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RESEARCH PAPER · Angewandte Chemie International Edition · 2016

Exchange of Coordinated Solvent During Crystallization of a Metal–Organic Framework Observed by In Situ High‐Energy X‐ray Diffraction

Yue Wu, Matthew I. Breeze, Guy J. Clarkson, Franck Millange, Dermot M. O'Hare, Richard I. Walton

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Exchange of Coordinated Solvent During Crystallization of a Metal–Organic Framework Observed by In Situ High‐Energy X‐ray DiffractionOriginalTime‐Resolved In Situ X‐ray Diffraction Reveals Metal‐Dependent Metal–Organic Framework Formation38Time‐Resolved In Situ X‐ray Diffraction Reveals Metal‐Dependent Metal–Organic Framework Formation10Combined in- and ex situ studies of pyrazine adsorption into the aliphatic MOF Al-CAU-13: structures, dynamics and correlations23Formation pathways of metal–organic frameworks proceeding through partial dissolution of the metastable phase27Structural variety in ytterbium dicarboxylate frameworks and in situ study diffraction of their solvothermal crystallisation14Synthesis of MOFs: a personal view on rationalisation, application and exploration37Two new metal–organic frameworks based on tetrazole–heterocyclic ligands accompanied by in situ ligand formation23High energy X-rays for following metal-organic framework formation: Identifying intermediates in interpenetrated MOF-5 crystallisation26Time-Resolved Powder X-ray Diffraction of the Solvothermal Crystallization of Cobalt Gallate Spinel Photocatalyst Reveals Transient Layered Double Hydroxides20Solvent exchange in a metal–organic framework single crystal monitored by dynamicin situX-ray diffraction6In situ monitoring metal-ligand exchange processes by optical spectroscopy and X-ray diffraction analysis: a review22Bi2O2CO3 Growth at Room Temperature: In Situ X-ray Diffraction Monitoring and Thermal Behavior17From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li2Mo3TeO12 to Polyoxometalates12Green Synthesis of a New Al‐MOF Based on the Aliphatic Linker Mesaconic Acid: Structure, Properties and In Situ Crystallisation Studies of Al‐MIL‐68‐Mes41Thermodynamic and Kinetic Effects in the Crystallization of Metal–Organic Frameworks173In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth610Atomic Force Microscopy Study of the Influence of the Synthesis Conditions on the Single‐Crystal Surface of Interdigitated Metal‐Organic Frameworks9Monitoring the Hydrothermal Growth of Cobalt Spinel Water Oxidation Catalysts: From Preparative History to Catalytic Activity20In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal–organic framework (MOF)19In Situ Diffraction Studies of Selected Metal–Organic Framework Materials for Guest Capture/Exchange Applications2Yb(III)-based MOFs with different bulky backbone ligands for optical detection and degradation of organic molecules in wastewater8The Metal–Organic Framework Collapse Continuum: Insights from Two-Dimensional Powder X-ray Diffraction93Investigation of the Kinetic Stabilization of a Ce4+‐based MOF by in‐situ Powder X‐ray Diffraction26Control of Metal–Organic Framework Crystallization by Metastable Intermediate Pre‐equilibrium Species66Control of Metal–Organic Framework Crystallization by Metastable Intermediate Pre‐equilibrium Species4The Chemistry of Nucleation: In Situ Pair Distribution Function Analysis of Secondary Building Units During UiO‐66 MOF Formation117A hydrothermally stable ytterbium metal–organic framework as a bifunctional solid-acid catalyst for glucose conversion36Analysis by synchrotron X-ray scattering of the kinetics of formation of an Fe-based metal-organic framework with high CO2 adsorption5Adsorption of Rhodamine B by Yttrium-Succinate metal organic framework (MOF)3Spectroscopy, microscopy, diffraction and scattering of archetypal MOFs: formation, metal sites in catalysis and thin films116Synthesis of Lanthanum metal-organic frameworks (La-MOFs) as degradation photocatalyst of Rhodamine-B7In situ synthesis and characterization of a series of new pyridyl containing complexes based on 3d metals: from oligomer to 3D framework7Synthesis and characterization of metal organic framework using succinic acid ligand with cobalt and iron metals as methylene blue dye adsorbent18In situ X-ray Diffraction Investigation of the Crystallisation of Perfluorinated Ce(IV)-based Metal-Organic Frameworks with UiO-66 and MIL-140 architectures2Exploiting in situ NMR to monitor the formation of a metal–organic framework43In Situ X‐ray Diffraction Investigation of the Crystallisation of Perfluorinated Ce IV ‐Based Metal–Organic Frameworks with UiO‐66 and MIL‐140 Architectures**23Holmium-based metal-organic frameworks using the BDC linker11In situ scattering studies of material formation during wet-chemical syntheses1Five zinc supramolecular assemblies constructed from flexible bispyridinecarboxamide and a series of substituted isophthalates: Synthesis and characterization3Fecht's acid revisited: a spirocyclic dicarboxylate for non-aromatic MOFs3Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals0In situ X‐ray Scattering of the Crystallisation of Basic Magnesium Chlorides using a Laboratory Instrument1Solvothermal and hydrothermal methods for preparative solid-state chemistry5Non-classical crystallization in soft and organic materials107Proton Conducting Metal‐Organic Frameworks (MOFs) via Post Synthetic Transmetallation and Water Induced Structural Transformations14Hydrates of N-((10-Chloroanthracen-9-yl)methyl)-3-(1H-imidazol-1-yl)propan-1-ammonium Cobalt(II), Copper(II), and Zinc(II) 2,6-Pyridinedicarboxylate: Reversible Crystallization0In-situ growth of high-crystallinity M3(hexaaminotriphenylene)2 (M = Co, Ni) thin film for field-effect transistor-based glucose biosensor2In situ monitoring nucleation and growth of metal organic frameworks: device, mechanism and application4Restoring Porosity and Uncovering Flexibility in Pillared 3D‐Linker Metal‐Organic Frameworks7Restoring Porosity and Uncovering Flexibility in Pillared 3D‐Linker Metal‐Organic Frameworks4Structure, spectral, thermal, and magnetic properties, and hydrolytic stability of three novel fluorinated MOFs based on Ho( iii ), Dy( iii ), and Yb( iii ) ions0Breaking activity-stability trade-off in chlorine electrolysis via grain boundary engineering1

