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RESEARCH PAPER · Inorganic Chemistry · 2011

Smart Heterostructures for Tailoring the Optical Properties of Photochromic Hybrid Organic–Inorganic Polyoxometalates

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Smart Heterostructures for Tailoring the Optical Properties of Photochromic Hybrid Organic–Inorganic PolyoxometalatesOriginalChromium, molybdenum and tungsten4Functionalized polyoxometalates with covalently linked bisphosphonate, N-donor or carboxylate ligands: from electrocatalytic to optical properties126Photo- and electrochromic properties of covalently connected symmetrical and unsymmetrical spiropyran–polyoxometalate dyads82Tuning the Photochromic Properties of Molybdenum Bisphosphonate Polyoxometalates67Syntheses and structural characterization of four new organic–inorganic hybrid compounds based on bicapped Keggin polyoxometalate {PMo12Sb2O40}9Sulfonium Polyoxometalates: A New Class of Solid-State Photochromic Hybrid Organic–Inorganic Materials74Novel Soft-Chemistry Route of Ag2Mo3O10·2H2O Nanowires and in Situ Photogeneration of a Ag@Ag2Mo3O10·2H2O Plasmonic Heterostructure32Synthesis and Visible-Light Photochromism of a New Composite Based on Polymolybdate Enclosed in Magadiite15Molybdenum Bisphosphonates with Cr(III) or Mn(III) Ions14New photoresponsive charge-transfer spiropyran/polyoxometalate assemblies with highly tunable optical properties58Photosensitivity in Ce/Sm-decorated Keggin polyoxomolybdates: an interesting photoinduced coloration phenomenon of mixed-metal clusters involving energy transfer from rare-earth fluorescence9Metal(II)-Directed Various Polyoxometalates-Based Hybrid Compounds: Assembly, Structures and Properties5A durable and fast-responsive photochromic and switchable luminescent polyviologen–polyoxometalate hybrid64Application of flexible bis-pyrazine–bis-amide ligands to construct various polyoxometalate-based metal–organic complexes20Controllable assembly of multicarboxylic acids functionalized heteropolyoxomolybdates and allochroic properties56Organic–inorganic hybrid rare earth complexes based on polymolybdates with intrinsic photosensitive properties17Fabrication of smart coatings based on wood substrates with photoresponsive behavior and hydrophobic performance49Hybrid polyoxometalate materials for photo(electro-) chemical applications384The Anderson–Evans polyoxometalate: From inorganic building blocks via hybrid organic–inorganic structures to tomorrows “Bio-POM”320Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion0Aromatic Sulfonium Polyoxomolybdates: Solid‐State Photochromic Materials with Tunable Properties30A new type of photomagnetic system: photoinduced charge transfer in polyoxometalate-based organic–inorganic hybrid6Magnetic double-tartaric bridging mono-lanthanide substituted phosphotungstates with photochromic and switchable luminescence properties103Optical Properties of Hybrid Organic‐Inorganic Materials and their Applications345Two supramolecular complexes based on polyoxometalates and Co-EDTA units via covalent connection or non-covalent interaction13Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down” synthetic method6The design of new photochromic polymers incorporating covalently or ionically linked spiropyran/polyoxometalate hybrids26Photoluminescence and Scintillation Modulation Upon UV/X‐ray‐Induced Photochromism in Europium Tungstate Phosphors14Hydrothermal Synthesis, Crystal Structure, and Catalytic Performance of Four Organic–Inorganic Hybrids Based on Polyoxometalates and O/N-Containing Groups1Polyoxomolybdates functionalized