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RESEARCH PAPER · Powder Diffraction · 2013

Crystallisation Kinetics of Metal Organic Frameworks From in situ Time-Resolved X-ray Diffraction

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Crystallisation Kinetics of Metal Organic Frameworks From in situ Time-Resolved X-ray DiffractionOriginalHigh valence 3p and transition metal based MOFs605In Situ Energy-Dispersive X-ray Diffraction for the Synthesis Optimization and Scale-up of the Porous Zirconium Terephthalate UiO-66219In Situ Studies of Solvothermal Synthesis of Energy Materials159Indium Imidazolate Frameworks with Differently Distorted ReO3-Type Structures: Syntheses, Structures, Phase Transitions, and Crystallization Studies13In situ powder X-ray diffraction study of the hydro-thermal formation of LiMn 2 O 4 nanocrystallites10Synthesis of metal-organic frameworks (MOFs) with microwave or ultrasound: Rapid reaction, phase-selectivity, and size reduction594Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields112Adsorption of hexavalent chromium by metal organic frameworks from aqueous solution258Impact of the Nature of the Organic Spacer on the Crystallization Kinetics of UiO‐66(Zr)‐Type MOFs49An in situ study of resin-assisted solvothermal metal-organic framework synthesis8Time-Resolved in Situ Diffraction Reveals a Solid-State Rearrangement During Solvothermal MOF Synthesis28In Situ Observation of Successive Crystallizations and Metastable Intermediates in the Formation of Metal–Organic Frameworks60In Situ Observation of Successive Crystallizations and Metastable Intermediates in the Formation of Metal–Organic Frameworks16Exchange of Coordinated Solvent During Crystallization of a Metal–Organic Framework Observed by In Situ High‐Energy X‐ray Diffraction53Exchange of Coordinated Solvent During Crystallization of a Metal–Organic Framework Observed by In Situ High‐Energy X‐ray Diffraction14In SituStudies of the Crystallization of Metal-Organic Frameworks10Chemistry of Metal-organic Frameworks Monitored by Advanced X-ray Diffraction and Scattering Techniques21Time‐Resolved In Situ X‐ray Diffraction Reveals Metal‐Dependent Metal–Organic Framework Formation38Time‐Resolved In Situ X‐ray Diffraction Reveals Metal‐Dependent Metal–Organic Framework Formation10In Situ Studies on Phase Transitions of Tris(acetylacetonato)-Aluminum(III) Al(acac)321An in situ investigation of the water-induced phase transformation of UTSA-74 to MOF-74(Zn)26In situ luminescence analysis: a new light on monitoring calcium phosphate phase transitions26Structural variety in ytterbium dicarboxylate frameworks and in situ study diffraction of their solvothermal crystallisation14High energy X-rays for following metal-organic framework formation: Identifying intermediates in interpenetrated MOF-5 crystallisation26Revealing the Initial Reaction Behavior in the Continuous Synthesis of Metal–Organic Frameworks Using Real-Time Synchrotron X-ray Analysis14Electrocatalytic Hydrogen Evolution Reaction of Metal Organic Frameworks decorated with poly (3-aminobenzoic acid)37In situ monitoring metal-ligand exchange processes by optical spectroscopy and X-ray diffraction analysis: a review22Polyaniline-metal organic framework nanocomposite as an efficient electrocatalyst for hydrogen evolution reaction129Silver Nanoparticles Synthesized by Microwave Heating: A Kinetic and Mechanistic Re-Analysis and Re-Interpretation38Formation Mechanisms of Nanocrystalline MnO 2 Polymorphs under Hydrothermal Conditions78Thermodynamic and Kinetic Effects in the Crystallization of Metal–Organic Frameworks173In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth610Elucidation of the Formation Mechanism of Metal–Organic Frameworks via in-Situ Raman and FTIR Spectroscopy under Solvothermal Conditions81In situ Monitoring of the Formation of [Bis(acetylacetonato)manganese(II)] Complexes10Electrospray Mass Spectrometry Investigation into the Formation of CPO-2712Copper(II) phthalocyanine/metal organic framework electrocatalyst for hydrogen evolution reaction application59A kinetic and mechanistic study into the transformation of calcium sulfate hemihydrate to dihydrate40Integrated Cleanroom Process for the Vapor-Phase Deposition of Large-Area Zeolitic Imidazolate Framework Thin Films78Analysis by synchrotron X-ray scattering of the kinetics of formation of an Fe-based metal-organic framework with high CO2 adsorption5Scalable and precise synthesis of two-dimensional metal organic framework nanosheets in a high shear annular microreactor23Role of Prenucleation Building Units in Determining Metal–Organic Framework MIL-53(Al) Morphology14Conformal Functionalization of Cotton Fibers via Isoreticular Expansion of UiO-66 Metal-Organic Frameworks12Large MOFs: synthesis strategies and applications where size matters51In situ scattering studies of material formation during wet-chemical syntheses1The effect of additives on the hydration of CaSO4·0.5H2O: A synchrotron X-ray diffraction study7Probing growth of metal–organic frameworks with X-ray scattering and vibrational spectroscopy6Solvothermal synthesis of zirconia nanomaterials: Latest developments and future45Solvothermal and hydrothermal methods for preparative solid-state chemistry5Crystallization of NiCo MOF-74 on a Porous NiO Film as an Anode for the Urea/H2O2 Fuel Cell19Trapping of Photoluminescent Kinetic Intermediates During High-Concentration Synthesis of Non-Emissive Metal-Organic Frameworks1Collaborative formation pattern of surface topography and residual stress in hard turning of steels3Probing Complex Chemical Processes at the Molecular Level with Vibrational Spectroscopy and X-ray Tools10Kinetic Trapping of Photoluminescent Frameworks During High-Concentration Synthesis of Nonemissive Metal–Organic Frameworks14Application of a UV nanosecond laser to the rapid and direct photothermal activation of Cu-BTC metal–organic frameworks2Stepwise Reactions in the Potassium and Ammonia-Intercalated Iron Selenide Superconductor Phase Diagram Followed by In Situ Powder Diffraction1Raman Marker Bands for In Situ Quality Control During Synthesis of 2D Conjugated Metal–Organic Frameworks2In situ monitoring nucleation and growth of metal organic frameworks: device, mechanism and application4Interplay Between Oxidation State, Intervalence Charge Transfer Transitions and Electronic Conductivity in a Series of Ru‐Based Metal–Organic Frameworks0