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  1. Time‐Resolved In Situ X‐ray Diffraction Reveals Metal‐Dependent Metal–Organic Framework Formation

    Angewandte Chemie International Edition · 2016-10-11

    Yue Wu, Sebastian Henke, Gregor Kieslich, Inke Schwedler, Miaosen Yang, Duncan A. X. Fraser, Dermot M. O'Hare

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  2. Time‐Resolved In Situ X‐ray Diffraction Reveals Metal‐Dependent Metal–Organic Framework Formation

    Angewandte Chemie · 2016-10-11

    Yue Wu, Sebastian Henke, Gregor Kieslich, Inke Schwedler, Miaosen Yang, Duncan A. X. Fraser, Dermot M. O'Hare

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  3. Combined in- and ex situ studies of pyrazine adsorption into the aliphatic MOF Al-CAU-13: structures, dynamics and correlations

    Dalton Transactions · 2017-01-01

    Helge Reinsch, Jannik Benecke, Martin Etter, Niclas Heidenreich, Norbert Stock

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  4. Formation pathways of metal–organic frameworks proceeding through partial dissolution of the metastable phase

    CrystEngComm · 2017-01-01

    Samantha L. Anderson, Andrzej Gładysiak, Peter G. Boyd, Christopher P. Ireland, Pascal Miéville, Davide Tiana, Bess Vlaisavljevich, Pascal Schouwink, Wouter van Beek, Kevin J. Gagnon, Berend Smit, Kyriakos C. Stylianou

