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RESEARCH PAPER · Coordination Chemistry Reviews · 2023

Polyoxometalate (POM)-based crystalline hybrid photochromic materials

Li Li, Yang-Tao Yu, Ning‐Ning Zhang, Shu-Hao Li, Jian-Ge Zeng, Hua Yang, Yang Hua

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Polyoxometalate (POM)-based crystalline hybrid photochromic materialsOriginalA Co-containing polyoxogermanotungstate for alkaline electrocatalytic water oxidation6Characterization, oxidative desulfurization performance evaluation and the catalytic reaction mechanism of polyoxometalate-coated, semi-encapsulated heart-shaped metal organic frameworks16Effect of iodide on the electronic and photoresponsive behaviors of 1D naphthalenediimide-based zinc coordination polymers3Electrochemical Sensor Based on Vanadium-Substituted Tungstophosphate with Fe3o4@Au/Mof Composite Modified Glassy Carbon Electrode for Food Nitrite Detection1Highly efficient NIR-II photothermal conversion from a 2,2′-biquinoline-4,4′-dicarboxylate-based photochromic complex10Iso- and hetero-polyoxovanadium glycolates [VIV6O 6 (glyc) 6 M III (OH) 6 ] 3− (M = V, Cr, Fe, and Al) encapsulating metal hydroxides0Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate16Photochromism and single-component white light emission from a metalloviologen complex based on 1,5-naphthyridine5Photofluorochromic organic supramolecular compounds for multiple dynamic anticounterfeiting19Polyoxometalate/ s -triazine hybrid heterostructures with ultrafast photochromic properties9Synthesis of bridged dinaphthoviologen derivatives for enhanced electrochromic performance and picric acid detection10Preparation of cellulose nanowhiskers‐reinforced polyurethane: Photoresponsive plastic with ultraviolet protection and superhydrophobic properties4Synthesis, structure, adsorption and electrochemical properties of the new two-dimensional cobalt coordination polymer based on bifunctional ligand5Styrylbenzoquinoline dyads as a new type of fluorescing photochromes operating via [2 + 2] photocycloaddition mechanism: Optimization of the structure5Photochromic ionogel with a wide temperature range and fatigue resistance for high-resolution rewritable information record19Transparent insulating photochromic PU/PTA films for Wide-Spectrum modulated smart windows13Temperature‐Responsive Polyoxometalates‐Based Materials: From Underlying Mechanism to Promising Applications27Revolutionizing drug delivery: The power of stimulus-responsive nanoscale systems38Two multifunctional Eu-MOFs with dual photochromic and luminous centers for multiple optical switches and anti-counterfeiting properties11Modular assembly of Co4-thiacalix[4]arene units and Keggin-type SiW12O40 for visible-light photothermal conversion9Two octamolybdate compounds based on an asymmetric viologen: Syntheses, structures and electrochemical performance5Scalable synthesis of a new {P2Mo18O62}-modified CuI/CuII-based metal–organic complex for multi-center synergistic catalysis of benzyl alcohol to benzoic acid1Dynamic, multi-color, multi-level stimulus-responsive luminescence in a co-crystallized coordination polymer: Modulation of energy transfer by acid-induced ligand protonation and photo-induced radical generation12Rapid fabrication of polyoxometalate-enhanced photo responsive films from ethyl cellulose (EC) and polyvinylpyrrolidone (PVP)15Photo-, Thermo-, and Vapochromic Behavior in a 2,4,6-Tris-2-pyridyl-1,3,5-triazine Ligand-Based Zn(II) Complex1Driving sustainable energy: The role of polyoxometalates (POMs) in photoelectrochemical hydrogen production30Transparent Photochromic Coatings for Smart Windows and Information Storage9Visible‐Light‐Driven Efficient Photocatalytic Reduction of Cr(VI) in a Wide pH Range by Two New Isopolymolybdate‐Based Ni(II)‐Complexes5Syntheses and Color-Changing Properties of Three PW11M (M = Ni, Cu, and Zn)-Based Viologen Compounds6Naphthalene diimide-based crystalline hybrid photochromic materials: structural types, photochromic mechanism, and applications44Inorganic–organic hybrids based on Keggin-type polyoxometalate@Cu/Ag for degradation/absorption of methylene blue and electrocatalytic property3Advanced Design for Stimuli‐Reversible Chromic Wearables With Customizable Functionalities46Photochromic Film Based on a Mixed-Heteroatom-Templated ErIII-Incorporated Polyoxometalate Used for Inkless Prints and Anti-Counterfeiting19Conjugated Naphthalenediimide-Pyridinium Salts in Donor–Acceptor Hybrid Materials for Enhanced Photochromic Properties13Advances