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RESEARCH PAPER · Crystal Growth & Design · 2009

[B4O9H2] Cyclic Borate Units as the Building Unit in a Family of Zinc Borate Structures

Avijit Kumar Paul, K. Sachidananda, Srinivasan Natarajan

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[B4O9H2] Cyclic Borate Units as the Building Unit in a Family of Zinc Borate StructuresOriginalStructural (XRD) and thermal (DSC, TGA) and BET analysis of materials derived from non-metal cation pentaborate salts47(en)Mn2(V2O7): A 3D manganese vanadate built by Mn–O layers and two types of pillars of V2O7 and en bridges7Syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines9Use of Polyazaheterocycles in the Assembly of New Cadmium Sulfate Frameworks: Synthesis, Structure, and Properties38A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104Open-framework aluminoborates co-templated by two types of primary amines45Lanthanide Sulfate Frameworks: Synthesis, Structure, and Optical Properties31Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties84K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge670Oxo Boron Clusters and Their Open Frameworks128A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks72Synthesis, Structure, Photochemical [2 + 2] Cycloaddition, Transformation, and Photocatalytic Studies in a Family of Inorganic–Organic Hybrid Cadmium Thiosulfate Compounds59Synthesis and structure of QD-6: A novel aluminoborate constructed from unprecedented [B@Al 6 O 24 ] and polyborate clusters12Synthesis and characterization of a new organic–inorganic hybrid zinc borate: [Zn(dab)0.5(dab′)0.5(B4O6(OH)2)]·H2O33An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process38A pillared–layered zincoborate with an anionic network containing unprecedented zinc oxide chains34Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response361Series of open-framework aluminoborates containing [B 5 O 10 ] clusters24Zn(1,3-DAP)[B 4 O 7 ]: a rare chiral zeolitic framework constructed of four-connected [B 4 O 9 ] clusters with a single-stranded helical channel39Cotemplating Synthesis of a Rare Borate Ni(en)3·Hen·[B9O13(OH)4]·H2O with a Chiral Polyanonic Chain Constructed from Two Different Clusters22Two Zincoborates Built by Metal–Nonmetal {Zn2B} Hybrid Clusters2Hydrogen-bonded assemblies of two organically templated borates: syntheses and crystal structures of [(1,10-phen)(H3BO3)2] and [2-EtpyH][(B5O6(OH)4]2New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7Octahedron-based gallium borates (Ga-PKU-1) with an open framework: acidity, catalytic dehydration and structure–activity relationship18Two novel pillared-layer lanthanide borates built by Ln@B 12 O 28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)26Recent advances in crystalline hydrated borates with non-metal or transition-metal complex cations111Interpenetrated and Catenated Zinc Thiosulfates Frameworks with dia and qtz Nets: Synthesis, Structure, and Properties10Tuning of coordination behavior of thiosulfate ion by organic linkers in cadmium thiosulfate compounds15[Zn(dap)3][Zn(dap)B5O8(OH)2]2: A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B5O8(OH)2]3− Clusters and [Zn(dap)]2+ Linkers7Novel amine templated three-dimensional zinc-organophosphonates with variable pore-openings21Synthesis, structural characterization and scalable preparation of new amino-zinc borates5Hydrothermal Synthesis and Structural Characterization of a New Hybrid Zinc Borate, [Zn(dap)2][B4O6(OH)2]8Na4Ca[B4O5(OH)4]3·14H2O: An Acentric Supramolecular Framework Borate Based on [B4O5(OH)4]2− Cluster Units8Synthesis, structure and characterization of two borates templated by in situ prepared organics7Synthesis and characterization of polyborates templated by cationic copper(II) complexes: Structural (XRD), spectroscopic, thermal (TGA/DSC) and magnetic properties15Rare Examples of Amine-Templated Organophosphonate Open-Framework Compounds: Combined Role of Metal and Amine for Structure Building21Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion9Photoluminescent carbon dots based on a rare 3D inorganic–organic hybrid cadmium borate crystal10Synthesis, structure and topological analysis of glycine templated highly stable cadmium sulfate framework: A New Lewis Acid catalyst10Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates42Synthesis and crystal structure of a new polymorph of potassium europium(III) bis(sulfate) monohydrate, KEu(SO4)2·H2O2An inorganic-organic hybrid solid with B5O7(OH)3 clusters bridged and decorated by zinc–amine complexes1First Example of a Nonanuclear Silver Sulfate Hybrid Cluster: Green Approach for Synthesis of Lewis Acid Catalyst21Two 1-D Coordination Polymers Containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}]·2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}]·1.5H2O (pn = 1,2-diaminopropane)13Synthesis, Characterization, and Crystal Structure Analysis of New Mixed Metal Sulfate NaPr(SO4)2(H2O)8Hexaborate(2−) and Dodecaborate(6−) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{κ3O-B6O7(OH)6}(κ3N-dien)]·0.5H2O (dien = NH(CH2–CH2NH2)2), (NH4)2[Zn{κ2O-B6O7(OH)6}2 (H2O)2]·2H2O and (1,3-pnH2)3[(κ1N-H3N{CH2}3NH2) Zn{κ3O-B12O18(OH)6}]2·14H2O (1,3-pn = 1,3-diaminopropane)11Two novel 3D borates: porous-layer and layer-pillar frameworks19Role of aromatic vs. aliphatic amine for the variation of structural, electrical and catalytic behaviors in a series of silver phosphonate extended hybrid solids24BO3 Triangle and B@Zn2O3 Cationic Layer in the Structure of the Hybrid Zinc Acetate Borate [ZnAc]·[ZnBO3]9Recent Advances in Crystalline Oxidopolyborate Complexes of d-Block or p-Block Metals: Structural Aspects, Syntheses, and Physical Properties16Oxidoborates Templated by Cationic Nickel(II) Complexes and Self-Assembled from B(OH)33Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals140Enhanced Interlayer Interaction and Second-Harmonic-Generation Response in a KBe 2 BO 3 F 2 -Type Inorganic–Organic Hybrid Zinc Borate33Structural Characterization and ORR Activity of a Copper Complex Borate and an Unexpected [Ni(atta)(SO4)0.5]+ Borate-Sulfate7Vanadate Encapsulated Polyoxoborate Framework with [V12B18] Clusters: An Efficient Bifunctional Electrocatalyst for Oxygen and Hydrogen Evolution Reactions28A thermostable pillared layered metal-borate- organic network featuring neighboring boron sites for oxidative dehydrogenation of propane16[CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy15

