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RESEARCH PAPER · Journal of Materials Chemistry A · 2017

The crystal structure and electrical properties of the oxide ion conductor Ba 3 WNbO 8.5

Kirstie S. McCombie, Eve J. Wildman, Sacha Fop, Ronald I. Smith, J.M.S. Skakle, Abbie Christina Mclaughlin

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The crystal structure and electrical properties of the oxide ion conductor Ba 3 WNbO 8.5OriginalHigh-Temperature Structural Evolution in the Ba3Mo(1–x)WxNbO8.5 System and Correlation with Ionic Transport Properties30Relationship between the Crystal Structure and Electrical Properties of Oxide Ion Conducting Ba3W1.2Nb0.8O8.631Hexagonal perovskite derivatives: a new direction in the design of oxide ion conducting materials98Hexagonal perovskite related oxide ion conductor Ba 3 NbMoO 8.5 : phase transition, temperature evolution of the local structure and properties40Cation Distributions and Anion Disorder in Ba3NbMO8.5 (M = Mo, W) Materials: Implications for Oxide Ion Conductivity47Superior photoresponse MIS Schottky barrier diodes with nanoporous:Sn–WO 3 films for ultraviolet photodetector application73The Ba 3 Mo 1−x W x NbO 8.5 ion conductors: insights into local coordination from X-ray and neutron total scattering15The relationship between oxide-ion conductivity and cation vacancy order in the hybrid hexagonal perovskite Ba 3 VWO 8.553High oxide ion and proton conductivity in a disordered hexagonal perovskite246Enhanced Oxygen Ion Conductivity and Mechanistic Understanding in Ba3Nb1–xVxMoO8.583High Proton Conductivity in Ba 5 Er 2 Al 2 ZrO 13 , a Hexagonal Perovskite-Related Oxide with Intrinsically Oxygen-Deficient Layers119Understanding the Correlation between Oxide Ion Mobility and Site Distributions in Ba3NbWO8.517Signature of Oxide-Ion Conduction in Alkaline-Earth-Metal-Doped Y3GaO617Polyol-mediated synthesis of Bi-deficient Mg2+-doped sodium bismuth titanate and study of oxide ion migration behavior with functional properties24A pressure induced reversal to the 9R perovskite in Ba 3 MoNbO 8.56Atomic Structure of the Initial Nucleation Layer in Hexagonal Perovskite BaRuO3 Thin Films3Cation Substitution of Hexagonal Triple Perovskites: A Case in Trimetallic Tellurates A2A′BTe2O910Hydration and Ionic Conduction Mechanisms of Hexagonal Perovskite Derivatives61Investigation of the Crystal Structure and Ionic Pathways of the Hexagonal Perovskite Derivative Ba3–xVMoO8.5–x10Synthesis and characterization of Ga-doped Ba3MoNbO8.5 electrolytes for intermediate temperature-solid oxide fuel cells18High Oxide‐Ion Conductivity in a Hexagonal Perovskite‐Related Oxide Ba7Ta3.7Mo1.3O20.15 with Cation Site Preference and Interstitial Oxide Ions49Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements63Variable Temperature Neutron Diffraction Study of the Oxide Ion Conductor Ba3VWO8.517Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.526Examining the consequences of calcium substitution on the physical properties and conduction mechanism of Y3GaO62Simultaneous Reduction of Proton Conductivity and Enhancement of Oxide-Ion