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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

Recent progress in polyoxometalate–viologen photochromic hybrids: structural design, photochromic mechanism, and applications

Li Li, Yang-Tao Yu, Hua Yang, Xiaonan Li, Hong Zhang

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Recent progress in polyoxometalate–viologen photochromic hybrids: structural design, photochromic mechanism, and applicationsOriginalThe effect of conjugation degree of aromatic carboxylic acids on electronic and photo-responsive behaviors of naphthalenediimide-based coordination polymers14A series of isopolymolybdate-viologen compounds: structures and photochromic, organic amine sensing, and double anti-counterfeiting properties5Electrospun glass nanofibers to strengthen polycarbonate plastic glass toward photoluminescent smart materials23A novel 3D hexagonal honeycomb Zn-MOF for effective detection of Fe3+, CrO42-, and Cr2O72- and selective dye adsorption in aqueous media24Novel extended viologen derivatives for photochromic and electrochromic dual-response smart windows71Multifunctional Aryl Sulfonium Decavanadates: Tuning the Photochromic and Heterogeneous Oxidative Desulfurization Catalytic Properties Using Salicylaldehyde-type Functional Moieties on Counterions6Tunable Chromic Properties of Viologen‐Metal Polymers Modulated by Coordination Modes for Inkless Erasable Printing25Multifunctional naphthalene diimide-based coordination polymers: Ultrafast visible light-induced photochromism, visual detection of blue light, inkless and erasable prints and electrochromism34Multifunctional Crystalline Coordination Polymers Constructed from 4,4′-Bipyridine-N,N′-dioxide: Photochromism, White-Light Emission, and Photomagnetism5A Series of POM–Viologen Photo-/Electrochromic Hybrids and Hydrogels Acting as Multifunctional Sensors for Detecting UV, Hg 2+ , and Organic Amines29Novel strategy toward color-tunable and glow-in-the-dark colorless smart natural wooden window13Polyoxometalate (POM)-based crystalline hybrid photochromic materials104An iron-containing POM-based hybrid compound as a heterogeneous catalyst for one-step hydroxylation of benzene to phenol6Three polyoxometalate-viologen color-changing materials with excellent photo-, thermo- and amine-chromic properties6A novel viologen-based hybrid crystalline material for photochromic glass films, information storage and anti-counterfeiting14Effect of iodide on the electronic and photoresponsive behaviors of 1D naphthalenediimide-based zinc coordination polymers3Photochromism and single-component white light emission from a metalloviologen complex based on 1,5-naphthyridine5Structure-induced selective adsorption of diverse dyes and Cr( vi ) photoreduction using two new polyoxometalate-based metal–viologen complexes17Tailorable and photochromic multifunctional methyl viologen/cellulose nanocrystal (CNC) films5The simultaneous modulation effect of N -substituents on the photochromic and electrochromic properties of naphthalenediimide-based coordination polymers33Glass nanofibers and lanthanide aluminate nanoparticles as reinforcement nanofillers for polyurethane composite toward smart applications9Three Viologen Compounds Containing Keggin and Mo-Capped Weakley Polyoxometalates: Photo-/Thermo-/Electro-Chromic Studies15Four POM-Viologen Color-Changing Materials with Fast Color Response under Various External Stimuli32A Multistimuli-Responsive Cd-MOF Constructed by an Extended Viologen-Based Carboxylate Ligand41Photoluminescent polypropylene nanofiber-supported polyethylene terephthalate integrated with strontium aluminate phosphor17Polyacrylamide/sodium alginate/sodium chloride photochromic hydrogel with high conductivity, anti-freezing property and fast response for information storage and electronic skin30Assessing the Influence of Confinement on the Stability of Polyoxometalate-Functionalized Surfaces: A Soft Sequential Immobilization Approach for Electrochromic Devices5Photochromic radical states in 3D covalent organic frameworks with zyg topology for enhanced photocatalysis57Differential response under X-ray/UV dual-mode excitation in single-component defect state phosphor X-ray imaging and Wavelength-Multiplexing information storage11Transparent insulating photochromic PU/PTA films for Wide-Spectrum modulated smart windows13Advances in viologen-based