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RESEARCH PAPER · Journal of Solid State Chemistry · 2016

Direct optical band gap measurement in polycrystalline semiconductors: A critical look at the Tauc method

Alex Dolgonos, Thomas O. Mason, Kenneth Reinhard Poeppelmeier

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Direct optical band gap measurement in polycrystalline semiconductors: A critical look at the Tauc methodOriginalDefect Tolerance to Intolerance in the Vacancy-Ordered Double Perovskite Semiconductors Cs2SnI6 and Cs2TeI6629Macro-/nanoporous Al-doped ZnO via self-sustained decomposition of metal-organic complexes for application in degradation of Congo red21High Throughput Light Absorber Discovery, Part 1: An Algorithm for Automated Tauc Analysis172Engineering Valence Band Dispersion for High Mobility p-Type Semiconductors98Effects of Precursor Concentration on the Growth of ZnO Nanorods1Siloxane-based metal–organic frameworks with remarkable catalytic activity in mild environmental photodegradation of azo dyes72Phase tuned synthesis of titanium dioxide nanoparticles for room temperature enhanced ammonia detection22Transparent conducting n-type ZnO:Sc – synthesis, optoelectronic properties and theoretical insight64Effect of doping concentration on the structural, morphological and optical properties of Ca-doped PbS thin films grown by CBD47Concentration dependent luminescence spectral investigation of Sm3+ doped Y2SiO5 nanophosphor16Self‐Tuning n‐Type Bi2(Te,Se)3/SiC Thermoelectric Nanocomposites to Realize High Performances up to 300 °C92Nanocrystalline ZnO–SnO2 mixed metal oxide powder: microstructural study, optical properties, and photocatalytic activity17Engineering highly effective and stable nanocomposite photocatalyst based on NH2-MIL-125 encirclement with Ag3PO4 nanoparticles112Anharmonicity and Octahedral Tilting in Hybrid Vacancy-Ordered Double Perovskites155In-situ formation of SiGe alloy by electron beam evaporation and the effect of post deposition annealing on the energy band gap0Photocatalytic and electrically conductive transparent Cl-doped ZnO thin films via aerosol-assisted chemical vapour deposition50High-Performance Inverted Polymer Solar Cells: Study and Analysis of Different Cathode Buffer Layers16CsCu5Se3: A Copper-Rich Ternary Chalcogenide Semiconductor with Nearly Direct Band Gap for Photovoltaic Application42Changes in Polymorph Composition in P25-TiO 2 during Pretreatment Analyzed by Differential Diffuse Reflectance Spectral Analysis54In-situ formation of Ge-rich SiGe alloy by electron beam evaporation and the effect of post deposition annealing on the energy band gap13Doping Induced Band-gap widening in Transition-metal doped ZnO Nanocrystals4The Diversity of Layered Halide Perovskites179Photodegradation of humic acid in aqueous solution using a TiO2-carbonaceous hyper-cross-linked polystyrene polymer nanocomposite10CuInS2 thin films obtained through an innovative CSVT deposition method from solvothermal-generated precursors13Measurement-based optimization and analysis of α-IGZO/Ag/α-IGZO transparent conducting electrodes fabricated using DC magnetron sputter deposition13Metallo-supramolecular assemblies of dinuclear Zn(II) and Mn(II) secondary building units (SBUs) and a bent silicon dicarboxylate ligand10Effect of surfactants on the optical and magnetic properties of cobalt-zinc ferrite Co0.5Zn0.5Fe2O468Conductivity and transparency limits of Sb-doped SnO2 grown by molecular beam epitaxy39Sol gel graphene/TiO2 nanoparticles for the