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RESEARCH PAPER · Small · 2021

Progress of Exsolved Metal Nanoparticles on Oxides as High Performance (Electro)Catalysts for the Conversion of Small Molecules

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Progress of Exsolved Metal Nanoparticles on Oxides as High Performance (Electro)Catalysts for the Conversion of Small MoleculesOriginalIron-based electrode materials for solid oxide fuel cells and electrolysers129Minimized thermal expansion mismatch of cobalt-based perovskite air electrodes for solid oxide cells25Improving the activity and stability of Ni-based electrodes for solid oxide cells through surface engineering: Recent progress and future perspectives34Exploring the Stability of Fe–Ni Alloy Nanoparticles Exsolved from Double-Layered Perovskites for Dry Reforming of Methane46Synthesis and Decomposition of Nd2–yCayCo1–xNixO4: The Effect of Resynthesis on the Catalytic Performance of Decomposition Products in the Partial Oxidation of Methane9Dry reforming of methane over Ni supported on LaMnO3 thin films27Enhancing the Intrinsic Activity and Stability of Perovskite Cobaltite at Elevated Temperature Through Surface Stress56Activating Lattice Oxygen in Perovskite Oxide by B‐Site Cation Doping for Modulated Stability and Activity at Elevated Temperatures153A new 2D layered aluminophosphate |Hada| 6 [Al 6 (PO 4 ) 8 ](H 2 O) 11 supported highly uniform Ag nanoparticles for 4-nitrophenol reduction2Layered-perovskite oxides with in situ exsolved Co–Fe alloy nanoparticles as highly efficient electrodes for high-temperature carbon dioxide electrolysis61A review on recent advances and trends in symmetrical electrodes for solid oxide cells147Exsolved Co3O4 with tunable oxygen vacancies for electrocatalytic H2O2 production51Improvement Co2 Eletrocatalytic Activity of Lctn Fuel Electrode for Solid Oxide Electrolysis Cells Via an Electro-Reduction Activation Strategy0Modulating the water gas shift reaction via strong interfacial interaction between a defective oxide matrix and exsolved metal nanoparticles7Performance and Improvement of Ni-based Catalysts for Ethane Dehydrogenation4Phase transition with in situ exsolution nanoparticles in the reduced Pr 0.5 Ba 0.5 Fe 0.8 Ni 0.2 O 3− δ electrode for symmetric solid oxide cells55Robust in situ exsolved nanocatalysts on perovskite oxide as an efficient anode for hydrocarbon fueled solid oxide fuel cells8Direct surface functionalization with metal and metal oxide nanostructures6A Flexible Method to Fabricate Exsolution‐Based Nanoparticle‐Decorated Materials in Seconds33The metal/oxide heterointerface delivered by solid-based exsolution strategy: A review53Robust Ruddlesden‐Popper phase Sr 3 Fe 1.3 Mo 0.5 N i0.2 O 7‐δ decorated with in‐situ exsolved Ni nanoparticles as an efficient anode for hydrocarbon fueled solid oxide fuel cells38A one-pot carbon-coating-ex-solution route to efficient Ru-MnO@C nanowire electrocatalysts with enhanced interfacial interactions7Exsolution-like synthesis of Ni/(Nd2O3,CaO) nanocomposites from Nd2-xCaxNiO4 precursors for catalytic applications7Exsolution: A promising strategy for constructing advanced composite solids16Dynamic Surface Evolution of Metal Oxides for Autonomous Adaptation to Catalytic Reaction Environments23Toward Superb Perovskite Oxide Electrocatalysts: Engineering of Coupled Nanocomposites31Tuning Ternary Alloyed Nanoparticle Composition and Morphology by Exsolution in Double Perovskite Electrodes for CO 2 Electrolysis48Hydrogen Production through Bi-Reforming of Methane: Improving Ni Catalyst Performance via an Exsolution Approach17Metal exsolution engineering on perovskites for electrocatalysis: a perspective35Exsolution of Ru Nanoparticles on BaCe0.9Y0.1O3‐δ Modifying Geometry and Electronic Structure of Ru for Ammonia Synthesis Reaction Under Mild Conditions19Enhanced Electrocatalytic Activity and Surface Exsolution in PrOx-Substituted Cerium Gadolinium Oxide7Carbon dioxide reduction processes on a samarium doped ceria electrocatalyst with exsolved Fe particles17Electrochemical C–N coupling of CO 2 and nitrogenous small molecules for the electrosynthesis of organonitrogen compounds311Heterointerface engineering of NiFe (oxy)hydroxides/CNTs by in situ anchoring of sub-nano Au for efficient water oxidation2Mechanistic insight into catalytic conversion of methane on a Sr 2 Fe 1.5 Mo 0.5 O 6− δ perovskite anode: a combined EIS-DRT, DFT and TPSR investigation20Artificial intelligence-aided preparation of perovskite SrFexZr1-xO3-δ catalysts for ozonation degradation of organic pollutant concentrated water after membrane treatment12Improvement CO2 Electrocatalytic Activity of LCTN Fuel Electrode for Solid Oxide Electrolysis Cells via an Electro-Reduction Activation