stimulus-responsive crystalline hybrid materials75Delignification of wood toward photoluminescent smart window infiltrated with glass nanofibers-reinforced polystyrene for multifunctional applications10A Lanthanide-Incorporated Phospho(III)tungstate Aggregate Constructed from [HPIIIW8O31]10– and [W11O39]12– Building Blocks and Its Nanocomposite with CdS for Ultrasensitive Photoelectrochemical Detection of Oxytetracycline8Metal Ion Modulated Electron Transfer in Metalloviologen Compounds: Photochromism and Differentiable Amine Detection23Multi‐stimuli‐responsive chromic switching self‐assembled with polyoxometalate and copper‐viologen frameworks18A Universal Strategy for Reversible Photochromism of Viologen Derivatives in Solutions21A donor-acceptor π-stacked multifunctional Eu-MOF based on a novel viologen-like photosensitive ligand: Degradation of tetracycline, photochromism, and photoluminescence7Development of strontium aluminate‐printed nonwoven fabric from recycled cotton cellulose for smart wearable photochromic applications10Light-Induced Antiferromagnetic to Ferromagnetic Transition in Halogen Substituted 1,4-Bis(imidazolyl)benzene Systems: An Effect of Spin–Orbit Coupling and π-Stacking in Enhanced Photomagnetism25Syntheses and performance study of three POM-viologen compounds with photo- and electric-stimulation response5From Simple Probe to Smart Composites: Water‐Soluble Pincer Complex With Multi‐Stimuli‐Responsive Luminescent Behaviors22Unlocking versatile capabilities: Mixed-valence decavanadate aerogels for boosting radar, infrared, and thermal stealth3Heteronuclear cadmium(II)/cobalt(III) cyanide coordination polymers with 1-methylimidazole and 1-ethylimidazole ligands: synthesis, characterization and catalytic activities5Photochromic behaviors, reversible crystalline−amorphous transformation and information anti-counterfeiting of one viologen-containing compound12POM‐Based Hydrogels for Efficient Synergistic Chemodynamic/Low‐Temperature Photothermal Antibacterial Therapy9A novel naphthalenediimide-based metal-organic framework for inkless erasable printing with ultra-long cycling performance2Multi-Stimuli Responsive Viologen-Imprinted Polyvinyl Alcohol and Tricarboxy Cellulose Nanocomposite Hydrogels5Syntheses and Color-Changing Properties of Three PW11M (M = Ni, Cu, and Zn)-Based Viologen Compounds6Naphthalenediimide and perylenediimide based donor-acceptor crystalline hybrid materials: Structures and applications90Ruthenium containing polyoxometalates: From synthesis, structures, properties to functional applications20Multistimuli-responsive materials based on two pyridinium ion-based complexes and their applications in tetracycline degradation and information anticounterfeiting6Recent advances in heterostructure-based organic field-effect transistor memory6Recent advances in viologen-based polymers and their photocatalytic applications5Selective Photochromism of 2,6-Di(1,6-naphthyridin-2-yl)pyridine-Based Zinc(II)-Complexes by Varying the Tethers of Dicarboxylate Coligands: Significance of Anion−π Interactions on Photo-Induced Electron Transfer2Quasi-metallic bandgap tunability at low static pressures and quintuple chromism by electron transfer in a viologen-derivative iodide3The photo/electrochromic properties of a Cd(II)-viologen and its application in fluorescence detection of tryptophan, inkless printing and information transmission5Delignification of wood and infiltration with alumina/polyvinylpyrrolidone nanofiber-reinforced nanocomposite toward photoluminescent smart window for detection and filtration of ultraviolet radiation0Recent advances in photo‐ or electro‐chromic smart windows and their thermal regulation13Photoluminescent iridium(III) complexes with mono-pyridinium substituted phenylpyridine ligands: synthesis, electrochemical and photophysical properties, and electroluminochromic performance2Immobilization of electrospun alumina nanofiber-embedded nanocomposite into delignified wood toward multifunctional ultraviolet filtering smart windows for energy efficiency of residential buildings5A multifunctional Cd(II)-viologen coordination polymer: ultrafast photo/electrochromic switching, tetracycline degradation and its applications in photochromic film and inkless printing6Synthesis, crystal structure, photochromism and photo-regulated luminescence of a viologen-functionalized material8Polyoxometalate‐Based