photocatalytic-assisted sensing and abatement of NO2174Investigation of photoelectrochemical activity of cobalt tin sulfide synthesized via microwave-assisted and solvothermal process14Influence of the Anatase and Rutile phases on the luminescent properties of rare-earth-doped TiO2 films16Optimization of PFN thickness in inverted high-performance PTB7:PC70BM solar cells10An experimental and theoretical study into NaSbS 2 as an emerging solar absorber42Fabrication of Fiber Optic Based Temperature Sensor6Inverse logarithmic derivative method for determining the energy gap and the type of electron transitions as an alternative to the Tauc method96Hydrothermal improvement for 3R-CuFeO2 delafossite growth by control of mineralizer and reaction atmosphere25Tuning the Luminescence of Layered Halide Perovskites804Synthesis of PbS:Mo(3%) thin film and investigation of its properties15New Bi2O3-ZnO composite deposited on glass wool. Effect of the synthesis method on photocatalytic efficiency under visible light31Synergy of Neodymium and Copper for Fast and Reversible Visible-light Promoted Photochromism, and Photocatalysis, in Cu/Nd-TiO 2 Nanoparticles42Structural and Microstructural Effects of Mo3+/Mo5+ Codoping on Properties and Photocatalytic Performance of Nanostructured TiO2 Thin Films26Enhanced Sol–Gel Route to Obtain a Highly Transparent and Conductive Aluminum-Doped Zinc Oxide Thin Film37Fabrication of ZIF-67@MIL-125-NH2 nanocomposite with enhanced visible light photoreduction activity151Low-Cost One-Step Fabrication of Highly Conductive ZnO:Cl Transparent Thin Films with Tunable Photocatalytic Properties via Aerosol-Assisted Chemical Vapor Deposition65Influence of electronic band structure on the efficiency of mid-infrared photonic devices.0Cr2S3(Et2DTC) complex and [Cr2S3-MoS2(Et2DTC)] bilayer thin films: single source stationed fabrication, compositional, optical, microstructural and electrochemical investigation9Impact of the absolute rutile fraction on TiO2 visible-light absorption and visible-light-promoted photocatalytic activity43Effect of deposition temperature of a-Si:H layer on the performance of silicon heterojunction solar cell32Exploring Tantalum as a Potential Dopant to Promote the Thermoelectric Performance of Zinc Oxide16Synthesis and characterization of novel Ag/ZnO nanoparticles for photocatalytic degradation of methylene blue under UV and solar irradiation139Touch Sensor Based on Flexible AlN Piezocapacitor Coupled With MOSFET29Doping of silver vanadate and silver tungstate nanoparticles for enhancement the photocatalytic activity of MIL-125-NH2 in dye degradation138Revisiting the optical bandgap of semiconductors and the proposal of a unified methodology to its determination477Development of Poly (vinylidene fluoride) and Polyaniline blend with high dielectric permittivity, excellent electromagnetic shielding effectiveness and Ultra low optical energy band gap: Effect of ionic liquid and temperature49Effect of dispersion on visible light transmittance and resistivity of indium tin oxide nanoparticles prepared by cetyltrimethylammonium bromide-assisted coprecipitation method6Resonant doping for high mobility transparent conductors: the case of Mo-doped In 2 O 3104Tunnel structure of tetragonal tungsten bronzes BaTa2O6, Ba0.8Ta2O5.8, and Ba0.5Ta2O5.5 studied using synchrotron X-ray and neutron diffraction5Prediction of Molecular Characteristics and Molecular Spectroscopy of Hydrochloric Acid-Doped Poly(ortho-Anthranilic Acid-co-para Nitroaniline) Thin Film19Gel Polymer Electrolyte Based on