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RESEARCH PAPER · Chemistry of Materials · 2017

Temperature and Eu2+-Doping Induced Phase Selection in NaAlSiO4 Polymorphs and the Controlled Yellow/Blue Emission

Ming Zhao, Zhiguo Xia, Мaxim S. Моlokeev, Lixin Ning, Quanlin Liu

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Temperature and Eu2+-Doping Induced Phase Selection in NaAlSiO4 Polymorphs and the Controlled Yellow/Blue EmissionOriginalRelationships between luminescence properties and polyhedron distortion in Ca 9−x−y−z Mg x Sr y Ba z Ce(PO 4 ) 7 :Eu 2+ ,Mn 2+50Luminescence properties of emission tunable single-phased phosphor La 7 O 6 (BO 3 )(PO 4 ) 2 : Ce 3+ , Tb 3+ , Eu 3+21Controllable Synthesis, Polymorphism and Structure‐Dependent Photoluminescence Properties of Europium Oxyfluorides10Tuning of photoluminescence by crystal-phase engineering in the Ba3P4O13:Eu2+ phosphor19Efficient red‐emitting phosphor of Eu 3+ ‐activated (Na 0.5 Gd 1.5 )(TiSb)O 7 derived via cation‐substitutions in Gd‐Pyrochlore4An efficient green phosphor of Ce 3+ and Tb 3+ -codoped Ba 2 Lu 5 B 5 O 17 and a model for elucidating the high thermal stability of the green emission53Analysis of the structure and abnormal photoluminescence of a red-emitting LiMgBO 3 :Mn 2+ phosphor22Broad-band emission of A 3 B′B′′ 2 O 9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder14Crystal structures, phase transitions and thermal expansion properties of NaZr 2 (PO 4 ) 3 –SrZr 4 (PO 4 ) 6 solid solutions21Lanthanide luminescence as a local probe in mixed anionic hydrides – a case study on Eu 2+ -doped RbMgH x F 3−x and KMgH x F 3−x18Modified optical properties via induced cation disorder in self-activated NaMg 2 V 3 O 1018Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances31NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers8Novel SrMg 2 La 2 W 2 O 12 :Mn 4+ far-red phosphors with high quantum efficiency and thermal stability towards applications in indoor plant cultivation LEDs89Photoluminescence tuning in a novel Bi 3+ /Mn 4+ co-doped La 2 ATiO 6 :(A = Mg, Zn) double perovskite structure: phase transition and energy transfer78Improvement of self‐activated luminescence from introduced cation disorder in Sr 6 V 2 O 1112Near UV-pumped yellow-emitting Sr9MgLi(PO4)7:Eu2+ phosphor for white-light LEDs100Luminescence properties and energy transfer of co-doped Ba3GdNa(PO4)3F:Ce3+,Tb3+ green-emitting phosphors10Highly Efficient Blue Emission and Superior Thermal Stability of BaAl 12 O 19 :Eu 2+ Phosphors Based on Highly Symmetric Crystal Structure388On the photoluminescence of multi-sites Ce3+ in T-phase orthosilicate and energy transfer from Ce3+ to Tb3+11Thermodynamic Stabilities, Electronic Properties, and Optical Transitions of Intrinsic Defects and Lanthanide Ions (Ce3+, Eu2+, and Eu3+) in Li2SrSiO426A single‐phase full‐color emitting phosphor Na 3 Sc 2 (PO 4 ) 3 :Eu 2+ /Tb 3+ /Mn 2+ with near‐zero thermal quenching and high quantum yield for near‐UV converted warm w‐LEDs53Lanthanide-doped KGd3F10 nanocrystals embedded glass ceramics: Self-crystallization, optical properties and temperature sensing15Next‐Generation Narrow‐Band Green‐Emitting RbLi(Li 3 SiO 4 ) 2 :Eu 2+ Phosphor for Backlight Display Application532Design and Development of a Bluish-Green Luminescent Material (K2HfSi3O9:Eu2+) with Robust Thermal Stability for White Light-Emitting Diodes106Rb3SiF7:Mn4+ and Rb2CsSiF7:Mn4+ Red-Emitting Phosphors with a Faster Decay Rate90Ultra‐narrow band blue emission of Eu 2+ in halogenated (Alumino)borate systems based on high lattice symmetry20Effect of Gd3+, Bi3+, or Sm3+ on luminescent properties of La2−xMgTiO6:xEu3+ phosphors18Layered Structure Produced Nonconcentration Quenching in a Novel Eu3+-Doped Phosphor185Solvothermal