by a flexible carboxylic acid and their photochromic properties7Optical Properties of Hybrid Organic–Inorganic Materials and their Applications – Part I : Luminescence and Photochromism3Aromatic sulfonium polyoxomolybdates: tuning the photochromic properties through substitutions on the counter ion moiety13Iron molybdenum nitrilotriacetate and iminodiacetate – spectroscopy, structural characterization and CO 2 adsorption3A Reversible Redox Reaction in a Keggin Polyoxometalate Crystal Driven by Visible Light: A Programmable Solid‐State Photochromic Switch18Photochromic polypropylene fibers based on UV-responsive silica@phosphomolybdate nanoparticles through melt spinning technology38Photocoloration in Hybrid Amino Acid Polyoxometalates16Viologen as a Colour Modulator in Photochromism of Polyoxomolybdate–Viologen Hybrids40Nouveaux matériaux hybrides organiques-inorganiques photochromes et/ou photoluminescents à base de polyoxométallates0Synthèse de polyoxométallates hybrides et étude de leurs propriétés en biologie et en optique0Reunderstanding the photoinduced charge transfer process of ammonium polyoxomolybdate251B1_0606_ PHOTOSWITCHABLE NANOMATERIALS FOR THE DESIGN OF LIGHT-RESPONSIVE SMART TEXTILES: FROM COATING TO ADVANCED FIBER-SPINNING TECHNOLOGY1A novel photochromism material based on both pyrimidinium and polyoxometalate: (C4N2H4–C4N2H3) [Mn(H2O)6]0.5{SiW12O40}0.5ˑ5H2O13Anderson-type polyoxometalates: from structures to functions104Assembly of a Hexameric Cluster of Polyoxomolybdotriphosphonate Builts from [Zn(H2O){TeMo6O21}{N(CH2PO3)3}]6– Subunits and Its Optical and Catalytic Properties18Photochemical and gas adsorption studies of Keggin polyoxometalate functionalized porous melamine terephthaldehyde material5Recent progress in polyoxometalate–viologen photochromic hybrids: structural design, photochromic mechanism, and applications96Polyoxometalate (POM)-based crystalline hybrid photochromic materials104Aryl selenonium vs. aryl sulfonium counterions in polyoxometalate chemistry: the impact of Se + cationic centers on the photocatalytic reduction of dichromate3Photoluminescent Layered Crystal Consisting of Anderson-Type Polyoxometalate and Surfactant toward a Potential Inorganic–Organic Hybrid Laser4Rapid and efficient mechanosynthesis of alkali and alkaline earth molybdates0Advanced Functional Photochromic Wearables with Superior Durability and Stability for Sustainable Applications18Synthesis of 1-azabicyclo[2.2.1]heptane derivatives and their hybrid perovskite and trigonal crystal structures0Cylindrical HP III -Sb III -Templated Five-Layer Polyoxotungstate with Conspicuous Photochromism Triggered by UV or Visible Light15Multi-color photochromic waterborne polyurethane with high color fastness from hydroxyl-functionalized trichromatic spiropyrans12A novel supramolecular Co-EDTA and Ni-anderson polyoxometalate hybrid as a high-performance electrocatalyst for alkaline water splitting6Synthesis, Structural Characterization, and Photochromic Behavior of a New Hybrid Diphosphomolybdate Compound0A photochromic proline-modified Dy 3+ -embedded selenotungstate with fluorescence switching0Halochromic Benzazolo-oxazolidine/Polyoxometalate Supramolecular Materials with Reversible High-Contrast Color-Switching1Synthesis, Structure, Photochromic and Electrochemical Behavior of a New Material Based on a Binuclear 1:1 Mo-citrate complex and the 3,3′-Diaminodipropylammonium Cations0Advanced inorganic photochromic materials: A bibliometric study with content analysis0Inorganic–Organic Hybrid Frameworks Constructed From Keggin‐Type Polyoxotungstates and Bolaamphiphiles0

