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RESEARCH PAPER · Angewandte Chemie International Edition · 2008

Open‐Framework Structures of Transition‐Metal Compounds

Srinivasan Natarajan, Sukhendu Bikas Mandal

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Open‐Framework Structures of Transition‐Metal CompoundsOriginalSynthesis and characterization of a cadmium germanium phosphate CdGe(OH)3PO4 with an open framework14ChemInform Abstract: Open‐Framework Structures of Transition‐Metal Compounds0Cooperative Self-Assembly of Chiral l -Malate and Achiral Succinate in the Formation of a Three-Dimensional Homochiral Framework31New indium selenite-oxalate and indium oxalate with two- and three-dimensional structures11Absolute helicity induction in three-dimensional homochiral frameworks98Crystal structure of barium distannide, BaSn215Crystal structure of barium iron(II) (monophosphate-hydrogenmonoborate- monophosphate), BaFe[BP2O8(OH)]1Adsorption–desorption and photocatalytic properties of inorganic–organic hybrid cadmium thiosulfate compounds83Magnetic and Porous Molecule-Based Materials56MOF-5/n-Bu4NBr: an efficient catalyst system for the synthesis of cyclic carbonates from epoxides and CO2 under mild conditions484Organically templated open-framework phosphites85Synthesis of a metal–organic framework film by direct conversion technique for VOCs sensing124The first observation of a Na2TiS2 related structure in a 2-D anionic manganese trimesate intercalated by cationic imidazole,8Water soluble synthetic dieptide-based biodegradable nanoporous materials15Synthesis, Characterization, and Properties of Organically Templated Lanthanide Oxalatophosphates with a Three-Dimensional Honeycomb Structure: (H4APPIP)[Ln3(C2O4)5.5(H2PO4)2]·5H2O (Ln = Er−Lu, APPIP = 1,4-Bis(3-aminopropyl)piperazine)20Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]·H2O, a New Organically Templated Neodymium(III) Oxalate‐sulfate9Nanoporous Crystals of Calixarene/Porphyrin Supramolecular Complex Functionalized by Diffusion and Coordination of Metal Ions62Hydrothermal synthesis, crystal structure and physical properties of a new gadolinium phosphite hydrate11Effect of structural and thermodynamic factors on the sorption of hydrogen by metal–organic framework compounds26Synthesis and Crystal Structure of SrFe[BP2O8(OH)2]5Cobalt−Oxo Core of a Water-Oxidizing Catalyst Film281Fluorite and Mixed‐Metal Kagome‐Related Topologies in Metal–Organic Framework Compounds: Synthesis, Structure, and Properties15Synthesis, characterization and magnetic property of a new 3D iron phosphite: |C4N3H14|[Fe3(HPO3)4F2(H2O)2] with intersecting channels7Control of Channel Size for Selective Guest Inclusion with Inlaid Anionic Building Blocks in a Porous Cationic Metal–Organic Host Framework40Design, structure, and properties of functional metal–ligand inorganic modules9Non-carboxylate based metal-organic frameworks (MOFs) and related aspects25Synthesis of Novel Organic−Inorganic Hybrid Compounds: Lanthanide Phosphites Incorporating a Squarate Ligand13One‐Dimensional Coordination Polymers of MnII, CuII, and ZnII Supported by Carboxylate‐Appended (2‐Pyridyl)alkylamine Ligands – Structure and Magnetism26Synthesis, structure and magnetic behavior of a new three-dimensional Manganese phosphite-oxalate: [C2N2H10][Mn2II(OH2)2(HPO3)2(C2O4)]9Atomistic theoretical models for nanoporous hybrid materials49Metal–Organic Frameworks: Opportunities for Catalysis1888Metall‐organische Gerüste für die Katalyse216Organic template-directed indium phosphite-oxalate hybrid material: Synthesis and characterization of a novel 3D |C6H14N2|[In2(HPO3)3(C2O4)] compound with intersecting channels17Lanthanum Phosphite Microspheres: Hydrothermal Synthesis, Ab Initio Structure Determination, Morphology and Photoluminescence of La(HO)(HPO3)4Preparation of Inorganic Materials Using