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  5. Structural variety in ytterbium dicarboxylate frameworks and in situ study diffraction of their solvothermal crystallisation

    CrystEngComm · 2017-01-01

    Matthew I. Breeze, Thomas W. Chamberlain, Guy J. Clarkson, Raíssa Pires De Camargo, Yue Wu, Juliana Fonseca de Lima, Franck Millange, Osvaldo Antônio Serra, Dermot M. O'Hare, Richard I. Walton

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  6. Synthesis of MOFs: a personal view on rationalisation, application and exploration

    Dalton Transactions · 2017-01-01

    Helge Reinsch, Norbert Stock

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  7. Two new metal–organic frameworks based on tetrazole–heterocyclic ligands accompanied by in situ ligand formation

    Dalton Transactions · 2017-01-01

    Qin Li, Mei‐Hui Yu, Jian Feng Xu, Ailin Li, Tong‐Liang Hu, Xian‐He Bu

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  8. High energy X-rays for following metal-organic framework formation: Identifying intermediates in interpenetrated MOF-5 crystallisation

    Microporous and Mesoporous Materials · 2017-04-22

    Yue Wu, Matthew I. Breeze, Dermot M. O'Hare, Richard I. Walton

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  9. Time-Resolved Powder X-ray Diffraction of the Solvothermal Crystallization of Cobalt Gallate Spinel Photocatalyst Reveals Transient Layered Double Hydroxides

    Chemistry of Materials · 2017-06-06

    Daniel Sean Cook, Yue Wu, Karla Lienau, René Moré, Reza J. Kashtiban, Oxana V. Magdysyuk, Greta Ricarda Patzke, Richard I. Walton

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  10. Solvent exchange in a metal–organic framework single crystal monitored by dynamicin situX-ray diffraction

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2017-07-25

    Jordan M. Cox, Ian M. Walton, Gage Bateman, Cassidy A. Benson, T. B. Mitchell, Eric D. Sylvester, Yu‐Sheng Chen, Jason B. Benedict

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  11. In situ monitoring metal-ligand exchange processes by optical spectroscopy and X-ray diffraction analysis: a review

    Reviews in Analytical Chemistry · 2017-08-19

    Huayna Terraschke, Merrit Rothe, Patric Lindenberg

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  12. Bi2O2CO3 Growth at Room Temperature: In Situ X-ray Diffraction Monitoring and Thermal Behavior

    ACS Omega · 2017-11-20

    René Moré, Michael Olah, S. Esmael Balaghi, Philipp Jäker, Sebastian Siol, Ying Zhou, Greta Ricarda Patzke

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  13. From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li2Mo3TeO12 to Polyoxometalates

    Chemistry - A European Journal · 2017-12-07

    Seung‐Jin Oh, Seong‐Ji Lim, Tae‐Soo You, Kang Min Ok

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  14. Green Synthesis of a New Al‐MOF Based on the Aliphatic Linker Mesaconic Acid: Structure, Properties and In Situ Crystallisation Studies of Al‐MIL‐68‐Mes

    Chemistry - A European Journal · 2017-12-11

    Helge Reinsch, Thomas Homburg, Niclas Heidenreich, Dominik Fröhlich, Stefan K. Henninger, Michael Wark, Norbert Stock

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  15. Thermodynamic and Kinetic Effects in the Crystallization of Metal–Organic Frameworks

    Accounts of Chemical Research · 2018-02-16

    Anthony Kevin Cheetham, Gregor Kieslich, Hamish H.‐M. Yeung

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  16. In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth

    Chemical Reviews · 2018-03-07

    Mary J. Van Vleet, Tingting Weng, Xinyi Li, J. R. Schmidt

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  17. Atomic Force Microscopy Study of the Influence of the Synthesis Conditions on the Single‐Crystal Surface of Interdigitated Metal‐Organic Frameworks

    ChemPhysChem · 2018-05-10

    Yoshinobu Kamakura, Nobuhiko Hosono, Aya Terashima, Susumu Kitagawa, Hirofumi Yoshikawa, Daisuke Tanaka