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  1. Structural (XRD) and thermal (DSC, TGA) and BET analysis of materials derived from non-metal cation pentaborate salts

    Dalton Transactions · 2010-01-01

    Michael A. Beckett, Peter Neil Horton, Michael B. Hursthouse, David A. Knox, James L. Timmis

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  2. (en)Mn2(V2O7): A 3D manganese vanadate built by Mn–O layers and two types of pillars of V2O7 and en bridges

    Inorganic Chemistry Communications · 2010-04-14

    Gao-Juan Cao, Shou‐Tian Zheng, Wei‐Hui Fang, Guo‐Yu Yang

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  3. Syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines

    Inorganica Chimica Acta · 2010-06-17

    Yun Mo Yang, Shilie Pan, Xueling Hou, Jing Guo, Feng Li, Jian Wei Han, Jixi Guo, Dianzeng Jia

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  4. Use of Polyazaheterocycles in the Assembly of New Cadmium Sulfate Frameworks: Synthesis, Structure, and Properties

    Crystal Growth & Design · 2010-08-04

    Avijit Kumar Paul, Udishnu Sanyal, Srinivasan Natarajan

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  5. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10

    Journal of Materials Chemistry · 2011-01-01

    Yun Mo Yang, Shilie Pan, Xueling Hou, Chuanyi Wang, Kenneth Reinhard Poeppelmeier, Zhaohui Chen, Hongping Wu, Zhongxiang Zhou

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  6. Open-framework aluminoborates co-templated by two types of primary amines

    Dalton Transactions · 2011-01-01

    Gao-Juan Cao, Jian Lin, Wei‐Hui Fang, Shou‐Tian Zheng, Guo‐Yu Yang

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  7. Lanthanide Sulfate Frameworks: Synthesis, Structure, and Optical Properties

    Crystal Growth & Design · 2011-02-16

    Bunlawee Yotnoi, Apinpus Rujiwatra, M. L. P. Reddy, Debajit Sarma, Srinivasan Natarajan