SiC:PVA Composites for Body Motion Sensor and Paper Based Application3Optical and electronic properties of high quality Sb-doped SnO2 thin films grown by mist chemical vapor deposition33Effect of Carrier Diffusion on Optical Bandgap Design of Metal Oxide/Metal/Metal Oxide Multilayer2Design, synthesis, crystal structure and luminescent properties of a new tantalum-phosphate K 3 BiTaP 3 O 13 with negligible concentration quenching and good thermostability24Enhanced Magnetic and Optoelectronic Properties of Cu-Doped ZnO: Mn Nanoparticles Synthesized by Solution Combustion Technique6Influence of deposition temperature on the structural and dispersion parameters of TiO2 thin films6Aerosol-assisted route to low-E transparent conductive gallium-doped zinc oxide coatings from pre-organized and halogen-free precursor20Fabrication and characterization of silica/Fe2.18Zn0.82O4 nanocomposites1Influence of Si on the Structural, Electrical, and Optical Properties of (Al, Ti, Si)N Films Deposited Via Reactive DC Sputtering3Plasma–liquid synthesis of MoO x and WO 3 as potential photocatalysts21Enhanced photocatalytic degradation of xylene by blackening TiO2 nanoparticles with high dispersion of CuO46Purely physical fabrication of 10 cm × 10 cm, highly uniform PbI2 thin films on rigid and flexible substrates for x-ray photodetection application7Synthesis and DFT calculations of linear and nonlinear optical responses of novel 2-thioxo-3-N,(4-methylphenyl) thiazolidine-4 one70CsPbBr 3 Single Crystal X-ray Detector with Schottky Barrier for X-ray Imaging Application100TiO2 Surface Hybridisation with Noble Metals (Ag and CuxO) for Solar De-NOx and VOC Removal0TiO2 Surface Hybridisation with Noble Metals (Ag and CuxO) for Solar De-NOx and VOC Removal0On the analysis of diffuse reflectance measurements to estimate the optical properties of amorphous porous carbons and semiconductor/carbon catalysts190Hybrid three MOFs composites (ZIF-67@ZIF-8@MIL-125-NH2): Enhancement the biological and visible‐light photocatalytic activity173Tuning of optical and electrical properties of transparent conducting AgInO2 thin films by compositional variations3Photocatalytic Aided Removal of Nitrogen Oxides and VOCs from Outdoor Environment: Graphene as a Highway for Electron Mobility in TiO2 Nanoparticles1Probing structural and photophysical features of Eu3+ activated NaCdPO4 orthophosphate phosphor51Oxygen Radical Control via Atmospheric Pressure Plasma Treatment for Highly Stable IGZO Thin-Film Transistors28Growth and vacuum post-annealing effect on the structural, electrical and optical properties of Sn-doped In2O3 thin films19Tauc-plot scale and extrapolation effect on bandgap estimation from UV–vis–NIR data – A case study of β-Ga2O3489Comparative study on organic effluent degradation capabilities and electrical transport properties of polygonal ZnCo2O4 spinels fabricated using different green fuels39Graphene oxide based coconut shell waste: synthesis by modified Hummers method and characterization201Synergistic effect of Co + Mo codoping on the photocatalytic performance of titania thin films7Graphene-TiO2 hybrids for photocatalytic aided removal of VOCs and nitrogen oxides from outdoor environment162Piezo/pyro/photo‐catalysis activities in Ba 0.85 Ca 0.15 (Ti 0.9 Zr 0.1 ) 1‐x Fe x O 3 ceramics61The influence of metallic Bi in BiVO4 semiconductor for artificial photosynthesis28Synthesis and Characterization of p-n Junction Ternary Mixed Oxides for Photocatalytic Coprocessing of CO2 and H2O15Determination of Optical Band Gap Energies