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RESEARCH PAPER · Crystal Growth & Design · 2018

Design and Control of the Luminescence of Cr3+-Doped Phosphors in the Near-Infrared I Region by Fitting the Crystal Field

Qiongyu Bai, Suling Zhao, Li Guan, Zhijun Wang, Panlai Li, Zheng Xu

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Design and Control of the Luminescence of Cr3+-Doped Phosphors in the Near-Infrared I Region by Fitting the Crystal FieldOriginalPersistent luminescence found in Mg 2+ and Pr 3+ co-doped LiNbO 3 single crystal39Synthesis, luminescence properties and energy transfer of Ca2MgWO6:Cr3+,Yb3+ phosphors50Double perovskite Cs 2 AgInCl 6 :Cr 3+ : broadband and near-infrared luminescent materials343Trends in Cr3+ red emissions from ZnGa2O4 nanostructures produced by pulsed laser ablation in a liquid medium18Design and synthesis of up-converted persistent luminescence Zn3Ga2SnO8:Cr3+, Yb3+, Er3+ phosphor23Green Zn3Al2Ge2O10: Mn2+ Phosphors: Solid-Phase Synthesis, Structure, and Luminescent Properties2Ratiometric optical thermometer with high sensitivity based on dual far-red emission of Cr3+ in Sr2MgAl22O3655[INVITED] Near-infrared phosphors and their full potential: A review on practical applications and future perspectives196Broadband near-infrared (NIR) emission realized by the crystal-field engineering of Y 3−x Ca x Al 5−x Si x O 12 :Cr 3+ ( x = 0–2.0) garnet phosphors263Designing a super broadband near infrared material Mg 3 Y 2 Ge 3 O 12 :Cr 3+ using cation inversion for future light sources21Two-site Cr 3+ occupation in the MgTa 2 O 6 :Cr 3+ phosphor toward broad-band near-infrared emission for vessel visualization215Melamine sponge-assisted synthesis of porous BCNO phosphor with yellow-green luminescence for Cr6+ detection16Site-related broadband sensitization in La3Ga5.5Nb0.5O14: Cr3+, Ln3+(Ln = Yb, Er) phosphors9Effects of Ca2+ doping on upconversion luminescence intensity and crystal field asymmetry of β-NaYF4:Yb3+/Er3+ microcrystals23Penetrating Biological Tissue Using Light-Emitting Diodes with a Highly Efficient Near-Infrared ScBO3:Cr3+ Phosphor232Luminescent properties of Li(Ga1-xCrx)5O8 (LGCO) phosphors12Synthesis and characterisation of Zn3Ga2SnO8:Cr3+, Yb3+, Er3+/α-tricalcium phosphate up-converted and persistent luminescence phosphor6Broadband near‐infrared emission enhancement in K 2 Ga 2 Sn 6 O 16 :Cr 3+ phosphor by electron‐lattice coupling regulation87Design of a Broadband NIR Phosphor for Security-Monitoring LEDs: Tunable Photoluminescence Properties and Enhanced Thermal Stability140Broadband near-infrared emitting from Li1.6Zn1.6Sn2.8O8:Cr3+ phosphor by two-site occupation and Al3+ cationic regulation70Near-infrared up-converted persistent luminescence in Zn3Ga2SnO8:Cr3+, Yb3+, Er3+ nano phosphor for imaging10Design and control of the luminescence in Cr3+-doped NIR phosphors via crystal field engineering105Multi-Site Cation Control of Ultra-Broadband Near-Infrared Phosphors for Application in Light-Emitting Diodes54Enticing applications of near‐infrared phosphors: Review and future perspectives44Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications242A dual-excited and dual near-infrared emission phosphor Mg 14 Ge 5 O 24 :Cr 3+ ,Cr 4+ with a super broad band for biological detection70Achieving the potential multifunctional near-infrared materials Ca 3 In 2−x Ga x Ge 3 O 12 :Cr 3+ using a solid state method59Multi-site Cr 3+ occupation-related