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  8. Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties

    Inorganic Chemistry · 2011-02-21

    Yun Mo Yang, Shilie Pan, Hongyi Li, Jian Wei Han, Zhaohui Chen, Wenwu Zhao, Zhongxiang Zhou

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  9. K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

    Journal of the American Chemical Society · 2011-05-02

    Hongping Wu, Shilie Pan, Kenneth Reinhard Poeppelmeier, Hongyi Li, Dianzeng Jia, Zhaohui Chen, Xiaoyun Fan, Yun Mo Yang, James M. Rondinelli, Haosu Luo

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  10. Oxo Boron Clusters and Their Open Frameworks

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  11. A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks

    Crystal Growth & Design · 2011-07-15

    Yun Mo Yang, Shilie Pan, Jian Wei Han, Xueling Hou, Zhongxiang Zhou, Wenwu Zhao, Zhaohui Chen, Min Zhang

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  12. Synthesis, Structure, Photochemical [2 + 2] Cycloaddition, Transformation, and Photocatalytic Studies in a Family of Inorganic–Organic Hybrid Cadmium Thiosulfate Compounds

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    Avijit Kumar Paul, Rajendran Karthik, Srinivasan Natarajan

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  13. Synthesis and structure of QD-6: A novel aluminoborate constructed from unprecedented [B@Al 6 O 24 ] and polyborate clusters

    Dalton Transactions · 2011-12-01

    Guo‐Ming Wang, Jinhua Li, Pei Wang, Zengxin Li, Yingxia Wang, Zhe‐Ming Wang, Jianhua Lin

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  14. Synthesis and characterization of a new organic–inorganic hybrid zinc borate: [Zn(dab)0.5(dab′)0.5(B4O6(OH)2)]·H2O

    Inorganic Chemistry Communications · 2012-03-09

    Pei Zhao, Lin Cheng, Guo‐Yu Yang

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  15. An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }

    Dalton Transactions · 2012-11-15

    Han‐Rui Tian, Wenhua Wang, Xiaoping Zhang, Yun‐Long Feng, Jian‐Wen Cheng

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  16. Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process

    Inorganic Chemistry · 2013-05-10

    Han‐Rui Tian, Wenhua Wang, Yan‐E Gao, Tingting Deng, Jiaying Wang, Yun‐Long Feng, Jian‐Wen Cheng

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  17. A pillared–layered zincoborate with an anionic network containing unprecedented zinc oxide chains

    Chemical Communications · 2014-01-01

    Pei Zhao, Zhien Lin, Wei Qi, Lin Cheng, Guo‐Yu Yang

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  18. Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response

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    Hongwei Yu, Hongping Wu, Shilie Pan, Zhihua Yang, Xueling Hou, Xin Su, Qun Jing, Kenneth Reinhard Poeppelmeier, James M. Rondinelli

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  19. Series of open-framework aluminoborates containing [B 5 O 10 ] clusters

    Dalton Transactions · 2014-11-10

    Li Wei, Guo‐Ming Wang, Huan He, Bai‐Feng Yang, Guo‐Yu Yang

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  20. Zn(1,3-DAP)[B 4 O 7 ]: a rare chiral zeolitic framework constructed of four-connected [B 4 O 9 ] clusters with a single-stranded helical channel

    Chemical Communications · 2014-11-19

    Chun‐Yang Pan, Lijuan Zhong, Fenghua Zhao, Hong-Mei Yang, Jian Zhou

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  21. Cotemplating Synthesis of a Rare Borate Ni(en)3·Hen·[B9O13(OH)4]·H2O with a Chiral Polyanonic Chain Constructed from Two Different Clusters

    Inorganic Chemistry · 2014-12-23

    Chun‐Yang Pan, Lijuan Zhong, Fenghua Zhao, Yuan‐Zhang Luo, Daguang Li

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  22. Two Zincoborates Built by Metal–Nonmetal {Zn2B} Hybrid Clusters

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  23. Hydrogen-bonded assemblies of two organically templated borates: syntheses and crystal structures of [(1,10-phen)(H3BO3)2] and [2-EtpyH][(B5O6(OH)4]

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  24. New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method

