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RESEARCH PAPER · Sustainable Energy & Fuels · 2018

Nitrogen/fluorine-codoped rutile titania as a stable oxygen-evolution photocatalyst for solar-driven Z-scheme water splitting

Akinobu Miyoshi, Junie Jhon M. Vequizo, Shunta Nishioka, Yuma Kato, Muneaki Yamamoto, Shunsuke Yamashita, Toshiyuki Yokoi, Akihide Iwase, Shunsuke Nozawa, Akira Yamakata, Tomoko Yoshida, Koji Kimoto, Akihiko Kudo, Kazuhiko Maeda

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Nitrogen/fluorine-codoped rutile titania as a stable oxygen-evolution photocatalyst for solar-driven Z-scheme water splittingOriginalTwo-Dimensional Metal Oxide Nanosheets as Building Blocks for Artificial Photosynthetic Assemblies192Controllable construction of oxygen vacancies by anaerobic catalytic combustion of dichloromethane over metal oxides for enhanced solar-to-hydrogen conversion4Enhanced water splitting through two-step photoexcitation by sunlight using tantalum/nitrogen-codoped rutile titania as a water oxidation photocatalyst18Reaction systems for solar hydrogen production via water splitting with particulate semiconductor photocatalysts1584Visible-Light-Driven Water Oxidation Using Anatase Titania Modified with First-Row Transition-Metal-Oxide Nanoclusters22Homogeneous Doping of Substitutional Nitrogen/Carbon in TiO2 Plates for Visible Light Photocatalytic Water Oxidation75Synthesis of a Layered Niobium Oxynitride, Rb2NdNb2O6N·H2O, Showing Visible-Light Photocatalytic Activity for H2 Evolution34Enhanced Visible Light Response of TiO 2 Codoped with Cr and Ta Photocatalysts by Electron Doping22Metal‐Complex/Semiconductor Hybrid Photocatalysts and Photoelectrodes for CO2 Reduction Driven by Visible Light280An overview of photocatalysis facilitated by 2D heterojunctions85Recent developments in carbon nitride based films for photoelectrochemical water splitting90SrTiO3/TiO2 heterostructure nanowires with enhanced electron-hole separation for efficient photocatalytic activity13Controlled colloidal metal nanoparticles and nanoclusters: recent applications as cocatalysts for improving photocatalytic water-splitting activity89Nano vs. bulk rutile TiO 2 :N,F in Z-scheme overall water splitting under visible light28Rutile TiO2–based new photocatalysts for visible light water oxidation1In Situ Spatial Charge Separation of an Ir@TiO2 Multiphase Photosystem toward Highly Efficient Photocatalytic Performance of Hydrogen Production35Recent Progress in Mixed‐Anion Materials for Solar Fuel Production58Anti-algal activity of a fluorine-doped titanium oxide photocatalyst against Microcystis aeruginosa and its photocatalytic degradation16Effects of Nitrogen/Fluorine Codoping on Photocatalytic Rutile TiO2 Crystal Studied by First-Principles Calculations14Band Engineering of Semiconductors Toward Visible‐Light‐Responsive Photocatalysts1New Visible‐Light‐Responsive Photocatalysts for Water Splitting Based on Mixed Anions1Rational Construction of a N, F Co‐doped Mesoporous Cobalt Phosphate with Rich‐Oxygen Vacancies for Oxygen Evolution Reaction and Supercapacitors11Visible Light-Responsive N-Doped TiO2 Photocatalysis: Synthesis, Characterizations, and Applications133Doped semiconductor photocatalysts1Recent Progress on Mixed-Anion Materials for Energy Applications110Cs,Rh-codoped WO 3 with a core–shell structure responsive up to 600 nm as an O 2 -evolving photocatalyst for Z -schematic water splitting2Semiconducting Polymers for Oxygen Evolution Reaction under Light Illumination338Development and Functionalization of Visible-Light-Driven Water-Splitting Photocatalysts41Fluorine-Assisted Low-Temperature Synthesis of GaN:ZnO-Related Solid Solutions with Visible-Light Photoresponse5A band-to-band transition visible-light-responsive anatase titania photocatalyst by N,F-codoping for water splitting and CO 2 reduction17Bandgap Tunable Oxynitride LaNb 2 O 7–x N x Nanosheets20Reduction of a Band Gap and Visible-Light Photocatalytic Activity Induced by the Interaction between 6s and 2p Orbitals known as Revised Lone Pair Model0Photocatalytic water splitting603Skin B/N-doped anatase TiO2 {0 0 1} nanoflakes for visible-light photocatalytic water oxidation8Photocatalytic Hydrogen Evolution Activity of Nitrogen/Fluorine-Codoped Rutile TiO22Probing Charge Carrier Behavior in Engineered Photocatalysts with Time-Resolved Visible to Mid-IR Absorption Spectroscopy14p–d coupling: prerequisite for band-like doping levels in metal oxides2Topochemical synthesis of mesoporous TiO 2 co-doped with nitrogen and fluorine for improved photocatalytic O 2 evolution under visible light0Time-Resolved X-ray Absorption Fine Structure Reveals Hole Injection Dynamics and Charge Carrier Kinetics in Cocatalysts for Water Oxidation0