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  18. Monitoring the Hydrothermal Growth of Cobalt Spinel Water Oxidation Catalysts: From Preparative History to Catalytic Activity

    Chemistry - A European Journal · 2018-05-23

    L.A. Reith, Karla Lienau, Daniel Sean Cook, René Moré, Richard I. Walton, Greta Ricarda Patzke

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  19. In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal–organic framework (MOF)

    Polyhedron · 2018-07-22

    Jianwei Ren, Nicholas Mulei Musyoka, Henrietta Wakuna Langmi, Joseph Walker, Mkhulu Kenneth Mathe, Shijun Liao

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  20. In Situ Diffraction Studies of Selected Metal–Organic Framework Materials for Guest Capture/Exchange Applications

    Unknown journal · 2018-07-27

    Winnie Wong-Ng

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  21. Yb(III)-based MOFs with different bulky backbone ligands for optical detection and degradation of organic molecules in wastewater

    Polyhedron · 2018-08-19

    Jun‐Jie Wang, Yi Chen, Minjie Liu, Rui-Yang Fan, Pan-Pan Si, Jie Yang, Ya-Ya Pan, Yan Chen, Shanshan Zhao, Jialiang Xu

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  22. The Metal–Organic Framework Collapse Continuum: Insights from Two-Dimensional Powder X-ray Diffraction

    Chemistry of Materials · 2018-09-04

    Ryan A. Dodson, Antek G. Wong‐Foy, Adam J. Matzger

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  23. Investigation of the Kinetic Stabilization of a Ce4+‐based MOF by in‐situ Powder X‐ray Diffraction

    Zeitschrift für anorganische und allgemeine Chemie · 2018-10-31

    Niclas Heidenreich, Steve Waitschat, Helge Reinsch

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  24. Control of Metal–Organic Framework Crystallization by Metastable Intermediate Pre‐equilibrium Species

    Angewandte Chemie International Edition · 2018-11-15

    Hamish H.‐M. Yeung, Adam F. Sapnik, Felicity Massingberd‐Mundy, Michael W. Gaultois, Yue Wu, Duncan A. X. Fraser, Sebastian Henke, Roman Pallach, Niclas Heidenreich, Oxana V. Magdysyuk, Nghia Trong Vo, Andrew L. Goodwin

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  25. Control of Metal–Organic Framework Crystallization by Metastable Intermediate Pre‐equilibrium Species

    Angewandte Chemie · 2018-11-15

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  26. The Chemistry of Nucleation: In Situ Pair Distribution Function Analysis of Secondary Building Units During UiO‐66 MOF Formation

    Chemistry - A European Journal · 2018-11-27

    Hui Xu, Sanna Sommer, Nils Lau Nyborg Broge, Junkuo Gao, Bo B. Iversen

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  27. A hydrothermally stable ytterbium metal–organic framework as a bifunctional solid-acid catalyst for glucose conversion

    Chemical Communications · 2019-01-01

    David Burnett, Ryan Oozeerally, Ralentri Pertiwi, Thomas W. Chamberlain, Nikolay Cherkasov, Guy J. Clarkson, Yuni Krisyuningsih Krisnandi, Volkan Degirmenci, Richard I. Walton

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  28. Analysis by synchrotron X-ray scattering of the kinetics of formation of an Fe-based metal-organic framework with high CO2 adsorption

    APL Materials · 2019-11-01

    Harry G. W. Godfrey, Lydia Briggs, Xue Han, William J. F. Trenholme, Christopher G. Morris, Mathew Savage, Louis Kimberley, Oxana V. Magdysyuk, Michael Drakopoulos, Claire A. Murray, Chiu Chung Tang, Mark D. Frogley, Gianfelice Cinque, Sihai Yang⧫, Martin W. Schröder

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  29. Adsorption of Rhodamine B by Yttrium-Succinate metal organic framework (MOF)