Conductivity by Aliovalent Doping in Ba 7 Nb 4 MoO 2037Improved oxide-ion and lower proton conduction of hexagonal perovskite-related oxides based on Ba7Nb4MoO20 by Cr6+ doping28Characteristics of electrolyte-supported SOFC single cells using hexagonal perovskite Ba3MoNbO8.5 and Ba7Nb4MoO20 ceramics8Proton and Oxide Ion Conductivity in Palmierite Oxides45A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o80Enhanced Oxide Ion Conductivity by Ta Doping of Ba3Nb1–xTaxMoO8.53Thermally Induced Oxygen Vacancies and High Oxide Ion Conduction in K2ZnV2O7 with a Melilite-Related Structure15Structural and electrical properties of Ba3NbMoO8.5 (BNM) hexagonal perovskite for solid electrolyte application4Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides32A variable temperature neutron diffraction study of dual ion conducting Sr3V2O88Oxide Ion Conduction in Ca-Doped Yb3Ga5O12 Garnet9Enhanced Oxygen Ion Conductivity in Ba3w1+Xv1-Xo8.5+X/2 (-0.2 ≤X ≤ 0.2) Hexagonal Perovskite Derivative Compounds0The role of vanadium substitution in the oxygen sublattice disorder of Ba 7 Nb 4 MoO 20 -based hexagonal perovskite oxide-ion conductors12Enhanced ionic conductivity through B-site Zr doping in NaNbO3 solid electrolytes14The novel Zn-doped hexagonal perovskite Ba7In6Al2O19: electrical conductivity and hydration3Ba3Ti0.4W1.6O8.6: An Oxygen- and B-Site-Deficient 9R Hexagonal Perovskite Exhibiting Triple Conduction3Tuning of the ionic conductivity of Ba 7 Nb 4 MoO 20 by pressure: a neutron diffraction and atomistic modelling study4Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides1Effect of germanium substitution on the structure and ionic conductivity of the hexagonal perovskite derivative compound Ba 3 WVO 8.52Improved Oxide-Ion and Lower Proton Conduction of Hexagonal Perovskite-Related Oxides Based on Ba7Nb4MoO20 by Cr6+ Doping0Enhanced oxygen ion conductivity in Ba3W1+xV1−xO8.5+x/2 (− 0.2 ≤ × ≤ 0.2) hexagonal perovskite derivative compounds4Hybrid Hexagonal Perovskite Ba3Ti0.7Mo1.3O8.3: Integrating High Cationic Disordering with Enhanced Tetrahedral Proportion to Achieve High Oxide Ionic Conductivity0Ba7Nb4MoO20: A Proton or Oxide Ion Conductor?13Topochemical Reaction Involving Double-to-Single Layer Conversion: Mo 3 Ta 2 O 10 N with a Kagomé Lattice3Understanding and design of interstitial oxygen conductors5Ba‐deficient and K‐doped Ba 3 MoNbO 8.5 : Hydration properties, electrical conduction, and stability0Fast Oxide Ion Conduction in Ba 3 MoNbO 8.5 Enhanced by Acceptor Substitution and Dehydration3Enhanced oxygen surface exchange in Sm-doped Ba3MoNbO8.5-δ hexagonal perovskites for solid oxide fuel cells0Lattice oxygen redistribution in Ba 7 Nb 4 MoO 20 by La-doping enables high oxide ion conductivity0Oxide-Ion Occupational Disorder, Conductivity, and Diffusion Pathways in Ba3MNbO8.5 (M = W, Mo)0Summary and Appendix0Enhanced sinterability of Ba3MoNb0.95Zr0.05O8.475 oxide ion conductor by adding K2CO30Charting the Landscape of Oxygen Ion Conductors: A 60-Year Dataset with Interpretable Regression Models1Impact of Spark Plasma Sintering on the Ionic Conductivity of La‐Doped NaNbO 31