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  1. Two-Dimensional Metal Oxide Nanosheets as Building Blocks for Artificial Photosynthetic Assemblies

    Bulletin of the Chemical Society of Japan · 2018-10-04

    Kazuhiko Maeda, Thomas E. Mallouk

    Read original paper ↗ ·

  2. Controllable construction of oxygen vacancies by anaerobic catalytic combustion of dichloromethane over metal oxides for enhanced solar-to-hydrogen conversion

    Sustainable Energy & Fuels · 2019-01-01

    Sufen Zhang, Jianni Liu, Xiaoyang Dong, Xiaoxia Jia, Ziwei Gao, Quan Gu

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  3. Enhanced water splitting through two-step photoexcitation by sunlight using tantalum/nitrogen-codoped rutile titania as a water oxidation photocatalyst

    Sustainable Energy & Fuels · 2019-01-01

    Shunta Nishioka, Kei-ichi Yanagisawa, Daling Lu, Junie Jhon M. Vequizo, Akira Yamakata, Koji Kimoto, Miki Inada, Kazuhiko Maeda

    Read original paper ↗ ·

  4. Reaction systems for solar hydrogen production via water splitting with particulate semiconductor photocatalysts

    Nature Catalysis · 2019-03-11

    Takashi Hisatomi, Kazunari Domen

    Read original paper ↗ ·

  5. Visible-Light-Driven Water Oxidation Using Anatase Titania Modified with First-Row Transition-Metal-Oxide Nanoclusters

    The Journal of Physical Chemistry C · 2019-04-02

    Megumi Okazaki, Yunan Wang, Toshiyuki Yokoi, Kazuhiko Maeda

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  6. Homogeneous Doping of Substitutional Nitrogen/Carbon in TiO2 Plates for Visible Light Photocatalytic Water Oxidation

    Advanced Functional Materials · 2019-04-15

    Tingting Wu, Ping Niu, Yongqiang Yang, Lichang Yin, Jun Tan, Huaze Zhu, John T. S. Irvine, Lianzhou Wang, Gang Yu Liu, Hui–Ming Cheng

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  7. Synthesis of a Layered Niobium Oxynitride, Rb2NdNb2O6N·H2O, Showing Visible-Light Photocatalytic Activity for H2 Evolution

    Inorganic Chemistry · 2019-04-16

    Haruki Wakayama, Keisuke Hibino, Kotaro Fujii, Takayoshi Oshima, Keiichi Yanagisawa, Yuuga Kobayashi, Koji Kimoto, Masatomo Yashima, Kazuhiko Maeda

    Read original paper ↗ ·

  8. Enhanced Visible Light Response of TiO 2 Codoped with Cr and Ta Photocatalysts by Electron Doping

    ACS Applied Energy Materials · 2019-04-23

    Fumiaki Amano, Masashi Nakata, Junie Jhon M. Vequizo, Akira Yamakata

    Read original paper ↗ ·

  9. Metal‐Complex/Semiconductor Hybrid Photocatalysts and Photoelectrodes for CO2 Reduction Driven by Visible Light

    Advanced Materials · 2019-05-08

    Kazuhiko Maeda

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  10. An overview of photocatalysis facilitated by 2D heterojunctions

    Nanotechnology · 2019-08-30

    Tongming Su, Zuzeng Qin, Hongbing Ji, Zili Wu

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  11. Recent developments in carbon nitride based films for photoelectrochemical water splitting

    Sustainable Energy & Fuels · 2019-10-21

    Wei Xiong, Fei Huang, Ruiqin Q. Zhang

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  12. SrTiO3/TiO2 heterostructure nanowires with enhanced electron-hole separation for efficient photocatalytic activity

    Frontiers of Materials Science · 2019-11-05

    Liuxin Yang, Zhou Chen, Jian Zhang, Chang‐An Wang

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  13. Controlled colloidal metal nanoparticles and nanoclusters: recent applications as cocatalysts for improving photocatalytic water-splitting activity