Ionic Liquids777Flux synthesis of (3,4)-connected zinc phosphites with different framework topologies12Natural gas treating by selective adsorption: Material science and chemical engineering interplay468A new organically templated vanadium tellurite: (H2dien)[(VO2)(TeO3)]2·2H2O (dien is diethylenetriamine)5New organically templated vanadium tellurites: (H2pn)[V2TeO8] (pn is propane-1,3-diamine)3Facile fabrication of metal–organic framework films promoted by colloidal seeds on various substrates29Silver(I) coordination polymers self-assembled through methanolysis of pyrazinecarbonitrile: Structure and photoluminescence6Catalytic performance of the high and low temperature polymorphs of (C 6 N 2 H 16 ) 0.5 [(VO)(HAsO 4 )F]: structural, thermal, spectroscopic and magnetic studies12Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium36Recent advances in crystal engineering746A new open-framework zinc arsenate [C4N3H16]2[Zn5(AsO4)4(HAsO4)2]4The First Organic-Templated Vanadyl(IV) Gallophosphates with Ambient 51V Hyperfine Structure, {V2Ga2O14} Cluster or Heterometal 12-Ring Channels9Structural Transformation of Three‐Dimensional Bimetallic Phosphites Containing Corner‐Sharing 4‐Ring Chains8[B4O9H2] Cyclic Borate Units as the Building Unit in a Family of Zinc Borate Structures58Jahn−Teller Distorted Frameworks and Magnetic Order in the Rb−Mn−P−O System5Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials54Coordination polymers using (2-pyridyl)alkylamine-appended carboxylates: magnetic properties40Crystal chemistry of cadmium oxysalt and associated minerals from Broken Hill, New South Wales.0Structural chemistry of organically-templated metal fluorides61Synthesis and structural comparisons of five new fluorinated metal organic frameworks (F-MOFs)68Synthesis, structure, transformation studies and catalytic properties of open-framework cadmium thiosulfate compounds32Amine-Templated Aluminoborates Exhibiting Graphite and Diamond Nets35Flux synthesis of two new open-framework zinc phosphites with 16-ring channels9Synthesis, structure and solid state NMR analysis of a new templated titanium(III/IV) fluorophosphate4The first organically templated gallium phosphite–oxalates: Synthesis, structures, and characterizationseer11Two- and Three-Dimensional Open-Framework Uranium Arsenates: Synthesis, Structure, and Characterization18Hierarchy of structures in the family of amine templated open-framework gallium arsenates2Design of open-framework germanates23Synthesis, Structure, and Magnetic Properties of Amine‐Templated Transition‐Metal Phosphites14Synthesis and Characterization of New Open-Framework Vanadium Tellurite Featuring an Unprecedented (3,7)-Connected Network: K3[(VVO4)(VIVO)4(TeO3)4]·4H2O3Two new layered bimetallic sulfides: Solvothermal synthesis, crystal structure, optical and magnetic properties25Hydrothermal synthesis and characterization of a new organically templated three-dimensional open-framework gallium phosphate–phosphite (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O9Ionothermal synthesis and crystal structures of metal phosphate chains13Germanate Frameworks Constructed from Oxo Germanium Cluster Building Units40Zinc Germanates Incorporating Organic Amine Ligands: Solvothermal Synthesis and Structural Characterization of Zn2Ge4O10(NH2CH2CH2CH2NH2) and ZnGe2O5(NH2CH2CH2NH2)8Untypical [VOPO4]−Layer in Vanadyl Phosphates with Variant Interlayer Gap of Double-Tiered Template3Abscheidung von Kohlendioxid: Perspektiven für neue Materialien291Carbon Dioxide Capture: Prospects for New Materials4033Use of Polyazaheterocycles in the Assembly of New Cadmium Sulfate Frameworks: Synthesis, Structure, and Properties38Water Stable Zr–Benzenedicarboxylate Metal–Organic Frameworks as Photocatalysts for Hydrogen Generation866Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-17Synthesis and