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RESEARCH PAPER · Journal of Materials Chemistry C · 2018

A highly efficient and thermally stable green phosphor (Lu 2 SrAl 4 SiO 12 :Ce 3+ ) for full-spectrum white LEDs

Yu Xiao, Wenge Xiao, Liangliang Zhang, Zhendong Hao, Guohui Pan, Yang Yang, Xia Zhang, Jiahua Zhang

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A highly efficient and thermally stable green phosphor (Lu 2 SrAl 4 SiO 12 :Ce 3+ ) for full-spectrum white LEDsOriginalAliovalent substitution toward reinforced structural rigidity in Ce 3+ -doped garnet phosphors featuring improved performance44Enhanced photoluminescence and thermal stability in solid solution Ca 1−x Sr x Sc 2 O 4 :Ce 3+ ( x = 0–1) via crystal field regulation and site-preferential occupation49Mixing the valence control of Eu 2+ /Eu 3+ and energy transfer construction of Eu 2+ /Mn 2+ in the solid solution (1 − x )Ca 3 (PO 4 ) 2 – x Ca 9 Y(PO 4 ) 7 for multichannel photoluminescence tuning34NaKLaNbO5:Eu3+: A highly efficient and thermally stable orange-red emitting phosphor for white light-emitting diodes24Green emitting spinel/Ba2SiO4:Eu2+/spinel sandwich structure robust ceramic phosphor prepared by spark plasma sintering17Effect of sintering temperature on luminescence properties of borosilicate matrix blue–green emitting color conversion glass ceramics*4Carbon Dots Exhibiting Concentration-Dependent Full-Visible-Spectrum Emission for Light-Emitting Diode Applications93White Light-Emitting Diodes With Ultrahigh Color Rendering Index by Red/Green Phosphor Layer Configuration Structure23Ultra-broadband cyan-to-orange emitting Ba 1+x Sr 1−x Ga 4 O 8 :Bi 3+ phosphors: luminescence control and optical temperature sensing95Enhanced green emission and thermal stability of Ba3Si6O12N2:Eu2+ by Ce3+/P5+-doping: Unity energy transfer, charge compensation and lattice strain release6Full-visible-spectrum lighting enabled by an excellent cyan-emitting garnet phosphor284Highly efficient and thermally stable luminescence of Ca 3 Gd 2 Si 6 O 18 :Ce 3+ ,Tb 3+ phosphors based on efficient energy transfer38Novel red-emitting Lu3Te2Li3O12: Eu3+ phosphor with high color purity for n-UV WLEDs2Near-ultraviolet chip-based phosphor-converted solar-spectrum white light-emitting diode2Luminescence properties of Ca2Sn2Al2O9: Mn as a long afterglow and field-emission displays material with high yellow color purity15Novel color tunable garnet phosphor of Tb3+ and Eu3+ co-doped Ca2YZr2Al3O12 with high thermal stability via energy transfer73Strategies for Designing Antithermal‐Quenching Red Phosphors216Highly Efficient Cyan-Green Emission in Self-Activated Rb3RV2O8 (R = Y, Lu) Vanadate Phosphors for Full-Spectrum White Light-Emitting Diodes (LEDs)87Broadband Near‐Infrared Garnet Phosphors with Near‐Unity Internal Quantum Efficiency308Tailoring narrow-band blue emitting Ca7(Mg, Zn)2P6O24: Eu2+ phosphate phosphor via crystal lattice distortion for WLEDs12Broad-Band and Stable Phosphor-in-Glass Enabling Ultrahigh Color Rendering for All-Inorganic High-Power WLEDs43Structural and photoluminescence behavior of a blue–green-emitting Y6Ba4(SiO4)6F2:xTb3+ fluorapatite phosphor5Adjustable photoluminescence of Bi3+ and Eu3+ in solid solution constructed by isostructural end components through composition and excitation-driven strategy90A near infrared-II broad emission material with multi-spectral excitation and long persistent luminescence properties21Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146Advancing Human-Centric LED Lighting Using Na2MgPO4F:Eu2+101Recent prospects on phosphor-converted LEDs for lighting, displays, phototherapy, and indoor farming164Using an excellent near-UV-excited cyan-emitting