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RESEARCH PAPER · Journal of Solid State Chemistry · 2002

The Crystal Structure of Triuranyl Diphosphate Tetrahydrate

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The Crystal Structure of Triuranyl Diphosphate TetrahydrateOriginalSynthesis and Structure of Ag6[(UO2)3O(MoO4)5]: A Novel Sheet of Triuranyl Clusters and MoO4 Tetrahedra43Crystal Structures of Three Framework Alkali Metal Uranyl Phosphate Hydrates65Advances in Understanding of the Crystal Chemistry of Hexavalent Uranium2THE CRYSTAL STRUCTURE OF BERGENITE, A NEW GEOMETRICAL ISOMER OF THE PHOSPHURANYLITE GROUP41A Novel Open Framework Uranyl Molybdate: Synthesis and Structure of (NH4)4[(UO2)5(MoO4)7](H2O)567CRYSTAL STRUCTURES AND SYNTHESIS OF THE COPPER-DOMINANT MEMBERS OF THE AUTUNITE AND META-AUTUNITE GROUPS: TORBERNITE, ZEUNERITE, METATORBERNITE AND METAZEUNERITE119Synthesis and crystal structure of α and β-Rb6U5V2O23, a new layered compound33Synthesis and crystal structure of new uranyl tungstates M2(UO2)(W2O8) (M=Na, K), M2(UO2)2(WO5)O (M=K, Rb), and Na10(UO2)8(W5O20)O844Synthesis and crystal structure of two new uranyl oxychloro-vanadate layered compounds: M7(UO2)8(VO4)2O8Cl with M=Rb, Cs27Direct Investigations of the Immobilization of Radionuclides in the Alteration Phases of Spent Nuclear Fuel4Structures and synthesis of framework Rb and Cs uranyl arsenates and their relationships with their phosphate analogues31The structure of hügelite, an arsenate of the phosphuranylite group, and its relationship to dumontite22Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)130Structures and syntheses of framework triuranyl diarsenate hydrates45Synthesis, crystal structure and electrical characterization of Cs4[(UO2)2(V2O7)O2], a uranyl divanadate with chains of corner-sharing uranyl square bipyramids45An Unprecedented Uranyl Phosphate Framework in the Structure of [(UO2)3(PO4)O(OH)(H2O)2](H2O)53Syntheses, Structures, Magnetic Properties, and X-ray Absorption Spectra of Carnotite-type Uranyl Chromium(V) Oxides: A[(UO2)2Cr2O8](H2O)n (A = K2, Rb2, Cs2, Mg; n = 0, 4)21Spectroscopic and Diffraction Study of Uranium Speciation in Contaminated Vadose Zone Sediments from the Hanford Site, Washington State113Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates40Analysis of uranyl-bearing phases by EXAFS spectroscopy: Interferences, multiple scattering, accuracy of structural parameters, and spectral differences115Theoretical studies on the nature of uranyl–silicate, uranyl–phosphate and uranyl–arsenate interactions in the model H2UO2SiO4· 3H2O, HUO2PO4· 3H2O, and HUO2AsO4· 3H2O molecules16Direct Investigations of the Immobilization of Radionuclides in the Alteration Products of Spent Nuclear Fuel2Topology of Microporous Structures51Solubility of (UO2)3(PO4)2⋅4H2O in H+-Na+-OH−-H2PO−4-HPO2−4-PO3−4-H2O and Its Comparison to the Analogous PuO2 +2 System15U6+ MINERALS AND INORGANIC COMPOUNDS: INSIGHTS INTO AN EXPANDED STRUCTURAL HIERARCHY OF CRYSTAL STRUCTURES627General Route to Three-Dimensional Framework Uranyl Transition Metal Phosphates with Atypical Structural Motifs: The Case Examples of Cs2{(UO2)4[Co(H2O)2]2(HPO4)(PO4)4} and Cs3+x[(UO2)3CuH4-x(PO4)5]·H2O40The A1−xUNbO6−x/2 compounds (x=0, A=Li, Na, K, Cs and x=0.5, A=Rb, Cs): from layered to tunneled structure15Predicting the Energy of the Water Exchange Reaction and Free Energy of Solvation for the Uranyl Ion in Aqueous Solution190Expanding the Crystal Chemistry of Actinyl Peroxides: Open Sheets of Uranyl Polyhedra in Na5[(UO2)3(O2)4(OH)3](H2O)1333New Layered Uranium Phosphate Fluorides: Syntheses, Structures, Characterizations, and Ion-Exchange Properties of A(UO2)F(HPO4)·xH2O (A = Cs+, Rb+, K+; x = 0−1)88Raman spectroscopic study of the uranyl oxyhydroxide hydrates: becquerelite, billietite, curite, schoepite and vandendriesscheite122Crystal chemistry of actinide phosphates and arsenates39Crystal chemistry of uranium oxocompounds: an overview21Structural chemistry of uranium vanadates: from 2-D to 3-D networks1Phosphate Bariers for Immobilization of Uranium Plumes0THE STEREOCHEMISTRY AND CHEMICAL COMPOSITION OF INTERSTITIAL COMPLEXES IN URANYL-OXYSALT MINERALS75[H2bipy]2[(UO2)6Zn2(PO3OH)4(PO4)4]·H2O: An