synthesis and modification of NaYF 4 :Yb/Er@NaLuF 4 :Yb for enhanced up-conversion luminescence for bioimaging18Li substituent tuning of LED phosphors with enhanced efficiency, tunable photoluminescence, and improved thermal stability205Structural Micromodulation on Bi3+-Doped Ba2Ga2GeO7 Phosphor with Considerable Tunability of the Defect-Oriented Optical Properties93A carnegieite type red emitting NaAlSiO4:Eu3+ phosphor: Concentration dependent time resolved photoluminescence and Judd-Ofelt analysis25Cation Substitution Induced Adjustment on Lattice Structure and Photoluminescence Properties of Mg14Ge5O24:Mn4+: Optimized Emission for w‐LED and Thermometry Applications99Samarium doped apatite-type orange-red emitting phosphor Ca5(PO4)2SiO4 with satisfactory thermal properties for n-UV w-LEDs47Phase-Selective Distribution of Eu2+ and Eu3+ in Oxide and Fluoride Crystals in Glass-Ceramics for Warm White-Light-Emitting Diodes96High thermal stable blue-emitting alkali silicate phosphor, Eu2+-activated Na2Mg2Si6O151High brightness and precise adjustment of multicolor-tunable luminescence of Lu2GeO5:Tb3+, Eu3+ phosphors for white LEDs14Photoluminescence and thermal stability of Tb3+-doped K4SrSi3O9 phosphor with electron transition mechanisms22Giant Photoluminescence Improvement and Controllable Emission Adjustment in Bi3+-Activated Ca4ZrGe3O12 Phosphors for High-Quality White Light-Emitting Diodes42Bismuth activated full spectral double perovskite luminescence materials by excitation and valence control for future intelligent LED lighting28Phase transition and fluorescence regulation of BaAl2Si2O8:Eu using Ba source184A zeolite based daytime passive radiative cooling material19A novel Mn4+-activated Li3CsGe8O18 red phosphor and cation substitution induced photoluminescence improvement11A novel narrow-band blue-emitting phosphor of Bi3+-activated Sr3Lu2Ge3O12 based on a highly symmetrical crystal structure used for WLEDs and FEDs183Delayed Concentration Quenching of Luminescence Caused by Eu3+-Induced Phase Transition in LaSc3(BO3)4114Multi-color emission of Dy3+/Eu3+ co-doped LiLuF4 single crystals for white light-emitting devices37Size-tunable β-NaYF4:Yb/Er up-converting nanoparticles with a strong green emission synthesized by thermal decomposition39Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications242A novel high efficiency and ultra-stable red emitting europium doped pyrophosphate phosphor for multifunctional applications31A review on the structural dependent optical properties and energy transfer of Mn 4+ and multiple ion-codoped complex oxide phosphors36Realizing luminescent and dielectric abilities via lattice-disturbance with Eu 3+ /Ti 4+ co-substitutions in Ba 2 NaNb 5 O 15 ceramics21Recent progress of effect of crystal structure on luminescence properties of Ce 3+ –Eu 2+ Co-doped phosphors14Stoichiometric tuning of lattice flexibility and Na diffusion in NaAlSiO 4 : quasielastic neutron scattering experiment and ab initio molecular dynamics simulations15Site‐Selective Occupancy of Eu2+ toward High Luminescence Switching Contrast in BaMgSiO4‐Based Photochromic Materials63Superior thermally-stable narrow-band green emitter from Mn2+-doped zero thermal expansion (ZTE) material78Surface Roughness-Governed Shape Stability of the Coal Fly Ash-Based Phase Change Material: Molten Salt Processing and Thermal Properties2Correlation between local lattice environment and upconversion emission in Ho3+-doped CaHfO3 in terms of substitution site dependence3Eu 2+ ‐doped oxyfluoride glass‐ceramic with nepheline as an efficient 400 nm UV‐LED color converter18Photoluminescence tuning in Ba3ScB3O9:Eu2+ phosphor by crystal-site engineering17Ion-exchanged LTA zeolite derived nepheline phase NaAlSiO4:Eu2+ ceramic phosphor