phosphor for enhancing the color rendering index of warm-white LEDs by filling the cyan gap81Effect of Ca2+ - Si4+ on Y3Al5O12:Ce ceramic phosphors for white laser-diodes lighting16Distortion and energy transfer assisted tunability in garnet phosphors62Novel Ba3Lu4O9:Bi3+,Eu3+ phosphors for white LEDs: Efficient energy transfer, broad near-UV excitation band and green-yellow-orange-red color tunable emissions13Optical thermometry based fluorescence intensity ratio in Y2Mg2Al2Si2O12:Bi3+,Eu3+ phosphors44Multi spectral responsive near infrared-II broad emission material and its LED device and imaging research12An Extra‐Broadband VIS‐NIR Emitting Phosphor toward Multifunctional LED Applications153(INVITED)Broadband emission of Lu2SrAl4SiO12:Eu2+ phosphor for full-spectrum lighting6Inkjet printed patterned bank structure with encapsulated perovskite colour filters for modern display23How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Glass‐Crystallized Luminescence Translucent Ceramics toward High‐Performance Broadband NIR LEDs120Full-Spectrum White Light-Emitting Diodes Enabled by an Efficient Broadband Green-Emitting CaY 2 ZrScAl 3 O 12 :Ce 3+ Garnet Phosphor255Luminescence and interstitial-defect-related self-reduction in Mn2+ activated Ba3BP3O12 phosphor13Unravel the effect of lattice distortion on the 4f-5d excitation of Ce3+ in garnet phosphors22Full-spectrum solid-state white lighting with high color rendering index exceeding 96 based on a bright broadband green-emitting phosphor45Multiobjective Machine Learning-Assisted Discovery of a Novel Cyan–Green Garnet: Ce Phosphors with Excellent Thermal Stability73Synthesis, crystal structure, and anti‐thermal quenching performance of Lu 2 Sr (1− x ) Al 4 SiO 12 : x Eu 2+ phosphors9Highly Efficient Broad-Band Green-Emitting Cerium(III)-Activated Garnet Phosphor Allows the Fabrication of Blue-Chip-Based Warm-White LED Device with a Superior Color Rendering Index69Efficient, Stable, and Ultra‐Broadband Near‐Infrared Garnet Phosphors for Miniaturized Optical Applications89Nanorods for Lighting and Display1Stable Nanorods on-chip LED for Healthy Indoor Lighting0Color-tunable emissions in Bi3+/Eu3+ activated phosphors for multi-mode optical thermometers35Enhanced Thermal Stability and Energy Transfer by Crystal‐Field Engineering in a Garnet Phosphor for Thermometry and NIR‐LED48Bright green emitting Terbium-MOF with high quantum yield achieved through post synthetic modifications20Self‐Activated Tungstate Phosphor for Near‐Infrared Light‐Emitting Diodes58Thermal stable cyan-emitting Ba9(Lu1.5Ga0.5)Si6O24:Ce3+ for high color-rendering white LEDs7Phosphor‐in‐Silica‐Glass: Filling the Gap between Low‐ and High‐Brightness Solid‐State Lightings46Photoluminescence Properties of Cyan-Emitting Lu3GaxAl5−xO12: Ce3+ Garnet Phosphors Synthesized in Nonreducing Atmosphere and at Different Temperature for High Quality w-LEDs7Recent progress in Ce 3+ /Eu 2+ -activated LEDs and persistent phosphors: focusing on the local structure and the electronic structure137Fabrication of LuAG:Ce3+ Ceramic Phosphors Prepared with Nanophosphors Synthesized by a Sol-Gel-Combustion Method1A broadband yellow-green emitting mixed orthoborate–pyroborate phosphor, Ba 2 Sc 2 B 4 O 11 :Ce 3+ , for white light emitting diodes23A novel narrow-band blue-emitting phosphor with high efficiency and thermal stability for WLEDs and FEDs31An efficient blue-excitable broadband Y 3 ScAl 4 O 12 :Ce 3+ garnet phosphor for WLEDs13Local Structure and Self‐Defect Evolution under Nonstoichiometric Effect Unlock Zero‐Thermal‐Quenching15Near-UV-excitable broadband green-emitting Ca2LaHf2GaAl2O12:Ce3+ garnet-type phosphors for high color rendering warm-white LEDs42P‐131: Thermally