Open-Framework Uranyl Zinc Phosphate Templated by Diprotonated 4,4′-Bipyridyl17Alternative approaches to structure description1Anion-topology approach0Basic concepts3Copyright Page0Dedication0Dimensional reduction in inorganic oxysalts0Graph theory applied to low-dimensional structural units in inorganic oxysalts2Preface0Structural Crystallography of Inorganic Oxysalts127Topology of framework structures in inorganic oxysalts0Channels occupancy and distortion in new lithium uranyl phosphates with three-dimensional open-frameworks14[Hg5O2(OH)4][(UO2)2(AsO4)2]: A complex mercury(II) uranyl arsenate6Quantum mechanical calculation of aqueuous uranium complexes: carbonate, phosphate, organic and biomolecular species78Thermodynamic Properties of Autunite, Uranyl Hydrogen Phosphate, and Uranyl Orthophosphate from Solubility and Calorimetric Measurements102A new series of pillared uranyl-vanadates based on uranophane-type sheets in the uranium-vanadium-linear alkyl diamine systems28Actinide Structural Chemistry4Delineating hydrated uranyl phosphates: Powder XRD and ATR-IR studies5U(VI) oxygen polyhedra as pillars for building frameworks from uranophane-type layers6From extended solids to nano-scale actinide clusters25Synthesis and study of uranyl phosphates (UO2)3(PO4)2·nH2O2Raman spectroscopic study of the uranyl titanate mineral brannerite (U,Ca,Y,Ce)2(Ti,Fe)2O6:effect of metamictisation14Raman spectroscopic study of the uranyl titanate mineral betafite (Ca,U)2(Ti,Nb)2O6(OH): effect of metamictization5New three-dimensional inorganic frameworks based on the uranophane-type sheet in monoamine templated uranyl-vanadates28Uranyl phosphate sheet reconstruction during dehydration of metatorbernite [Cu(UO2)2(PO4)2{middle dot}8H2O]15Linear Alkyl Diamine-Uranium-Phosphate Systems: U(VI) to U(IV) Reduction with Ethylenediamine10State of uranophosphates MIPUO6·nH2O (MI = H+, Li+, Na+, K+, Rb+, Cs+, NH+4) in saturated aqueous solutions3State of uranyl phosphates and arsenates in aqueous solutions13In-Situ Raman Spectroscopy Studies of Room-Temperature and Hydrothermal Reactions1Molecular-Scale Structure of Uranium(VI) Immobilized with Goethite and Phosphate123Crystal Chemistry of Uranium Oxides and Minerals27Synthesis and characterization of MIIU3O10 · nH2O (MII = Mg, Mn, Co, Ni, Cu, Zn, Cd) triuranates7Molten salt flux synthesis and crystal structure of a new open-framework uranyl phosphate Cs3(UO2)2(PO4)O2: Spectroscopic characterization and cationic mobility studies21Raman spectroscopic study of natural and synthetic brannerite37Study of the state of uranyl orthovanadate (UO2)3(VO4)2·4H2O in aqueous solutions1Synthesis and study of polyuranates MIIIU3O10.5·6H2O (MIII = La, Ce, Pr, Nd, Sm)4Uranyl orthovanadate of composition (UO2)3(VO4)2 · 4H2O: Synthesis and characterization3Density Functional Theory Study of the Complexation of the Uranyl Dication with Anionic Phosphate Ligands with and without Water Molecules33The structure hierarchy hypothesis44Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5A Revised and Expanded Structure Hierarchy of Natural and Synthetic Hexavalent Uranium Compounds172Quantitative EXAFS Analysis32Development of a phosphate precipitation method for the recovery of uranium from lean tenor alkaline leach liquor68Rb2[Ca(NpO2)2(PO4)2], the First Mixed Alkali–Alkaline Earth Metals Neptunyl(V) Phosphate: Crystal Chemistry and Sheet Stereoisomerism7How Do Actinyls Interact with Hyperphosphorylated Yolk Protein Phosvitin?6Mild hydrothermal synthesis of potassium uranyl phosphates with layered and framework structures2Uranium speciation control by uranyl sulfate and phosphate in tailings subject to a Sahelian climate, Cominak, Niger23Structural and Charge Transport Properties of Composites of Phosphate-Silicate Protonic Glass with Uranyl Hydroxy-Phosphate and Hydroxy-Arsenate Obtained by Mechano-Chemical Synthesis Undergoing Hydration Changes2The crystal chemistry of plutonium( iv ) borophosphate1Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)32Hydrothermal synthesis and structure of organically templated layered neptunyl( vi ) phosphate (NpO 2 ) 3 (PO 4 ) 2 (Terpy)0Arbuscular mycorrhizal fungi influence the speciation and subcellular abundance of uranium in plant roots5

