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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2011

Oxo Boron Clusters and Their Open Frameworks

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Oxo Boron Clusters and Their Open FrameworksOriginalChemInform Abstract: Oxo Boron Clusters and Their Open Frameworks0Boron, aluminium, gallium, indium and thallium7Hydrothermal synthesis of three-dimensional open-framework beryllium phosphites with 3,4-connected networks6Two Unusual Chiral Lanthanide–Sulfate Frameworks with Helical Tubes and Channels Constructed from Interweaving Two Double-Helical Chains26A series of novel gallium and indium borates constructed from [B5O8(OH)2]3− clusters and metal complex linkers17An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19From discrete borate cluster to three-dimensional open framework32Solvothermal synthesis of new open-framework metal phosphites with structure-directing agents generated in situ6Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process38Synthesis, Structure, and Luminescent Property of the Templated Borate [C9H14N]·[B5O6(OH)4]15LiBa1.5[B5O8(OH)3]: A new 1-D metal borate chain constructed from B5O9(OH)36− cluster units7A pillared–layered zincoborate with an anionic network containing unprecedented zinc oxide chains34Incorporating [GaB 4 O 11 (OH)] 8− clusters to construct luminescent galloborate with open-framework layers18New open-framework cobalt sulfate-oxalates based on molecular and chain-like building blocks171-Ethyl-3-methyl-1H-imidazol-3-ium spiropentaborate3Open‐Framework Beryllium Hydrogen Phosphates with (3,4)‐Connected Networks5Sr8MB18O36 (M = Zn or Cd): Design and Synthesis of Two New Borates with a Special Ratio of 8:16A new acentric metal borate Mg[B6O9(OH)2]·4H2O: Synthesis, structure and optical property23A 3D Aluminoborate Open Framework Interpenetrated by 2D Zinc–Amine Coordination‐Polymer Networks in Its 11‐Ring Channels129A 3D Aluminoborate Open Framework Interpenetrated by 2D Zinc–Amine Coordination‐Polymer Networks in Its 11‐Ring Channels19NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units41Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO331An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property94Series of open-framework aluminoborates containing [B 5 O 10 ] clusters24Zn(1,3-DAP)[B 4 O 7 ]: a rare chiral zeolitic framework constructed of four-connected [B 4 O 9 ] clusters with a single-stranded helical channel39Na 2 B 10 O 17 ·H 2 en: a three-dimensional open-framework layered borate co-templated by inorganic cations and organic amines64Open-framework beryllium phosphates with a zeolitic CrB 4 topology and their structural analogues containing 12-ring channels13Organically templated linear metal sulfites2Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr 2 B 5 O 9 (OH)·H 2 O29Two New Borates Containing [B5O6(OH)4] Clusters, Accompanying a Novel In Situ Organic Reaction Between Ethylenediamine and CH3COO− Group8Gold–Oxoborate Nanocomposites and Their Biomedical Applications17Two New Mixed Metal Borates Made of Mg(B6O7(OH)6)2 and B8O14(OH)4 Cluster Units33D supramolecular open-framework constructed by inorganic [B5O6(OH)4]− and organic [CH3COO]− anions2Two Borate Supramolecular Frameworks Based on B4O5(OH)4 Cluster Units2Synthesis and characterization of a disordered variant of KB5O7(OH)22A Series of Aluminoborates Templated or Supported by Zinc–Amine Complexes51A zeolite CAN-type aluminoborate with gigantic 24-ring channels49Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation Response41Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels109Ln2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 (Ln = Y, Sm, Eu, Gd, Dy): A Series of Lanthanide Galloborates Decorated by Acetate Anions26LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures15Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks4Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations1Two deep-ultraviolet nonlinear optical alkaline-earth metal borates based on different types of oxoboron clusters56[Zn(H2O)4][B6O10]: An open-framework borate with acentric structure6Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes44Two Zeolitic Open-Framework Aluminoborates Directed by Similar Zn-Complexes23An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units56Novel borate supramolecular frameworks constructed from isolated B4/B5 clusters and 1-D B17-based chains8Na2(H2en)[B5O8(OH)]2[B3O4(OH)]2 and Na3(HCOO)[B5O8(OH)]: Two Borates Co‐Templated by Inorganic Cations and Organic Compounds20A new mixed alkali metal borate: LiCs[B5O8(OH)]·H2O11A three-dimensional lead borate with a fluorite net constructed from different cluster building units5Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate34Synthesis, structure and characterization of a new nonlinear optical calcium borate [Ca2B5O9]·[H(OH)2]6NH 4 B 11 O 16 (OH) 2 : a new ammonium borate with wavy-shaped polycyclic 2∞[B 11 O 16 (OH) 2 ] layers27Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates42An MOF-like Interpenetrated 2D Plus 2D to 3D Inorganic Grid Assembled by Linear Inorganic Pillars, Structures, and Properties in Supercapacitance13An inorganic-organic hybrid solid with B5O7(OH)3 clusters bridged and decorated by zinc–amine complexes1Why Some Noncentrosymmetric Borates Do Not Make Good Nonlinear Optical Materials: A Case Study with K3B5O8(OH)222Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units8Mg(H 2 O) 6 B 4 O 5 (OH) 4 (H 2 O) 3 : a new hydrated borate with a short DUV cutoff