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RESEARCH PAPER · Inorganic Chemistry · 2012

Tuning the Photochromic Properties of Molybdenum Bisphosphonate Polyoxometalates

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Tuning the Photochromic Properties of Molybdenum Bisphosphonate PolyoxometalatesOriginalDiphosphates and diphosphonates in polyoxometalate chemistry173Engineering polyoxometalates with emergent properties969Functionalized polyoxometalates with covalently linked bisphosphonate, N-donor or carboxylate ligands: from electrocatalytic to optical properties126Photo- and electrochromic properties of covalently connected symmetrical and unsymmetrical spiropyran–polyoxometalate dyads82Polyoxometalates Functionalized by Bisphosphonate Ligands: Synthesis, Structural, Magnetic, and Spectroscopic Characterizations and Activity on Tumor Cell Lines84Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties12Four Novel Oxomolybdenum-Organodiphosphonate Hybrids in the Presence of Cu(II)–Organonitrogen Building Blocks: Synthesis, Crystal Structures, and Surface Photovoltage Properties27Chromium, molybdenum and tungsten3Sulfonium Polyoxometalates: A New Class of Solid-State Photochromic Hybrid Organic–Inorganic Materials74Assembly of Dimeric and Tetrameric Complexes of Polyoxomolybdobisphosphonates Built from [(Mo3O8){O3PC(O)(CH2-3-C5NH5)PO3}]2– Subunits34An organic–inorganic hybrid Dy(III)-containing polyoxomolybdate based on functionalized diphosphonate ligands10Molybdenum Bisphosphonates with Cr(III) or Mn(III) Ions14Design and optical investigations of a spironaphthoxazine/polyoxometalate/spiropyran triad45Photosensitivity in Ce/Sm-decorated Keggin polyoxomolybdates: an interesting photoinduced coloration phenomenon of mixed-metal clusters involving energy transfer from rare-earth fluorescence9Tuning the structure of metal phosphonates using uncoordinating methyl group: syntheses, structures and properties of a series of metal diphosphonates22Investigation of the structure variation of metal diphosphonates with the changing of N-donor auxiliary ligands and their properties12Self‐Assembled Hybrid Molybdenum Phosphonate Porous Nanomaterials and Their Catalytic Activity for the Synthesis of Benzimidazoles28A durable and fast-responsive photochromic and switchable luminescent polyviologen–polyoxometalate hybrid64Controllable assembly of multicarboxylic acids functionalized heteropolyoxomolybdates and allochroic properties56Grafting transition metal–organophosphonate fragments onto heteropolyoxomolybdate: activity in photocatalysis23Organic–inorganic hybrid rare earth complexes based on polymolybdates with intrinsic photosensitive properties17DFT investigations on the structure and properties of MBP dimers and crystal with strong hydrogen-bonding interactions4Fully Oxidized and Mixed-Valent Polyoxomolybdates Structured by Bisphosphonates with Pendant Pyridine Groups: Synthesis, Structure and Photochromic Properties11Polyoxomolybdate Bisphosphonate Heterometallic Complexes: Synthesis, Structure, and Activity on a Breast Cancer Cell Line53Hybrid polyoxometalate materials for photo(electro-) chemical applications384Coordination Polymers of Increasing Complexity Derived from Alkali Metal Cations and (4-Amino-1-hydroxybutylidine)-1,1-bisphosphonic Acid (Alendronic Acid): The Competitive Influences of Coordination and Supramolecular Interactions11Covalent Attachment of Thiophene Groups to Polyoxomolybdates or Polyoxotungstates for the Formation of Hybrid Films9Reversible Luminescence Modulation upon Photochromic Reactions in Rare-Earth Doped Ferroelectric Oxides by in Situ Photoluminescence Spectroscopy106Aromatic Sulfonium Polyoxomolybdates: Solid‐State Photochromic Materials with Tunable Properties30Magnetic double-tartaric bridging mono-lanthanide substituted phosphotungstates with photochromic and switchable luminescence properties103Two multifunctional organic-inorganic hybrid complexes based on polyoxometalates, BiEDTA and sodium linker: crystal structures, photochromic, and catalytic performances4A novel Ni/Na – Containing inorganic-organic hybrid supramolecule based on polyoxometalate and EDTA with ultraviolet-visible light photochromism13Light-induced decarboxylation in a photo-responsive iron-containing complex