broadband NIR luminescence in Cr 3+ -doped Li 3 Mg 2 NbO 634Turning-on persistent luminescence out of chromium-doped zinc aluminate nanoparticles by instilling antisite defects under mild conditions13Li/Na substitution and Yb3+ co-doping enabling tunable near-infrared emission in LiIn2SbO6:Cr3+ phosphors for light-emitting diodes143Broadband near-infrared phosphor BaMgAl10O17:Cr3+ realized by crystallographic site engineering254Competitive Cr 3+ occupation in persistent phosphors toward tunable traps distribution for dynamic anti‐counterfeiting22Research on a new type of near-infrared phosphor Li2MgZrO4:Cr3+- synthesis, crystal structure, photoluminescence and thermal stability18Cr-doped ZnGa2O4: Simple synthesis of intense red-NIR emitting nanoparticles with enhanced quantum efficiency14Regulating chromium ions site occupancy and enhancing near-infrared luminescence properties of Sr2P2O7:Cr3+ phosphor through synthesizing under reduction atmosphere28Multifunctional Near-Infrared (NIR) Phosphors with NIR I and NIR II Luminescence for Biological Detection29Design and tuning Cr 3+ -doped near-infrared phosphors for multifunctional applications via crystal field engineering26Efficient Cr 3+ -activated NaInP 2 O 7 phosphor for broadband near-infrared LED applications21Insertion of metal cations into hybrid organometallic halide perovskite nanocrystals for enhanced stability: eco-friendly synthesis, lattice strain engineering, and defect chemistry studies17Cr3+-Sphere Effect on the Whitlockite-Type NIR Phosphor Sr9Sc(PO4)7 with High Heat Dissipation for Digital Medical Applications35Novel broadband near-infrared emitting phosphor LiGe2(PO4)3:Cr3+ with tuning and enhancement of NIR emission by codoping Sb5+49Spectral design in Cr3+-doped NIR phosphors via crystal field modulation20Design of a Novel Near-Infrared Luminescence Material Li2Mg3TiO6:Cr3+ with an Ultrawide Tuning Range Applied to Near-Infrared Light-Emitting Diodes111Effect of Citric Acid Amount in the Synthesis of LiGa5O8:Cr3+ Nano-Phosphor2Optical enhancement of nonstoichiometry-induced heterojunction in lanthanide doped double perovskite phosphors for WLEDs and scintillation applications22Structural and photoluminescence properties of Cr3+ doped LaVO4 phosphor20Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources489Optimization of persistent luminescence performance of zinc gallogermanates10Structure and tunable broadband near-infrared luminescence of Cr3+ in borophosphate glass23Achievement of broadband NIR emission in double perovskite NaLaMgWO6 via non-equivalent substitution of Cr3+17Double‐Site Occupation Triggered Broadband and Tunable NIR‐I and NIR‐II Luminescence in AlNbO4:Cr3+ Phosphors15Near‐Infrared Windows I and II Phosphors for Theranostic Applications: Spectroscopy, Bioimaging, and Light‐Emitting Diode Photobiomodulation110Luminescence properties and spectral modulation of the ultra-broadband, highly efficient near-infrared luminescent material CaGa4O7:Cr3+, Cr4+, Yb3+13A broadband near-infrared Cr 3+ -doped phosphor applied to near-infrared light-emitting diodes: enhanced luminescence and thermal stability by annealing20Broadening of the near-infrared emission band of the Mg 2 Al 4 Si 5 O 18 :Cr 3+ phosphor for illumination emission applications12Regulating the trap distribution of ZnGa 2 O 4 :Cr 3+ by Li + /Ga 3+ doping for upconversion-like trap energy transfer NIR persistent luminescence48Tunable Near-Infrared