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  1. Synthesis and Structure of Ag6[(UO2)3O(MoO4)5]: A Novel Sheet of Triuranyl Clusters and MoO4 Tetrahedra

    Inorganic Chemistry · 2002-07-17

    Sergey V. Krivovichev, Peter Carman Burns

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  2. Crystal Structures of Three Framework Alkali Metal Uranyl Phosphate Hydrates

    Journal of Solid State Chemistry · 2002-08-01

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  3. Advances in Understanding of the Crystal Chemistry of Hexavalent Uranium

    MRS Proceedings · 2003-01-01

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  4. THE CRYSTAL STRUCTURE OF BERGENITE, A NEW GEOMETRICAL ISOMER OF THE PHOSPHURANYLITE GROUP

    The Canadian Mineralogist · 2003-02-01

    Andrew J. Locock, Peter Carman Burns

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  5. A Novel Open Framework Uranyl Molybdate: Synthesis and Structure of (NH4)4[(UO2)5(MoO4)7](H2O)5

    Inorganic Chemistry · 2003-03-14

    Sergey V. Krivovichev, Christopher L. Cahill, Peter Carman Burns

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  6. CRYSTAL STRUCTURES AND SYNTHESIS OF THE COPPER-DOMINANT MEMBERS OF THE AUTUNITE AND META-AUTUNITE GROUPS: TORBERNITE, ZEUNERITE, METATORBERNITE AND METAZEUNERITE

    The Canadian Mineralogist · 2003-04-01

    Andrew J. Locock, Peter Carman Burns

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  7. Synthesis and crystal structure of α and β-Rb6U5V2O23, a new layered compound

    Journal of Solid State Chemistry · 2003-04-30

    S. Obbade, C. Dion, L. Duvieubourg, Mohamed Saadi, F. Abraham

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  8. Synthesis and crystal structure of new uranyl tungstates M2(UO2)(W2O8) (M=Na, K), M2(UO2)2(WO5)O (M=K, Rb), and Na10(UO2)8(W5O20)O8

    Journal of Solid State Chemistry · 2003-05-01

    S. Obbade, C. Dion, Émilie Bekaert, S. Yagoubi, Mohamed Saadi, F. Abraham

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  9. Synthesis and crystal structure of two new uranyl oxychloro-vanadate layered compounds: M7(UO2)8(VO4)2O8Cl with M=Rb, Cs