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  1. High-Temperature Structural Evolution in the Ba3Mo(1–x)WxNbO8.5 System and Correlation with Ionic Transport Properties

    Inorganic Chemistry · 2018-05-24

    Andrea Bernasconi, Cristina Tealdi, Lorenzo Malavasi

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  2. Relationship between the Crystal Structure and Electrical Properties of Oxide Ion Conducting Ba3W1.2Nb0.8O8.6

    Inorganic Chemistry · 2018-09-12

    Kirstie S. McCombie, Eve J. Wildman, C. Ritter, Ronald I. Smith, J.M.S. Skakle, Abbie Christina Mclaughlin

    Read original paper ↗ ·

  3. Hexagonal perovskite derivatives: a new direction in the design of oxide ion conducting materials

    Chemical Communications · 2019-01-01

    Sacha Fop, Kirstie S. McCombie, Eve J. Wildman, J.M.S. Skakle, Abbie Christina Mclaughlin

    Read original paper ↗ ·

  4. Hexagonal perovskite related oxide ion conductor Ba 3 NbMoO 8.5 : phase transition, temperature evolution of the local structure and properties

    Journal of Materials Chemistry A · 2019-01-01

    Matthew S. Chambers, Kirstie S. McCombie, Josie E. Auckett, Abbie Christina Mclaughlin, John T. S. Irvine, Philip A. Chater, John S. O. Evans, Ivana Radosavljević Evans

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  5. Cation Distributions and Anion Disorder in Ba3NbMO8.5 (M = Mo, W) Materials: Implications for Oxide Ion Conductivity

    Chemistry of Materials · 2019-02-08

    Josie E. Auckett, Katherine L. Milton, Ivana Radosavljević Evans

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  6. Superior photoresponse MIS Schottky barrier diodes with nanoporous:Sn–WO 3 films for ultraviolet photodetector application

    New Journal of Chemistry · 2020-01-01

    Marnadu Raj, J. Chandrasekaran, S. Maruthamuthu, P. M. Vivek, Vijayakumar Elayappan

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  7. The Ba 3 Mo 1−x W x NbO 8.5 ion conductors: insights into local coordination from X-ray and neutron total scattering

    Journal of Materials Chemistry A · 2020-01-01

    Mauro Coduri, Andrea Bernasconi, Henry E. Fischer, Lorenzo Malavasi

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  8. The relationship between oxide-ion conductivity and cation vacancy order in the hybrid hexagonal perovskite Ba 3 VWO 8.5

    Journal of Materials Chemistry A · 2020-01-01

    Asma Gilane, Sacha Fop, Falak Sher, Ronald I. Smith, Abbie Christina Mclaughlin

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  9. High oxide ion and proton conductivity in a disordered hexagonal perovskite

    Nature Materials · 2020-03-02

    Sacha Fop, Kirstie S. McCombie, Eve J. Wildman, J.M.S. Skakle, John T. S. Irvine, Paul A. Connor, Cristian Daniel Savaniu, C. Ritter, Abbie Christina Mclaughlin

    Read original paper ↗ ·

  10. Enhanced Oxygen Ion Conductivity and Mechanistic Understanding in Ba3Nb1–xVxMoO8.5

    Chemistry of Materials · 2020-05-08

    Sacha Fop, Kirstie S. McCombie, Ronald I. Smith, Abbie Christina Mclaughlin

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  11. High Proton Conductivity in Ba 5 Er 2 Al 2 ZrO 13 , a Hexagonal Perovskite-Related Oxide with Intrinsically Oxygen-Deficient Layers

    Journal of the American Chemical Society · 2020-05-15

    Taito Murakami, James Hester, Masatomo Yashima

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  12. Understanding the Correlation between Oxide Ion Mobility and Site Distributions in Ba3NbWO8.5

    Inorganic Chemistry · 2020-09-24

    Josie E. Auckett, Matthias Josef Gutmann, Ivana Radosavljević Evans

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  13. Signature of Oxide-Ion Conduction in Alkaline-Earth-Metal-Doped Y3GaO6

    ACS Omega · 2020-11-16

    Pragati Singh, Pragati Singh, Raghvendra Pandey, Tadeusz Miruszewski, Kacper Dzierzgowski, Aleksandra Dorota Mielewczyk-Gryń, Prabhakar Singh, Prabhakar Singh

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  14. Polyol-mediated synthesis of Bi-deficient Mg2+-doped sodium bismuth titanate and study of oxide ion migration behavior with functional properties