Broadband Photoluminescence of Mg2latao6:Cr3+ Phosphors for Light-Emitting Diodes0Ion Substitution Strategy toward High-Efficiency Near-Infrared Photoluminescence of Cs2KIn1–yAlyF6:Cr3+ Solid Solutions54Two-site occupation in Cr3+-activated BaIn2(P2O7)2 phosphor for broadband near-infrared thermometry and LED applications30Effects of Cr3+ content on the structure and fluorescence properties of SiO2–Na2O–Y2O3–P2O5 glasses and glass-ceramics with Na3YSi2O7 crystal phase11Highly efficient and stable Cr3+-activated oxyfluoride near-infrared emitting phosphor for night vision and plant growth12Tunable broadband near-infrared photoluminescence of Mg2LaTaO6:Cr3+ phosphors for light-emitting diodes20Multi-site occupancy high-efficient Mg2LaTaO6:Cr3+ phosphor for application in broadband NIR pc-LEDs62A novel broadband near‐infrared Ca 2 Y 3 Sb 3 O 14 : Cr 3+ rhombohedral pyrochlores phosphor and its application in pc‐LEDs12Compositional modulation induced broadband NIR luminescence enhancement in A2ScNbO6:Cr3+ (A = Ba, Sr)12High performance NIR-I to NIR-II emission of a Cr 3+ -doped Cs 2 NaLuCl 6 phosphor with an IQE and EQE of up to 92.9% and 60.75%44Site-selective occupancy of Cr 3+ enabling tunable emission from near infrared I to II in fluoride LiInF 4 :Cr 3+18Grafting Carbon Dots on Persistent Luminescence Phosphors to Generate Remarkably Improved NIR Afterglow for Microenvironment Fluorescence Detection5Thermally stable fluoride phosphor Na3Sc2Li3F12:Cr3+ with broadband emission for NIR pc-LED applications23A far-red-emitting LiGaTiO4:Cr3+ phosphor for potential application in plant growth LEDs18Surface chemical analysis and luminescent properties of La7O6(BO3)(PO4)2: Sm3+ phosphor19Efficient broadband near-infrared emission based on copper-alloyed metal halides1Photoluminescence properties of SnO2 nanoparticles doped with group VI elements (Cr, Mo, W) synthesized by pulsed laser ablation in liquid5Antithermal-Quenching Near-Infrared Emitting Lu2SrAl4SiO12:Cr3+ Garnet-Type Phosphor for High-Resolution Nonvisual Imaging38Energy-transfer enhanced Cr 3+ /Ni 2+ co-doped tantalate phosphors for broadband NIR pc-LED applications9Matrix composition induced performance tuning in Cr3+/Er3+ doped zinc gallogermanates NIR afterglow phosphors4Tunable NIR Emission of Cr3+-Activated Double-Perovskite Tantalates and Improvement of Luminescence Properties via Codoping Yb3+11Controllable morphology and enhanced luminescence in hydrothermally Cr3+-Doped Na3GaF6 phosphors for NIR imaging7Broadening and Enhancing the Emission of Phosphor Li2MgTi3O8:Cr3+ by Cation Substitution10Ultra-broadband near-infrared-I and II emission from chromium doped double perovskite for multifunction application4Synergy between Defects and Lattice Distortion Drives Self‐Powered Elastico‐Near‐Infrared Mechanoluminescence in Cr 3+ ‐Doped Spinel Oxides13Structure, near-infrared broadband luminescence and long afterglow properties in CaGd2Ga4GeO12: Cr3+ garnet phosphor for multifunctional applications3Broadband NIR-I/II emitting phosphor Cr3+-Ni2+ Co-doped Mg3Y2Ge3O12 for deep-tissue imaging & night vision2High-performance multifunctional NIR phosphor K2NaAlF6:Mn4+,Cr3+ for pc-LED and X-ray imaging via efficient energy transfer3HF-free green synthesis of a highly efficient Na3Li3Sc2F12:Cr3 + near-infrared phosphor with exceptional thermal stability for real-time vein projection0Insight Into Cr 3+ ‐Activated Oxynitride Near‐Infrared Phosphors0