crystal structure of a new open-framework iron phosphate (NH4)4Fe3(OH)2F2[H3(PO4)4]: Novel linear trimer of corner-sharing Fe(III) octahedra18Ordered Porous Crystalline Transition Metal Oxides5Structures and H2 Adsorption Properties of Porous Scandium Metal–Organic Frameworks87Double magnetic phase transition in ND4Fe(DPO4)2 and NH4Fe(HPO4)210Investigation of the structure and phase transitions of the polymeric inorganic–organic hybrids: [M(Im)4V2O6]∞; M = Mn, Co, Ni, Im = imidazole1Framework-structured weak ferromagnets407Molecular transition-metal phosphonates83Syntheses and characterizations of heteroatom-containing open-framework aluminophosphates6Synthesis of hydrophobic layered luminescent films: Organic–inorganic hybrid mono-n-dodecyloxy-phosphinyl-cerium (terbium)2Vanadium fluoroarsenates—folding sheets into highly corrugated layers and crystalline arrays of large inorganic tubes5Ionothermal Syntheses and Characterizations of New Open-Framework Metal Borophosphates25Synthesis of cyclic carbonates and dimethyl carbonate using CO2 as a building block catalyzed by MOF-5/KI and MOF-5/KI/K2CO335A Cubic, 12-Connected, Microporous Metal−Organometallic Phosphate Framework Sustained by Truncated Tetrahedral Nodes57Rational Assembly of Soluble Copper(II) Phosphonates: Synthesis, Structure and Magnetism of Molecular Tetranuclear Copper(II) Phosphonates41Lanthanide Sulfate Frameworks: Synthesis, Structure, and Optical Properties31Inorganic Supramolecular Compounds with 3-D Chiral Frameworks Show Potential as Both Mid-IR Second-Order Nonlinear Optical and Piezoelectric Materials132New open-framework phosphate and phosphite compounds of gallium18Flux synthesis of two new organically templated zinc phosphites with different 3,4-connected frameworks7NaSc3[HPO3]2[HPO2(OH)]6: Synthesis, Crystal Structure, and Thermal Decomposition7Fluoride-Rich, Hydrofluorothermal Routes to Functional Transition Metal (Mn, Fe, Co, Cu) Fluorophosphates77Synthesis and characterization of three open-framework zinc phosphites with (3,4)-connected frameworks6Tetrahedral/octahedral frameworks with different local interruptions: Syntheses and structures of two new inorganic niobium phosphates3Unprecedented Zeolite-Like Framework Topology Constructed from Cages with 3-Rings in a Barium Oxonitridophosphate47Li1.43[FeII4.43FeIII0.57(HPO3)6]·1.5H2O: A Phosphite Oxoanion-Based Compound with Lithium Exchange Capability and Spin-Glass Magnetic Behavior41Fluoridized iron phosphate as a novel adsorbent for selective separation/isolation of cytochrome c9Powder neutron diffraction investigation of the crystal and magnetic structures of NH4Fe(HPO4)2and its deuterated form4Structural systematic design of organic templated samarium sulfates and their luminescence property14Distorted cubic tetranuclear vanadium(iv) phosphonate cages: double-four-ring (D4R) containing transition metal ion phosphonate cages29Position of substituent dependent dimensionality in Ln–Cu heterometallic coordination polymers14Adsorption complexes of copper and copper oxide in the deep eutectic solvent 2:1 urea–choline chloride64A facile route for preparing a mesoporous palladium coordination polymer as a recyclable heterogeneous catalyst25A series of new rare earth sulfates based on lanthanide contraction and dual organic-amine templating effects12Cobalt(ii) fluorophosphate frameworks19Conductive metal–organic frameworks and networks: fact or fantasy?290Copper(ii) fluorophosphates17Gas sorption and luminescence properties of a terbium(iii)-phosphine oxide coordination material with two-dimensional pore topology42LO and "Synergic" Framework-to-Template O-HLN Hydrogen Bonds and C-HLO Interactions (APA = 2-Amino-1-phenyleneammonium, C 6H9N2 + )0Mixed Ni–Cu-oxide nanowire array on conductive substrate and its application as enzyme-free glucose sensor46Synthesis, structure and band