edge9Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block18Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions98BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge38Syntheses, Structures and Characterizations of Two New Polyborates Containing Heptaborate Sub-clusters5[O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains6Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196UV emitting Gd incorporated LiBaB9O15 phosphors: An ESR and photoluminescence investigation2Discovery and Supramolecular Interactions of Neutral Palladium‐Oxo Clusters Pd16and Pd2437Discovery and Supramolecular Interactions of Neutral Palladium‐Oxo Clusters Pd16and Pd2412Three Inorganic–Organic Hybrid Gallo-/Alumino-Borates with Porous-Layered Structures Containing [MB4O10(OH)] (M = Al/Ga) Cluster Units12Borates: A Rich Source for Optical Materials1090Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer11A New Tubular Borate Built By [B14O24(OH)6]12− Cluster Units12K2Na3[{B6O10(OH)}{B3O4(OH)3}] ⋅ H2O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear‐Optical Property20Finding a Series of BaBOF3 Fluorooxoborate Polymorphs with Tunable Symmetries: A Simple but Flexible Case37Identical in Formula but Not Isotypic in Configuration: Discovery of a New Highly Polymerized [B12O24] Cluster in Cs3AlB6O1212Discovery of a Neutral 40-PdII-Oxo Molecular Disk, [Pd40O24(OH)16{(CH3)2AsO2}16]: Synthesis, Structural Characterization, and Catalytic Studies26Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals140Na 3 B 6 O 10 (HCOO): an ultraviolet nonlinear optical sodium borate-formate33Syntheses, structures and optical properties of two B 3 O 7 cluster-based borates9Two layered galloborates from centric to acentric structures: syntheses and NLO properties27Two porous-layered borates built by B 7 O 13 (OH) clusters and AlO 4 /GaO 4 tetrahedra7Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate36Discrete, Cationic Palladium(II)‐Oxo Clusters via f‐Metal Ion Incorporation and their Macrocyclic Host‐Guest Interactions with Sulfonatocalixarenes35Discrete, Cationic Palladium(II)‐Oxo Clusters via f‐Metal Ion Incorporation and their Macrocyclic Host‐Guest Interactions with Sulfonatocalixarenes4Design of New Borates with Deep Ultraviolet Transparency Inspired by the Flexibility of Unusual Triple-Layered Frameworks3Borate particulate photocatalysts for photocatalytic applications: A review127Two Mixed Alkali-Metal Borates Templated from Cations to Clusters10Tailoring Hybrid Aluminoborate Frameworks by Incorporating Multicomponent Cadmium–Amine Complexes with Various Conformations8Rearrangement of [B2O5] Dimers within [B7O14] Clusters Enables Enhanced Optical Anisotropy in Li3Cs6Al2B14O28F4Two New Nonaborates with {B9} Cluster Open-Frameworks and Short Cutoff Edges4NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge9Anchoring polydentate N/O-ligands in metal phosphite/phosphate/phosphonate (MPO) for functional hybrid materials81Cs[B 3 O 3 F 2 (OH) 2 ]: discovery of a hydroxyfluorooxoborate guided by selective organic–inorganic transformation13Discovery of SrZn 2 B 6 O 12 with an unprecedented quadruple-layered configuration0Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation7LiCs 3 AlB 7 O 14 : achieving enhanced optical anisotropy via [AlO 4 ] tetrahedron introduction to rearrange the anionic framework5Three new aluminoborates: from 1D tube to 3D framework9Parametric study of visible light active Bi2ZnB2O7 photocatalyst for dye degradation25Recent progress in ultraviolet and deep-ultraviolet nonlinear optical aluminoborates17HgB2S4: A d10 Metal Thioborate with Giant Birefringence and Wide Band Gap31Two New Aluminoborates with 3D Porous-Layered Frameworks2Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties9Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12From Layered Borate to Porous-Layered Aluminoborate7Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges9Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates4Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers3[H2dab][GaB5O10]: an Acentric Galloborate with a 4-Connected Uninodal Framework6Cu(I)‐Induced ‘Click Reaction’ Involving Coordination and Covalent Assembly of Hybrid Borates for the Electrocatalytic CO 2 Reduction4Cu(I)‐Induced ‘Click Reaction’ Involving Coordination and Covalent Assembly of Hybrid Borates for the Electrocatalytic CO 2 Reduction11Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices1Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8Inorganic Borate Functionalized {Ni6SiW9} Polyoxometalates: From Cluster to Cage Cluster4A new transition metal borate, Co6(B24O39(OH)6(H2O)6·2.21H2O, synthesized via a mild hydrothermal synthesis0[CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy15Extending the Chemistry of Scheelite‐type Oxides with Borates8Extending the Chemistry of Scheelite‐type Oxides with Borates2Li6[{BO3}{B15O21(OH)6}]: An Acentric Layered Borate Constructed from Unprecedented Oxoboron Cluster Building Units6Four zinc borates: From acentric chain to centric porous layer0Amidine-Linked Closo-Dodecaborate–Silica Hybrids: Synthesis and Characterization0Two {B 6 }-Based Borates: From 1D Chain to 3D Framework1Novel multifunctionalized transition metal borate materials in photo-electro catalysis, sensing and biobased applications1F−/OH− terminal modification of [B3O6] clusters: Constructing deep-ultraviolet hydroxyfluorooxoborates with tunable optical performance0Two Acentric Borates with 2-/3-D Frameworks: Syntheses, Structures, and Nonlinear Optical Properties0Two transition metal borates built from unprecedented {B11} clusters with nonlinear optical properties0