    AIP conference proceedings · 2020-01-01

    Miranti Agustin, Dita Arifa Nurani, Agustino Zulys, Yuni Krisyuningsih Krisnandi

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  30. Spectroscopy, microscopy, diffraction and scattering of archetypal MOFs: formation, metal sites in catalysis and thin films

    Chemical Society Reviews · 2020-01-01

    Miguel Rivera‐Torrente, Laurens D. B. Mandemaker, Matthias Filez, Guusje Delen, Beatriz Seoane, Florian Meirer, Bert Marc Weckhuysen

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  31. Synthesis of Lanthanum metal-organic frameworks (La-MOFs) as degradation photocatalyst of Rhodamine-B

    AIP conference proceedings · 2020-01-01

    Achmad Buhori, Agustino Zulys, Jarnuzi Gunlazuardi

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  32. In situ synthesis and characterization of a series of new pyridyl containing complexes based on 3d metals: from oligomer to 3D framework

    Journal of Solid State Chemistry · 2020-03-20

    Zhehui Weng, Pengzhi Xiang, Jie Ling, Meixia Huang, Wenfeng Yang, Zhaofa Zheng, Xiujun Deng, Haidong Ju, Yao Huang

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  33. Synthesis and characterization of metal organic framework using succinic acid ligand with cobalt and iron metals as methylene blue dye adsorbent

    IOP Conference Series Materials Science and Engineering · 2020-07-01

    Dita Arifa Nurani, B C B Butar, Yuni Krisyuningsih Krisnandi

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  34. In situ X-ray Diffraction Investigation of the Crystallisation of Perfluorinated Ce(IV)-based Metal-Organic Frameworks with UiO-66 and MIL-140 architectures

    ChemRxiv · 2020-11-19

    Stephen J. I. Shearan, Jannick Jacobsen, Ferdinando Costantino, Roberto D’Amato, Dmitri Novikov, Norbert Stock, Enrico Andreoli, Marco Taddei

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  35. Exploiting in situ NMR to monitor the formation of a metal–organic framework

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    Corey L. Jones, Colan E. Hughes, Hamish H.‐M. Yeung, Alison Paul, Kenneth D M Harris, Timothy L. Easun

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  36. In Situ X‐ray Diffraction Investigation of the Crystallisation of Perfluorinated Ce IV ‐Based Metal–Organic Frameworks with UiO‐66 and MIL‐140 Architectures**

    Chemistry - A European Journal · 2021-01-22

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  37. Holmium-based metal-organic frameworks using the BDC linker

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  38. In situ scattering studies of material formation during wet-chemical syntheses

    Elsevier eBooks · 2021-08-04

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  39. Five zinc supramolecular assemblies constructed from flexible bispyridinecarboxamide and a series of substituted isophthalates: Synthesis and characterization

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  40. Fecht's acid revisited: a spirocyclic dicarboxylate for non-aromatic MOFs

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  41. Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals

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  42. In situ X‐ray Scattering of the Crystallisation of Basic Magnesium Chlorides using a Laboratory Instrument

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  43. Solvothermal and hydrothermal methods for preparative solid-state chemistry

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  44. Non-classical crystallization in soft and organic materials

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  46. Hydrates of N-((10-Chloroanthracen-9-yl)methyl)-3-(1H-imidazol-1-yl)propan-1-ammonium Cobalt(II), Copper(II), and Zinc(II) 2,6-Pyridinedicarboxylate: Reversible Crystallization

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  47. In-situ growth of high-crystallinity M3(hexaaminotriphenylene)2 (M = Co, Ni) thin film for field-effect transistor-based glucose biosensor

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  48. In situ monitoring nucleation and growth of metal organic frameworks: device, mechanism and application

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  49. Restoring Porosity and Uncovering Flexibility in Pillared 3D‐Linker Metal‐Organic Frameworks

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  50. Restoring Porosity and Uncovering Flexibility in Pillared 3D‐Linker Metal‐Organic Frameworks

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