of CS/MWCNT Bio-nanocomposites by Tauc and ASF Methods124Synthesis and photocatalytic performance of Ag-TiVOX nanocomposite12Synthesis of V- and Mo-doped/codoped TiO2 powders for photocatalytic degradation of methylene blue35Qualitative Approaches Towards Useful Photocatalytic Materials8Influence of the Carbon Concentration on (p) Poly-SiC x Layer Properties With Focus on Parasitic Absorption in Front Side Poly-SiC x /SiO x Passivating Contacts of Solar Cells8CS/PVA/PVP/GO Hibrit Kompozitlerin Hazırlanması ve Optik Bant Boşluğu Enerjilerinin Belirlenmesi0Improved photoelectrocatalytic activity of anodic TiO2 nanotubes by boron in situ doping coupled with geometrical optimization: Application of a potent photoanode in the purification of dye wastewater11Effect of low-temperature underwater plasma produced of new properties of Mo–Ti mixed oxide composites for electron transport layer in the dye-sensitized solar cells20Doped-poly (anthranilic acid-co-o-phenylene diamine) thin film for optoelectronic applications35Facile fabrication of vanadium sensitized silver titanium oxides (V–Ag/TiO2) photocatalyst nanocomposite for pollutants removal in river water15CuxO and carbon–modified TiO2–based hybrid materials for photocatalytically assisted H2 generation16Effect of methylammonium lead tribromide perovskite based-photoconductor under gamma photons radiation30The influence of oxygen deficiency on the dispersion parameters of TiO2 films1Latest directions in p-type transparent conductor design89Microwave-assisted sol–gel synthesis of TiO 2 -mixed metal oxide nanocatalyst for degradation of organic pollutant54Photodegradation processes21Interface Engineering of a Silicon/Graphene Heterojunction Photodetector via a Diamond-Like Carbon Interlayer33Room-temperature deposition of ZnO-graphene nanocomposite hybrid photocatalysts for improved visible-light-driven degradation of methylene blue61A Generalized Semiempirical Approach to the Modeling of the Optical Band Gap of Ternary Al-(Ga, Nb, Ta, W) Oxides Containing Different Alumina Polymorphs6Preparation of Ni/CuO/MCM-41 for indole oxidation: optimisation processes5Doping and Annealing Effects on the Optical Bandgap of the Nickel Doped Copper Oxide Thin Films0Effect of La doping on the structural and gas sensing properties of PbS thin films deposited by spray pyrolysis10Effect of TiO2 on the chemical durability and optical properties of Mo-based phosphate glasses41Use of Sodium Diethyldithiocarbamate to Enhance the Open‐Circuit Voltage of CH3NH3PbI3 Perovskite Solar Cells9Conductive Polymer-Assisted Metal Oxide Hybrid Semiconductors for High-Performance Thin-Film Transistors18Large-Grain Double Cation Perovskites with 18 μs Lifetime and High Luminescence Yield for Efficient Inverted Perovskite Solar Cells83Band gap engineering of metal-organic frameworks for solar fuel productions139CS/PVA/PVP/GO Hibrit Kompozitlerin Hazırlanması ve Optik Bant Boşluğu Enerjilerinin Belirlenmesi2Synthesis of Ni-Co-CNT nanocomposite and evaluation of its photocatalytic dye (Reactive Red 120) degradation ability using response surface methodology33Facile one-step deposition of ZnO-graphene nanosheets hybrid photoanodes for enhanced photoelectrochemical water splitting34Spectroscopic Properties and Dispersion Parameters of B2O3 – SiO2 – Bi2O3 – TiO2 – Y2O3 Glasses0Sulfophosphate Glass Doped with Er3+ and TiO2 Nanoparticles: Thermo-Optical Characterization by Photothermal Spectroscopy8Tunable Band Gaps in MUV-10(M): A Family of Photoredox-Active MOFs with Earth-Abundant Open Metal