    Journal of Alloys and Compounds · 2020-12-24

    Pragati Singh, Raghvendra Pandey, Prabhakar Singh

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  15. A pressure induced reversal to the 9R perovskite in Ba 3 MoNbO 8.5

    Journal of Materials Chemistry A · 2021-01-01

    B. Sherwood, Christopher J. Ridley, Craig L. Bull, Sacha Fop, J.M.S. Skakle, Abbie Christina Mclaughlin, Eve J. Wildman

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  16. Atomic Structure of the Initial Nucleation Layer in Hexagonal Perovskite BaRuO3 Thin Films

    Advanced Materials Interfaces · 2021-02-28

    Sangmoon Yoon, Jong Mok Ok, Sang A Lee, Jegon Lee, Amanda Huon, Andrew R. Lupini, Woo Seok Choi, Ho Nyung Lee

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  17. Cation Substitution of Hexagonal Triple Perovskites: A Case in Trimetallic Tellurates A2A′BTe2O9

    Inorganic Chemistry · 2021-04-06

    Congcong Jin, Miriding Mutailipu, Wenqi Jin, Shujuan Han, Zhihua Yang, Shilie Pan

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  18. Hydration and Ionic Conduction Mechanisms of Hexagonal Perovskite Derivatives

    Chemistry of Materials · 2021-06-06

    Sacha Fop, James Alexander Dawson, Andrew Dominic Fortes, C. Ritter, Abbie Christina Mclaughlin

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  19. Investigation of the Crystal Structure and Ionic Pathways of the Hexagonal Perovskite Derivative Ba3–xVMoO8.5–x

    Inorganic Chemistry · 2021-08-18

    Dylan N. Tawse, Asma Gilane, Sacha Fop, Alfonso Martı́nez-Felipe, Falak Sher, Ronald I. Smith, Abbie Christina Mclaughlin

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  20. Synthesis and characterization of Ga-doped Ba3MoNbO8.5 electrolytes for intermediate temperature-solid oxide fuel cells

    Ceramics International · 2021-11-01

    Dongliang Liao, Gurong Lin, Feng Chen, Xian Pan, Kaiping Peng

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  21. High Oxide‐Ion Conductivity in a Hexagonal Perovskite‐Related Oxide Ba7Ta3.7Mo1.3O20.15 with Cation Site Preference and Interstitial Oxide Ions

    Small · 2021-12-19

    Taito Murakami, Toshiya Shibata, Yuta Yasui, Kotaro Fujii, James Hester, Masatomo Yashima

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  22. Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements

    Journal of Materials Chemistry A · 2022-01-01

    Mauro Coduri, Maths Karlsson, Lorenzo Malavasi

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  23. Variable Temperature Neutron Diffraction Study of the Oxide Ion Conductor Ba3VWO8.5

    Inorganic Chemistry · 2022-01-11

    Asma Gilane, Sacha Fop, Dylan N. Tawse, C. Ritter, Abbie Christina Mclaughlin

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  24. Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.5

    The Journal of Physical Chemistry C · 2022-01-27

    Yuta Yasui, Takafumi Tsujiguchi, Yuichi Sakuda, James Hester, Masatomo Yashima

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  25. Examining the consequences of calcium substitution on the physical properties and conduction mechanism of Y3GaO6

    Journal of Materials Science Materials in Electronics · 2022-03-23

    Pragati Singh, Pragati Singh, Raghvendra Pandey, K. K. Srivastava, Prabhakar Singh, Prabhakar Singh

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  26. Simultaneous Reduction of Proton Conductivity and Enhancement of Oxide-Ion Conductivity by Aliovalent Doping in Ba 7 Nb 4 MoO 20

    Inorganic Chemistry · 2022-05-03

    Yuki Suzuki, Taito Murakami, Kotaro Fujii, James Hester, Yuta Yasui, Masatomo Yashima

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  27. Improved oxide-ion and lower proton conduction of hexagonal perovskite-related oxides based on Ba7Nb4MoO20 by Cr6+ doping