based on polyoxometalate and oxalato ligands49Four transition-metal-bridging risedronate-based polyoxomolybdates: Syntheses, structures, characterizations and magnetic properties14Synthetic Considerations in the Self-Assembly of Coordination Polymers of Pyridine-Functionalized Hybrid Mn-Anderson Polyoxometalates37Engineering Multifunctionality in Hybrid Polyoxometalates: Aromatic Sulfonium Octamolybdates as Excellent Photochromic Materials and Self-Separating Catalysts for Epoxidation55A novel pored supramolecular compound (C4H6N3)2·(P2Mo18O62)·(C4H7N3)2·(H2O)4: synthesis, crystal structure and photochromic property2Structural Characterization of 2D Zirconomolybdate by Atomic Scale HAADF-STEM and XANES and Its Highly Stable Electrochemical Properties as a Li Battery Cathode5Aromatic sulfonium polyoxomolybdates: tuning the photochromic properties through substitutions on the counter ion moiety13Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation50Photochromic polypropylene fibers based on UV-responsive silica@phosphomolybdate nanoparticles through melt spinning technology38Photocoloration in Hybrid Amino Acid Polyoxometalates16Synthèse de polyoxométallates hybrides et étude de leurs propriétés en biologie et en optique0Ln( iii )-Containing polyoxomolybdates based on β-{Mo 8 O 28 }: microwave synthesis and optical and magnetic properties7Defect modulated luminescent and photochromic behaviors in Pr/Er codoped Na0.5Bi2.5Nb2O9 ceramics for display and optical storage32A novel photochromism material based on both pyrimidinium and polyoxometalate: (C4N2H4–C4N2H3) [Mn(H2O)6]0.5{SiW12O40}0.5ˑ5H2O13Effects of additive NH 3 with citric acid in the precursor and controlling the deposited thickness for growing molybdenum oxide crystals and nanorods9Synthèse et caractérisation de composites polyoxométallates / nanoparticules métalliques pour des applications biomédicales0Two photochromic hybrid materials assembled from naphthalene diimide as photocatalysts for the degradation of carcinogenic dye basic red 9 under visible light8Polyoxovanadates with Ethylidene-Pyridine Functionalized Bisphosphonate Ligands: Synthesis, Structure, Spectroscopic Characterization, Magnetic, and Antibacterial Studies23Assembly of a Hexameric Cluster of Polyoxomolybdotriphosphonate Builts from [Zn(H2O){TeMo6O21}{N(CH2PO3)3}]6– Subunits and Its Optical and Catalytic Properties18Bisphosphonates: Synthesis, structures, properties, medical and industrial applications20dl -Serine Covalently Ornamented and Ln 3+ -Incorporated Arsenotungstates with Fast-Responsive Photochromic and Photoinduced Luminescent Switchable Behaviors20dl -Alanine Covalently Bonded Giant Arsenotungstate with Rapid Photochromic and Decent Proton Conduction Properties17Layer-by-Layer Construction of a Nanoarchitecture by Polyoxometalates and Polymers: Enhanced Electrochemical Hydrogen Evolution Reaction28Diphosphoryl‐functionalized Polyoxometalates: Structurally and Electronically Tunable Hybrid Molecular Materials19Diphosphoryl‐functionalized Polyoxometalates: Structurally and Electronically Tunable Hybrid Molecular Materials3A Macrocyclic Polyoxomolybdate with Phosphate and Phosphonate Linkers: Synthesis, Structure, and Proton Conductivity8A Dawson-type {P 4 W 24 } modified using phenylphosphonic acid with excellent proton conductivity3A High Nucleus Cu-Incorporated Giant Phosphotungstate with Photocatalytic Oxidation C–H of Toluene6Nano-étoiles d'or décorées de polyoxométallates pour la thérapie combinatoire du cancer0Advanced Functional Photochromic Wearables with Superior Durability and Stability for Sustainable Applications18Chemo–Phototherapeutic Effect of Polyoxometalate-Stabilized Gold Nanostars for Cancer Treatment9Inorganic-organic hybrids of stannic-containing polyoxometalate and 2-aminopyridine: synthesis, characterization, and catalytic applications0Polyoxometalate-Based Self-Healing Photochromic Smart Windows for Excellent Solar Heat Management6Overview of organophosphonate covalently modified polyoxometalates: From synthesis and structural diversity to applications14Electrochemical Energy Storage Studies in 3d–3d Mixed-Metal Diphosphonate Oxovanadates: Structure–Property Correlation and Superior Performance of a Copper–Vanadium Electrode in Symmetric Supercapacitors0