in crystalline metal–organic photochromic materials19Charge transfer stimulated visible-light photochromism of naphthalenediimide-based zinc halide coordination polymers for detecting/filtering harmful blue rays7Hybrid polysaccharide film infused with polyoxometalates for inkless printing and solar ultraviolet sensing8Mechanism of the generation of ultra-stable radicals in fast photochromic naphthalenediimide-based coordination polymers19NIR-II absorption and photothermal conversion in a photochromic metal–organic framework based on cis -2,2′-biquinoline-4,4′-dicarboxylate0Synergistic crystalline catalysts assembled with Wells–Dawson-type polyoxometalates and heterovalent metal complexes for efficient benzylic C–H bond oxidation25The Modulation Effect of N-Substituents on Photochromic Properties of Naphthalenediimide-based Coordination Polymers5Aminobenzoic Acid Covalently Modified Polyoxotungstates Based on {XW6} Clusters with Proton Conductivity Property17Engineering boron-imidazolate-based polyoxometalates for photooxidative C=C bond cleavage in aqueous media12The photo/electrochromic properties of a Cd(II)-viologen and its application in fluorescence detection of tryptophan, inkless printing and information transmission5Synergistic Photochromism, Fluorescence Switching, and Photomagnetism of Three Mn(II) Complexes Based on a Thiazolothiazole Extended Viologen Derivative11Preparation, performance and application of photochromic thermal expansion microcapsules containing spiropyran in water-based ink6Sn-TiO2/PTA Nanocomposite Films for High-Contrast Rewritable Media with Visible-Light-Driven Black Coloration0Thiacalix[4]arene-functionalized molecular clusters involving the Keggin-type PM 4Mo 8 (M = Co, Ni) motif: Electrochemical and photothermal conversion properties14Study of crystallographic and photochromic properties of five 1-(1-cyclohexylmethane)-4,4′-bipyridinium-based complexes1Construction and Proton Conductivities of Multidimensional Isopolymolybdate-Based Metal–Organic Frameworks4Smart Coatings: Fundamentals, Preparation Approaches, and Applications47Linear-light regulated bidirectional electron transfer of a pyromellitic diimide-based photochromic coordination polymer for inkless and erasable printing and information anticounterfeiting11Exclusion complexes of γ-cyclodextrin with conjugation-extended viologens displaying photochromic and fluorescent properties in solid-state3Methyl Viologen@β-Zeolite with Absorption/Fluorescence Dual-Mode and Photo/Chemical Synergistic Stimuli-Responsive Chromism2Multiple Dynamic Anticounterfeiting Using Photochromic Luminescence Organic Cocrystals27Two Multistimuli-Responsive POM/Viologen Hybrids: From Inkless Printing to Smart Hydrogels and Electronic Skin7Frontiers in Polyoxometalate‐Based Hybrids for Photothermal Catalysis20Gas-Foaming Preparation of Fast Fading Porous Photochromic Hydrogels for Information Switching5Construct Ordered Proton Channels in Polyoxometalate-Based Metal–Organic Frameworks for Enhancing Proton Conduction6Design and Synthesis of Photofluorochromic Coordination Polymers Featuring Dual-Mode Output for Dynamic Anticounterfeiting2Multi-stimuli-responsive tetraphenylethylene derivatives: Aggregation-induced emission, reversible mechano- and photochromism for anti-counterfeiting applications5Solvent-coordination directed control of electron transfer dynamics in photoactive complexes5Exploring the Photochromic Performance of Two Viologen-Based Complexes7Recent Progress in Photoresponsive Room-Temperature Phosphorescent Materials: From Mechanistic Insights to Functional Applications7Tetrahydroxyhexanedioic Acid-Ornamented Phosphite-and-Bismuth-Bridging Eu III -Encapsulated Phospho(III)tungstate and Its Photochromic and Photoluminescence Switching Properties8Lattice solvent-modulated multicolor photochromism in a donor-acceptor type iodoargentate hybrid0Nanopatterning in Surfactant-Encapsulated Polyoxometalate Systems: A Kinetically Hindered Phase Transition Drives Structural Complexity0The modulation effect of π-conjugated systems on photoinduced electron transfer of arylenediimide-based photochromic coordination polymers2Competitive effects of Mo6+ doping and MoO3 phase formation on the photochromic properties of KSr2Nb5O15-based ceramics0Polyoxometalate-Zr-Organic Cage Hybrid Ionic Salts Exhibiting Rapid Photochromic Behavior3D–π–A-type tetraphenylethylene-based AIEgen: multi-stimuli-responsive behavior and multilevel anti-counterfeiting applications2Exciplex-based multi-stimuli-responsive luminescent materials: photo-recoverable mechanochromic luminescence for reusable paper applications2Gluconic acid-bridged Eu III -incorporated polyoxometalate-based thin film: a dual-mode multifunctional platform for photochromic–photoluminescent switching applications0Multi-functional applications of a metal-free viologen supramolecular compound: UV detection, amine sensing, and ink-free printing1Photoswitchable imaging contrast agents as an emerging frontier in precision bioimaging11Two magnesium-based metal–organic frameworks (Mg-MOFs): structures, photochromism, and fluorescence sensing of Fe 3+ ions and cysteine molecules0Enhancing photochromic properties of triphenylethylene derivatives via the modulation of intermolecular interactions1Coordination modes-directed two different octamolybdate-based architectures with diverse aqueous electrochemical energy storage performances2Tricomponent synergistic ultrafast photochromism of pyromelliticdiimide-polyoxometalate hybrids for information encryption and smart windows5Thermally tunable naphthalene diimide solvates enable selective sensing, reversible photochromism, and anti-counterfeiting applications1Electron-Transfer-Mediated Dynamic Control of Photochromism and Fluorescence/Phosphorescence in a Smart Metal–Organic Framework0Crystalline Hybrid Photochromic Materials With Photoresponsive Properties Driven by Electron Transfer: Recent Advances4The Potential of Photochromic Materials Based on Transition‐Metal Oxides and Polyoxometalates3Rational Design of a {InCu 6 } Heterometallic Oxo Cluster for Superior Proton Conduction: Mechanistic Insights and Humidity Gradient‐Based Power Generation0Rational Design of a {InCu 6 } Heterometallic Oxo Cluster for Superior Proton Conduction: Mechanistic Insights and Humidity Gradient‐Based Power Generation2Phosphotungstic Acid Modulated PNIPAM/P(AA‐ co ‐AM) Bilayer Hydrogels With Programmable Thermo‐Responsive Kinetics and Enhanced Toughness0UV-visible-light/Ethylenediamine-vapor dual-responsive sensor utilizing solvated Eu(III)-isolated polyoxometalate0A multifunctional viologen-Cd framework integrating high-performance photocurrent switching, selective histidine sensing and inkless erasable printing0Substituent position-dependent photochromism in carbazole-dithienylethene systems: Enabling visible-light responsiveness through extended conjugation0Insight into integrated multi-stimuli chromism in viologen-based composite hydrogels0Dual-channel optical decoupling of photochromism and room-temperature phosphorescence via ground-state charge transfer for non-destructive anti-counterfeiting0Synergistic construction of a stable electron storage by alkali metal and cyano groups for enhanced photochromism in C3N5 nanosheets0Bridging mechanisms and functional realization of stimuli-responsive ionic hydrogels: From molecular design to emerging applications0Ultraviolet-Adaptive Transparent Films with Electromagnetic Interference Shielding for Smart Window Applications6Refining the Impact of Structural Variations on Photochromism and Photothermal Conversion in Viologen Crystals1A degradable organic-inorganic hybrid photochromic system with dual electron-donating mechanism for advanced anti-counterfeiting0Evaporation-induced alignment of boron nitride nanofillers in supramolecular polymer composites for integrated thermal management, self-healing, and recyclability1A fluorescent/photochromic dual-function Mo-based hydrogel for information encryption1Counteranion-Regulated Thermo-, Photo-, and Electrochromism in Viologen-Based Crystalline Solids1Polyoxometalate clusters for precision theranostics: from structural engineering to diagnosis and therapy0Solid-state photochromism of spiropyran toward real-world applications0Ginkgo-inspired polyvinyl alcohol/phosphomolybdic acid films: Mo6+/Mo5+ transition-driven multi-functionality for flame retardancy, fire warning and UV dosimetry0An Oxalate- and Phosphite-Bridging Multi-HoIII-Encapsulated Tellurotungstate and Its Photochromic Performance0Constructing Superhydrophobic High-internal-phase Emulsion Fluoro-coatings from Hydrophilic Polyoxometalates for Durable Photochromic Functionality0

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  49. Study of crystallographic and photochromic properties of five 1-(1-cyclohexylmethane)-4,4′-bipyridinium-based complexes

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  50. Construction and Proton Conductivities of Multidimensional Isopolymolybdate-Based Metal–Organic Frameworks

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