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RESEARCH PAPER · Dalton Transactions · 2016

Na 3 Y 3 (BO 3 ) 4 : a new noncentrosymmetric borate with an open-framework structure

Faxian Shan, Lei Kang, Guochun Zhang, Jiyong Yao, Zheshuai Lin, Mingjun Xia, Xinyuan Zhang, Ying Fu, Yicheng Wu

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Na 3 Y 3 (BO 3 ) 4 : a new noncentrosymmetric borate with an open-framework structureOriginalPositive and negative contribution to birefringence in a family of carbonates: A Born effective charges analysis36LiRb 2 LaB 2 O 6 : a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge14Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties17LiCs 2 La(BO 3 ) 2 and Li 3 K 9 La 3 (BO 3 ) 7 : new mixed alkali metal lanthanum borates with three-dimensional open frameworks and short cut-off edges10A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses103The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups195Y2(CO3)3·H2O and (NH4)2Ca2Y4(CO3)9·H2O: Partial Aliovalent Cation Substitution Enabling Evolution from Centrosymmetry to Noncentrosymmetry for Nonlinear Optical Response37KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer18Non-concentration quenching, good thermal stability and high quantum efficiency of K 5 Y(P 2 O 7 ) 2 :Eu 3+ /Tb 3+ phosphors with a novel two-dimensional layer structure78Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block18Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)28A new non-centrosymmetric Gd-based borate crystal Rb 7 SrGd 2 (B 5 O 10 ) 3 : growth, structure, and nonlinear optical and magnetic properties24Design, synthesis, crystal structure and luminescent properties introduced by Eu 3+ of a new type of rare-earth borophosphate CsNa 2 REE 2 (BO 3 )(PO 4 ) 2 (REE = Y, Gd)23Synthesis and characterization of three new rare-earth orthoborates: Ba 2 MgY 2 (BO 3 ) 4 , Ba 2 CdY 2 (BO 3 ) 4 , and Ba 2 CdSc(BO 3 ) 310Two New Ferroborates with Three‐Dimensional Framework and Wide Transmittance Window2New double holmium borates: Rb3HoB6O12 and Rb3Ho2B3O910Syntheses, structure determination and characterization of two novel non-centrosymmetric mixed alkali rare-earth orthoborates: K3Li3RE7(BO3)9 (RE=Dy, Tb)7Synthesis and crystal structures of novel alkali rare-earth orthoborates K3RE3(BO3)4 (RE = Pr, Nd, Sm–Lu)19Synthesis, crystal structure, and thermal stability of double borate Na3ErB2O62Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge8Synthesis and Growth of Rare Earth Borates NaSrR(BO3)2 (R = Ho–Lu, Y, Sc)19Growth and characterization of Na 3 R(BO 3 ) 2 (R = La–Gd) borates: crystal structure, high-temperature behavior, and optical properties7KNa 2 La 2 (BO 3 ) 3 : a shortite-type lanthanide borate exhibiting strong nonlinear optical activity induced by isolated [BO 3 ] triangles and distorted [LaO 9 ] polyhedra26Thermal expansion and ionic conductivity of Na3Sc(BO3)2 and Na3Sc2(BO3)34A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates18Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Hydroflux Synthesis and Structural Phase Transition of Rare‐Earth Borate Hydroxides Na2[RE(BO3)(OH)2] (RE=Y, Gd−Er)7Phase Relations Between Na3Nd(BO3)2, Na3Nd2(BO3)3, NdBO3 and Their Luminescence Properties3K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response10A new structure type of the Na3Yb(BO3)2: Synthesis, crystal structure, thermal behavior, ionic conductivity, and spectroscopy2Phase formation in ternary systems of sodium, rare-earth (scandium, indium, and ytterbium), and boron oxides0Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials1

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  1. Positive and negative contribution to birefringence in a family of carbonates: A Born effective charges analysis

    Journal of Solid State Chemistry · 2016-09-09

    Qun Jing, Guang Yang, Juan Hou, Maozhu Sun, Haibin Cao

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  2. LiRb 2 LaB 2 O 6 : a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge

    Dalton Transactions · 2016-11-28

    Dongdong Xu, Fangfang Zhang, Yanzhou Sun, Zhihua Yang, Bing‐Hua Lei, Lili Liu, Shilie Pan

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  3. Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties

    Inorganic Chemistry · 2017-06-23

    Molin Zhou, Xingxing Jiang, Yangwu Guo, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  4. LiCs 2 La(BO 3 ) 2 and Li 3 K 9 La 3 (BO 3 ) 7 : new mixed alkali metal lanthanum borates with three-dimensional open frameworks and short cut-off edges

    Dalton Transactions · 2018-01-01

    Ruru Ma, Yun Mo Yang, Cong Hu, Xiaoyu Dong, Zhihua Yang, Shilie Pan

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  5. A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses

    Chemistry of Materials · 2018-03-08

    Zhiqing Xie, Miriding Mutailipu, Guijie He, Guopeng Han, Ying Wang, Zhihua Yang, Min Zhang, Shilie Pan

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  6. The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups

    Coordination Chemistry Reviews · 2018-04-06

    Yaoguo Shen, Sangen Zhao, Junhua Luo

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  7. Y2(CO3)3·H2O and (NH4)2Ca2Y4(CO3)9·H2O: Partial Aliovalent Cation Substitution Enabling Evolution from Centrosymmetry to Noncentrosymmetry for Nonlinear Optical Response

    Chemistry of Materials · 2018-12-12

    Guang Peng, Chensheng Lin, Yi Jin Yang, Dan Zhao, Zheshuai Lin, Ning Ye, Jin‐Shun Huang

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  8. KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer

    Dalton Transactions · 2019-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Ting Wang, Yao Guo, Xiao‐Fang Guan, Xian‐Ming Zhang

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  9. Non-concentration quenching, good thermal stability and high quantum efficiency of K 5 Y(P 2 O 7 ) 2 :Eu 3+ /Tb 3+ phosphors with a novel two-dimensional layer structure

    Journal of Materials Chemistry C · 2019-01-01

    Dan Zhao, Ya-Li Xue, Shirui Zhang, Lin‐Ying Shi, Baozhong Liu, Yan-Ping Fan, Qingxia Yao, Shao-Jie Dai

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  10. Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block

    Inorganic Chemistry Frontiers · 2019-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhizhong Zhang, Zhihua Yang, Shilie Pan

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  11. Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)

    Science China Materials · 2019-03-22

    Zhiqing Xie, Ying Wang, Shichao Cheng, Guopeng Han, Zhihua Yang, Shilie Pan

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  12. A new non-centrosymmetric Gd-based borate crystal Rb 7 SrGd 2 (B 5 O 10 ) 3 : growth, structure, and nonlinear optical and magnetic properties

    Dalton Transactions · 2020-01-01

    Wang Liu, Xiaomeng Liu, Jun Shen, Yunfei Li, Huimin Song, Jingcheng Feng, Zheshuai Lin, Guochun Zhang

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  13. Design, synthesis, crystal structure and luminescent properties introduced by Eu 3+ of a new type of rare-earth borophosphate CsNa 2 REE 2 (BO 3 )(PO 4 ) 2 (REE = Y, Gd)

    Dalton Transactions · 2020-01-01

    Dan Zhao, Yali Xue, Ruijuan Zhang, Yan-Ping Fan, Baozhong Liu, Yanan Li, Shirui Zhang

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  14. Synthesis and characterization of three new rare-earth orthoborates: Ba 2 MgY 2 (BO 3 ) 4 , Ba 2 CdY 2 (BO 3 ) 4 , and Ba 2 CdSc(BO 3 ) 3

    Dalton Transactions · 2020-01-01

    Runqing Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  15. Two New Ferroborates with Three‐Dimensional Framework and Wide Transmittance Window

    European Journal of Inorganic Chemistry · 2020-03-19

    Huimin Song, Naizheng Wang, Yunfei Li, Wang Liu, Zheshuai Lin, Jiyong Yao, Guochun Zhang

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  16. New double holmium borates: Rb3HoB6O12 and Rb3Ho2B3O9

    Solid State Sciences · 2020-04-22

    Alexey Karpovich Subanakov, Evgeniy V. Kovtunets, Баир Гармаевич Базаров, Sesegma G. Dorzhieva, Jibzema G. Bazarova

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  17. Syntheses, structure determination and characterization of two novel non-centrosymmetric mixed alkali rare-earth orthoborates: K3Li3RE7(BO3)9 (RE=Dy, Tb)

    Solid State Sciences · 2020-10-01

    P.Y. Chen, Guirong Wang

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  18. Synthesis and crystal structures of novel alkali rare-earth orthoborates K3RE3(BO3)4 (RE = Pr, Nd, Sm–Lu)