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    I. Duribreux, Mohamed Saadi, S. Obbade, C. Dion, F. Abraham

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  10. Direct Investigations of the Immobilization of Radionuclides in the Alteration Phases of Spent Nuclear Fuel

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  11. Structures and synthesis of framework Rb and Cs uranyl arsenates and their relationships with their phosphate analogues

    Journal of Solid State Chemistry · 2003-09-16

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  12. The structure of hügelite, an arsenate of the phosphuranylite group, and its relationship to dumontite

    Mineralogical Magazine · 2003-10-01

    Andrew J. Locock, Peter Carman Burns

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  13. Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)

    Inorganic Chemistry · 2003-10-04

    Lauren A. Borkowski, Christopher L. Cahill

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  14. Structures and syntheses of framework triuranyl diarsenate hydrates

    Journal of Solid State Chemistry · 2003-10-15

    Andrew J. Locock, Peter Carman Burns

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  15. Synthesis, crystal structure and electrical characterization of Cs4[(UO2)2(V2O7)O2], a uranyl divanadate with chains of corner-sharing uranyl square bipyramids

    Journal of Solid State Chemistry · 2004-01-17

    S. Obbade, C. Dion, Mohamed Saadi, F. Abraham

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  16. An Unprecedented Uranyl Phosphate Framework in the Structure of [(UO2)3(PO4)O(OH)(H2O)2](H2O)

    Inorganic Chemistry · 2004-02-24

    Peter Carman Burns, Cara M. Alexopoulos, Peter J. Hotchkiss, Andrew J. Locock

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  17. Syntheses, Structures, Magnetic Properties, and X-ray Absorption Spectra of Carnotite-type Uranyl Chromium(V) Oxides: A[(UO2)2Cr2O8](H2O)n (A = K2, Rb2, Cs2, Mg; n = 0, 4)

    Chemistry of Materials · 2004-03-09

    Andrew J. Locock, S. Skanthakumar, Peter Carman Burns, L. Soderholm

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  18. Spectroscopic and Diffraction Study of Uranium Speciation in Contaminated Vadose Zone Sediments from the Hanford Site, Washington State

    Environmental Science & Technology · 2004-04-17

    Jeffrey G. Catalano, Steven M. Heald, John M. Zachara, Gordon E. Brown

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  19. Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates

    Journal of Solid State Chemistry · 2004-06-21

    Andrew J. Locock, Peter Carman Burns

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  20. Analysis of uranyl-bearing phases by EXAFS spectroscopy: Interferences, multiple scattering, accuracy of structural parameters, and spectral differences

    American Mineralogist · 2004-07-01

    Jeffrey G. Catalano, Gordon E. Brown

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  21. Theoretical studies on the nature of uranyl–silicate, uranyl–phosphate and uranyl–arsenate interactions in the model H2UO2SiO4· 3H2O, HUO2PO4· 3H2O, and HUO2AsO4· 3H2O molecules

    Chemical Physics Letters · 2004-09-14

    Devashis Majumdar, K. Balasubramanian

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  22. Direct Investigations of the Immobilization of Radionuclides in the Alteration Products of Spent Nuclear Fuel

    Unknown journal · 2004-12-27

    Peter Carman Burns, Robert J. Finch, David J. Wronkiewicz

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  23. Topology of Microporous Structures

    Reviews in Mineralogy and Geochemistry · 2005-01-01

    Sergey V. Krivovichev

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  24. Solubility of (UO2)3(PO4)2⋅4H2O in H+-Na+-OH−-H2PO−4-HPO2−4-PO3−4-H2O and Its Comparison to the Analogous PuO2 +2 System

    Journal of Solution Chemistry · 2005-04-01

    Dhanpat Rai, Yuanxian Xia, Linfeng Rao, Nancy J. Hess, Andrew R. Felmy, Dean A. Moore, David E. McCready

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  25. U6+ MINERALS AND INORGANIC COMPOUNDS: INSIGHTS INTO AN EXPANDED STRUCTURAL HIERARCHY OF CRYSTAL STRUCTURES

