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RESEARCH PAPER · Coordination Chemistry Reviews · 2018

Multinary metal chalcogenides with tetrahedral structures for second-order nonlinear optical, photocatalytic, and photovoltaic applications

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Multinary metal chalcogenides with tetrahedral structures for second-order nonlinear optical, photocatalytic, and photovoltaic applicationsOriginalThe first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies29Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold59Second-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations4Cu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination26Cu x S nanoparticle@carbon nanorod composites prepared from metal–organic frameworks as efficient electrode catalysts for quantum dot sensitized solar cells20ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences50Monoclinic gallium selenide: an AgGaS 2 -type structure variant with balanced infrared nonlinear optical performance43Partial substitution induced centrosymmetric to noncentrosymmetric structure transformation and promising second-order nonlinear optical properties of (K 0.38 Ba 0.81 )Ga 2 Se 495Pb 2 Cd(SeO 3 ) 2 X 2 (X = Cl and Br): two halogenated selenites with phase matchable second harmonic generation27Recent progress in quantum dot-sensitized solar cells employing metal chalcogenides50Synthesis and nonlinear optical properties of new gallium thiophosphate Rb 2 Ga 2 P 2 S 913SrCdGeS4 and SrCdGeSe4: Promising Infrared Nonlinear Optical Materials with Congruent-Melting Behavior74Rational design of the nonlinear optical materials dinaphtho[2,3-b:2′,3′-d]thiophene-5,7,12,13-tetraone (DNTTRA) and its phenyldiazenyl derivatives using first-principles calculations6Interfacial engineering of graphitic carbon nitride (g-C3N4)-based metal sulfide heterojunction photocatalysts for energy conversion: A review528Transition Metal Free Monoclinic Eu8In17.33S34 and Its Anisotropic Photoelectronic Responses25Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48Solution-Based Synthesis and Processing of Metal Chalcogenides for Thermoelectric Applications23Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide188Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide48Ba10In6Zn7S10Se16 and Ba10In6Zn7Se26: Two new infrared nonlinear optical materials with T2 super tetrahedron6Sn2Ga2S5: A Type of IR Nonlinear-Optical Material22In situ hydrothermal synthesis of rGO-wrapped Fe1−xS particles for lithium storage9LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition12Mercury-indium-sulfide nanocrystals: A new member of the family of ternary in based chalcogenides15Wurtzite CuNi2InS4 Nanocrystals: A Quaternary Chalcogenide Magnetic Semiconductor5Preparation of quinary CuNi Zn2−InS4 nanocrystals with wurtzite structure and tunable band gap7Performance improvement of dye sensitized solar cells based on cadmium sulfide/S, N co doped carbon dots nanocomposites33A highly distorted HgS 4 tetrahedron-induced moderate second-harmonic generation response of EuHgGeS 462Ba 6 In 6 Zn 4 Se 19 : a high performance infrared nonlinear optical crystal with [InSe 3 ] 3− trigonal planar functional motifs22Strong nonlinear optical effect attained by atom-response-theory aided design in the Na 2 M II MIV2Q 6 (M II = Zn, Cd; M IV = Ge, Sn; Q = S, Se) chalcogenide system27Syntheses, structures, and photocatalytic properties of open-framework Ag–Sn–S compounds26Quantum-mechanical oxidation states of metal ions in the solid-state binary sulfides8Ternary chalcogenides XGaS2 (X = Ag or Cu) for photocatalytic hydrogen generation from water splitting under irradiation of visible light15One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy17The effect of substitution of Sb with Zn on the optical and physical properties of Se90Sb10-xZnx (x = 0, 2, 4, 6, 10 at. %) thin films26(Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template38Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials164Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials55Hexagonal In2Se3: A Defect Wurtzite-Type Infrared Nonlinear Optical Material with Moderate Birefringence Contributed by Unique InSe5 Unit75Highly uniform hollow CuCo2S4@C dodecahedra derived from ZIF–67 for high performance lithium–ion batteries28LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold32Theoretical investigation on defect engineering for tuning photocatalytic activities in isostructural ScxmCuynOz−1 (m = Ca, n = Ni)0KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19Synthesis from aqueous solutions and optical properties of Ag–In–S quantum dots12Crystal chemistry, second-order nonlinear optical, and magnetic properties of Eu8Sn4Se2014Enhanced catalytic performance of CuFeS2 chalcogenide prepared by microwave-assisted route for photo-Fenton oxidation of emerging pollutant in water62A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt39Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides114Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50Optoelectronic and photocatalytic properties of I–III–VI QDs: Bridging