Sites0Hexagonal basalt-like ceramics LaxMg1-xTiO3 (x = 0 and 0.5) contrived via deep eutectic solvent for selective electrochemical detection of dopamine20Day-Light Photocatalytic Degradation of Methylene Blue Using Graphene/ZnO Nanocomposite2RETRACTED ARTICLE: Combined Experimental and TDDFT-DFT Computation, Characterization, and Optical Properties for Synthesis of Keto-Bromothymol Blue Dye Thin Film as Optoelectronic Devices21Degradation of Аntibiotic Chlortetracycline in Аqueous Solution by Ce/Bi2WO6 Photocatalysis under Solar Light4Photocatalytic Degradation of Antibiotic Norfloxacin Aqueous Solution by Ce/Bi2WO6: Optimization and Simulation of Process by RSM17Photocatalytic Activity of Fibrous Ti/Ce Oxides Obtained by Hydrothermal Impregnation of Short Flax Fibers8Synthesis, Characterization, Linear and NLO Properties of Novel N-(2,4-Dinitrobenzylidene)-3-Chlorobenzenamine Schiff Base: Combined Experimental and DFT Calculations44Synthesis, characterization and DFT calculations of linear and NLO properties of novel (Z)-5-benzylidene-3-N(4-methylphenyl)-2-thioxothiazolidin-4-one53Synthesis, characterization, surface analysis, optical activity and solvent effects on the electronic absorptions of Schiff base-functionalized amino thiophene derivatives: Experimental and TD-DFT investigations22Tunable Band Gaps in MUV-10(M): A Family of Photoredox-Active MOFs with Earth-Abundant Open Metal Sites58Effect of MWCNT addition on the optical band gap of PVA/CS transient biocomposites25BaBi2O6: A Promising n-Type Thermoelectric Oxide with the PbSb2O6Crystal Structure39Effects of free carriers on the optical properties of high mobility transition metal doped In2O3 transparent conductors29Revisiting the electronic nature of nanodiamonds8Optical and Nanomechanical Properties of C Coated BN Thin Film Deposited by Thermionic Vacuum Arc Technique2Synthesis and Characterization of Eco-Friendly CMC/Maghemite Nanocomposite Films12On the role of oxidation states in the electronic structure via the formation of oxygen vacancies of a doped MoVTeNbOx in propylene oxidation33Plant-Mediated Biological Synthesis of Ag-Ago-Ag2O Nanocomposites Using Leaf Extracts of Solanum Elaeagnifolium for Antioxidant, Anticancer, and DNA Cleavage Activities6Doping limitation due to self-compensation by native defects in In-doped rocksalt Cd x Zn1−x O3Fabrication of electrospun BaTiO3/chitosan/PVA nanofibers and application for dye-sensitized solar cells4Hole selective nickel oxide as transparent conductive oxide6Photocatalytic removal of benzene over Ti 3 C 2 T x MXene and TiO 2 –MXene composite materials under solar and NIR irradiation29Effect of ferroelectric polarization on piezo/photocatalysis in Ag nanoparticles loaded 0.5(Ba 0.7 Ca 0.3 )TiO 3 –0.5Ba(Zr 0.1 Ti 0.9 )O 3 composites towards the degradation of organic pollutants32Bandgap analysis and carrier localization in cation-disordered ZnGeN228Investigation of factors affecting the stability of compounds formed by isovalent substitution in layered oxychalcogenides, leading to identification of Ba 3 Sc 2 O 5 Cu 2 Se 2 , Ba 3 Y 2 O 5 Cu 2 S 2 , Ba 3 Sc 2 O 5 Ag 2 Se 2 and Ba 3 In 2 O 5 Ag 2 Se 25Optical Properties of Near Infrared Persistent Phosphor Caznge2o6: Cr3+, M3+ (M3+ = B3+; Al3+; Ga3+)0Photocatalytic hydrogen generation from a methanol–water mixture in the presence of g-C 3 N 4 and graphene/g-C 3 N 410Synergistic effect of Zn doping on thermoelectric properties to realize a high figure-of-merit and conversion efficiency in Bi 2− x Zn x Te 3 based thermoelectric generators30