for laser illumination14Structural Diversity and Incompatibility Induced Complex Phase Formation Behavior in the Stuffed Tridymites Ca 1– x Sr x Ga 2 O 47Dilute Element Compounds: A Route to Enriching Inorganic Functional Materials5Enhancing the Photoluminescence Property of Pr3+ Ions by Understanding the Polymorphous Influence of the K3Lu(PO4)2 Host6Effect of Synthesis Temperature on the Structure and Luminescence Properties of the NaAlSiO 4 :Er 3+ Phosphors4Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230NaAlSiO4: Eu2+ Glass Ceramics: Self‐Reduced In Situ Growth and High‐Power LED/LD Lighting44Structural Design for Controlling the Lattice Strain Relaxation Process in TiO2/SiO2 Core–Shell Nanoparticles6Preparation and luminescent properties of double perovskite-type La2-x-yYxMgTiO6:yEu3+ red fluorescent materials4A full visible LED enabled by a broadband yellow emission nepheline phosphor derived from a europium doped SOD zeolite16Luminescence and energy transfer of single-phase white-emitting phosphor Ba 2 Mg(PO 4 ) 2 :Ce 3+ , Eu 2+ for white LEDs9Green-emitting Bi3+-doped La2SrSc2O7 phosphor for pc-WLED lighting: Luminescent properties and energy transfer strategy50Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group19Polymorphism and polymorph-dependent luminescence properties of the first lithium oxonitridolithosilicate Li 3 SiNO 2 :Eu 2+6Eu2+/Ce3+-doped NaAlSiO4 selective occupation-induced emission structure unit evolution and its luminescence characteristics7Cyan-to-yellow color tunable NaAlSiO4:Eu2+ with high quantum efficiency and thermal stability for white light-emitting diodes14Development of a novel Eu3+-doped tantalate red-emitting phosphor for w-LEDs application17Design the green emitting phosphor Ca9La(PO4)7:Eu2+ by the structural modulation and its application to white LEDs5Nanostructural Evolution of Calcium-Containing Alkali-Activated Metakaolin During High Temperature Exposure5Deep‐Red (Sr,Ba)Lu2O4: Eu2+ Phosphor for Full‐Spectrum Lighting7Eu2+-Eu3+ Co-doping provoking polyhedron-cluster-based emission structural unit evolution triggering phases transition and blue-green-red multimode luminescence emission2Achieving Eu 2+ Luminescence at Trivalent Lattice Site in Rb 3 Y(PO 4 ) 2 :Eu toward Multicolor Emissions by Carbon and Hydrogen Coreduction23Degree of Crystal Structure Distortion-Induced Tunable LiGaO2 Long Persistent Luminescence for Optical Information Encryption19High thermally stable and efficient rare-earth celsian by phase transformation of Ba2+-Exchanged SOD zeolite4Cl− skeleton modification and K+ charge compensation construct Eu2+ subcrystalline luminescent structure in NaAlSiO46Thermal stable and bright yellow-emitting phosphor Na3+xK1-x(AlSiO4)4:Eu2+ for solid-state lighting2Low‐Coordination Crystallographic Lattice Engineering to Discover Ce 3+ ‐Activated Ultra‐Wide Visible‐to‐Near‐Infrared Luminescent Materials9Promising excitation-responsive phosphors CaxMgSi2Ox+5: Eu2+, Dy3+ with dual-mode luminescent centers for advanced anti-counterfeiting technology10Luminescence From Localized States in Solids: A First‐Principles Perspective27Cation-tunable blue phosphor (Ba,Mg)(Y,Sc)4Si5O17:Eu2+: enhanced quantum yield and thermal stability8Sustainable pathway towards red mud valorization through biomass thermochemical conversion and metals recovery19A Single‐Phase High‐Color‐Rendering NaAlSiO4:Pb2+/Tb3+/Eu3+ Phosphor for White Light‐Emitting Diodes7Develop Superior Green‐Emitting K‐Rich Eu 2+ ‐Activated Nepheline Phosphors for n‐UV‐Driven Pc‐WLEDs1Li+-induced preferential site occupancy and enhanced Eu2+ reduction toward highly efficient blue-emitting Na3RbMg7(PO4)6:Eu2+3Tunable white-light emission and persistent luminescence in NaBa4(BO3)3: Ce3+, Eu2+, Dy3+ phosphors0