    Journal of Materials Chemistry A · 2020-01-01

    Tokuhisa Kawawaki, Yutaro Mori, Kosuke Wakamatsu, Shuhei Ozaki, Masanobu Kawachi, Sakiat Hossain, Yuichi Negishi

    Read original paper ↗ ·

  14. Nano vs. bulk rutile TiO 2 :N,F in Z-scheme overall water splitting under visible light

    Journal of Materials Chemistry A · 2020-01-01

    Akinobu Miyoshi, Kosaku Kato, Toshiyuki Yokoi, Jan J. Wiesfeld, Kiyotaka Nakajima, Akira Yamakata, Kazuhiko Maeda

    Read original paper ↗ ·

  15. Rutile TiO2–based new photocatalysts for visible light water oxidation

    Elsevier eBooks · 2020-01-01

    Akinobu Miyoshi, Megumi Okazaki, Kazuhiko Maeda

    Read original paper ↗ ·

  16. In Situ Spatial Charge Separation of an Ir@TiO2 Multiphase Photosystem toward Highly Efficient Photocatalytic Performance of Hydrogen Production

    The Journal of Physical Chemistry C · 2020-07-10

    Ton Nu Quynh Trang, Nguyễn Đăng Nam, Lê Thị Ngọc Tú, Hau Quoc Pham, Tran Van Man, Van Thi Thanh Ho, Vũ Thị Hạnh Thu

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  17. Recent Progress in Mixed‐Anion Materials for Solar Fuel Production

    Solar RRL · 2020-10-24

    Akinobu Miyoshi, Kazuhiko Maeda

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  18. Anti-algal activity of a fluorine-doped titanium oxide photocatalyst against Microcystis aeruginosa and its photocatalytic degradation

    New Journal of Chemistry · 2021-01-01

    Xuechun Wei, Hongxiang Zhu, Jianhua Xiong, Wenyu Huang, Ji Feng Shi, Shuangfei Wang, Hainong Song, Qilin Feng, Kai Zhong

    Read original paper ↗ ·

  19. Effects of Nitrogen/Fluorine Codoping on Photocatalytic Rutile TiO2 Crystal Studied by First-Principles Calculations

    Inorganic Chemistry · 2021-01-26

    Akinobu Miyoshi, Akihide Kuwabara, Kazuhiko Maeda

    Read original paper ↗ ·

  20. Band Engineering of Semiconductors Toward Visible‐Light‐Responsive Photocatalysts

    Unknown journal · 2021-02-26

    Akihide Iwase

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  21. New Visible‐Light‐Responsive Photocatalysts for Water Splitting Based on Mixed Anions

    Unknown journal · 2021-02-26

    Kazuhiko Maeda

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  22. Rational Construction of a N, F Co‐doped Mesoporous Cobalt Phosphate with Rich‐Oxygen Vacancies for Oxygen Evolution Reaction and Supercapacitors

    Chemistry - A European Journal · 2021-04-01

    Dong‐Sheng Pan, Zheng‐Han Guo, Jin‐Kun Li, Sai Huang, Ling‐Li Zhou, Jun‐Ling Song

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  23. Visible Light-Responsive N-Doped TiO2 Photocatalysis: Synthesis, Characterizations, and Applications

    Transactions of Tianjin University · 2021-07-29

    Shiwen Du, Juhong Lian, Fuxiang Zhang

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  24. Doped semiconductor photocatalysts

    Elsevier eBooks · 2021-08-28

    Takashi Hisatomi, Kazunari Domen

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  25. Recent Progress on Mixed-Anion Materials for Energy Applications

    Bulletin of the Chemical Society of Japan · 2021-11-15

    Kazuhiko Maeda, Fumitaka Takeiri, Genki Kobayashi, Satoru Matsuishi, Hiraku Ogino, Shintaro Ida, Takao Mori, Yoshiharu Uchimoto, Setsuhisa Tanabe, Tetsuya Hasegawa, Nobuhito Imanaka, Hiroshi Kageyama

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  26. Cs,Rh-codoped WO 3 with a core–shell structure responsive up to 600 nm as an O 2 -evolving photocatalyst for Z -schematic water splitting

    Sustainable Energy & Fuels · 2022-01-01

    Kenta Watanabe, Yugo Miseki, Kazuhiro Sayama

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  27. Semiconducting Polymers for Oxygen Evolution Reaction under Light Illumination