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  1. Diphosphates and diphosphonates in polyoxometalate chemistry

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  2. Engineering polyoxometalates with emergent properties

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  3. Functionalized polyoxometalates with covalently linked bisphosphonate, N-donor or carboxylate ligands: from electrocatalytic to optical properties

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  4. Photo- and electrochromic properties of covalently connected symmetrical and unsymmetrical spiropyran–polyoxometalate dyads

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  5. Polyoxometalates Functionalized by Bisphosphonate Ligands: Synthesis, Structural, Magnetic, and Spectroscopic Characterizations and Activity on Tumor Cell Lines

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  6. Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties

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  7. Four Novel Oxomolybdenum-Organodiphosphonate Hybrids in the Presence of Cu(II)–Organonitrogen Building Blocks: Synthesis, Crystal Structures, and Surface Photovoltage Properties

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    Shou‐Hui Sun, Zhen‐Gang Sun, Yan‐Yu Zhu, Da‐Peng Dong, Cheng‐Qi Jiao, Jiang Miao Zhu, Jing Li, Wei Chu, Hui Tian, Mingjing Zheng, Wanyue Shao, Yan-Fei Lu

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  8. Chromium, molybdenum and tungsten

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  9. Sulfonium Polyoxometalates: A New Class of Solid-State Photochromic Hybrid Organic–Inorganic Materials

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  10. Assembly of Dimeric and Tetrameric Complexes of Polyoxomolybdobisphosphonates Built from [(Mo3O8){O3PC(O)(CH2-3-C5NH5)PO3}]2– Subunits

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  11. An organic–inorganic hybrid Dy(III)-containing polyoxomolybdate based on functionalized diphosphonate ligands

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  12. Molybdenum Bisphosphonates with Cr(III) or Mn(III) Ions

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  13. Design and optical investigations of a spironaphthoxazine/polyoxometalate/spiropyran triad

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  14. Photosensitivity in Ce/Sm-decorated Keggin polyoxomolybdates: an interesting photoinduced coloration phenomenon of mixed-metal clusters involving energy transfer from rare-earth fluorescence

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  15. Tuning the structure of metal phosphonates using uncoordinating methyl group: syntheses, structures and properties of a series of metal diphosphonates

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  16. Investigation of the structure variation of metal diphosphonates with the changing of N-donor auxiliary ligands and their properties

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  17. Self‐Assembled Hybrid Molybdenum Phosphonate Porous Nanomaterials and Their Catalytic Activity for the Synthesis of Benzimidazoles

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  18. A durable and fast-responsive photochromic and switchable luminescent polyviologen–polyoxometalate hybrid

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  19. Controllable assembly of multicarboxylic acids functionalized heteropolyoxomolybdates and allochroic properties

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  20. Grafting transition metal–organophosphonate fragments onto heteropolyoxomolybdate: activity in photocatalysis

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  21. Organic–inorganic hybrid rare earth complexes based on polymolybdates with intrinsic photosensitive properties

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  22. DFT investigations on the structure and properties of MBP dimers and crystal with strong hydrogen-bonding interactions

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  23. Fully Oxidized and Mixed-Valent Polyoxomolybdates Structured by Bisphosphonates with Pendant Pyridine Groups: Synthesis, Structure and Photochromic Properties

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  24. Polyoxomolybdate Bisphosphonate Heterometallic Complexes: Synthesis, Structure, and Activity on a Breast Cancer Cell Line

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  27. Covalent Attachment of Thiophene Groups to Polyoxomolybdates or Polyoxotungstates for the Formation of Hybrid Films

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  29. Aromatic Sulfonium Polyoxomolybdates: Solid‐State Photochromic Materials with Tunable Properties

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  30. Magnetic double-tartaric bridging mono-lanthanide substituted phosphotungstates with photochromic and switchable luminescence properties

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  31. Two multifunctional organic-inorganic hybrid complexes based on polyoxometalates, BiEDTA and sodium linker: crystal structures, photochromic, and catalytic performances

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  32. A novel Ni/Na – Containing inorganic-organic hybrid supramolecule based on polyoxometalate and EDTA with ultraviolet-visible light photochromism

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  33. Light-induced decarboxylation in a photo-responsive iron-containing complex based on polyoxometalate and oxalato ligands

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  34. Four transition-metal-bridging risedronate-based polyoxomolybdates: Syntheses, structures, characterizations and magnetic properties

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  35. Synthetic Considerations in the Self-Assembly of Coordination Polymers of Pyridine-Functionalized Hybrid Mn-Anderson Polyoxometalates

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  36. Engineering Multifunctionality in Hybrid Polyoxometalates: Aromatic Sulfonium Octamolybdates as Excellent Photochromic Materials and Self-Separating Catalysts for Epoxidation

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  38. Structural Characterization of 2D Zirconomolybdate by Atomic Scale HAADF-STEM and XANES and Its Highly Stable Electrochemical Properties as a Li Battery Cathode

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  39. Aromatic sulfonium polyoxomolybdates: tuning the photochromic properties through substitutions on the counter ion moiety

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  40. Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation

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  41. Photochromic polypropylene fibers based on UV-responsive silica@phosphomolybdate nanoparticles through melt spinning technology

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  42. Photocoloration in Hybrid Amino Acid Polyoxometalates

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  49. Two photochromic hybrid materials assembled from naphthalene diimide as photocatalysts for the degradation of carcinogenic dye basic red 9 under visible light

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