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  1. Relationships between luminescence properties and polyhedron distortion in Ca 9−x−y−z Mg x Sr y Ba z Ce(PO 4 ) 7 :Eu 2+ ,Mn 2+

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  3. Controllable Synthesis, Polymorphism and Structure‐Dependent Photoluminescence Properties of Europium Oxyfluorides

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  4. Tuning of photoluminescence by crystal-phase engineering in the Ba3P4O13:Eu2+ phosphor

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  7. Analysis of the structure and abnormal photoluminescence of a red-emitting LiMgBO 3 :Mn 2+ phosphor

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  8. Broad-band emission of A 3 B′B′′ 2 O 9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder

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  9. Crystal structures, phase transitions and thermal expansion properties of NaZr 2 (PO 4 ) 3 –SrZr 4 (PO 4 ) 6 solid solutions

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  10. Lanthanide luminescence as a local probe in mixed anionic hydrides – a case study on Eu 2+ -doped RbMgH x F 3−x and KMgH x F 3−x

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  11. Modified optical properties via induced cation disorder in self-activated NaMg 2 V 3 O 10

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  12. Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances

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  14. Novel SrMg 2 La 2 W 2 O 12 :Mn 4+ far-red phosphors with high quantum efficiency and thermal stability towards applications in indoor plant cultivation LEDs

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  15. Photoluminescence tuning in a novel Bi 3+ /Mn 4+ co-doped La 2 ATiO 6 :(A = Mg, Zn) double perovskite structure: phase transition and energy transfer

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  16. Improvement of self‐activated luminescence from introduced cation disorder in Sr 6 V 2 O 11

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  17. Near UV-pumped yellow-emitting Sr9MgLi(PO4)7:Eu2+ phosphor for white-light LEDs

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  31. Li substituent tuning of LED phosphors with enhanced efficiency, tunable photoluminescence, and improved thermal stability

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  35. Samarium doped apatite-type orange-red emitting phosphor Ca5(PO4)2SiO4 with satisfactory thermal properties for n-UV w-LEDs

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  42. Phase transition and fluorescence regulation of BaAl2Si2O8:Eu using Ba source

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  43. 4A zeolite based daytime passive radiative cooling material

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  44. A novel Mn4+-activated Li3CsGe8O18 red phosphor and cation substitution induced photoluminescence improvement

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  45. A novel narrow-band blue-emitting phosphor of Bi3+-activated Sr3Lu2Ge3O12 based on a highly symmetrical crystal structure used for WLEDs and FEDs

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  46. Delayed Concentration Quenching of Luminescence Caused by Eu3+-Induced Phase Transition in LaSc3(BO3)4

    Chemistry of Materials · 2020-07-20

    Nan Yang, Junhao Li, Ziwang Zhang, Dawei Wen, Qiongyun Liang, Jianbang Zhou, Jing Sen Yan, Jianxin Shi

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  47. Multi-color emission of Dy3+/Eu3+ co-doped LiLuF4 single crystals for white light-emitting devices

    Optical Materials · 2020-08-01

    Feng Ying Xu, Lizhi Fang, Xiong Zhou, Haiping Xia, Jianli Zhang, Hongwei Song, Baojiu Chen

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  48. Size-tunable β-NaYF4:Yb/Er up-converting nanoparticles with a strong green emission synthesized by thermal decomposition

    Optical Materials · 2020-09-29

    Hua Li, Xiaobo Shi, Xia Li, Lingbo Zong

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  49. Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications

    Accounts of Materials Research · 2020-10-22

    Ming Zhao, Qinyuan Zhang, Zhiguo Xia

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  50. A novel high efficiency and ultra-stable red emitting europium doped pyrophosphate phosphor for multifunctional applications

    Inorganic Chemistry Frontiers · 2021-01-01

    Chuang Wang, Ying Li, Shuanglong Chen, Yanyan Li, Qingyi Lv, Bohuai Shao, Ge Zhu, Lei Zhao

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