between traditional and emerging new QDs28Rational design of multinary copper chalcogenide nanocrystals for photocatalytic hydrogen evolution16Pb 18 O 8 Cl 15 I 5 : A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties166Pb18O8Cl15I5: A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties29Tetrahedral CuZnInSe3 nanocrystals: One-pot synthesis, properties, and solar cell application4Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm38Isomorphous Substitution Synthesis and Photoelectric Properties of Spinel AgInSnS4 Nanosheets21AMnAs3S6 (A = Cs, Rb): Phase-Matchable Infrared Nonlinear Optical Functional Motif [As3S6]3– Obtained via Surfactant–Thermal Method32KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold42Investigation of the second-order nonlinear optical property of Sr6Sb6S173Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42A series of M 3 PS 4 (M = Ag, Cu and Ag/Cu) thiophosphates with diamond-like structures exhibiting large second harmonic generation responses and moderate ion conductivities28A series of oxysulfides RE 2 M 2 S 3 O 4 (RE = Y, Tm; M = Zr, Hf) featuring a unique MS 3 O 4 motif and {[M 2 S 3 O 4 ] 8− } ∞ wrinkle layer13Chalcogenides as well as chalcogenides-based nanomaterials and its importance in photocatalysis19M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances9Thermodynamic Examination of Quaternary Compounds in the Ag–Fe–(Ge, Sn)–Se Systems by the Solid-State EMF Method2Use of chalcogenides-based nanomaterials for photocatalytic heavy metal reduction and ions removal3A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling Effect25Newly emerging borate-based nonlinear optical materials for organic pollutant degradation: A review33Synthesis, spectral, stereochemical, biological, molecular docking and DFT studies of 3-alkyl/3,5-dialkyl-2r,6c-di(naphthyl)piperidin-4-one picrates derivatives12The Equilibrium Phase Formation and Thermodynamic Properties of Functional Tellurides in the Ag–Fe–Ge–Te System22Structural and optical study of glutathione-capped Ag–In–S nanocrystals5Carbon-dots-mediated highly efficient hole transfer in I-III-VI quantum dots for photocatalytic hydrogen production102AgSbS2-xSex thin films: Structure, composition, morphology and photodetection properties33ASb5S8 (A = K, Rb, and Cs): Thermal Switching of Infrared Nonlinear Optical Properties across the Crystal/Glass Transformation39Dual-plasmon-induced photocatalytic performance enhancement in Au-PbS-CdS nanodumbbells with double Au caps on the ends11Structural and optoelectronic properties change in Bi/In2Se3 heterostructure films by thermal annealing and laser irradiation67Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)38A review of the structural diversity of [P x S y ] n − motifs and their potential application prospects in metal thiophosphates21Li 4 MgGe 2 S 7 : The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap214Li4MgGe2S7: The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap16Structural, Optical, and Electronic Properties of Two Quaternary Chalcogenide Semiconductors: Ag2SrSiS4 and Ag2SrGeS420First-principles analysis of desired inherent photovoltaic functionalities of tetragonal CuAlX2 (X=O, S, Se and Te)8CsCdGa3O6: A I-II-III-O (I = alkali metal, II = divalent metal, III = Al, Ga, In) type oxide featuring [Ga4O14]16− helical belts linked [Ga6O6]6+ and [Ga8O8]8+ cages11Syntheses, Structures and Properties of Alkali and Alkaline Earth Metal Diamond-Like Compounds Li2MgMSe4 (M = Ge, Sn)12A successful exploitation of gamma-radiation on chalcogenide Cu2InSnS4 towards clean water under photocatalysis approach24Boosting Photocatalytic Activity Using Carbon Nitride Based 2D/2D van der Waals Heterojunctions143Spectroscopic ( UV and fluorescence), biological, DFT and molecular docking studies of 3,5‐diethyl‐2r,6c‐di(4‐fluorophenyl)piperidin‐4‐one picrate3Na+/Ag+ substitution induced birefringence enhancement from AgGaS2 to NaGaS218Applications, Conclusions, and Perspectives1KEu 2 In 3 B 12 S 13 : a novel type of thioborate featuring B 12 S 12 cluster and unique In 6 S 6 12-membered ring10Novel solution synthesis of the overlooked cubic phase Cu 2 GeTe 3 nanocrystals for optoelectronic devices8Precursor design and impact of structure on the fabrication of materials2Recent advances in solution assisted synthesis of transition metal chalcogenides for photo-electrocatalytic hydrogen evolution81Sulfur-source-dependent phase-selective preparation of Cu 3 NiInSnS 6 nanocrystals and their optical and magnetic properties1Oxynitride Perovskite: Computational Approach to Correlate Structural, Electronic, and Optical Properties of c-BiAlO3/N316Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation17Cubic Crystal Structure Formation and Optical Properties within the Ag–BII–MIV–X (BII = Sr, Pb; MIV = Si, Ge, Sn; X = S, Se) Family of Semiconductors8Validation of Density Functional Theory Methods for Predicting the Optical Properties of Cu-Based Multinary Chalcogenide Semiconductors11NaGa3Se5: An Infrared Nonlinear Optical Material with Balanced Performance Contributed by Complex {[Ga3Se5]−}∞ Anionic Network14Halides and