    The Canadian Mineralogist · 2005-12-01

    Peter Carman Burns

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  26. General Route to Three-Dimensional Framework Uranyl Transition Metal Phosphates with Atypical Structural Motifs: The Case Examples of Cs2{(UO2)4[Co(H2O)2]2(HPO4)(PO4)4} and Cs3+x[(UO2)3CuH4-x(PO4)5]·H2O

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  27. The A1−xUNbO6−x/2 compounds (x=0, A=Li, Na, K, Cs and x=0.5, A=Rb, Cs): from layered to tunneled structure

    Journal of Solid State Chemistry · 2006-06-22

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  28. Predicting the Energy of the Water Exchange Reaction and Free Energy of Solvation for the Uranyl Ion in Aqueous Solution

    The Journal of Physical Chemistry A · 2006-06-23

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  29. Expanding the Crystal Chemistry of Actinyl Peroxides: Open Sheets of Uranyl Polyhedra in Na5[(UO2)3(O2)4(OH)3](H2O)13

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  30. New Layered Uranium Phosphate Fluorides: Syntheses, Structures, Characterizations, and Ion-Exchange Properties of A(UO2)F(HPO4)·xH2O (A = Cs+, Rb+, K+; x = 0−1)

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  31. Raman spectroscopic study of the uranyl oxyhydroxide hydrates: becquerelite, billietite, curite, schoepite and vandendriesscheite

    Journal of Raman Spectroscopy · 2006-12-07

    Ray L. Frost, Jiří Čejka, Matt L. Weier

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  32. Crystal chemistry of actinide phosphates and arsenates

    Elsevier eBooks · 2007-01-01

    Andrew J. Locock

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  33. Crystal chemistry of uranium oxocompounds: an overview

    Elsevier eBooks · 2007-01-01

    Peter Carman Burns

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  34. Structural chemistry of uranium vanadates: from 2-D to 3-D networks

    Elsevier eBooks · 2007-01-01

    F. Abraham, S. Obbade

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  35. Phosphate Bariers for Immobilization of Uranium Plumes

    Unknown journal · 2007-01-26

    Peter Carman Burns

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  36. THE STEREOCHEMISTRY AND CHEMICAL COMPOSITION OF INTERSTITIAL COMPLEXES IN URANYL-OXYSALT MINERALS

    The Canadian Mineralogist · 2008-04-01

    Mandy Schindler, Frank Christopher Hawthorne

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  37. [H2bipy]2[(UO2)6Zn2(PO3OH)4(PO4)4]·H2O: An Open-Framework Uranyl Zinc Phosphate Templated by Diprotonated 4,4′-Bipyridyl

    Inorganic Chemistry · 2008-08-23

    Yaqin Yu, Wei Zhan, Thomas E. Albrecht‐Schmitt

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  38. Alternative approaches to structure description

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·
  39. Anion-topology approach

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·
  40. Basic concepts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  41. Copyright Page

    Unknown journal · 2009-01-22

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  42. Dedication

    Unknown journal · 2009-01-22

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  43. Dimensional reduction in inorganic oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  44. Graph theory applied to low-dimensional structural units in inorganic oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  45. Preface

    Unknown journal · 2009-01-22

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  46. Structural Crystallography of Inorganic Oxysalts

    Unknown journal · 2009-01-22

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  47. Topology of framework structures in inorganic oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  48. Channels occupancy and distortion in new lithium uranyl phosphates with three-dimensional open-frameworks

    Journal of Solid State Chemistry · 2009-02-27

    Catherine Renard, S. Obbade, F. Abraham

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  49. [Hg5O2(OH)4][(UO2)2(AsO4)2]: A complex mercury(II) uranyl arsenate

    Journal of Solid State Chemistry · 2009-04-09

    Yaqin Yu, Kai Jiang, Thomas E. Albrecht‐Schmitt

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  50. Quantum mechanical calculation of aqueuous uranium complexes: carbonate, phosphate, organic and biomolecular species

    Chemistry Central Journal · 2009-08-18

    James D. Kubicki, Gary P. Halada, Prashant K. Jha, Brian L. Phillips

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