Stability study for Quantum Rod On‐chip Light‐Emitting Diodes under High Power Illumination0Recent progress on garnet phosphor ceramics for high power solid-state lighting104Enhancing External Quantum Efficiency of Blue-Emitting Phosphor Ba(K)-β-Al2O3:Eu2+ by Lattice Site Engineering for Full-Spectrum Lighting40Realizing full-spectrum LED lighting with a bright broadband cyan-green-emitting CaY2ZrGaAl3O12:Ce3+ garnet phosphor25Ultra-broadband emission up to 181 nm of VO4-activated yellow phosphor for white light-emitting diodes with high color rendering index5Achieving broadband near-infrared emission with superior anti-thermal quenching by optimizing the excited-state population of Cr 3+ in Gd 3 ScGa 4 O 12 garnet phosphors107Ce:(Lu,Sr) 3 (Al,Si) 5 O 12 transparent ceramics for high-power white LEDs/LDs with ultra-high luminance saturation threshold12High-performance green-emitting Ca 2 YScAl 2 Si 2 O 12 :Ce 3+ garnet phosphors and their applications in high-quality blue-chip-pumped white LEDs48Highly efficient and thermally stable broadband green-emitting BaY 2 Sc 2 Al 2 SiO 12 :Ce 3+ phosphors enabling warm-white LEDs with high luminous efficacy and high color rendering index44Metal oxide-based phosphors for chemical sensors0Structure, luminescence properties, and valence-induced spectral behavior of a bismuth-activated garnet phosphor9Novel Eu3+ doped Li2ZnTi3O8 phosphor: Synthesis, structural and optical characterization for white light emitting diodes21Less is more: An oxyfluoride garnet broadband cyan-green phosphor towards highly efficient full-spectrum WLEDs22Highly emissive 0D Tin(II) hybrid for white LED6Luminescence properties and energy transfer of Ce3+, Tb3+ codoped Ba2GaB4O9Cl Phosphor10Color-tunability and energy transfer of a highly thermal-stable BaZnB4O8:Tb3+/Eu3+ phosphor for single-component w-LEDs21Antithermal-Quenching Near-Infrared Emitting Lu2SrAl4SiO12:Cr3+ Garnet-Type Phosphor for High-Resolution Nonvisual Imaging38Highly Efficient Wide-Spectrum Green Y 2 Bascal 3 Sio 12:Ce 3+ Phosphor for Advanced White Leds Applications0Highly Efficient Wide-Spectrum Green Y2bascal3sio12:Ce3+ Phosphor for Advanced White Leds Applications0Novel high-efficiency and superior thermal stability red-emitting phosphors for WLEDs2Nuv Excited Fe3+ Doped Oxide Perovskite Phosphor with Broadband Near-Infrared Emission0Phosphor-converted light-emitting diodes in the marine environment: current status and future trends40Research progress on the design and regulation of Eu 2+ /Ce 3+ -activated anti-/zero thermal quenching phosphors9A thermally stable Ce3+ activated green phosphor for illuminating and temperature sensing application10An Efficient Broadband Cyan Phosphor for Full‐Spectrum pc‐WLEDs24Near ultraviolet excited Fe3+ doped oxide perovskite Ca3TeO6 phosphor with broadband near-infrared emission12Highly efficient wide-spectrum green Y2BaScAl3SiO12:Ce3+ phosphor for advanced white LEDs applications5Resonance energy transfer coordinated by cationic substitution engineering realized visible to NIR plants lighting source0Luminescence properties of Ce3+-activated BaLu2Al3ScSiO12 cyan-green emitting garnet phosphors for white LEDs4Intrinsically Thermally Robust Nanocrystals for High‐Flux Photonics9Sunlike Full‐Spectrum White Light‐Emitting Diodes Based on Efficient and Eco‐Friendly Hybrid Copper Halide Ionic Crystals1Broadband green-yellow emitting BaY2Al3ScSiO12:Ce3+ garnet phosphor for high-quality white LED applications5Luminescence properties and Judd-Ofelt analysis of cool green emitting terbium fumarate MOF synthesized via microwave assisted co-precipitation method2Anti-thermal quenching phosphor Lu2SrAl4SiO12: Cr3 +, Fe3+ for application in temperature sensing0