oxyhalides-based photocatalysts for abatement of organic water contaminants – An overview35Heteroanionic Melilite Oxysulfide: A Promising Infrared Nonlinear Optical Candidate with a Strong Second-Harmonic Generation Response, Sufficient Birefringence, and Wide Bandgap65Novel Strategy toward Chromium-Based Thiospinel Multifunctional Magnetic Materials from Amorphous Chromites7From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**22Synthesis and Optical Properties of Ag–Ga–S Quantum Dots13Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O32Syntheses, crystal structures, photocatalysis, and photoelectric responses of quaternary sulfides ACuZnS2 (A = K, Rb, Cs)73,5-Diethyl-2r,6c-di(4-chlorophenyl)piperidin-4-one picrate: synthesis, spectral, biological, DFT, ADME and molecular docking studies4AgIn 5 Se 8 : a defect diamond-like non-linear optical selenide22An overview of Mg-based IR nonlinear optical materials23Synthesis, spectroscopic profiling, biological evaluation, DFT, molecular docking and mathematical studies of 3,5-diethyl-2r,6c-diphenylpiperidin-4-one picrate3Role of Tellurium Ions for Electrochemically Synthesized Zinc Telluride 2D Structures on Nonconductive Substrate4Raman and X-ray diffraction study of Ag–In–S polycrystals, films, and nanoparticles10Zn2BS3Br: An Infrared Nonlinear Optical Material with Significant Dual-Property Enhancements Designed through a Template Grafting Strategy20Synthesis, Thermodynamic Properties, and Structural Characteristics of Multicomponent Compounds in the Ag–Ni–Sn–S System3Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfides32Structure and Optical Properties of LixAg1–xGaSe2 and LixAg1–xInSe27{[In2S7]8–}∞ Chain and Isolated HgS4 Planar Unit Constructed One-Dimensional Pentanary Sulfide K2Ba7HgIn4S16 Exhibiting Nonlinear-Optical Activity10Three‐in‐One Strategy Constructing the First High‐Performance Nonlinear Optical Sulfide Crystallizing with the P43 Space Group27Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance57Chemical Pressure Effect on the Stabilization of Rock-Salt ZnO—Lin−2MeOn−1 Solid Solutions Synthesized at High Pressure2Influence of Vacancy Defects on the Interfacial Structural and Optoelectronic Properties of ZnO/ZnS Heterostructures for Photocatalysis13Three-in-One Tetrahedral Functional Units Constructing Diamondlike Ag2In2SiS3.06Se2.94 with High-Performance Nonlinear-Optical Activity4AEAg7(PS4)3 (AE = Ba, Sr): The homovalent substitution of lead by alkaline earth metals achieves the separation of the two phases and enlarges the band gap1Thermoelectric Transport Properties of Co0.5Fe0.5Se2, Co0.5Fe0.5Te2, and Their Solid-Solution Compositions5Recent advances in semiconductor heterojunctions: a detailed review of the fundamentals of photocatalysis, charge transfer mechanism and materials542Cation substitution varieties of I-II2-III-VI4 semiconductors and their effects on electronic and phononic properties12Crystal structure, electronic structure, and optical properties of Cu4ZnGe2S7 and Cu4CdGe2S7: Polar diamond-like semiconductors exhibiting second harmonic generation10DFT insights into the effects of substitutionally doped Sb defects in CuIn(S,Se)2 solar cell absorber0Synthesis, spectral, quantum chemical, biological, molecular docking and mathematical investigations of piperidin-4-one oxime picrates2Influence of Te replacement by Bi in In10Se70Te20-xBix films and its structural, optical, morphological, surface wettability and thermal behaviors for optoelectronic applications16High Performance Quaternary Chalcogenides for Solar Energy Conversion3Exploration, Prediction, and Experimental Verification of Structure and Optoelectronic Properties in I 2 -Eu-IV-X 4 (I = Li, Cu, Ag; IV = Si, Ge, Sn; X = S, Se) Chalcogenide Semiconductors6The impact of carboxylic acid anchoring groups on the optoelectronic and nonlinear optical properties of Ru complex dyes: A computational approach6Nonlinear Optical Phosphide CuInSi2P4: The Inaugural Member of Diamond-Like Family I–III–IV2–V4 Inspired by ZnGeP216Efficient charge separation and transportation using 1D iron-sulfide@titania heterojunctions as photoanodes for improved interface stability and photoelectrochemical activity to produce hydrogen7Electron transfer and energy exchange between a covalent organic framework and CuFeS 2 nanoparticles7Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals9Metal-chalcogenides nanocomposites as counter electrodes for quantum dots sensitized solar cells1Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties4Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates5Construction of Z-scheme InN/BTe heterostructure for enhanced photocatalytic hydrogen evolution: DFT calculation and mechanism study34Superalkalides based on stacked janus molecule with improved optical nonlinearity10Hydrothermal synthesis of multifunctional Cu2Te nanoparticles as photocatalyst and as supercapacitor electrode22Spectral, computational, molecular properties, biological and docking aspect of 3-allyl-2,6-diarylpiperidin-4-one oximes1Structure and optical properties of LixAg1–xAlSe23K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6