Nanozyme with Oxidase‐Mimic Activity for Point‐of‐Care Perfluorooctane Sulfonate Detection with Colorimetry4Tetra-Pr3+-Incorporated Tellurotungstate Covalently Modified by d-methionine: Proton Conduction and Photochromic Properties3Linear-light regulated bidirectional electron transfer of a pyromellitic diimide-based photochromic coordination polymer for inkless and erasable printing and information anticounterfeiting11Exclusion complexes of γ-cyclodextrin with conjugation-extended viologens displaying photochromic and fluorescent properties in solid-state3Development of glazed epoxy resin nanocomposites toward mechanically reliable, multifunctional, and long-persistent photoluminescent ceramics5Polyoxometalate-based metal-organic complexes with dual-site synergy for catalytic synthesis of p-benzoquinone9The Photochromism of UiO-66 Encapsulated Polyoxometalate Composites2Recent progress in antimicrobial activity, mechanism, and application of polyoxometalate and its hybrid composites5Dual-Functional Viologen-Based Metal–Organic Framework for Thermochromic and Fluorescence Detection of Fe3+, Cr2O72–, and Tetracycline24Highly Photosensitive Metal–Organic Cage Based on 2,4,6-Tri(4-pyridyl)-1,3,5-triazine Ligand8Recent Progress in Photoresponsive Room-Temperature Phosphorescent Materials: From Mechanistic Insights to Functional Applications7Tetrahydroxyhexanedioic Acid-Ornamented Phosphite-and-Bismuth-Bridging Eu III -Encapsulated Phospho(III)tungstate and Its Photochromic and Photoluminescence Switching Properties8Boosting Visible Light Photocatalytic Performance of Polyoxometalate/Viologen-Based Crystalline Complexes for Cr(VI) Reduction0Two naphthalene diimide cadmium coordination polymers: Synthesis, photocontrolled luminescence, photo/electrochromism, inkless erasable printing and triethylamine detection3The modulation effect of π-conjugated systems on photoinduced electron transfer of arylenediimide-based photochromic coordination polymers2A Vanadium-Based Polyoxometalate Nanozyme for 2-Mercaptobenzothiazole Colorimetric Detection and Visible-Light-Driven Degradation in Water2Polyoxometalate-Zr-Organic Cage Hybrid Ionic Salts Exhibiting Rapid Photochromic Behavior3D–π–A-type tetraphenylethylene-based AIEgen: multi-stimuli-responsive behavior and multilevel anti-counterfeiting applications2Multi-functional applications of a metal-free viologen supramolecular compound: UV detection, amine sensing, and ink-free printing1Recent advances in single-crystal polyoxometalate-based metal–organic complex catalytic systems for sulfide–sulfoxide selective transformations2Regulating Electronic Functionality in Lindqvist Polyoxometalates: A Molecular Approach to Tunable Metal Oxides6Enhancing photochromic properties of triphenylethylene derivatives via the modulation of intermolecular interactions1The Modulation Effect of Positional Isomeric Electron Donors on Bidirectional Electron Transfer of Photochromic Cd(II) Coordination Polymers3Synthesis, crystal structure, photochromic behavior and photomodulated luminescence of a calcium-based coordination polymer constructed from 2,5-thiophenedicarboxylic acid and viologen linker0Electrospun alumina nanofiber-reinforced and silica-glazed polyester resin nanocomposites for multifunctional ceramic coatings0Photoinduced Formation of Heterobiradical Species in Crystalline Uranyl–Organic Frameworks Incorporating Cucurbit[8]uril-Viologen [3]Pseudorotaxane1Photochargeable Materials for Persistent Solar Energy Storage and “Dark” Catalysis3Chemical Reconfiguration via [2 + 2] Cycloaddition: Directing Photobleaching Switching in a Copper Complex0Crystalline Hybrid Photochromic Materials With Photoresponsive Properties Driven by Electron Transfer: Recent Advances4Two novel 0-D coordination polymers based on cyanoviologen: Multischromism, photo-controlled luminescence, organic amine detection, dual anti-counterfeiting and photocatalytic degradation3Photoluminescent Carbon Dot-Immobilized Cellulose Nanocrystal-Reinforced Tricarboxy Cellulose Hydrogel for Anticounterfeiting Applications0Refining the Impact of Structural Variations on Photochromism and Photothermal Conversion in Viologen Crystals1Halide-controlled solid-state photochromism in viologen-cyclodextrin complexes0Smart ceramic coating from lanthanide aluminate-encapsulated silica nanoparticle-immobilized electrospun glass nanofiber-reinforced epoxy nanocomposite0