Strategy4A robust direct-propane solid oxide fuel cell with hierarchically oriented full ceramic anode consisting with in-situ exsolved metallic nano-catalysts33Near-field enhancement of optical second harmonic generation in hybrid gold–lithium niobate nanostructures23Exsolved materials for CO2 reduction in high-temperature electrolysis cells32Roadmap on exsolution for energy applications71Phase Transition Engineering of Host Perovskite toward Optimal Exsolution‐facilitated Catalysts for Carbon Dioxide Electrolysis3Phase Transition Engineering of Host Perovskite toward Optimal Exsolution‐facilitated Catalysts for Carbon Dioxide Electrolysis40Exsolution versus particle segregation on (Ni,Co)-doped and undoped SrTi0.3Fe0.7O3-δ perovskites: Differences and influence of the reduction path on the final system nanostructure19Cobalt-Doped MnFeCrO4 Spinel as the Fuel Electrode for Solid Oxide Electrolysis Cells4Co-Exsolution of Ni-Based Alloy Catalysts for the Valorization of Carbon Dioxide and Methane33High-temperature CO2 electrolysis in solid oxide electrolysis cells cathode: Advances and perspective27Microwave-Driven Exsolution of Ni Nanoparticles in A-Site Deficient Perovskites36Thermo-electrochemical modeling of thermally regenerative flow batteries28Revealing the Reaction Mechanism of CO2/H2O Coelectrolysis on Perovskite-Based Cathode Materials18Metal exsolution from perovskite-based anodes in solid oxide fuel cells27Architecting multi-active center on 3DOM La0.76Ce0.19Ag0.05Mn0.9Co0.1O3-δ perovskite for soot oxidation11A Zero-Dimensional Perovskite with Multi-Exciton Emission and Transient Response for Advanced Information Encryption0In situ construction of a double perovskite heterostructure with exsolved FeNi 3 alloy nanoparticles for CO 2 electrolysis in solid oxide electrolysis cells35Ultra-selective and Stable Ethylene Detection via Exsolution of Catalytic Ni Nanoparticles in Chemiresistive Gas Sensors0Pulsed laser deposition as an efficient tool to enhance the performance of electrocatalysis design, strategies and current perspectives26CO2 Electrolyzers354Effects of lanthanide doping on the electrode properties and exsolution behavior of A-site deficient Sr1.9Fe1.3Ni0.2Mo0.5O6-δ double perovskites14Ammonolysis‐Driven Exsolution of Ru Nanoparticle Embedded in Conductive Metal Nitride Matrix to Boost Electrocatalyst Activity17Highly Reversible Zn–Air Batteries Enabled by Tuned Valence Electron and Steric Hindrance on Atomic Fe–N 4 –C Sites113Diving deep into solid oxide-based CO2 electrolysis: Operando insights7Surface exsolved NiFeOx nanocatalyst for enhanced alkaline oxygen evolution catalysis13In situ exsolved CoFe alloy nanoparticles for stable anodic methane reforming in solid oxide electrolysis cells83Construction of RuO 2 ‐Ru/MoO 2 @carbon cloth bifunctional electrocatalyst for efficient overall water splitting22Insight on Strain Relaxation Effect in Perovskites for High‐Temperature Hydrogen Oxidation Reaction27A zero-dimensional perovskite with high-efficiency luminescence and transient response for advanced information encryption27Incorporation of Pd Single‐Atom Sites in Perovskite with an Excellent Selectivity toward Photocatalytic Semihydrogenation of Alkynes7Incorporation of Pd Single‐Atom Sites in Perovskite with an Excellent Selectivity toward Photocatalytic Semihydrogenation of Alkynes21The synergistic effect of Cl doping and Bi coupling to promote the carrier separation of BiOBr for efficient photocatalytic nitrogen reduction26Enhancing performance of lower-temperature solid oxide fuel cell cathodes through surface engineering69Exsolution of Ni nanoparticles from La0.4Sr0.4Ti0.8Ni0.2O3-δ perovskite for ethanol steam reforming14Squeezing Out Nanoparticles from Perovskites: Controlling Exsolution with Pressure21The effects of nano-socketed metal particles over perovskite surfaces on the electrochemical synthesis of high-value fuels13Perovskite nanocomposites: synthesis, properties, and applications from renewable energy to optoelectronics32Efficient Hydrogen Production by Combined Reforming of Methane over Perovskite-Derived Promoted Ni Catalysts3Uranium electrolytic deposition with regenerable Se2− active sites at low cell voltage8Hierarchical exsolution in vertically aligned heterostructures8Investigate the symmetrical electrode material based on Pr and Ni doping SmBaFe2O5+δ for its electrochemical and stability performance for solid oxide cell4Ni supported on Al2O3-La2O3 derived from layered double hydroxides for efficient thermal catalytic decomposition of ammonia to hydrogen29Nanosurface‐Reconstructed Fuel Electrode by Selective Etching for Highly Efficient and Stable Solid Oxide Cells7Ultra-selective and stable ethylene detection via exsolution of catalytic Ni nanoparticles in