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  1. Persistent luminescence found in Mg 2+ and Pr 3+ co-doped LiNbO 3 single crystal

    Journal of Materials Chemistry C · 2018-01-01

    Shaopeng Lin, Chenwei Xiong, Decai Ma, Huashan Li, Siwei Long, Biao Wang

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  2. Synthesis, luminescence properties and energy transfer of Ca2MgWO6:Cr3+,Yb3+ phosphors

    Materials Research Bulletin · 2018-10-16

    Dandan Xu, Qi Zhang, Xuanmin Wu, Wanwen Li, Jianxin Meng

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  3. Double perovskite Cs 2 AgInCl 6 :Cr 3+ : broadband and near-infrared luminescent materials

    Inorganic Chemistry Frontiers · 2019-01-01

    Fangyi Zhao, Zhen Song, Jing Wei Zhao, Quanlin Liu

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  4. Trends in Cr3+ red emissions from ZnGa2O4 nanostructures produced by pulsed laser ablation in a liquid medium

    Journal of Physics and Chemistry of Solids · 2019-01-19

    Maria S. Relvas, M.R.N. Soares, Sónia O. Pereira, Ana Violeta Girao, F.M. Costa, T. Monteiro

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  5. Design and synthesis of up-converted persistent luminescence Zn3Ga2SnO8:Cr3+, Yb3+, Er3+ phosphor

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  6. Green Zn3Al2Ge2O10: Mn2+ Phosphors: Solid-Phase Synthesis, Structure, and Luminescent Properties

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  7. Ratiometric optical thermometer with high sensitivity based on dual far-red emission of Cr3+ in Sr2MgAl22O36

    Ceramics International · 2019-11-02

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  8. [INVITED] Near-infrared phosphors and their full potential: A review on practical applications and future perspectives

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  9. Broadband near-infrared (NIR) emission realized by the crystal-field engineering of Y 3−x Ca x Al 5−x Si x O 12 :Cr 3+ ( x = 0–2.0) garnet phosphors

    Journal of Materials Chemistry C · 2019-12-12

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  10. Designing a super broadband near infrared material Mg 3 Y 2 Ge 3 O 12 :Cr 3+ using cation inversion for future light sources

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  11. Two-site Cr 3+ occupation in the MgTa 2 O 6 :Cr 3+ phosphor toward broad-band near-infrared emission for vessel visualization

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  12. Melamine sponge-assisted synthesis of porous BCNO phosphor with yellow-green luminescence for Cr6+ detection

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  13. Site-related broadband sensitization in La3Ga5.5Nb0.5O14: Cr3+, Ln3+(Ln = Yb, Er) phosphors

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2020-01-20

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  14. Effects of Ca2+ doping on upconversion luminescence intensity and crystal field asymmetry of β-NaYF4:Yb3+/Er3+ microcrystals

    Journal of Luminescence · 2020-01-31

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  15. Penetrating Biological Tissue Using Light-Emitting Diodes with a Highly Efficient Near-Infrared ScBO3:Cr3+ Phosphor

    Chemistry of Materials · 2020-02-05

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  16. Luminescent properties of Li(Ga1-xCrx)5O8 (LGCO) phosphors

    Ceramics International · 2020-03-14

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  17. Synthesis and characterisation of Zn3Ga2SnO8:Cr3+, Yb3+, Er3+/α-tricalcium phosphate up-converted and persistent luminescence phosphor

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  18. Broadband near‐infrared emission enhancement in K 2 Ga 2 Sn 6 O 16 :Cr 3+ phosphor by electron‐lattice coupling regulation

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  19. Design of a Broadband NIR Phosphor for Security-Monitoring LEDs: Tunable Photoluminescence Properties and Enhanced Thermal Stability

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  20. Broadband near-infrared emitting from Li1.6Zn1.6Sn2.8O8:Cr3+ phosphor by two-site occupation and Al3+ cationic regulation

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  21. Near-infrared up-converted persistent luminescence in Zn3Ga2SnO8:Cr3+, Yb3+, Er3+ nano phosphor for imaging

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  22. Design and control of the luminescence in Cr3+-doped NIR phosphors via crystal field engineering

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  23. Multi-Site Cation Control of Ultra-Broadband Near-Infrared Phosphors for Application in Light-Emitting Diodes

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  24. Enticing applications of near‐infrared phosphors: Review and future perspectives

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  25. Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications

