liu, Huijian Zhao, Xianghao Kong, Ning Ye, Zhanggui Hu, Conggang Li

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  5. Design and Synthesis of a Rare Earth Borate Ultraviolet Nonlinear Optical Crystal K 3 Lu 2 (BO 3 ) 3

    Inorganic Chemistry · 2025-10-20

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu

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  6. Growth and Characterization of Novel SrB2O4 Crystals

    Crystals · 2025-10-25

    Magdalena Angelova, Rusi Rusew, Rositsa Nikolova, Boris Lubomirov Shivachev

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  7. Rb7.5Ln2.5B15O30 (Ln = Gd and Eu): All-in-One Noncentrosymmetric Pentaborates with Strong Second-Harmonic Generation and Efficient Luminescence

    SSRN Electronic Journal · 2026-01-01

    S. D. Lee, Yunseung Kuk, Congcong Jin, Wei Zeng, Kang Min Ok

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  8. Two scandium borate UV NLO crystals designed through chemical element substitution

    Chemical Communications · 2026-01-01

    Zelong Liu, Huijian Zhao, Longyun Xu, Ning Jia, Ning Ye, Zhanggui Hu, Conggang Li

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  9. Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency

    Inorganic Chemistry · 2026-02-05

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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  10. Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials

    Materials Today Physics · 2026-07-04

    D K Li, Yujie Zhang, H Liu, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  11. Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates

    Advanced Functional Materials · 2026-07-10

    Huijian Zhao, Kangyan Fan, Conggang Li, Zelong Liu, Pifu Gong, Ning Ye, Zhanggui Hu

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  12. Research advances in rare-earth nonlinear optical crystalline materials in 2025

    Journal of Rare Earths · 2026-07-21

    Tiantian He, Dandan Zhou, Fang Kong, Jianggao Mao

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  13. Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates

    Inorganic Chemistry · 2026-08-04

    Xiuying Zhang, Yebiao Wu, Qiya Huang, Lehui Liu, Peican Chen, Hongming Liu

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  14. A novel tetrafluoroborate with giant birefringence assembled from biocompatible adenine

    Journal of Molecular Structure · 2026-09-06

    Guangzhizhen Fan, Yuze Li, Lixiang Qin, Zhou Yanling, Hongming Liu

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  15. Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 10

    European Journal of Inorganic Chemistry · 2026-09-15

    Jingru Xu, Jiawei Zhao, Paipai Zhang, Juhui Cui, Hong Lei Du, Minqiang Gai

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