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  1. ChemInform Abstract: Oxo Boron Clusters and Their Open Frameworks

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  2. Boron, aluminium, gallium, indium and thallium

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  3. Hydrothermal synthesis of three-dimensional open-framework beryllium phosphites with 3,4-connected networks

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  4. Two Unusual Chiral Lanthanide–Sulfate Frameworks with Helical Tubes and Channels Constructed from Interweaving Two Double-Helical Chains

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  5. A series of novel gallium and indium borates constructed from [B5O8(OH)2]3− clusters and metal complex linkers

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  6. An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }

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  7. From discrete borate cluster to three-dimensional open framework

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  8. Solvothermal synthesis of new open-framework metal phosphites with structure-directing agents generated in situ

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  9. Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process

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  10. Synthesis, Structure, and Luminescent Property of the Templated Borate [C9H14N]·[B5O6(OH)4]

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  11. LiBa1.5[B5O8(OH)3]: A new 1-D metal borate chain constructed from B5O9(OH)36− cluster units

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  17. Sr8MB18O36 (M = Zn or Cd): Design and Synthesis of Two New Borates with a Special Ratio of 8:1

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  18. A new acentric metal borate Mg[B6O9(OH)2]·4H2O: Synthesis, structure and optical property

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  19. A 3D Aluminoborate Open Framework Interpenetrated by 2D Zinc–Amine Coordination‐Polymer Networks in Its 11‐Ring Channels

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  21. NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

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  22. Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3

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  24. Series of open-framework aluminoborates containing [B 5 O 10 ] clusters

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  25. Zn(1,3-DAP)[B 4 O 7 ]: a rare chiral zeolitic framework constructed of four-connected [B 4 O 9 ] clusters with a single-stranded helical channel

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  26. Na 2 B 10 O 17 ·H 2 en: a three-dimensional open-framework layered borate co-templated by inorganic cations and organic amines

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  28. Organically templated linear metal sulfites

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  29. Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr 2 B 5 O 9 (OH)·H 2 O

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  31. Gold–Oxoborate Nanocomposites and Their Biomedical Applications

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  32. Two New Mixed Metal Borates Made of Mg(B6O7(OH)6)2 and B8O14(OH)4 Cluster Units

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  33. 3D supramolecular open-framework constructed by inorganic [B5O6(OH)4]− and organic [CH3COO]− anions

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  35. Synthesis and characterization of a disordered variant of KB5O7(OH)2

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  36. A Series of Aluminoborates Templated or Supported by Zinc–Amine Complexes

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  37. A zeolite CAN-type aluminoborate with gigantic 24-ring channels

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  38. Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation Response

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  39. Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels

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  40. Ln2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 (Ln = Y, Sm, Eu, Gd, Dy): A Series of Lanthanide Galloborates Decorated by Acetate Anions

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  41. LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures

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  42. Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks

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  43. Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations

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  44. Two deep-ultraviolet nonlinear optical alkaline-earth metal borates based on different types of oxoboron clusters

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  45. [Zn(H2O)4][B6O10]: An open-framework borate with acentric structure

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  46. Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes

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  47. Two Zeolitic Open-Framework Aluminoborates Directed by Similar Zn-Complexes

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  48. An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

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