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  1. Aliovalent substitution toward reinforced structural rigidity in Ce 3+ -doped garnet phosphors featuring improved performance

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  2. Enhanced photoluminescence and thermal stability in solid solution Ca 1−x Sr x Sc 2 O 4 :Ce 3+ ( x = 0–1) via crystal field regulation and site-preferential occupation

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  3. Mixing the valence control of Eu 2+ /Eu 3+ and energy transfer construction of Eu 2+ /Mn 2+ in the solid solution (1 − x )Ca 3 (PO 4 ) 2 – x Ca 9 Y(PO 4 ) 7 for multichannel photoluminescence tuning

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  4. NaKLaNbO5:Eu3+: A highly efficient and thermally stable orange-red emitting phosphor for white light-emitting diodes

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  5. Green emitting spinel/Ba2SiO4:Eu2+/spinel sandwich structure robust ceramic phosphor prepared by spark plasma sintering

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  6. Effect of sintering temperature on luminescence properties of borosilicate matrix blue–green emitting color conversion glass ceramics*

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  7. Carbon Dots Exhibiting Concentration-Dependent Full-Visible-Spectrum Emission for Light-Emitting Diode Applications

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  8. White Light-Emitting Diodes With Ultrahigh Color Rendering Index by Red/Green Phosphor Layer Configuration Structure

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  9. Ultra-broadband cyan-to-orange emitting Ba 1+x Sr 1−x Ga 4 O 8 :Bi 3+ phosphors: luminescence control and optical temperature sensing

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  10. Enhanced green emission and thermal stability of Ba3Si6O12N2:Eu2+ by Ce3+/P5+-doping: Unity energy transfer, charge compensation and lattice strain release

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  11. Full-visible-spectrum lighting enabled by an excellent cyan-emitting garnet phosphor

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  12. Highly efficient and thermally stable luminescence of Ca 3 Gd 2 Si 6 O 18 :Ce 3+ ,Tb 3+ phosphors based on efficient energy transfer

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  13. Novel red-emitting Lu3Te2Li3O12: Eu3+ phosphor with high color purity for n-UV WLEDs

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  14. Near-ultraviolet chip-based phosphor-converted solar-spectrum white light-emitting diode

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  15. Luminescence properties of Ca2Sn2Al2O9: Mn as a long afterglow and field-emission displays material with high yellow color purity

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  16. Novel color tunable garnet phosphor of Tb3+ and Eu3+ co-doped Ca2YZr2Al3O12 with high thermal stability via energy transfer

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  17. Strategies for Designing Antithermal‐Quenching Red Phosphors

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  18. Highly Efficient Cyan-Green Emission in Self-Activated Rb3RV2O8 (R = Y, Lu) Vanadate Phosphors for Full-Spectrum White Light-Emitting Diodes (LEDs)

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  19. Broadband Near‐Infrared Garnet Phosphors with Near‐Unity Internal Quantum Efficiency

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  20. Tailoring narrow-band blue emitting Ca7(Mg, Zn)2P6O24: Eu2+ phosphate phosphor via crystal lattice distortion for WLEDs

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  30. Distortion and energy transfer assisted tunability in garnet phosphors

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  31. Novel Ba3Lu4O9:Bi3+,Eu3+ phosphors for white LEDs: Efficient energy transfer, broad near-UV excitation band and green-yellow-orange-red color tunable emissions

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  32. Optical thermometry based fluorescence intensity ratio in Y2Mg2Al2Si2O12:Bi3+,Eu3+ phosphors

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  33. Multi spectral responsive near infrared-II broad emission material and its LED device and imaging research

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  34. An Extra‐Broadband VIS‐NIR Emitting Phosphor toward Multifunctional LED Applications

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  35. (INVITED)Broadband emission of Lu2SrAl4SiO12:Eu2+ phosphor for full-spectrum lighting

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  36. Inkjet printed patterned bank structure with encapsulated perovskite colour filters for modern display

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  37. How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications

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  38. Glass‐Crystallized Luminescence Translucent Ceramics toward High‐Performance Broadband NIR LEDs

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  39. Full-Spectrum White Light-Emitting Diodes Enabled by an Efficient Broadband Green-Emitting CaY 2 ZrScAl 3 O 12 :Ce 3+ Garnet Phosphor

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  40. Luminescence and interstitial-defect-related self-reduction in Mn2+ activated Ba3BP3O12 phosphor

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  41. Unravel the effect of lattice distortion on the 4f-5d excitation of Ce3+ in garnet phosphors

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  42. Full-spectrum solid-state white lighting with high color rendering index exceeding 96 based on a bright broadband green-emitting phosphor

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  43. Multiobjective Machine Learning-Assisted Discovery of a Novel Cyan–Green Garnet: Ce Phosphors with Excellent Thermal Stability

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  44. Synthesis, crystal structure, and anti‐thermal quenching performance of Lu 2 Sr (1− x ) Al 4 SiO 12 : x Eu 2+ phosphors

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  45. Highly Efficient Broad-Band Green-Emitting Cerium(III)-Activated Garnet Phosphor Allows the Fabrication of Blue-Chip-Based Warm-White LED Device with a Superior Color Rendering Index

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  46. Efficient, Stable, and Ultra‐Broadband Near‐Infrared Garnet Phosphors for Miniaturized Optical Applications

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  47. Nanorods for Lighting and Display

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  48. Stable Nanorods on-chip LED for Healthy Indoor Lighting

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  49. Color-tunable emissions in Bi3+/Eu3+ activated phosphors for multi-mode optical thermometers

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  50. Enhanced Thermal Stability and Energy Transfer by Crystal‐Field Engineering in a Garnet Phosphor for Thermometry and NIR‐LED

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