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  5. Novel extended viologen derivatives for photochromic and electrochromic dual-response smart windows

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  6. Multifunctional Aryl Sulfonium Decavanadates: Tuning the Photochromic and Heterogeneous Oxidative Desulfurization Catalytic Properties Using Salicylaldehyde-type Functional Moieties on Counterions

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  7. Tunable Chromic Properties of Viologen‐Metal Polymers Modulated by Coordination Modes for Inkless Erasable Printing

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  8. Multifunctional naphthalene diimide-based coordination polymers: Ultrafast visible light-induced photochromism, visual detection of blue light, inkless and erasable prints and electrochromism

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  9. Multifunctional Crystalline Coordination Polymers Constructed from 4,4′-Bipyridine-N,N′-dioxide: Photochromism, White-Light Emission, and Photomagnetism

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    Ning‐Ning Zhang, Liu-Di Xin, Li Li, Yanan Zhang, Ping-Ping Wu, Yong‐Fang Han, Yong Li Yan, Konggang Qu

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  10. A Series of POM–Viologen Photo-/Electrochromic Hybrids and Hydrogels Acting as Multifunctional Sensors for Detecting UV, Hg 2+ , and Organic Amines

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  13. An iron-containing POM-based hybrid compound as a heterogeneous catalyst for one-step hydroxylation of benzene to phenol

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  14. Three polyoxometalate-viologen color-changing materials with excellent photo-, thermo- and amine-chromic properties

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  15. A novel viologen-based hybrid crystalline material for photochromic glass films, information storage and anti-counterfeiting

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  16. Effect of iodide on the electronic and photoresponsive behaviors of 1D naphthalenediimide-based zinc coordination polymers

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  17. Photochromism and single-component white light emission from a metalloviologen complex based on 1,5-naphthyridine

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  19. Tailorable and photochromic multifunctional methyl viologen/cellulose nanocrystal (CNC) films

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  20. The simultaneous modulation effect of N -substituents on the photochromic and electrochromic properties of naphthalenediimide-based coordination polymers

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  23. Four POM-Viologen Color-Changing Materials with Fast Color Response under Various External Stimuli

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  31. Advances in viologen-based stimulus-responsive crystalline hybrid materials

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  32. Delignification of wood toward photoluminescent smart window infiltrated with glass nanofibers-reinforced polystyrene for multifunctional applications

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  33. A Lanthanide-Incorporated Phospho(III)tungstate Aggregate Constructed from [HPIIIW8O31]10– and [W11O39]12– Building Blocks and Its Nanocomposite with CdS for Ultrasensitive Photoelectrochemical Detection of Oxytetracycline

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  35. Multi‐stimuli‐responsive chromic switching self‐assembled with polyoxometalate and copper‐viologen frameworks

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  36. A Universal Strategy for Reversible Photochromism of Viologen Derivatives in Solutions

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  40. Syntheses and performance study of three POM-viologen compounds with photo- and electric-stimulation response

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  41. From Simple Probe to Smart Composites: Water‐Soluble Pincer Complex With Multi‐Stimuli‐Responsive Luminescent Behaviors

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  42. Unlocking versatile capabilities: Mixed-valence decavanadate aerogels for boosting radar, infrared, and thermal stealth

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  43. Heteronuclear cadmium(II)/cobalt(III) cyanide coordination polymers with 1-methylimidazole and 1-ethylimidazole ligands: synthesis, characterization and catalytic activities

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  44. Photochromic behaviors, reversible crystalline−amorphous transformation and information anti-counterfeiting of one viologen-containing compound

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  45. POM‐Based Hydrogels for Efficient Synergistic Chemodynamic/Low‐Temperature Photothermal Antibacterial Therapy

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  46. A novel naphthalenediimide-based metal-organic framework for inkless erasable printing with ultra-long cycling performance

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    Letian Zhang, Bin Xia, Nan Lu, Quan-Wen Li, Xia Zhang, Na Li, Xian‐He Bu

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  47. Multi-Stimuli Responsive Viologen-Imprinted Polyvinyl Alcohol and Tricarboxy Cellulose Nanocomposite Hydrogels

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  48. Syntheses and Color-Changing Properties of Three PW11M (M = Ni, Cu, and Zn)-Based Viologen Compounds

    Crystal Growth & Design · 2024-11-02

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  49. Naphthalenediimide and perylenediimide based donor-acceptor crystalline hybrid materials: Structures and applications

    Coordination Chemistry Reviews · 2024-11-29

    Zhengfen Liu, Xiaobo Li, Weijun Dai, Jian‐Jun Liu, Mei‐Jin Lin

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  50. Ruthenium containing polyoxometalates: From synthesis, structures, properties to functional applications

    Polyoxometalates · 2024-12-16

    Qiyang Cai, Ruili Gao, Yanfei Wang, Jiashen Xing, Qingyang Zhang, Muzi Zhu, Xinyuan Qin, Meihong Liao, Yichao Huang

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