gap energy of covalently linked cluster-assembled materials33Synthesis, structures and properties of the new lithium cobalt(II) phosphate Li4Co(PO4)210Neutron powder diffraction investigation in ammonium iron(III) bis (hydrogenphosphate)3Poly[octakis(1H-imidazole-κN3)octa-μ-oxido-tetraoxidodicopper(II)tetravanadate(V)]1Hydrothermal synthesis of three-dimensional open-framework beryllium phosphites with 3,4-connected networks6Two Unusual Chiral Lanthanide–Sulfate Frameworks with Helical Tubes and Channels Constructed from Interweaving Two Double-Helical Chains26Deposition of Metal Clusters into the Functionalized Metal Organic Frameworks0Redox‐Active Metal‐Centered Oxalato Phosphate Open Framework Cathode Materials for Lithium Ion Batteries169Redox‐Active Metal‐Centered Oxalato Phosphate Open Framework Cathode Materials for Lithium Ion Batteries29Syntheses and structures of two open-framework zinc phosphites with extra-large 24-ring channels19Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity52From dihydrated iron(III) phosphate to monohydrated ammonium–iron(II) phosphate: Solvothermal reaction mediated by acetone–urea mixtures11Synthesis, characterization and template removal of an iron-containing aluminophosphate molecular sieve with LAU topology5APA2[Zn3(HPO4)4(H2O)2], a Layered Zincophosphate Featuring Template-to-Framework N–H⋯O and “Synergic” Framework-to-Template O–H⋯N Hydrogen Bonds and C–H⋯O Interactions (APA = 2-Amino-1-phenyleneammonium, C6H9N2+)2Construction of two novel indium phosphites with (3,6)- and (3,5)-connected frameworks: Synthesis, structure and characterization13Hydrothermal synthesis and structural characterisation of [H 2 DABCO] 3 [Cu 16 Cl 22 ]: a new copper( i ) chloride framework15The synthesis, structure and magnetism studies of two manganese sulfates with a 3D zeolite GIS framework and 1D chain structure8Six novel transition-metal phosphite compounds, with structure related to yavapaiite: Crystal structures and magnetic and thermal properties of AI[MIII(HPO3)2] (A=K, NH4, Rb and M=V, Fe)30Manganese(iii) fluorophosphate frameworks26An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19Complex anion inclusion compounds: flexible anion-exchange materials17A hybrid metal phosphate–phosphite material grafted with electron deficient organic components showing interesting fluorescent and photosensitive properties72A layered oxalatophosphate framework as a cathode material for Li-ion batteries85Amine templated open-framework vanadium(iii) phosphites with catalytic properties34Copper rubidium diphosphate, Rb2Cu3(P2O7)2: synthesis, crystal structure, thermodynamic and resonant properties8Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials18In situ template generation via N-alkylation in the syntheses of open-framework zinc phosphites and phosphate29Solvent-free synthesis of new manganese phosphate–oxalate hybrid solids15Two new piperazine templated lanthanide sulfates with 2D corrugated layered crystal structures5An inorganic–organic hybrid zinc phosphite framework with unusual topology9Solvothermal synthesis of new open-framework metal phosphites with structure-directing agents generated in situ6(C4N2H12)3[Ln3(OH)(SO4)7] (Ln = Sm, Eu, and Tb): A Series of Honeycomb-like Open-Framework Lanthanide Sulfates with Extra-Large Channels Containing 24-Membered Rings31Improving the flame retardancy and mechanical properties of high-density polyethylene-g-maleic anhydride with a novel organic metal phosphonate21Solvent-free synthesis of new metal phosphite structures varying from 1D chain to 2D slab and 3D network9Synthesis of Cerium N-Morpholinomethylphosphonic Acid and Its Flame Retardant Application in High Density Polyethylene16Development of hydrogen-selective CAU-1 MOF membranes for hydrogen purification by ‘dual-metal-source’ approach96Ammonium diphosphitoindate(III)6