chemiresistive gas sensors6Toward Advanced Fuel Electrodes for High‐Performance Proton‐Conducting Ceramic Cells26Unveiling the Mechanism of Exsolution of Silver Nanoparticles for Decorating Lanthanum Strontium Ferrite4Mechanism from catalyst to catalysis on Ir segregated SrIrO3 for hydrogen evolution reaction10Disassembling and reassembling perovskites for oxygen electrocatalysis10Dual-functional engineering of Fe nanoparticles and oxygen vacancies in Sr 1.9 Fe 1.5 Mo 0.5 O 6− δ perovskites for high-efficiency CO 2 /H 2 O co-electrolysis1Enhancing the Performance of Sr2Fe1.3Ni0.2Mo0.5O6−δ as Methane-Fueled SOFC Anode via In-Situ Exsolution of Ni-Fe Nano-Catalyst3Exsolved medium-entropy alloy FeCoCuNi in titanate fibers enables solid oxide cells with superb electrochemical performance5In situ exsolution of FeCo alloy nanoparticles for highly efficient CO 2 electrolysis1Coal mine methane utilization: environmental friendly catalytic technology for sustainable development9Development of supported nickel-containing catalysts for methane tri-reforming: influence of pretreatment conditions2Tailoring oxide nanoparticle exsolution in La0.5Ba0.5-yCo1-xFexO3-δ2Physical Vapor Deposition Techniques for CO 2 Electroreduction: A Review16Ruddlesden–Popper-Type Oxide La2NiO4+δ with Oxygen Interstitials as Efficient Electrode for Proton Ceramic Electrolysis Cells5Advances in Nanostructured Electrodes for Solid Oxide Cells by Infiltration or Exsolution9In‐Situ Exsolved Metal Nanoparticles for Solid Oxide Fuel Cell Anode: Mechanism, Design Strategies and Application9Defective perovskite supported palladium-nickel nanocatalyst for effective electrochemical nitrate reduction26Harmonizing Nanoparticle Exsolution From Ce–Sm Oxide Matrix for Stable Methane Dry Reforming39Harmonizing Nanoparticle Exsolution From Ce–Sm Oxide Matrix for Stable Methane Dry Reforming8Recent advances and future prospects in exsolution technology for solid oxide cells20Scaling CO 2 Electroreduction Revolution: Pathways from Laboratory Breakthroughs to Industrial Implementation16Efficient cogeneration of electricity and light olefins over combined highly dispersed Pt and ZnNi alloy NPs in propane-fueled SOFCs2Impact of dopant levels, composition, temperature, and microstructure on exsolved iron and cobalt catalysts for the reverse water-gas shift reaction0Beneficial element segregation in the perovskite oxygen electrode for active and durable reversible solid oxide cells1Unraveling the Evolution and Regulation Mechanisms of Reversible Exsolution in Perovskite‐Based Nanoparticles20Development of Supported Nickel-Containing Catalysts for Methane Tri-reforming: Effect of Pretreatment Conditions0A-site deficiency synergistic in situ Fe-Sn alloy exsolution to optimize solid oxide electrolytic cell performance1Engineering Metal‐Metal Junctions from Layered Double Hydroxide Frameworks for High‐Rate Solid Oxide Cells1Calcination temperature of the perovskite parent compound controls active metal exsolution and catalytic performance for ethanol steam reforming1Cr doping regulates FeNi alloy nanoparticle exsolution on Sr 2 Fe 1.1 Ni 0.2 Cr 0.2 Mo 0.5 O 6− δ cathode to facilitate CO 2 electrolysis1In Situ Exsolved Co‐BaO‐La 2 O 3 Interface from Barium‐Doped Perovskites for Catalyzing Ammonia Decomposition Reaction1High-Temperature Electrochemical Ethane Oxidative Dehydrogenation Coupled with H 2 O/CO 2 Electrolysis in Tubular Solid Oxide Electrolysis Cells1Impact of Phase-Separated Janus-Type Formation on the Reversibility of Multicomponent Exsolved Nanoparticles from Complex Perovskites0Engineering the artificial carbon cycle via tandem strategies and cross-scale integration in electrocatalytic CO2 reduction0Tailoring Defect Chemistry via Lu Doping Enables Highly Active and Stable High-Temperature Electrochemical Dehydrogenation0Acceptor‐Doped Cerium Oxides Enabling Metallic Nanocatalyst Exsolution for Hydrogen Production From Ammonia0Acceptor‐Doped Cerium Oxides Enabling Metallic Nanocatalyst Exsolution for Hydrogen Production From Ammonia0Exploring the potential of dynamic periodic operation on tackling challenging reactions under traditional steady state - a review0Exsolution of active and thermally stable Ru nanoparticles on CeO2 via one-pot infiltration for enhanced direct-ammonia solid oxide fuel cells (DA-SOFCs)0

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  47. High-temperature CO2 electrolysis in solid oxide electrolysis cells cathode: Advances and perspective

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    Yao Luo, Tong Liu, Yao Wang, Mingyue Ding

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  48. Microwave-Driven Exsolution of Ni Nanoparticles in A-Site Deficient Perovskites

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