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  32. Optimization of PFN thickness in inverted high-performance PTB7:PC70BM solar cells

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  35. Inverse logarithmic derivative method for determining the energy gap and the type of electron transitions as an alternative to the Tauc method

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  38. Synthesis of PbS:Mo(3%) thin film and investigation of its properties

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  40. Synergy of Neodymium and Copper for Fast and Reversible Visible-light Promoted Photochromism, and Photocatalysis, in Cu/Nd-TiO 2 Nanoparticles

    ACS Applied Energy Materials · 2019-04-09

    David Maria Tobaldi, Luc Lajaunie, Miguel López‐Haro, Rute A. S. Ferreira, Matteo Leoni, M.P. Seabra, José J. Calvino, Luís D. Carlos, João António Labrincha

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  41. Structural and Microstructural Effects of Mo3+/Mo5+ Codoping on Properties and Photocatalytic Performance of Nanostructured TiO2 Thin Films

    The Journal of Physical Chemistry C · 2019-04-17

    Zhiyuan Liu, Wen‐Fan Chen, Xichao Zhang, Ji Zhang, Pramod Koshy, Charles Christopher Sorrell

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  42. Enhanced Sol–Gel Route to Obtain a Highly Transparent and Conductive Aluminum-Doped Zinc Oxide Thin Film

    Materials · 2019-05-29

    Mohammad Hossein Nateq, Riccardo Ceccato

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  43. Fabrication of ZIF-67@MIL-125-NH2 nanocomposite with enhanced visible light photoreduction activity

    Journal of environmental chemical engineering · 2019-06-01

    Reda M. Abdelhameed, Mahmoud El‐Shahat

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  44. Low-Cost One-Step Fabrication of Highly Conductive ZnO:Cl Transparent Thin Films with Tunable Photocatalytic Properties via Aerosol-Assisted Chemical Vapor Deposition

    ACS Applied Electronic Materials · 2019-06-03

    Arreerat Jiamprasertboon, Sebastian C. Dixon, Sanjayan Sathasivam, Michael J. Powell, Yao Lu, Theeranun Siritanon, Claire J. Carmalt

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  45. Influence of electronic band structure on the efficiency of mid-infrared photonic devices.

    Surrey Research Insight Open Access (The University of Surrey) · 2019-06-07

    Timothy D. Eales

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  46. Cr2S3(Et2DTC) complex and [Cr2S3-MoS2(Et2DTC)] bilayer thin films: single source stationed fabrication, compositional, optical, microstructural and electrochemical investigation

    Environmental Technology · 2019-06-12

    Shaan Bibi Jaffri, Khuram Shahzad Ahmad, Saba Ifthikhar

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  47. Impact of the absolute rutile fraction on TiO2 visible-light absorption and visible-light-promoted photocatalytic activity

    Journal of Photochemistry and Photobiology A Chemistry · 2019-06-17

    David Maria Tobaldi, Luc Lajaunie, Nejc Rožman, Ana P. F. Caetano, M.P. Seabra, Andrijana Sever Škapin, Raúl Arenal, João António Labrincha

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  48. Effect of deposition temperature of a-Si:H layer on the performance of silicon heterojunction solar cell

    Journal of Materials Science Materials in Electronics · 2019-06-18

    Tianyu Ruan, Minghao Qu, Jianqiang Wang, Yongcai He, Xixiang Xu, Cao Yu, Yongzhe Zhang, Hui Yan

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  49. Exploring Tantalum as a Potential Dopant to Promote the Thermoelectric Performance of Zinc Oxide

    Materials · 2019-06-26

    Blanca I. Arias‐Serrano, Wenjie Xie, Myriam H. Aguirre, David Maria Tobaldi, Artur R. Sarabando, Sh. Rasekh, Sergey Mikhaylovich Mikhalev, J.R. Frade, Anke Weidenkaff, Andrei V. Kovalevsky

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  50. Synthesis and characterization of novel Ag/ZnO nanoparticles for photocatalytic degradation of methylene blue under UV and solar irradiation

    Journal of Physics and Chemistry of Solids · 2019-07-02

    Michel F. Abdel-Messih, Mohamed Abdelhay Ahmed, Ayman Soltan, Samy S. Anis

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