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  1. Chromium, molybdenum and tungsten

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  2. Functionalized polyoxometalates with covalently linked bisphosphonate, N-donor or carboxylate ligands: from electrocatalytic to optical properties

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  3. Photo- and electrochromic properties of covalently connected symmetrical and unsymmetrical spiropyran–polyoxometalate dyads

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  4. Tuning the Photochromic Properties of Molybdenum Bisphosphonate Polyoxometalates

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  5. Syntheses and structural characterization of four new organic–inorganic hybrid compounds based on bicapped Keggin polyoxometalate {PMo12Sb2O40}

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  6. Sulfonium Polyoxometalates: A New Class of Solid-State Photochromic Hybrid Organic–Inorganic Materials

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  7. Novel Soft-Chemistry Route of Ag2Mo3O10·2H2O Nanowires and in Situ Photogeneration of a Ag@Ag2Mo3O10·2H2O Plasmonic Heterostructure

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  8. Synthesis and Visible-Light Photochromism of a New Composite Based on Polymolybdate Enclosed in Magadiite

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  9. Molybdenum Bisphosphonates with Cr(III) or Mn(III) Ions

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  10. New photoresponsive charge-transfer spiropyran/polyoxometalate assemblies with highly tunable optical properties

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  11. Photosensitivity in Ce/Sm-decorated Keggin polyoxomolybdates: an interesting photoinduced coloration phenomenon of mixed-metal clusters involving energy transfer from rare-earth fluorescence

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  12. Metal(II)-Directed Various Polyoxometalates-Based Hybrid Compounds: Assembly, Structures and Properties

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  13. A durable and fast-responsive photochromic and switchable luminescent polyviologen–polyoxometalate hybrid

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  14. Application of flexible bis-pyrazine–bis-amide ligands to construct various polyoxometalate-based metal–organic complexes

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  15. Controllable assembly of multicarboxylic acids functionalized heteropolyoxomolybdates and allochroic properties

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  16. Organic–inorganic hybrid rare earth complexes based on polymolybdates with intrinsic photosensitive properties

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  17. Fabrication of smart coatings based on wood substrates with photoresponsive behavior and hydrophobic performance

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  18. Hybrid polyoxometalate materials for photo(electro-) chemical applications

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  19. The Anderson–Evans polyoxometalate: From inorganic building blocks via hybrid organic–inorganic structures to tomorrows “Bio-POM”

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  20. Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion

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  21. Aromatic Sulfonium Polyoxomolybdates: Solid‐State Photochromic Materials with Tunable Properties

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  22. A new type of photomagnetic system: photoinduced charge transfer in polyoxometalate-based organic–inorganic hybrid

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  23. Magnetic double-tartaric bridging mono-lanthanide substituted phosphotungstates with photochromic and switchable luminescence properties

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  24. Optical Properties of Hybrid Organic‐Inorganic Materials and their Applications

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  25. Two supramolecular complexes based on polyoxometalates and Co-EDTA units via covalent connection or non-covalent interaction

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  26. Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down” synthetic method

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  28. Photoluminescence and Scintillation Modulation Upon UV/X‐ray‐Induced Photochromism in Europium Tungstate Phosphors

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  29. Hydrothermal Synthesis, Crystal Structure, and Catalytic Performance of Four Organic–Inorganic Hybrids Based on Polyoxometalates and O/N-Containing Groups

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  30. Polyoxomolybdates functionalized by a flexible carboxylic acid and their photochromic properties

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  31. Optical Properties of Hybrid Organic–Inorganic Materials and their Applications – Part I : Luminescence and Photochromism

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  32. Aromatic sulfonium polyoxomolybdates: tuning the photochromic properties through substitutions on the counter ion moiety

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  33. Iron molybdenum nitrilotriacetate and iminodiacetate – spectroscopy, structural characterization and CO 2 adsorption

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  34. A Reversible Redox Reaction in a Keggin Polyoxometalate Crystal Driven by Visible Light: A Programmable Solid‐State Photochromic Switch

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  35. Photochromic polypropylene fibers based on UV-responsive silica@phosphomolybdate nanoparticles through melt spinning technology

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  36. Photocoloration in Hybrid Amino Acid Polyoxometalates

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  37. Viologen as a Colour Modulator in Photochromism of Polyoxomolybdate–Viologen Hybrids

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  38. Nouveaux matériaux hybrides organiques-inorganiques photochromes et/ou photoluminescents à base de polyoxométallates

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  40. Reunderstanding the photoinduced charge transfer process of ammonium polyoxomolybdate

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  41. 1B1_0606_ PHOTOSWITCHABLE NANOMATERIALS FOR THE DESIGN OF LIGHT-RESPONSIVE SMART TEXTILES: FROM COATING TO ADVANCED FIBER-SPINNING TECHNOLOGY

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  42. A novel photochromism material based on both pyrimidinium and polyoxometalate: (C4N2H4–C4N2H3) [Mn(H2O)6]0.5{SiW12O40}0.5ˑ5H2O

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  49. Photoluminescent Layered Crystal Consisting of Anderson-Type Polyoxometalate and Surfactant toward a Potential Inorganic–Organic Hybrid Laser

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