    Journal of the Ceramic Society of Japan · 2022-06-30

    Yuichi Sakuda, James Hester, Masatomo Yashima

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  28. Characteristics of electrolyte-supported SOFC single cells using hexagonal perovskite Ba3MoNbO8.5 and Ba7Nb4MoO20 ceramics

    Results in Materials · 2022-09-02

    S. Nakayama

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  29. Proton and Oxide Ion Conductivity in Palmierite Oxides

    Chemistry of Materials · 2022-09-06

    Sacha Fop, James Alexander Dawson, Dylan N. Tawse, Matthew G. Skellern, J.M.S. Skakle, Abbie Christina Mclaughlin

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  30. A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o8

    SSRN Electronic Journal · 2023-01-01

    Abbie Christina Mclaughlin, Dylan N. Tawse, Sacha Fop, C. Ritter, Alfonso Martı́nez-Felipe

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  31. Enhanced Oxide Ion Conductivity by Ta Doping of Ba3Nb1–xTaxMoO8.5

    Inorganic Chemistry · 2023-01-17

    Brent Sherwood, Eve J. Wildman, Ronald I. Smith, Abbie Christina Mclaughlin

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  32. Thermally Induced Oxygen Vacancies and High Oxide Ion Conduction in K2ZnV2O7 with a Melilite-Related Structure

    ACS Materials Au · 2023-06-09

    Huina Wei, Jiazheng Hao, Jian Yang, Yun Lv, Feiran Shen, Wenda Zhang, Jie Chen, Lunhua He, Laijun Liu, Xiaojun Kuang, Jungu Xu

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  33. Structural and electrical properties of Ba3NbMoO8.5 (BNM) hexagonal perovskite for solid electrolyte application

    Applied Physics A · 2023-10-24

    Hera Tarique, Raza Shahid, Anjani Kumar Singh, Radheshyam Nokhwal, Vivek Dixit, Raghvendra Pandey

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  34. Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides

    Chemistry of Materials · 2023-11-14

    Yuichi Sakuda, Taito Murakami, Maxim Avdeev, Kotaro Fujii, Yuta Yasui, James Hester, Masato Hagihala, Yoichi Ikeda, Yusuke Nambu, Masatomo Yashima

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  35. A variable temperature neutron diffraction study of dual ion conducting Sr3V2O8

    Journal of Solid State Chemistry · 2023-12-19

    Dylan N. Tawse, Sacha Fop, C. Ritter, Alfonso Martı́nez-Felipe, Abbie Christina Mclaughlin

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  36. Oxide Ion Conduction in Ca-Doped Yb3Ga5O12 Garnet

    Inorganic Chemistry · 2023-12-27

    Man Tian, Qin Cun Cao, Huina Wei, Keke Hou, Xiaoxu Duan, Wenzhuo Chen, Jungu Xu

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  37. Enhanced Oxygen Ion Conductivity in Ba3w1+Xv1-Xo8.5+X/2 (-0.2 ≤X ≤ 0.2) Hexagonal Perovskite Derivative Compounds

    SSRN Electronic Journal · 2024-01-01

    Nitin Kumar, K. Sandeep Rao, Uday Prabhakarrao Deshpande, Vasant Sathe, A. K. Sahu, Srungarpu Nagabhusan Achary, S. Deshpande

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  38. The role of vanadium substitution in the oxygen sublattice disorder of Ba 7 Nb 4 MoO 20 -based hexagonal perovskite oxide-ion conductors

    Journal of Materials Chemistry A · 2024-01-01

    BIFFO Abdulkadir Olatunbosun, Theodosios Famprikis, Pedro B. Groszewicz

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  39. Enhanced ionic conductivity through B-site Zr doping in NaNbO3 solid electrolytes

    Journal of Power Sources · 2024-06-24

    Deepanshu Kaneria, Deepak Yadav, Deepak Yadav, Udeshwari Jamwal, Shivam Kumar Mittal, K. L. Yadav