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  26. A dual-excited and dual near-infrared emission phosphor Mg 14 Ge 5 O 24 :Cr 3+ ,Cr 4+ with a super broad band for biological detection

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  27. Achieving the potential multifunctional near-infrared materials Ca 3 In 2−x Ga x Ge 3 O 12 :Cr 3+ using a solid state method

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  28. Multi-site Cr 3+ occupation-related broadband NIR luminescence in Cr 3+ -doped Li 3 Mg 2 NbO 6

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  29. Turning-on persistent luminescence out of chromium-doped zinc aluminate nanoparticles by instilling antisite defects under mild conditions

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  30. Li/Na substitution and Yb3+ co-doping enabling tunable near-infrared emission in LiIn2SbO6:Cr3+ phosphors for light-emitting diodes

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  31. Broadband near-infrared phosphor BaMgAl10O17:Cr3+ realized by crystallographic site engineering

    Chemical Engineering Journal · 2021-03-07

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  32. Competitive Cr 3+ occupation in persistent phosphors toward tunable traps distribution for dynamic anti‐counterfeiting

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  33. Research on a new type of near-infrared phosphor Li2MgZrO4:Cr3+- synthesis, crystal structure, photoluminescence and thermal stability

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  34. Cr-doped ZnGa2O4: Simple synthesis of intense red-NIR emitting nanoparticles with enhanced quantum efficiency

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  35. Regulating chromium ions site occupancy and enhancing near-infrared luminescence properties of Sr2P2O7:Cr3+ phosphor through synthesizing under reduction atmosphere

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  36. Multifunctional Near-Infrared (NIR) Phosphors with NIR I and NIR II Luminescence for Biological Detection

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  37. Design and tuning Cr 3+ -doped near-infrared phosphors for multifunctional applications via crystal field engineering

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  38. Efficient Cr 3+ -activated NaInP 2 O 7 phosphor for broadband near-infrared LED applications

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  39. Insertion of metal cations into hybrid organometallic halide perovskite nanocrystals for enhanced stability: eco-friendly synthesis, lattice strain engineering, and defect chemistry studies

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  40. Cr3+-Sphere Effect on the Whitlockite-Type NIR Phosphor Sr9Sc(PO4)7 with High Heat Dissipation for Digital Medical Applications

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  41. Novel broadband near-infrared emitting phosphor LiGe2(PO4)3:Cr3+ with tuning and enhancement of NIR emission by codoping Sb5+

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  42. Spectral design in Cr3+-doped NIR phosphors via crystal field modulation

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  43. Design of a Novel Near-Infrared Luminescence Material Li2Mg3TiO6:Cr3+ with an Ultrawide Tuning Range Applied to Near-Infrared Light-Emitting Diodes

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  44. Effect of Citric Acid Amount in the Synthesis of LiGa5O8:Cr3+ Nano-Phosphor

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  45. Optical enhancement of nonstoichiometry-induced heterojunction in lanthanide doped double perovskite phosphors for WLEDs and scintillation applications

    Chemical Engineering Journal · 2022-04-05

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  46. Structural and photoluminescence properties of Cr3+ doped LaVO4 phosphor

    Solid State Sciences · 2022-05-04

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  47. Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources

    Laser & Photonics Review · 2022-08-07

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  48. Optimization of persistent luminescence performance of zinc gallogermanates

    Materials Today Chemistry · 2022-08-22

    Celina Matuszewska, Tomasz W. Pańczuk, Peter A. Tanner, Ka‐Leung Wong

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  49. Structure and tunable broadband near-infrared luminescence of Cr3+ in borophosphate glass

    Ceramics International · 2022-08-28

    Haozhang Liang, Zhiwei Luo, Kaipeng Wu, Juxia Tong, Chengjian Wen, Ping Zhang, Songxuan Liu, Ziyou Zhou, Anxian Lu

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  50. Achievement of broadband NIR emission in double perovskite NaLaMgWO6 via non-equivalent substitution of Cr3+

    Journal of Luminescence · 2022-12-05

    Fen Xiao, Haiping Xie, Chengning Xie, Rongxi Yi, Yonghui Zeng, Huiling Yuan

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