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  1. The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies

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  2. Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold

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  3. Second-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations

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  4. Cu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination

    Journal of Solid State Chemistry · 2018-09-25

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  5. Cu x S nanoparticle@carbon nanorod composites prepared from metal–organic frameworks as efficient electrode catalysts for quantum dot sensitized solar cells

    Journal of Materials Chemistry A · 2018-12-23

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  6. ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences

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  7. Monoclinic gallium selenide: an AgGaS 2 -type structure variant with balanced infrared nonlinear optical performance

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  11. Synthesis and nonlinear optical properties of new gallium thiophosphate Rb 2 Ga 2 P 2 S 9

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  17. Solution-Based Synthesis and Processing of Metal Chalcogenides for Thermoelectric Applications

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  18. Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide

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  19. Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide

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  20. Ba10In6Zn7S10Se16 and Ba10In6Zn7Se26: Two new infrared nonlinear optical materials with T2 super tetrahedron

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  22. In situ hydrothermal synthesis of rGO-wrapped Fe1−xS particles for lithium storage

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  23. LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition

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  29. Ba 6 In 6 Zn 4 Se 19 : a high performance infrared nonlinear optical crystal with [InSe 3 ] 3− trigonal planar functional motifs

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  30. Strong nonlinear optical effect attained by atom-response-theory aided design in the Na 2 M II MIV2Q 6 (M II = Zn, Cd; M IV = Ge, Sn; Q = S, Se) chalcogenide system

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  32. Quantum-mechanical oxidation states of metal ions in the solid-state binary sulfides

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  33. Ternary chalcogenides XGaS2 (X = Ag or Cu) for photocatalytic hydrogen generation from water splitting under irradiation of visible light

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  34. One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy

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  35. The effect of substitution of Sb with Zn on the optical and physical properties of Se90Sb10-xZnx (x = 0, 2, 4, 6, 10 at. %) thin films

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