    Chemical Reviews · 2022-01-13

    Yuanxing Fang, Yidong Hou, Xianzhi Fu, Xinchen Wang

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  28. Development and Functionalization of Visible-Light-Driven Water-Splitting Photocatalysts

    Nanomaterials · 2022-01-21

    Tokuhisa Kawawaki, Masanobu Kawachi, Daichi Yazaki, Yuki Akinaga, Daisuke Hirayama, Yuichi Negishi

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  29. Fluorine-Assisted Low-Temperature Synthesis of GaN:ZnO-Related Solid Solutions with Visible-Light Photoresponse

    ACS Applied Materials & Interfaces · 2022-04-22

    Akinobu Miyoshi, Shuhei Yasuda, Tomoki Kanazawa, Rie Haruki, Keiichi Yanagisawa, Ya Nan Tang, Ryusuke Mizuochi, Toshiyuki Yokoi, Shunsuke Nozawa, Koji Kimoto, Kazuhiko Maeda

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  30. A band-to-band transition visible-light-responsive anatase titania photocatalyst by N,F-codoping for water splitting and CO 2 reduction

    Journal of Materials Chemistry A · 2022-11-24

    Juhong Lian, Kengo Shibata, Yejun Xiao, Shiwen Du, Toshiya Tanaka, Yu Qi, Osamu Ishitani, Kazuhiko Maeda, Zhaochi Feng, Fuxiang Zhang

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  31. Bandgap Tunable Oxynitride LaNb 2 O 7–x N x Nanosheets

    Small · 2023-01-15

    Chu‐Wei Hsu, Takuro Miyano, Keisuke Awaya, Masayuki Tsushida, Kazuto Hatakeyama, Michio Koinuma, Shintaro Ida

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  32. Reduction of a Band Gap and Visible-Light Photocatalytic Activity Induced by the Interaction between 6s and 2p Orbitals known as Revised Lone Pair Model

    Journal of the Japan Society of Colour Material · 2023-05-20

    Kengo Oka, Naoki Noma, Mitsunobu Iwasaki

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  33. Photocatalytic water splitting

    Nature Reviews Methods Primers · 2023-06-01

    Shunta Nishioka, Frank E. Osterloh, Xinchen Wang, Thomas E. Mallouk, Kazuhiko Maeda

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  34. Skin B/N-doped anatase TiO2 {0 0 1} nanoflakes for visible-light photocatalytic water oxidation

    Journal of Colloid and Interface Science · 2023-06-10

    Guoqiang Deng, Xiangdong Kang, Yongqiang Yang, Lianzhou Wang, Gang Yu Liu

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  35. Photocatalytic Hydrogen Evolution Activity of Nitrogen/Fluorine-Codoped Rutile TiO2

    ACS Omega · 2023-10-23

    Akinobu Miyoshi, Megumi Okazaki, Kosaku Kato, Tomoki Kanazawa, Toshiyuki Yokoi, Shunta Nishioka, Shunsuke Nozawa, Akira Yamakata, Kazuhiko Maeda

    Read original paper ↗ ·

  36. Probing Charge Carrier Behavior in Engineered Photocatalysts with Time-Resolved Visible to Mid-IR Absorption Spectroscopy

    The Journal of Physical Chemistry C · 2023-11-07

    Hanggara Sudrajat, Irene Carra, Ilenia Rossetti, Raphaël Schneider, Juan Carlos Colmenares

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  37. p–d coupling: prerequisite for band-like doping levels in metal oxides

    Journal of Materials Chemistry A · 2024-01-01

    Kangyu Zhang, Li-Chang Yin, Guoqiang Deng, Xing-Qiu Chen, Hui–Ming Cheng, Gang Yu Liu

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  38. Topochemical synthesis of mesoporous TiO 2 co-doped with nitrogen and fluorine for improved photocatalytic O 2 evolution under visible light

    Nanoscale Horizons · 2025-11-07

    Shuwei Liu, Ryosuke Nishikubo, Fumitaka Ishiwari, Xian Zhang, Megumi Okazaki, Shunsuke Nozawa, Akinori Saeki, Kazuhiko Maeda

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  39. Time-Resolved X-ray Absorption Fine Structure Reveals Hole Injection Dynamics and Charge Carrier Kinetics in Cocatalysts for Water Oxidation

    ACS Catalysis · 2026-05-13

    Tomoki Kanazawa, Chomponoot Suppaso, Issei Yamamoto, Dongxiao Fan, Rie Haruki, Ryo Fukaya, Kazuhiko Maeda, Shin‐ichi Adachi, Shunsuke Nozawa

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