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  1. Synthesis and characterization of a cadmium germanium phosphate CdGe(OH)3PO4 with an open framework

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  2. ChemInform Abstract: Open‐Framework Structures of Transition‐Metal Compounds

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  3. Cooperative Self-Assembly of Chiral l -Malate and Achiral Succinate in the Formation of a Three-Dimensional Homochiral Framework

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  4. New indium selenite-oxalate and indium oxalate with two- and three-dimensional structures

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  5. Absolute helicity induction in three-dimensional homochiral frameworks

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  6. Crystal structure of barium distannide, BaSn2

    Zeitschrift für Kristallographie - New Crystal Structures · 2008-12-01

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  7. Crystal structure of barium iron(II) (monophosphate-hydrogenmonoborate- monophosphate), BaFe[BP2O8(OH)]

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    Prashanth Wilfred Menezes, S.D. Hoffmann, Yurii M. Prots', Rüdiger Kniep

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  8. Adsorption–desorption and photocatalytic properties of inorganic–organic hybrid cadmium thiosulfate compounds

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  9. Magnetic and Porous Molecule-Based Materials

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  10. MOF-5/n-Bu4NBr: an efficient catalyst system for the synthesis of cyclic carbonates from epoxides and CO2 under mild conditions

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  11. Organically templated open-framework phosphites

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  12. Synthesis of a metal–organic framework film by direct conversion technique for VOCs sensing

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  13. The first observation of a Na2TiS2 related structure in a 2-D anionic manganese trimesate intercalated by cationic imidazole,

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  14. Water soluble synthetic dieptide-based biodegradable nanoporous materials

    Green Chemistry · 2009-01-01

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  15. Synthesis, Characterization, and Properties of Organically Templated Lanthanide Oxalatophosphates with a Three-Dimensional Honeycomb Structure: (H4APPIP)[Ln3(C2O4)5.5(H2PO4)2]·5H2O (Ln = Er−Lu, APPIP = 1,4-Bis(3-aminopropyl)piperazine)

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  16. Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]·H2O, a New Organically Templated Neodymium(III) Oxalate‐sulfate

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  17. Nanoporous Crystals of Calixarene/Porphyrin Supramolecular Complex Functionalized by Diffusion and Coordination of Metal Ions

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    Rita De Zorzi, N. Guidolin, Lucio Randaccio, Roberto Purrello, Silvano Geremia

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  18. Hydrothermal synthesis, crystal structure and physical properties of a new gadolinium phosphite hydrate

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  19. Effect of structural and thermodynamic factors on the sorption of hydrogen by metal–organic framework compounds

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  20. Synthesis and Crystal Structure of SrFe[BP2O8(OH)2]

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  21. Cobalt−Oxo Core of a Water-Oxidizing Catalyst Film

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  22. Fluorite and Mixed‐Metal Kagome‐Related Topologies in Metal–Organic Framework Compounds: Synthesis, Structure, and Properties

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  23. Synthesis, characterization and magnetic property of a new 3D iron phosphite: |C4N3H14|[Fe3(HPO3)4F2(H2O)2] with intersecting channels

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  24. Control of Channel Size for Selective Guest Inclusion with Inlaid Anionic Building Blocks in a Porous Cationic Metal–Organic Host Framework

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  25. Design, structure, and properties of functional metal–ligand inorganic modules

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  26. Non-carboxylate based metal-organic frameworks (MOFs) and related aspects

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  27. Synthesis of Novel Organic−Inorganic Hybrid Compounds: Lanthanide Phosphites Incorporating a Squarate Ligand

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  28. One‐Dimensional Coordination Polymers of MnII, CuII, and ZnII Supported by Carboxylate‐Appended (2‐Pyridyl)alkylamine Ligands – Structure and Magnetism

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  29. Synthesis, structure and magnetic behavior of a new three-dimensional Manganese phosphite-oxalate: [C2N2H10][Mn2II(OH2)2(HPO3)2(C2O4)]

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  30. Atomistic theoretical models for nanoporous hybrid materials

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  31. Metal–Organic Frameworks: Opportunities for Catalysis

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  32. Metall‐organische Gerüste für die Katalyse

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  33. Organic template-directed indium phosphite-oxalate hybrid material: Synthesis and characterization of a novel 3D |C6H14N2|[In2(HPO3)3(C2O4)] compound with intersecting channels