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  25. Octahedron-based gallium borates (Ga-PKU-1) with an open framework: acidity, catalytic dehydration and structure–activity relationship

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  26. Two novel pillared-layer lanthanide borates built by Ln@B 12 O 28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

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  27. Recent advances in crystalline hydrated borates with non-metal or transition-metal complex cations

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  28. Interpenetrated and Catenated Zinc Thiosulfates Frameworks with dia and qtz Nets: Synthesis, Structure, and Properties

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  29. Tuning of coordination behavior of thiosulfate ion by organic linkers in cadmium thiosulfate compounds

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  30. [Zn(dap)3][Zn(dap)B5O8(OH)2]2: A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B5O8(OH)2]3− Clusters and [Zn(dap)]2+ Linkers

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  31. Novel amine templated three-dimensional zinc-organophosphonates with variable pore-openings

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  32. Synthesis, structural characterization and scalable preparation of new amino-zinc borates

    Dalton Transactions · 2017-01-01

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  33. Hydrothermal Synthesis and Structural Characterization of a New Hybrid Zinc Borate, [Zn(dap)2][B4O6(OH)2]

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  34. Na4Ca[B4O5(OH)4]3·14H2O: An Acentric Supramolecular Framework Borate Based on [B4O5(OH)4]2− Cluster Units

    Journal of Cluster Science · 2017-04-20

    Chong‐An Chen, Qi Wei, Bai‐Feng Yang, Guo‐Yu Yang

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  35. Synthesis, structure and characterization of two borates templated by in situ prepared organics

    Inorganica Chimica Acta · 2017-05-09

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  36. Synthesis and characterization of polyborates templated by cationic copper(II) complexes: Structural (XRD), spectroscopic, thermal (TGA/DSC) and magnetic properties

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  37. Rare Examples of Amine-Templated Organophosphonate Open-Framework Compounds: Combined Role of Metal and Amine for Structure Building

    Crystal Growth & Design · 2017-10-02

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  38. Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion

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  39. Photoluminescent carbon dots based on a rare 3D inorganic–organic hybrid cadmium borate crystal

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  40. Synthesis, structure and topological analysis of glycine templated highly stable cadmium sulfate framework: A New Lewis Acid catalyst

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  41. Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates

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  42. Synthesis and crystal structure of a new polymorph of potassium europium(III) bis(sulfate) monohydrate, KEu(SO4)2·H2O

    Acta Crystallographica Section E Crystallographic Communications · 2018-01-26

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  43. An inorganic-organic hybrid solid with B5O7(OH)3 clusters bridged and decorated by zinc–amine complexes

    Inorganic Chemistry Communications · 2018-08-11

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  44. First Example of a Nonanuclear Silver Sulfate Hybrid Cluster: Green Approach for Synthesis of Lewis Acid Catalyst

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  45. Two 1-D Coordination Polymers Containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}]·2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}]·1.5H2O (pn = 1,2-diaminopropane)

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  46. Synthesis, Characterization, and Crystal Structure Analysis of New Mixed Metal Sulfate NaPr(SO4)2(H2O)

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  47. Hexaborate(2−) and Dodecaborate(6−) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{κ3O-B6O7(OH)6}(κ3N-dien)]·0.5H2O (dien = NH(CH2–CH2NH2)2), (NH4)2[Zn{κ2O-B6O7(OH)6}2 (H2O)2]·2H2O and (1,3-pnH2)3[(κ1N-H3N{CH2}3NH2) Zn{κ3O-B12O18(OH)6}]2·14H2O (1,3-pn = 1,3-diaminopropane)

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  48. Two novel 3D borates: porous-layer and layer-pillar frameworks

    Dalton Transactions · 2019-10-28

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  49. Role of aromatic vs. aliphatic amine for the variation of structural, electrical and catalytic behaviors in a series of silver phosphonate extended hybrid solids

    Dalton Transactions · 2020-01-01

    Tanmay Rom, Avijit Kumar Paul

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  50. BO3 Triangle and B@Zn2O3 Cationic Layer in the Structure of the Hybrid Zinc Acetate Borate [ZnAc]·[ZnBO3]

    Inorganic Chemistry · 2021-01-08

    Wei Li, Jun-Xia Deng, Chun‐Yang Pan

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