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  1. High valence 3p and transition metal based MOFs

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  2. In Situ Energy-Dispersive X-ray Diffraction for the Synthesis Optimization and Scale-up of the Porous Zirconium Terephthalate UiO-66

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  7. Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields

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  9. Impact of the Nature of the Organic Spacer on the Crystallization Kinetics of UiO‐66(Zr)‐Type MOFs

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  10. An in situ study of resin-assisted solvothermal metal-organic framework synthesis

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  14. Exchange of Coordinated Solvent During Crystallization of a Metal–Organic Framework Observed by In Situ High‐Energy X‐ray Diffraction

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  15. Exchange of Coordinated Solvent During Crystallization of a Metal–Organic Framework Observed by In Situ High‐Energy X‐ray Diffraction

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  16. In SituStudies of the Crystallization of Metal-Organic Frameworks

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  17. Chemistry of Metal-organic Frameworks Monitored by Advanced X-ray Diffraction and Scattering Techniques

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  18. Time‐Resolved In Situ X‐ray Diffraction Reveals Metal‐Dependent Metal–Organic Framework Formation

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  20. In Situ Studies on Phase Transitions of Tris(acetylacetonato)-Aluminum(III) Al(acac)3

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  21. An in situ investigation of the water-induced phase transformation of UTSA-74 to MOF-74(Zn)

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  26. Electrocatalytic Hydrogen Evolution Reaction of Metal Organic Frameworks decorated with poly (3-aminobenzoic acid)

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  27. In situ monitoring metal-ligand exchange processes by optical spectroscopy and X-ray diffraction analysis: a review

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