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  40. The novel Zn-doped hexagonal perovskite Ba7In6Al2O19: electrical conductivity and hydration

    Chimica Techno Acta · 2024-09-30

    Irina E. Animitsa, Daniil V. Korona, Arina V. Bushueva, Roman D. Andreev, С. С. Нохрин

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  41. Ba3Ti0.4W1.6O8.6: An Oxygen- and B-Site-Deficient 9R Hexagonal Perovskite Exhibiting Triple Conduction

    Inorganic Chemistry · 2024-11-04

    Zien Cheng, Yuling An, Rong Wang, Jöerg C. Neuefeind, Xiaoyan Yang, Rihong Cong, Tao Yang, Pengfei Jiang

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  42. Tuning of the ionic conductivity of Ba 7 Nb 4 MoO 20 by pressure: a neutron diffraction and atomistic modelling study

    Journal of Materials Chemistry A · 2024-12-20

    Victoria Watson, Ying Zhou, Dylan N. Tawse, Oscar J. B. Ballantyne, Christopher J. Ridley, James Alexander Dawson, Abbie Christina Mclaughlin

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  43. Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides

    Springer theses · 2025-01-01

    Yuichi Sakuda

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  44. Effect of germanium substitution on the structure and ionic conductivity of the hexagonal perovskite derivative compound Ba 3 WVO 8.5

    Journal of Materials Chemistry C · 2025-01-01

    Nitin Kumar, K. Sandeep Rao, Anu, A. K. Sahu, Srungarpu Nagabhusan Achary, Sudhanshu K. Deshpande

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  45. Improved Oxide-Ion and Lower Proton Conduction of Hexagonal Perovskite-Related Oxides Based on Ba7Nb4MoO20 by Cr6+ Doping

    Springer theses · 2025-01-01

    Yuichi Sakuda

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  46. Enhanced oxygen ion conductivity in Ba3W1+xV1−xO8.5+x/2 (− 0.2 ≤ × ≤ 0.2) hexagonal perovskite derivative compounds

    Ionics · 2025-02-01

    Nitin Kumar, K. Sandeep Rao, Uday Prabhakarrao Deshpande, Vasant Sathe, A. K. Sahu, Srungarpu Nagabhusan Achary, Sudhanshu K. Deshpande

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  47. Hybrid Hexagonal Perovskite Ba3Ti0.7Mo1.3O8.3: Integrating High Cationic Disordering with Enhanced Tetrahedral Proportion to Achieve High Oxide Ionic Conductivity

    Chemistry of Materials · 2025-06-22

    Zien Cheng, Liyang Zhang, Yuling An, Iván da Silva, Jöerg C. Neuefeind, Zhengyang Zhou, Congling Yin, Rihong Cong, Tao Yang, Pengfei Jiang

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  48. Ba7Nb4MoO20: A Proton or Oxide Ion Conductor?

    Journal of the American Chemical Society · 2025-07-01

    Sara Adeeba Ismail, Kazuaki Toyoura, Lulu Jiang, Amir Masoud Dayaghi, Hui Min Guo, Maxim Avdeev, Huaican Chen, Wen Yin, Wang Hay Kan, Truls Norby, Donglin Han

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  49. Topochemical Reaction Involving Double-to-Single Layer Conversion: Mo 3 Ta 2 O 10 N with a Kagomé Lattice

    Journal of the American Chemical Society · 2025-07-24

    Ryoya Higuchi, K. Ishida, Cédric Tassel, Baptiste Vignolle, Daichi Kato, Kantaro Murayama, Hsin‐Hui Huang, Akihide Kuwabara, Shunsuke Kobayashi, Yusuke Nambu, Hiroyasu Matsudaira, Shunsaku Kitagawa, Kenji Ishida, Congling Yin, Hiroshi Takatsu, Hiroshi Kageyama

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  50. Understanding and design of interstitial oxygen conductors

    Computational Materials Science · 2025-07-26

    Jun Meng

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