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  34. Lanthanum Phosphite Microspheres: Hydrothermal Synthesis, Ab Initio Structure Determination, Morphology and Photoluminescence of La(HO)(HPO3)

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  35. Preparation of Inorganic Materials Using Ionic Liquids

    Advanced Materials · 2009-09-08

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  36. Flux synthesis of (3,4)-connected zinc phosphites with different framework topologies

    Journal of Solid State Chemistry · 2009-09-11

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  37. Natural gas treating by selective adsorption: Material science and chemical engineering interplay

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  38. A new organically templated vanadium tellurite: (H2dien)[(VO2)(TeO3)]2·2H2O (dien is diethylenetriamine)

    Acta Crystallographica Section C Crystal Structure Communications · 2009-09-17

    Xi‐He Huang, Zhongqian Liu, Chang‐Cang Huang, Lijuan Shen, Xiaobao Yan

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  39. New organically templated vanadium tellurites: (H2pn)[V2TeO8] (pn is propane-1,3-diamine)

    Acta Crystallographica Section C Crystal Structure Communications · 2009-09-25

    Xi‐He Huang, Zhongqian Liu, Chang‐Cang Huang, Lijuan Shen, Xiaobao Yan

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  40. Facile fabrication of metal–organic framework films promoted by colloidal seeds on various substrates

    CrystEngComm · 2009-10-01

    Xiaoqin Zou, Guangshan Zhu, Feng Zhang, Mingyi Guo, Shilun Qiu

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  41. Silver(I) coordination polymers self-assembled through methanolysis of pyrazinecarbonitrile: Structure and photoluminescence

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    Jong Won Shin, Ji Hoe Han, Bong Gon Kim, Sang Hun Jang, Sang Gyeong Lee, Kil Sik Min

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  42. Catalytic performance of the high and low temperature polymorphs of (C 6 N 2 H 16 ) 0.5 [(VO)(HAsO 4 )F]: structural, thermal, spectroscopic and magnetic studies

    Dalton Transactions · 2009-11-12

    Teresa Berrocal, Jose Luis Mesa, José Luis Pizarro, Begoña Bazán, Marta Iglesias, José Luis Vilas‐Vilela, Teófilo Rojo, María Isabel Arriortua

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  43. Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium

    Inorganic Chemistry · 2009-11-13

    Padmini Ramaswamy, N.N. Hegde, Ramanath Prabhu, V.M. Vidya, Ayan Datta, Srinivasan Natarajan

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  44. Recent advances in crystal engineering

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    Christer B. Aakeröy, Neil R. Champness, Christoph Janiak

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  45. A new open-framework zinc arsenate [C4N3H16]2[Zn5(AsO4)4(HAsO4)2]

    Inorganic Chemistry Communications · 2009-11-19

    Vandavasi Koteswara Rao, Srinivasan Natarajan

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  46. The First Organic-Templated Vanadyl(IV) Gallophosphates with Ambient 51V Hyperfine Structure, {V2Ga2O14} Cluster or Heterometal 12-Ring Channels

    Inorganic Chemistry · 2009-11-30

    Li‐Hsun Huang, Yi‐Chun Lai, Hui‐Chun Lai, Yun‐Wei Chiang, Jinhua Huang, Sue‐Lein Wang

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  47. Structural Transformation of Three‐Dimensional Bimetallic Phosphites Containing Corner‐Sharing 4‐Ring Chains

    Zeitschrift für anorganische und allgemeine Chemie · 2009-12-01

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  48. [B4O9H2] Cyclic Borate Units as the Building Unit in a Family of Zinc Borate Structures

    Crystal Growth & Design · 2009-12-03

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  49. Jahn−Teller Distorted Frameworks and Magnetic Order in the Rb−Mn−P−O System

    Inorganic Chemistry · 2009-12-30

    Fiona C. Coomer, Neal J. Checker, Adrian J. Wright

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  50. Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials

    Chemical Communications · 2010-01-01

    Xianchun Liu, Yan Xing, Xinlong Wang, Hong‐Bin Xu, Xizheng Liu, Kui‐Zhan Shao, Zhong‐Min Su

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