    Journal of Materials Science · 2020-11-06

    Pengyun Chen, M. Mangir Murshed, Thorsten M. Gesing

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  19. Synthesis, crystal structure, and thermal stability of double borate Na3ErB2O6

    Chimica Techno Acta · 2021-10-20

    Alexey Karpovich Subanakov, Evgeniy V. Kovtunets, Баир Гармаевич Базаров, Jibzema G. Bazarova

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  20. Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Jianlong Huang, Chengfa Wu, Jianbang Chen, Zhiyong Guo, Wenjuan Ma, Feng Yu, Bin Dai

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  21. Synthesis and Growth of Rare Earth Borates NaSrR(BO3)2 (R = Ho–Lu, Y, Sc)

    Inorganic Chemistry · 2022-05-03

    Artem B. Kuznetsov, К. А. Кох, Nursultan E. Sagatov, Pavel N. Gavryushkin, Мaxim S. Моlokeev, В. А. Светличный, Лапин Иван Николаевич, Nadezda G. Kononova, Vyacheslav S. Shevchenko, Asset Bolatov, Bolat Uralbekov, A. A. Goreyavcheva, Alexander E. Kokh

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  22. Growth and characterization of Na 3 R(BO 3 ) 2 (R = La–Gd) borates: crystal structure, high-temperature behavior, and optical properties

    CrystEngComm · 2023-01-01

    Artem B. Kuznetsov, Ammar Y. Jamous, В. А. Светличный, Sergey N. Volkov, Ilya V. Korolkov, К. А. Кох, Liudmila A. Gorelova, Maria Georgievna Krzhizhanovskaya, Sergey M. Aksenov, Alexander E. Kokh

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  23. KNa 2 La 2 (BO 3 ) 3 : a shortite-type lanthanide borate exhibiting strong nonlinear optical activity induced by isolated [BO 3 ] triangles and distorted [LaO 9 ] polyhedra

    Inorganic Chemistry Frontiers · 2023-01-01

    Jie Song, Conggang Li, Jinmiao Jiao, Yuheng She, Wenli Zhao, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu

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  24. Thermal expansion and ionic conductivity of Na3Sc(BO3)2 and Na3Sc2(BO3)3

    Solid State Sciences · 2023-12-02

    Evgeniy V. Kovtunets, Alexey Karpovich Subanakov, Tatyana Sergeevna Spiridonova, Баир Гармаевич Базаров, Andrey Sobolev, Jibzema G. Bazarova

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  25. A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates

    Chemical Science · 2024-01-01

    Jie Song, Huijian Zhao, Conggang Li, Ning Ye, Zhanggui Hu, Yicheng Wu

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  26. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  27. Hydroflux Synthesis and Structural Phase Transition of Rare‐Earth Borate Hydroxides Na2[RE(BO3)(OH)2] (RE=Y, Gd−Er)

    Chemistry - A European Journal · 2024-08-28

    Yuxi Li, Eduardo Carrillo‐Aravena, Jiang Qu, Gohil Singh Thakur, Michael Ruck

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  28. Phase Relations Between Na3Nd(BO3)2, Na3Nd2(BO3)3, NdBO3 and Their Luminescence Properties

    Journal of Structural Chemistry · 2024-09-01

    Artem B. Kuznetsov, Ammar Y. Jamous, В. А. Светличный, K. A. Kokh

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  29. K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response

    Inorganic Chemistry · 2024-12-07

    Fanlu Bu, Xiaorong Liu, Hongwei Yu, Runqing Liu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  30. A new structure type of the Na3Yb(BO3)2: Synthesis, crystal structure, thermal behavior, ionic conductivity, and spectroscopy

    Solid State Sciences · 2024-12-31

    Alexey Karpovich Subanakov, Evgeniy V. Kovtunets, Tatyana Sergeevna Spiridonova, Andrey Sobolev, Мaxim S. Моlokeev, Dmitry Olegovich Sofich, Alexandr Bogdanov, Баир Гармаевич Базаров

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  31. Phase formation in ternary systems of sodium, rare-earth (scandium, indium, and ytterbium), and boron oxides

    Proceedings of universities Applied chemistry and biotechnology · 2025-05-27

    Alexey Karpovich Subanakov, Evgeniy V. Kovtunets, A. N. Sobolev, A. S. Tankhaeva

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  32. Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials

    Materials Today Physics · 2026-07-04

    D K Li, Yujie Zhang, H Liu, Hongping Wu, Zhanggui Hu, Hongwei Yu

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